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This study examines kinetic enhancement by nanosecond dielectric barrier discharge (ns-DBD) plasma on fuel-lean, Φ = 0.7, dimethyl ether (DME), oxygen (O 2), and argon (Ar) premixture during deflagration to detonation transition (DDT) experiments in a microchannel. Nonequilibrium plasma produces active species and radicals as well as fast and slow heating of a mixture to promote ignition due to energetic electrons, ions, and electronic and vibrational excitations. Experiments are conducted to examine the influence of the plasma discharge on the premixture and on the resultant deflagration to detonation transition (DDT) onset time and distance through the use of high-speed imaging and one-dimensional, two-beam, femtosecond/picosecond, coherent anti-Stokes Raman scattering (CARS). A high-speed camera is used to trace the time histories of flame front position and velocity and to identify the dynamics and onset of DDT. The results show that plasma discharge can nonlinearly affect the onset time and distance of DDT. It is shown that a small number of plasma discharge pulses prior to ignition result in reduced DDT onset time and distance by 60% and 40%, respectively, when compared to the results without pre-excitation by ns discharges. The results also show that an increase of number of the plasma discharge pulses results in an extended DDT onset time and distance of 224% and 94%, respectively. Time history of the deflagration wave speed of DME and the analysis of ignition timescale under the choking condition of the burned gas of the deflagration wave suggest low temperature ignition may play a role for DME near the isobaric choking condition of the burned gas and the DDT. Plasma-induced low temperature oxidation of the reactive mixture is assessed via the CO 2 to O 2 ratio as measured through fs/ps CARS during the gas excitation in discharges. CARS measurements also confirm negligible vibrational and rotational heating of the gas by discharge. The present experiments demonstrate the ability of nonequilibrium plasma to alter the chemistry of DME/O 2 /Ar premixtures in order to control DDT for applications in advanced propulsion engines. [ABSTRACT FROM AUTHOR]

This paper is part of a broader program aimed at investigating the effects of co-firing clean fuels such as ammonia or hydrogen with hydrocarbons. The focus is on soot formation as well as flame stability in turbulent mixed-mode combustion, which is highly relevant in practical combustors. Ammonia substitution for nitrogen results in reduced flame stability, and this is correlated to differences in flame speed and extinction strain rate. While it is known that the addition of ammonia suppresses soot, visual inspection of compositionally inhomogeneous flames of ethylene-ammonia indicates a reduction in ammonia's ability to suppress soot formation. Measurements of soot volume fraction and laser-induced fluorescence in selected UV and visible bands are made along the centreline in selected flames to test this hypothesis. Experimental results are then compared to simulations in laminar diffusion flames, stratified counterflow flames, and partially premixed flames. All results confirm the soot-inhibiting ability of ammonia. Increasing inhomogeneity, leading to higher centreline mixture fractions, enhances soot formation, and the level of enhancement is greater for flames with ammonia than without. Moreover, it is found that partial premixing is ultimately responsible for determining the amount of soot formed as opposed to stratification of fuel mixtures near the pilot. [ABSTRACT FROM AUTHOR]

Optical centrifuges are laser-based molecular traps that can rotationally accelerate molecules to energies rivalling or exceeding molecular bond energies. Here we report time and frequency-resolved ultrafast coherent Raman measurements of optically centrifuged CO2 at 380 Torr spun to energies beyond its bond dissociation energy of 5.5 eV (Jmax = 364, Erot = 6.14 eV, Erot/kB = 71, 200 K). The entire rotational ladder from J = 24 to J = 364 was resolved simultaneously which enabled a more accurate measurement of the centrifugal distortion constants for CO2. Remarkably, coherence transfer was directly observed, and time-resolved, during the field-free relaxation of the trap as rotational energy flowed into bending-mode vibrational excitation. Vibrationally excited CO2 (ν2 > 3) was observed in the time-resolved spectra to populate after 3 mean collision times as a result of rotational-to-vibrational (R-V) energy transfer. Trajectory simulations show an optimal range of J for R-V energy transfer. Dephasing rates for molecules rotating up to 5.5 times during one collision were quantified. Very slow decays of the vibrational hot band rotational coherences suggest that they are sustained by coherence transfer and line mixing. In this work the authors use coherent anti-Stokes Raman scattering to study collisional vibrational excitation in highly rotationally excited CO2 molecules prepared in an optical centrifuge. [ABSTRACT FROM AUTHOR]

The impact on the use of carbon dioxide (CO2) as a diluent in the fuel and oxidizer streams on the formation and evolution of precursor nanoparticles and soot in axisymmetric ethylene laminar coflow diffusion flames is experimentally explored using optical diagnostics in this paper. The optical diagnostics employed are based on temporally and spectrally resolved point measurements of laser-induced fluorescence, elastic scattering, and laser-induced incandescence. The measurements provide insight to indicative structure and concentration of precursor nanoparticles, and enable the determination of volume fraction and mean diameter of soot. Previous studies have indicated that the use of CO2 as a diluent compared to nitrogen can reduce soot formation through both chemical and thermal effects. However, the effect of CO2 addition on precursor nanoparticles' concentrations and structure is not well understood, hence exploring the impact of CO2 on precursor nanoparticles is one of the primary aims of this study. Flames with CO2 as a diluent in the jet only, coflow only, and both streams are identified and investigated. For the flames studied with respect to the replacement of N2 with CO2: i), the soot volume fraction and mean soot diameter is reduced, and ii) precursor nanoparticles concentration is reduced, and the structural transformation is delayed. [ABSTRACT FROM AUTHOR]

Optical centrifuges are laser-based molecular traps that can rotationally accelerate molecules to energies rivalling or exceeding molecular bond energies. Here we report time and frequency-resolved ultrafast coherent Raman measurements of optically centrifuged CO 2 at 380 Torr spun to energies beyond its bond dissociation energy of 5.5 eV (J max  = 364, E rot  = 6.14 eV, E rot /k B  = 71, 200 K). The entire rotational ladder from J = 24 to J = 364 was resolved simultaneously which enabled a more accurate measurement of the centrifugal distortion constants for CO 2 . Remarkably, coherence transfer was directly observed, and time-resolved, during the field-free relaxation of the trap as rotational energy flowed into bending-mode vibrational excitation. Vibrationally excited CO 2 (ν 2  > 3) was observed in the time-resolved spectra to populate after 3 mean collision times as a result of rotational-to-vibrational (R-V) energy transfer. Trajectory simulations show an optimal range of J for R-V energy transfer. Dephasing rates for molecules rotating up to 5.5 times during one collision were quantified. Very slow decays of the vibrational hot band rotational coherences suggest that they are sustained by coherence transfer and line mixing., (© 2023. The Author(s).)