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Energy density in nonaqueous redox flow batteries (RFBs) is often limited by the modest solubility of the redox-active organic molecules (ROMs). In addition, the lack of a separator that prevents ROMs from crossing between anolyte and catholyte solutions necessitates the use of 1:1 mixtures of two ROMs in both the anolyte and catholyte solutions in symmetric RFBs, further limiting concentrations. We show that permanently cationic oligomers of viologen, tris(dialkylamino)cyclopropenium, and phenothiazine molecules have high solubility in acetonitrile and cross over an anion exchange membrane at slow to undetectable rates, enabling the creation of asymmetric RFBs with low crossover. No added supporting electrolyte is necessary, with only the PF

Cyanopyridines and cyanophenylpyridines were investigated as anolytes for nonaqueous redox flow batteries (RFBs). The three isomers of cyanopyridine are reduced at potentials of -2.2 V or lower vs. ferrocene

This report describes the development of a photochemical method for C(sp

We describe the nonaqueous redox-matched flow battery (RMFB), where charge is stored on redox-active moieties covalently tethered to non-circulating, insoluble polymer beads and charge is transferred between the electrodes and the beads via soluble mediators with redox potentials matched to the active moieties on the beads. The RMFB reported herein uses ferrocene and viologen derivatives bound to crosslinked polystyrene beads. Charge storage in the beads leads to a high (approximately 1.0-1.7 M) effective concentration of active material in the reservoirs while preventing crossover of that material. The relatively low concentration of soluble mediators (15 mM) eliminates the need for high-solubility molecules to create high energy density batteries. Nernstian redox exchange between the beads and redox-matched mediators was fast relative to the cycle time of the RMFB. This approach is generalizable to many different redox-active moieties via attachment to the versatile Merrifield resin.