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© 2020 Elsevier Ltd The increase in human consumption of plant and animal oils has led to the rise in waste cooking oil (WCO) production. Instead of disposing the used cooking oil as waste, recent technological advance has enabled the use of WCO as a sustainable feedstock for biofuels production, thereby maximising the value of biowastes via energy recovery while concomitantly solving the disposal issue. The current regulatory frameworks for WCO collection and recycling practices imposed by major WCO producing countries are reviewed, followed by the overview of the progress in biodiesel conversion techniques, along with novel methods to improve the feasibility for upscaling. The factors which influence the efficiency of the reactions such as properties of feedstock, heterogenous catalytic processes, cost effectiveness and selectivity of reaction product are discussed. Ultrasonic-assisted transesterification is found to be the least energy intensive method for producing biodiesel. The production of bio-jet fuels from WCO, while scarce, provide diversity in waste utilisation if problems such as carbon chain length, requirements of bio-jet fuel properties, extreme reaction conditions and effectiveness of selected catalyst-support system can be solved. Technoeconomic studies revealed that WCO biofuels is financially viable with benefit of mitigating carbon emissions, provided that the price gap between the produced fuel and commercial fuels, sufficient supply of WCO and variation in the oil properties are addressed. This review shows that WCO is a biowaste with high potential for advanced transportation fuel production for ground and aviation industries. The advancement in fuel production technology and relevant policies would accelerate the application of sustainable WCO biofuels.

Sustainable Aviation Fuel (SAF) has become an important measure in the aviation industry’s efforts to mitigate carbon emissions and reduce their overall environmental impacts. However, commercial usage is relatively stunted due to a plethora of drawbacks in the production process and economic feasibility of the fuel. In this study, the currently accepted technologies for producing synthetic jet fuels under the American Society for Testing Material (ASTM D7566) standard specification for aviation turbine fuel are reviewed. The emphasis is placed in terms of their reactions, type of catalysts used for the conversion pathways of Fisher-Tropsch (FT), Hydroprocessed Esters and Fatty Acids (HEFA) and Alcohol-to-Jet (ATJ), and the use of biomass resources as feedstock. The advancement in the production process and physicochemical properties of the uncertified biojet fuels are reviewed and discussed. Generally, Co- and Fe-based catalysts are commonly used for the FT process, while bimetallic catalysts consisting of Pt, Pd, Ni and Mo have shown excellent activities and selectivities for the HEFA process. For the ATJ process, zeolites such as HZSM-5, beta and SAPO have shown remarkable ethanol dehydration efficiency, while TiO2 and ferrierite have been studied for the combined iso-butanol dehydration and oligomerisation processes. Fundamental factors influencing the reaction efficiency including the feedstock properties, reaction conditions, catalytic reusability and catalyst supports are discussed. Finally, the key challenges and prospects for biojet fuel commercialisation are addressed.

To support the ongoing energy transition and minimize the environmental footprint of combustion related technologies, the paper presents a novel approach for combustion control in gas turbines and burners. It relies on spatially targeted injection of inert components in the spray core where existent concepts fail to deliver the desired dilution rate and are unable to fully govern the spatial distribution of heat release rates. Combustion process control is thus possible by actively adjusting the composition and mass flow of spatially selective introduction of inert species in the spray, optionally combined with classic, external exhaust gas recirculation, leading to an ultimate fuel-flexible concept which is capable of adjustments to heterogeneous fuels, their reactivity and physical properties. The proof of concept is demonstrated in a gas turbine combustion chamber first by investigating the isolated effects of spatially selective injection of inert species, its comparison to external exhaust gas recirculation and a combination of both. The results confirm the superiority of the approach as spatially selective mixture inertization is capable of 7% reduction of NO emissions with merely 3% increase of CO emissions and even 9% reduction of PM emissions. Furthermore, the concept proved transferrable together with all its benefits to combustion cycles with external exhaust gas recirculation. In this case, the 63% reduction of NO emissions with no observed CO penalty is possible. Simultaneous exploitation of spatially selective inertization, as well as external exhaust gas recirculation forms a fully controllable concept - spatially selective dilution control (SSDC), which enables extensive adjustability of dilution rates throughout the spray core and primary zone of combustion chamber. Compared to baseline case, such approach was proved to simultaneously reduce CO, NO and PM emissions normalized to fuel thermal power for 39%, 63% and 91%, respectively. The confirmation of applicability of the novel approach and its potential to influence the local conditions is opening a series of possible uses, either as an original design feature for future fuel-flexible systems or as a retrofit approach in existent combustion systems.