1. High Thermopower of Agarose‐Based Ionic Thermoelectric Gel Through Micellization Effect Decoupling the Cation/Anion Thermodiffusion.
- Author
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Li, Qikai, Yu, Dangkai, Wang, Shuaihua, Zhang, Xinbo, Li, Yuchen, Feng, Shien‐Ping, and Liu, Weishu
- Subjects
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THERMOPHORESIS , *ANIONS , *CATIONS , *AGAROSE , *HYDROUS , *THERMOELECTRIC power - Abstract
Ionic thermoelectric (i‐TE) gels can have a high thermopower, if the thermodiffusion of mobile cation/anion is decoupled, attracting increasing attentions. Herein, it is shown a high p‐type i‐TE thermopower of 41.8 mV K−1 in agarose‐based ionic thermoelectric gels of AG‐x Na:DBS (AG: agarose, Na:DBS: sodium dodecyl benzene sulfonate). The exclusively high thermopower is relative to the successfully decoupling the thermodiffusion of cation Na+ and anion DBS−. A unique porous structure is formed due to the micellization of the amphiphilic DBS− with the hydrophilic benzenesulfonic group attached to the hydrous agarose gel chains, while the hydrophobic alkyl chain point to the pore centers. As a result, the DBS− micelles are almost immobile as compared with Na+, which can be reconsidered as a part of the gel matrix. The work shines a light on decoupling of cation/anion thermodiffusion through tailoring the microstructure of the quasi‐solid i‐TE materials. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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