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High-precision potassium (K) isotope measurements in marine carbonates allow using this novel geochemical proxy to constrain seawater chemistry through geologic time. However, these measurements are still scarce due to the challenges of low-K contents in carbonates during K ion chromatography, such as insufficient sample purification, non-quantitative yield, and high accumulative blank. Here we optimize a dual-column K purification method that addresses these challenges, achieving a satisfactory K separation using 100–150 mg carbonates for routine high-precision K isotope analysis on the Sapphire™ MC-ICP-MS. We then report K isotope compositions in multiple certified reference materials, including limestone, dolostone, coral, and basalt for future inter-laboratory comparisons. The optimized K purification method provides great potential for future K isotope studies of marine carbonates. [ABSTRACT FROM AUTHOR]

The snowball Earth hypothesis predicts that continental chemical weathering diminished substantially during, but rebounded strongly after, the Marinoan ice age some 635 Mya. Defrosting the planet would result in a plume of fresh glacial meltwater with a different chemical composition from underlying hypersaline seawater, generating both vertical and lateral salinity gradients. Here, we test the plumeworld hypothesis using lithium isotope compositions in the Ediacaran Doushantuo cap dolostone that accumulated in the aftermath of the Marinoan snowball Earth along a proximal-distal (nearshore-offshore) transect in South China. Our data show an overall decreasing δ 7 Li trend with distance from the shoreline, consistent with the variable mixing of a meltwater plume with high δ 7 Li (due to incongruent silicate weathering on the continent) and hypersaline seawater with low δ 7 Li (due to synglacial distillation). The evolution of low δ 7 Li of synglacial seawater, as opposed to the modern oceans with high δ 7 Li, was likely driven by weak continental chemical weathering coupled with strong reverse weathering on the seafloor underneath silica-rich oceans. The spatial pattern of δ 7 Li is also consistent with the development and then collapse of the meltwater plume that occurred at the time scale of cap dolostone accumulation. Therefore, the δ 7 Li data are consistent with the plumeworld hypothesis, considerably reduced chemical weathering on the continent during the Marinoan snowball Earth, and enhanced reverse weathering on the seafloor of Precambrian oceans., Competing Interests: Competing interests statement:The authors declare no competing interest.