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Semantic segmentation of Polarimetric SAR (PolSAR) images is an important research topic in remote sensing. Many deep neural network-based semantic segmentation methods have been applied to PolSAR image segmentation tasks. However, a lack of effective means to deal with the similarity of object features and speckle noise in PolSAR images exists. Thisstudy aims to improve the discriminative capability of neural networks for various intensities of backscattering coefficients while reducing the effects of noise in PolSAR semantic segmentation tasks. Firstly, we propose pre-processing methods for PolSAR image data, which consist of the fusion of multi-source data and false color mapping. Then, we propose a Multi-axis Sequence Attention Segmentation Network (MASA-SegNet) for semantic segmentation of PolSAR data, which is an encoder–decoder framework. Specifically, within the encoder, a feature extractor is designed and implemented by stacking Multi-axis Sequence Attention blocks to efficiently extract PolSAR features at multiple scales while mitigating inter-class similarities and intra-class differences from speckle noise. Moreover, the process of serialized residual connection design enables the propagation of spatial information throughout the network, thereby improving the overall spatial awareness of MASA-SegNet. Within the decoder, it is used to accomplish the semantic segmentation task. The superiority of this algorithm for semantic segmentation will be explored through feature visualization. The experiments show that our proposed spatial sequence attention mechanism can effectively extract features and reduce noise interference and is thus able to obtain the best results on two large-scale public datasets (the AIR-POlSAR-Seg and FUSAR-Map datasets). [ABSTRACT FROM AUTHOR]

The partial replacement of chemical fertilizer with straw return is considered an effective method for improving the accumulation of organic matter and soil fertility, but the characteristics of soil nitrogen fixation and mineralization in a double-cropped rice paddy system are unclear. Based on a 12-year field experiment, we conducted a waterlogged incubation experiment for 49 days to determine the effect of long-term straw return combined with reducing chemical fertilizer application on the dynamic changes of mineralized soil nitrogen (N) content and mineralized N rate under the treatments, including NPK (chemical fertilizers application with straw removal), SBR (straw burned return), and SR (straw return). Results showed that, compared with SBR and NPK, SR significantly increased available nitrogen by 7.4% and 16.5%, respectively, due to the higher ammonium nitrogen and nitrate nitrogen, as well as the total carbon, available phosphorus, and slowly available potassium, suggesting that it could stock a sufficient nitrogen source. During the incubation period, the amount of N mineralization was relatively higher under SR than under SBR and NPK treatments, especially during the later mineralization time, whereas there was no difference in the N mineralization rate. In addition, SR significantly increased soil cumulative N mineralization and N mineralization potential. However, SBR significantly decreased the soil mineralizable N ratio compared with SR and NPK, which may result in a worsening of the N mineralization potential. The results indicated that long-term straw return combined with reducing chemical fertilizer application could significantly improve the N supply capacity of paddy rice field soil to better coordinate the soil N supply and immobilization. [ABSTRACT FROM AUTHOR]

In order to solve the difficulty of characterizing the optical constants of ZnS at high temperatures, the multi-phonon absorption dielectric function model which includes temperature parameters is constructed and modified in this paper. The multi-phonon absorption parameters of ZnS have been inverted based on variable temperature infrared transmittance spectra. The variable temperature infrared transmittance spectra of ZnS have been well fitted. The temperature dependence of the dissociation energy of ZnS materials is demonstrated, and the optical constants of the ZnS material have been obtained at 25 °C, 100 °C, 200 °C, 300 °C, and 400 °C. • The relationship between the value of m max and temperature is established in the multi-phonon absorption model of ZnS. • The ZnS multi-phonon parameters for various temperatures obtained by spectral inversion conform to physical laws. • Highly accurate variable-temperature optical constants of ZnS were obtained based on the multi-phonon absorption model. [ABSTRACT FROM AUTHOR]

Flexible thermoelectrics, including flexible thermoelectric materials and devices, can directly convert the heat from human body into useful electricity, providing a promising solution for uninterrupted power to wearables. In the past decade, flexible thermoelectrics has achieved notable progress. Various kinds of flexible thermoelectric materials have been developed and some of them have been fabricated into flexible thermoelectric devices, showing the ability to generate nW‐level or even μW‐level electricity. Herein, the basic design principles and typical configurations of flexible thermoelectric devices, as well as the requirements on thermoelectric materials to achieve high performance flexible thermoelectric devices, are first introduced. Then, the recent progress achieved in flexible thermoelectric devices based on organics materials, traditional inorganic materials, other organic/inorganic composites/hybrids, and plastic deformable inorganic semiconductors, respectively, are summarized. Finally, an outlook on the future development of flexible thermoelectrics is briefly given. This study sheds light on the further development of flexible thermoelectrics. [ABSTRACT FROM AUTHOR]

The goal of this study was to enhance the utilization of millet straw and reduce N 2 O emissions, used the semi-interpenetrating (Semi-IPN) technology to develop a novel straw-based material (CSC-g-PAA/PPVA) through the composite integration of modified straw and linear polymer (PPVA). The fourier-transform infrared, x-ray diffraction, x-photoelectron spectroscopy and scanning electron microscopy techniques were be measured to provide evidence of the structure and morphology characterization of CSC-g-PAA/PPVA. The results demonstrated that it exhibited excellent water absorbency and enhanced the adsorption capacity of inorganic nitrogen, with the maximum adsorption of NH 4 + and NO 3 - were 94.5 mg/g and 70.3 mg/g, respectively. The properties of CSC-g-PAA/PPVA could significantly reduce N 2 O emissions, which was 42.5–95.7% lower than that of the fertilization groups, demonstrated that the modified material produced in this study had significant potential to reduce greenhouse gas emissions. [Display omitted] • The soil conditioner is derived from corn straw, which can enhance waste straw utilization. • The product is rich in typical functional group, providing active sites for NH 4 +, NO 3 - retention. • The straw-based conditioner has significant potential to reduce N 2 O emissions in soil. • Preparing by waste straw can reduce cost, is beneficial to industrial production. [ABSTRACT FROM AUTHOR]

Humans have innately established close and profound ties with the, and through these relationships shaped many kinds of landscapes. Among these are sacred landscapes, which have drawn the attention of researchers due to their cultural significance. In the field of health geography, large-sized sacred regional landscapes are now the focus of studies for their therapeutic properties. However, few scholars have focused on small sacred landscape systems at the community level (constructed by local communities) or the physical and psycological health benefits that these landscapes offer to the local residents. These small-sized and widespread, but often hidden, sacred landscapes are closely tied to people's daily lives and work. They have evolved and grown over millennia to become critical sociocultural phenomena. This study takes the sacred bao ye landscape of the Dong people of China as the research subject. By adopting the case study approach, field research, semi-structured interviews, and textual analysis, it summarizes the types, geographical distribution, rituals and processes of bao ye as a sacred landscape of the Huanggang village in Guizhou Province, and concludes with an analysis of motivation and health benefits to the bao ye worship. In this paper we argue that bao ye is a sacred landscape system focusing on the healthy development of children, and constitutes a local belief developed in an isolated environment lacking medical resources, which remains in practice. The sacred landscape of bao ye offers a therapeutic environment, providing children with increased opportunities to engage with and build deep connections to nature. Thruogh this process children may develop a bond with nature that inspires them to protect nature on their own accord. We argue that bao ye offers an important case study for understanding the landscape-people-healing interactivity at the community level. • Sacred landscapes have beneficial effects on the physical and mental health of humans. • The community-level sacred landscape of Bao ye is important for the healthy development of local children. • The sacred landscape system of the Dong people helps to better protect this precious traditional cultural landscape. [ABSTRACT FROM AUTHOR]

[Display omitted] • Interaction of flavor substances in sesame-flavor baijiu was studied firstly. • Volatile change was the reason for the interaction affecting the flavor perception. • Structure and phase ratio affected the volatility of esters. • The interaction prediction model is established firstly to realize rapid judgment. The interaction between 1,3-dimethyltrisulfide and aroma-active compounds in sesame-flavor baijiu was evaluated by Feller's additive model and Odor Activity Value Approach, and the reason for the interaction can promote the release of fruity and caramel aromas of ethyl caproate, ethyl was explored by the Partition Coefficient Approach. The interaction results indicated that 1,3-dimethyltrisulfide caprate and furan-2-ylmethanol. Others showed masking effect. The Partition Coefficient showed that the effect of 1,3-dimethyltrisulfide on the volatility of esters was one of the reasons for the interaction affecting the flavor perception, and the volatility of ethyl esters with longer carbon chains at high phase ratio (PRs) is more likely to be promoted. Besides, the prediction model was initially proposed: y = 2.0112 ln(x) + 0.1461, which indicated that esters with the olfactory threshold lower than 33.80 μg/L are more likely to have positive effects with 1,3-dimethyltrisulfide, the negative effect is more likely to occur conversely. [ABSTRACT FROM AUTHOR]

• Melanoidins were mostly produced during distillation. • Melanoidins were primarily composed of carbohydrates. • Melanoidins formed during fermentation and distillation had structural differences. • Carbohydrates, proteins and phenols are involved in melanoidin formation diversely. Chinese liquor (baijiu) is a typical fermented food. In which production, melanoidins are formed in fermenting grains during low-temperature fermentation with long-term, and in distilled grains with high-temperature distillation for short-term. Here, the formation and structural characterization of melanoidins in these two distinct stages were first investigated through chemical composition analysis and spectroscopic identification. Our research showed that proteins and phenols continuously participate in melanoidin formation during fermentation and distillation processes. Distillation could produce melanoidins with larger amounts, darker colors, higher molecular weights, and more stable states than fermentation. The chemical composition including 10 carbohydrates, 17 amino acids, 5 free phenolic acids, and 7 bound phenolic acids was successfully identified in melanoidins. Ion chromatography was proposed to be an efficient method to investigate carbohydrates in melanoidins. Moreover, the potential impact of microorganisms on melanoidins was first revealed to be the possible utilization of glucose in melanoidins. [ABSTRACT FROM AUTHOR]

The goal of this study was to enhance the utilization of millet straw and endow it with the fertilizer function through modifying the carboxymethylcellulose (CMC-NH 4), based on wheat straw, by acidification and ammonification to improve water and fertilizer efficiency. Amine group was introduced through the electrophilic substitution to supply nutrients to crops. The order of influential factors on the water absorption property was determined by an orthogonal experiment and showed that the highest water absorbency of 224.7 g/g, which was achieved for the conditions of 3:1 carboxymethylcellulose to nitric acid solution (mass percentage concentration of 50%), 3:1 carboxymethylcellulose to ammonia solution with the mass percentage concentration is 30%. The CMC-NH 4 was characterized by scanning electron microscopy, fourier-transform infrared, x-ray diffraction, and X-ray photoelectron spectroscopy techniques, and the results indicated that application of CMC-NH 4 promoted the growth indexes of wheat, improved wheat yields. Therefore, the waste straw was modified into the soil conditioner with specific function by the group targeted modification strategy. In addition, the fertilizer efficiency and water-retention behavior of CMC-NH 4 encouraged its use as a safe water- and fertilizer-retaining agent in agricultural applications. [Display omitted] • The product prepared by straw can reduces cost, is easy for agricultural extension. • The CMC-NH 4 is rich in ammonium, could provide fertilizer for crop growth. • The product shows excellent water retention and could prevent water percolation. [ABSTRACT FROM AUTHOR]

• High-frequency resonance is suppressed by broadband MMC impedance reshaping. • Phase compensation is adopted to eliminate the negative damping of MMC. • The proposed method is effective under various operating scenarios of ac grid. • A controller parameter design method is presented in detail. Negative damping in modular multilevel converter (MMC) impedance may lead to high-frequency resonance (HFR) in MMC-high-voltage direct current systems. The existing solution is based on amplitude attenuation by digital filters. However, filters have weak amplitude attenuation and obvious phase shifts in the attenuation band, resulting in the transfer of negative damping. The system still has a risk of HFR when grid condition is changed. This study proposed a broadband active damping method based on phase compensation to address this limitation. The embedding position and scheme of the phase compensation controller are optimally designed through impedance-based analysis. By tuning parameters correctly, the negative damping of MMC is eliminated over a wide frequency range (500–2000 Hz). Thus, the proposed method performs better in HFR suppressing under varying grid conditions. In addition, considering the harmonic amplification problem caused by the differential link, an inertia link and a proportional link are further employed to increase high frequency impedance magnitude. Time-domain simulations in MATLAB/SIMULINK verify the effectiveness of the proposed method. [ABSTRACT FROM AUTHOR]

Liquid-liquid microextraction (LLME) combined with gas chromatography-mass spectrometry (GC-MS) and headspace-gas chromatography-ion mobility spectrometry (HS-GC-IMS) were used to detect the variations in volatile compounds during the distillation process of strong flavor raw Baijiu. The 3D fingerprint spectrum clearly showed a variation in volatile compounds from different distillation stages, and most alcohol-soluble and low molecular weight compounds showed a downward trend with the extension of distillation time, but water-soluble, high molecular weight and high boiling compounds showed the opposite result. Then, 50 aroma compounds were sniffed and identified by gas chromatography-olfactometry-mass spectrometry (GC-O-MS) and multivariate statistical analysis including principal component analysis (PCA) and partial least squares discriminant analysis (PLS-DA) confirmed four aroma active markers related to classification. Finally, the receiver operating characteristic (ROC) curve was further used to verify that ethyl butanoate and ethyl hexanoate were the most effective difference marker to distinguish the head Baijiu samples and butanoic acid was the most effective difference marker for distinguishing the heart Baijiu samples from the tail Baijiu samples. [Display omitted] • LLME coupled with GC-O-MS was used to analyze the changes of aroma active compounds. • GC-MS and GC-IMS were compared the differences in the detection of compounds. • ROC curve was used to verify the most effective difference markers. [ABSTRACT FROM AUTHOR]

In order to enhance utilization of millet straw and reduce fertilizer loss, a novel multifunctional fertilizer (MS-g-PAA/PDMUA) was developed using straw cellulose and linear polymer (PDMUA) by semi-interpenetrating technology. The structure and morphology characterization of MS-g-PAA/PDMUA were measured by fourier-transform infrared, x-ray diffraction, x-photoelectron spectroscopy and scanning electron microscopy techniques, to provide evidence of semi-IPNs networks and component interactions, and the results show that the product exhibited excellent water absorbency (562.3 g/g) and enhanced the soil infiltration. Cumulative release of N, P was 49.2% and 55.1%, respectively, after 40 days, coming up to the Committee of European Normalization (CEN) standard. The agricultural application of MS-g-PAA/PDMUA showed that it could promote growth indexes of wheat, which could improve wheat yields. Therefore, desirable water retention, slow-release properties, and wheat growth effects highlight the product's potential for agriculture application. [Display omitted] ● MS-g-PAA/PDMUA is derived from millet straw, can enhance waste straw utilization. ● The MS-g-PAA/PDMUA is rich in nitrogen and phosphorus, which promote wheat growth. ● The product has excellent water retention and slow fertilizer-release properties. ● Preparing by waste straw can reduce cost, is beneficial to industrial production. [ABSTRACT FROM AUTHOR]

Soy sauce aroma type baijiu (SSAB) is one of the four basic baijiu flavor types. It has an elegant sauce flavor, empty cup aroma, lasting, mellow and sweet entrance, soft with obvious acidity, delicate taste and long aftertaste. However, to date, no study has identified the key aroma compounds in SSAB. This study introduces SSAB and its production process, and summarizes the research status on flavor compounds. Through analysis and review, some assumptions are made to explain why the key aroma compound of SSAB remains unidentified. We provide insights for the analysis of key aroma compounds in SSAB and lay a theoretical foundation for the improvement and rapid development of SSAB quality. • Specific summarizes the research of key volatile compounds in soy sauce aroma type baijiu. • Summarizes the research of off-odor components in soy sauce aroma type baijiu. • First time to analyzes why the key flavor of soy sauce aroma type baijiu have not been discovered. [ABSTRACT FROM AUTHOR]

• A steady cone-jet occurs in a greater range of liquid flow rates for a hemispherical capillary. • Varicose and whipping regimes are easily obtained with a hemispherical nozzle. • The transition from varicose and whipping usually depends on interfacial forces on the jet. • A general parameter to determine varicose, transition, and whipping regimes is presented. A cone-jet regime in electrohydrodynamic atomization (EHDA) is widely applied into printing, electro-spinning, spray-coating, and biological mass spectrometry. Regulating different instabilities of jet is crucial for optimizing its operating parameters. In present work, an atypical, hemispherical capillary with inner diameter of 0.40 mm and cap size of 6.20 mm was employed as atomization nozzle, through which a steady cone-jet regime was confirmed versus suitable feeding liquid flow rate and electric potential. A permanent and highly charged jet emits from a Taylor cone apex and further disintegrates into fine highly charged drops in the form of varicose or whipping instabilities. The results indicate that a steady cone-jet is observed in the specific ranges of the feeding liquid flow rate, electric potential and conductivity. The typical breakup instabilities including varicose and whipping are clearly observed with an increase in liquid flow rate for a fixed electric potential for most of liquids, and the transition from varicose to whipping instability easily occurs. For a steady cone-jet, the jet breakup instabilities usually depends on the competition between interfacial forces on the electrified jet. The transition process involving a low-viscosity jet with a large flow rate is observed, and the general parameter G = Γ 2 δ μ 0.52 is calculated to account for surface charge, surface tension, and viscosity effects, where Γ is the electric force to surface tension ratio and δ μ is the inertia to viscous force ratio. Finally, the varicose, transition regime, and whipping are classified with first and second critical threshold values G = 40 and G = 102, respectively. Meanwhile, as the electrified jet transforms from varicose to whipping instabilities, the jet breakup length shows a trend of increasing first and then decreasing. [ABSTRACT FROM AUTHOR]

• The necking time is independent of electric field in a reasonable range of flow rate. • The transition from dripping to jetting is enhanced by electric field for relatively small tube. • A model for the transition from periodic dripping to jetting is established in an electric field. • A critical criterion for the transition is presented and in reasonable agreement with experiments. A liquid is issued from the outlet of the capillary tube vertically, and drop formation may be in the form of periodic dripping, dripping faucet and jetting, which usually depends on flow rate or Weber number. We consider the critical Weber number (W e C = ρV 0 2 D / σ) at which the transition from periodic dripping to jetting occurs in the presence of an electric field, where high-resolution images are recorded. The necking time is mainly related to nozzle diameter and surface tension, and independent of electric potential and flow rate (in a reasonable range).The first threshold limit decreases with an increase in electric potential, where the dripping faucet is clearly affected and the point of drop detachment gradually increases. When the drop formation is in the form of dripping faucet, the transition from dripping faucet to jetting regime is enhanced by electric potential, where a sudden transition could be observed in an extremely limited range of liquid flow rate. The critical criterion (Weber number) is presented to determine the transition from dripping to jetting in the presence of an electric field. The critical Weber number is in a reasonable agreement with the experiment, although the predicted results are quantitatively divergent with experimental data. [ABSTRACT FROM AUTHOR]

Baijiu is a unique and traditional distilled liquor in China. Flavor plays a crucial rule in baijiu. Up to now, the research on the flavor of baijiu has progressed from the identification of volatile compounds to the research on key aroma compounds, but the release mechanism of these characteristic compounds is still unclear. Meanwhile, volatile compounds account for only a tiny fraction, whereas ethanol and water account for more than 98% of the content in baijiu. By summarizing the ethanol–water hydrogen bond structure in different alcoholic beverages, it was found that flavor compounds can affect the association strength of the ethanol–water hydrogen bond, and ethanol–water can also affect the interface distribution of flavor compounds. Therefore, the research on ethanol–water microstructure in baijiu is helpful to realize the simple visualization of adulteration detection, aging determination and flavor release mechanism analysis of baijiu, and further uncover the mystery of baijiu. [ABSTRACT FROM AUTHOR]

• The feruloyl esterase activity in different layers of Jiupei at different fermentation times were determined and tracked. • The microorganisms with feruloyl esterase activity were screened and identified in Jiupei of sesame-flavor baijiu. • The conditions of enzyme production were optimized by liquid fermentation. Baijiu is a national beverage in China. Some functional compounds have been identified in baijiu, one of which is ferulic acid. One route for in situ ferulic acid synthesis is catalysed by feruloyl esterase from microorganisms using baijiu raw materials as substrates. However, few studies have focused on microorganisms obtained from baijiu that have feruloyl esterase activity. In this work, microorganisms with feruloyl esterase activity were screened in the fermented raw materials of baijiu. Four different microorganisms with feruloyl esterase activity were identified, and one strain, designated J1, showed high feruloyl esterase activity. The strain J1 belonged to the genus Acetobacter and showed the closest relationship with Acetobacter fabarum and Acetobacter lovaniensis. The feruloyl esterase production capacity of J1 was confirmed, and the fermentation conditions were optimised. The optimal enzyme production conditions for the highest feruloyl esterase activity required an initial fermentation pH of 7.0 at 30 °C, an inoculation volume of 10 %, and culturing for 24 h. [ABSTRACT FROM AUTHOR]

Under the influence of space weather, abnormal disturbances in the ionosphere will distort the ionosphere model seriously and affect the global navigation satellite system negatively. This study analyzes the ionospheric activity characteristics and the ionospheric model performance in low latitude during a strong geomagnetic storm from 7 to 9 September 2017. The research goals are to determine the abnormal behavior of the ionosphere during the geomagnetic storm and to refine the ionosphere model in the low latitude. In the experiment, the vertical total electron content (VTEC) peak value at low latitudes caused by this geomagnetic storm was significantly higher than that on the geomagnetic quiet day, and the VTEC peak value increased by approximately 75%. In the main phase of the geomagnetic storm, the degree of VTEC variation with longitude is significantly higher than that of the geomagnetic quiet day. The VTEC variation trend in the northern hemisphere is more severe than that in the southern hemisphere. In the region where VTEC decreases with longitude, the VTEC in the northern hemisphere is higher than that in the southern hemisphere on the same longitude at low latitudes, and this phenomenon is not significantly affected by the geomagnetic disturbance of the recovery phase. During the geomagnetic storm, the daily minimum value of VTEC at different latitudes was basically the same, approximately 5 TECU, indicating that the nighttime VTEC of the ionosphere in low latitudes was weakly affected by latitude and geomagnetic storms. Geomagnetic disturbances during geomagnetic storms will lead to anomalous features of the "Fountain effect" in the ionosphere at low latitudes. In addition, this geomagnetic storm event caused the accuracy of spherical harmonics (SH), polynomial, and ICE models to decrease by 7.12%, 27.87%, and 48.56%, respectively, and caused serious distortion, which is negative VTEC values fitted by the polynomial model. [ABSTRACT FROM AUTHOR]

Currently, research on the small-signal stability of grid-forming converters under two control modes, grid-following and grid-forming, mainly focuses on low-level converters. However, studies on the differences between grid-following modular multilevel converters (MMC) and grid-forming MMC are limited. A comprehensive analysis of the wideband oscillation risk differences in MMC-HVDC systems under these two control modes from the perspective of impedance characteristics is necessary. Therefore, based on the harmonic state-space (HSS) modeling theory, this article establishes wideband sequence impedance models for grid-forming and grid-following MMC. Subsequently, this article identifies key control parameters affecting the impedance characteristics of MMC under two control modes. The wideband oscillation risks of MMC-HVDC systems under both control modes are compared. The study indicates that when the grid strength weakens, grid-following MMC faces instability risks, while grid-forming MMC can maintain stability. In instances where high-frequency resonance peaks exist in the impedance of the grid, both control modes of MMC may face instability risks. Furthermore, by adjusting the obtained key control parameters of MMC, this article effectively suppresses the oscillation risk discussed above. Finally, the analysis results are verified through an electromagnetic transient simulation. [ABSTRACT FROM AUTHOR]

A two-stage process has been developed for the pyrolysis of high-density polyethylene to obtain light olefins, where probable mechanisms for each stage pyrolysis were proposed in our previous study. This work aims to establish molecular-level kinetic models for the first-stage pyrolysis at a lower temperature and for the second-stage pyrolysis at a higher temperature, respectively, to predict the overall reaction performances in accordance to the role of detailed mechanisms. A structure-oriented lumping (SOL) method based molecular-level kinetic model can effectively describe the first-stage pyrolysis, while a detailed molecular-level kinetic model is developed for the second-stage pyrolysis to track the evolutions of all alkanes, olefins, and diolefins, with special focus on the formation of light olefins. The established separate models can achieve the automatic generation of complex reaction networks and present good agreement with experimental data obtained from the first- and second-stage. In addition, the first-stage model indicates that the random scission plays an important role in the pyrolysis process at lower temperatures, while the chain-end scission mechanism dominates the second-stage reaction to produce light olefins at higher temperatures. As a whole, the molecular-level modelling scheme behaves excellently at a wide range of temperature, which provides guidance for upgrading the pyrolysis process. • A molecular level kinetic model is established for the two-stage HDPE pyrolysis. • The reaction network is generated automatically and visualized. • This model achieves excellent agreement with experimental data. • The competition of two scissions and important role of temperature are quantified. [ABSTRACT FROM AUTHOR]

• The onset and termination electric potential to form the steady cone-jet electrospray increase as conductivity increasing. • The lower and upper limitation of liquid flowrate to form the steady cone-jet electrospray decrease as conductivity increases. • The varicose instability can transform into whipping instability as the electrical conductivity increasing. • The jet breakup instability transition mechanism is interpreted by theoretical analysis. • The whipping to similar micro-dripping instability can be observed for EG with higher conductivity. In present work, the effect of the electrical conductivity on the steady cone-jet electrospray are experimentally investigated, where the operating diagram and the jet breakup instability are extensively examined. A hemispherical tube is employed as spraying nozzle severed as high electric potential electrode in a needle-plated electrode configuration compared to the common and sheathed tubes. The cone-jet electrospray is visualized by a high-resolution camera and extensively analyzed offline. The aqueous solution in ethanol, Diethyleneglycol (DEG) and Ethylene glycol (EG) are atomized with varied electrical conductivity under different high electric potentials and flowrates. Experimental results indicate that the cone-jet electrospray can operate in the certain ranges of operating parameter for all types of capillaries. The operating diagram for the hemispherical tube is significantly broader than other tubes because of various electric field strength distribution. The onset electric potential to determine a steady cone-jet electrospray gradually increases and the termination value also increases as the electrical conductivity increases. The lower and upper flowrate to form a steady cone-jet electrospray also increase as the electrical conductivity increases. The jet breakup instability can transit from varicose to whipping due to low the reference flow rate as electrical conductivity increases, which is agreement with theoretical analysis. In particular, for EG, the transition from whipping to similar micro-dripping is observed as the electrical conductivity increases, while the transition also occurs as flowrate increases for EG with higher electrical conductivity. The increase in the electrical conductivity and flowrate elongates the cone due to EHD body force, which causes the electric field varying, further resulting in the difference in jet breakup instability. Moreover, the electrical conductivity also plays an important role in jet breakup length. The instability variation of jet with conductivity (DEG), q V =1000 nL/s, ϕ =8.00 kV (Hemispherical nozzle with D o =0.70mm); The variation with liquid flow rate of EG with higher conductivity (K =8.5 × 10−4 s/m, ϕ =10.20 kV, (Hemispherical nozzle with D o =0.70mm) [Display omitted] [ABSTRACT FROM AUTHOR]

Accurate measurements of the three-dimensional structure characteristics of urban buildings and their greenhouse effect are important for evaluating the impact of urbanization on the radiation energy budget and research on the urban heat island (UHI) effect. The decrease in evapotranspiration or the increase in sensible heat caused by urbanization is considered to be the main cause of the UHI effect, but little is known about the influence of the main factor "net radiant flux" of the urban surface heat balance. In this study, experimental observation and quantitative model simulation were used to find that with the increase of building surface area after urbanization, the direct solar radiation flux and net radiation flux on building surface areas changed significantly. In order to accurately quantify the relationship between the positive and negative effects, this study puts forward the equivalent calculation principle of "aggregation element", which is composed of a building's sunny face and its shadow face, and the algorithm of the contribution of the area to thermal effect. This research clarifies the greenhouse effect of a building with walls of glass windows. Research shows that when the difference between absorption rates of a concrete wall and grass is −0.21, the cooling effect is shown. In the case of concrete walls with glass windows, the difference between absorption rates of a building wall and grass is −0.11, which is also a cooling effect. The greenhouse effect value of a building with glass windows reduces the cooling effect value to 56% of the effect of a building with concrete walls. The simulation of changes in net radiant flux and flux density shows that the greenhouse effect of a 5-story building with windows yields 15.5% less cooling effect than one with concrete walls, and a 30-story building with windows reduces the cooling effect by 23.0%. The simulation results confirmed that the difference in the equivalent absorption rate of the aggregation element is the "director" of cooling and heating effects, and the area of the aggregation element is the "amplifier" of cooling and heating effects. At the same time, the simulation results prove the greenhouse effect of glass windows, which significantly reduces the cold effect of concrete wall buildings. The model reveals the real contribution of optimized urban design to mitigating UHI and building a comfortable environment where there is no atmospheric circulation. [ABSTRACT FROM AUTHOR]

Maize is one of the most successful crops with regard to the utilization of heterosis. The haploid induction technique is one of the fastest methods to obtain pure maize material at the present stage. However, the molecular mechanism of haploid doubling is rarely reported. In this study, we treated B73 and ZNC442 haploid young shoots with colchicine for 0 h, 6.2 h, and 10 h, and analyzed the differentially expressed genes (DEGs). We found that colchicine treatment for 6.2 h and 10 h compared to 0 h resulted in a total of 4868 co-DEGs. GO enrichment analysis and KEGG metabolic pathway analysis found significantly enriched 282 GO terms and 31 significantly pathways, respectively. Additionally, The GO term and KEGG pathway genes of spindle, cytoskeleton, microtubules and nuclear division were selected for analysis, and three candidate genes were screened by taking intersections. Zm00001d033112, Zm00001d010525, and Zm00001d043386 were annotated as kinesin-associated protein 13, kinesin-like protein KIN-10C, and kinesin light-chain LC6, respectively. The real-time fluorescence quantification (RT-PCR) results revealed that Zm00001d033112, Zm00001d010525, and Zm00001d043386 had the same trends as RNA-seq. Interestingly, Zm00001d033112 is homologous gene AT3G20150 in Arabidopsis, which was involved in the regulation of chromosome movement and mitotic spindle assembly. Our study suggests that kinesin genes may play an important role in doubling chromosomes, thus providing valuable information for future studies on the molecular mechanisms of chromosome doubling in maize. [ABSTRACT FROM AUTHOR]

The Yangtze River Economic Belt (YREB) is an important strategic area in China. However, frequent extreme precipitation events have caused great economic losses and human casualties in this region. In this article, we explore the spatial and temporal links between extreme precipitation events and Sunspot Number (SSN), El Niño Southern Oscillation (ENSO), Arctic Oscillation (AO) and Pacific Decadal Oscillation (PDO) in this important economic belt. According to the research findings, all of the extreme precipitation indices (EPIs) except for consecutive dry days (CDD) and consecutive wet days (CWD) showed an upward trend in the YREB over the 59 years. The spatial distributions of very wet days (R95p), extremely wet days (R99p), max 1-day precipitation amount (Rx1day) and max 5-day precipitation amount (Rx5day) had similar distribution patterns, showing decreasing trends from east to west. The EPIs generally had a 2–4-year band, suggesting stronger and more elusive changes. The wavelet coherence (WTC) spectra suggested that SSN, ENSO, AO, and PDO have different effects on extreme precipitation events during different time periods. Before 1985, the SSN, ENSO, AO, PDO and extreme precipitation events shared similar oscillation periods, but after 1985, their oscillation periods were no longer consistent with each other. In addition, solar activity and the AO mainly had negative correlations with extreme precipitation events, while the ENSO and PDO had predominantly positive correlations with the EPIs. This paper provides a reference for national economic strategic planning and natural resource management in the YREB. [ABSTRACT FROM AUTHOR]

[Display omitted] • FeNi nanoalloys were encapsulated in graphitic carbon nanofibers derived from Prussian blue analogue (PBA). • Limited oxidation and aggregation of FeNi nanoalloys in CNF were obtained by changing PBAs loading. • Synergistic effect between non-noble plasmonic nanoalloys and graphitic carbon nanofibers was constructed by electrospinning. • Optimized photothermal conversion efficiency was reached by the constructed composited fiber membrane. • A extremely low usage dosage of photothermal materials can enable the construction of 2D evaporation membrane. Sustainable and energy-efficient water purification by harnessing solar energy is critical to tackling the challenges of water scarcity and the on-going water pollution crisis. Nevertheless, the biggest challenge to the practical deployment of solar-driven water purification, however, continues to be the poor solar evaporation efficiency of materials. Herein, FeNi nanoalloys encapsulated in graphitic carbon nanofibers (FeNi 3 /CNF) using Prussian blue analogue (PBAs) derivatives were fabricated using electrospinning and carbonization. The PBAs metal precursors play a critical role in encapsulating and safeguarding the FeNi alloy nanostructures from oxidation and agglomeration challenges. Furthermore, the synergistic effects between the non-noble hybrid plasmonic nanoalloys and graphitic CNFs can be constructed and optimized from the mass loading of PBAs precursor. Benefiting from the broad solar absorption band, high specific surface area, abundant micro-mesopores, and well-organized interlayer channel, the resultant 2D FeNi 3 /CNF solar evaporator demonstrates an efficient water evaporation rate of 1.51 kg m-2h−1 with an outstanding solar evaporation efficiency of 93.3 % under one sun irradiation, among the best values reported thus far. Impressively, the resultant 2D FeNi 3 /CNF solar evaporator can be constructed using only 0.02 kg m−2 loading of photothermal materials without compromising evaporation performance, which highlights its cost-efficiency in the practical application. Furthermore, the desalinated water meets the drinking standards of the World Health Organization (WHO) with an efficient 99 % separation of multiple organic industrial dye pollutants. Hence, this work demonstrates an efficient cost-effective approach to novel non-noble plasmonic alloy-based metal–carbon composites for enhanced solar-driven interfacial evaporation and wastewater purification. [ABSTRACT FROM AUTHOR]

Significant breakthroughs in the theory and applications of ferrofluid have broadened their usage in areas such as sealing and actuation. However, the development of numerical ferrofluid dynamics has been slow owing to inadequate multi-field coupling techniques and incomplete equations for turbulence in ferrofluid flow. The understanding of low-Reynolds-number turbulent flow mechanisms in ferrofluid at small scales, particularly in sealing and actuation applications, remains limited, therefore hindering further advancements. This article delves into the turbulent flow equations for general fluid and discusses the influence of different-scale vortices on the average fluid motion. An anisotropic turbulence model was introduced and verified using fluid flow around a cylinder. Magnetic and flow fields data were coupled through node ranking and interpolation methods. By introducing the interaction force of magnetic dipoles, the turbulent equations were refined within Euler grids, thereby establishing a numerical model for the turbulent motion of ferrofluids influenced by multiple fields. This model was applied to study the deformation and migration processes of ferrofluid under an external magnetic field. The variations in ferrofluid motion under magnetic forces were encapsulated, and macroscopic flow comparisons were made through experiments, which demonstrated good consistency. This research provides new methods and ideas for use in ferrofluid numerical studies. Additionally, it offers valuable technical support that can aid in developing industrial products such as sealing and driving devices based on ferrofluids. [ABSTRACT FROM AUTHOR]

Developing production technology pathways of sustainable aviation fuel (SAF) that align with China's national conditions and aviation transportation needs is crucial for promoting the SAF industry and achieving China's carbon peak and carbon neutrality goals. This article first projects the future SAF demand in China for the coming decades. Using SAF demand data as an input, this article employs the TOPSIS analysis method to comprehensively evaluate the suitability of four SAF production technology pathways at different stages of development in China, which are Hydroprocessed Esters and Fatty Acids (HEFA), Alcohol-to-Jet (AtJ), Natural Gas + Fischer–Tropsch Synthesis (G + FT), and Power-to-Liquid (PtL). The research results reveal the following trends: HEFA-based processes are the most suitable technology pathways for China in the near term; the G + FT route, based on energy crops, appears the most likely to support civil aviation needs in the medium to long term. In the long run, the PtL route holds significant potential, especially with the decreasing costs of green electricity, advancements in carbon capture, utilization, and storage (CCUS) technology, and improvements in SAF synthesis methods. In the final section of this article, we provide recommendations to drive the development of the SAF industry in China. [ABSTRACT FROM AUTHOR]

The pollution of heavy metals is extremely serious in China, including zinc (Zn), copper (Cu), lead (Pb), and cadmium (Cd). Heavy-metal-transporting ATPase (HMA) belongs to a subfamily of the P-ATPase family, which absorbs and transports Zn, Cu, Pb, and Cd in plants. Here, we describe a ZmHMA-encoding HMA family protein that positively regulates Cd and Zn tolerance. The real-time fluorescence quantification (RT-PCR) results revealed that ZmHMA3 had a high expression in B73, and the expression of ZmHMA3 was sensitive to Cd in yeast cells, which was related to Cd accumulation in yeast. Additionally, the Arabidopsis thaliana homologous mutants of AtHMA2 showed Cd sensitivity compared with WT. The overexpressing ZmHMA3 plants showed higher tolerance under Cd and Zn stresses than the wild type. The overexpression of ZmHMA3 led to higher Cd and Zn accumulation in tissues based on the subcellular distribution analysis. We propose that ZmHMA3 improves maize tolerance to Cd and Zn stresses by absorbing and transporting Cd and Zn ions. This study elucidates the gene function of the ZmHMA3 response to Cd and Zn stress and provides a reference for improving the characteristics of heavy metals enrichment in existing maize varieties and the plant remediation technology of heavy-metal-contaminated soil. [ABSTRACT FROM AUTHOR]

Waste plastics have emerged as a global environmental issue. Polyethylene, accounting for about 25% of global plastic production, has been acknowledged as the major cause of "white pollution". In this paper, a generalized molecular-level kinetic model was proposed to understand the pyrolysis of polyethylene applying structure-oriented lumping, Poisson distribution, and genetic algorithm. The number of ordinary differential equations derived from the reaction kinetics were dramatically reduced by this simplified network with 14-rule design. The generalizability was confirmed by case studies without any change in the rule design. Under most conditions, the mean relative error between experimental and model data could be controlled within 5%, while abnormal deviations indicate the obstacle of heat transfer. The simulation curve could provide guidance for the experiments by locating the peak value of products. From 400–470 °C in Case 2, the increase in the reaction proportion of producing light oil explains the experimental results from the perspective of molecular-level reaction network. The comparison between PE and PS pyrolysis elaborates different pyrolysis mechanisms based on the different molecular structures. • Established a generalized molecular-level model for polyethylene pyrolysis. • Offered an efficient tool avoiding repeated work in pyrolysis simulation. • Confirmed the generalizability by case studies without changing the rule design. • Provided guidance for the experiments by locating the peak value of products. [ABSTRACT FROM AUTHOR]

The accumulation of waste plastics has been one of the most urgent and difficult environmental challenges. In this work, the pyrolysis of polyethylene (PE) has been studied by thermogravimetric analysis (TGA), pyrolysis/gas chromatography/mass spectrometry (PyGC-MS), and a two-stage tube reactor. The pyrolysis behavior of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) is compared, and there are almost no differences in the thermogravimetric curves obtained by TGA and the yield of gaseous products obtained in a two-stage process. The evolution of light olefins (C 2 –C 4) during the pyrolysis of PE is investigated in a two-stage process with a constant condition in the first stage (500 °C) and various conditions in the second stage (700–1000 °C, 0.2–0.4 s). The temperature in the second stage has a more significant effect on the yield and selectivity of light olefins than the residence time, and the ethylene, propylene, and butene yields do not increase monotonously as the temperature rises. The highest yield of light olefins of 76.1 wt% is obtained at 800 °C with a selectivity of 91.7%. The maximum yields of ethylene, propylene, and butene are 45.1 wt%, 17.3 wt%, and 24.3 wt%, respectively. The scission mechanisms are proposed to provide insight into the process during which PE molecules transform into light olefins. • There are almost no differences between the pyrolysis characteristics of high-density and low-density polyethylene. • The evolution of light olefins during the polyethylene pyrolysis is investigated by PyGC-MS and a two-stage tube reactor. • A high yield of light olefins of 76.1 wt% with a high selectivity of 91.7% is obtained at 800 °C. • Probable mechanisms for two-stage pyrolysis of PE are proposed to reveal the interplay of reactions. [ABSTRACT FROM AUTHOR]

The accuracy of insulators and their defect identification by UAVs (unmanned aerial vehicles) in transmission-line inspection needs to be further improved, and the model size of the detection algorithm is significantly reduced to make it more suitable for edge-end deployment. In this paper, the algorithm uses a lightweight GhostNet module to reconstruct the backbone feature extraction network of the YOLOv4 model and employs depthwise separable convolution in the feature fusion layer. The model is lighter on the premise of ensuring the effect of image information extraction. Meanwhile, the ECA-Net channel attention mechanism is embedded into the feature extraction layer and PANet (Path Aggregation Network) to improve the recognition accuracy of the model for small targets. The experimental results show that the size of the improved model is reduced from 244 MB to 42 MB, which is only 17.3% of the original model. At the same time, the mAp of the improved model is 0.77% higher than that of the original model, reaching 95.4%. Moreover, the mAP compared with YOLOv5-s and YOLOX-s, respectively, is improved by 1.98% and 1.29%. Finally, the improved model is deployed into Jetson Xavier NX and run at a speed of 8.8 FPS, which is 4.3 FPS faster than the original model. [ABSTRACT FROM AUTHOR]

With the increasing proportion of renewable power generations in the power system, the power grid impedance may fluctuate greatly, and it is difficult for the virtual synchronous generator (VSG) with a single control structure to meet the stability requirements. Thus, the control principles of the two types of VSGs are compared to conclude that there are similarities in the control structure of the two VSGs. And the small signal models of the two types of VSGs are established to analyze the stability boundaries, coming to the conclusion that the stability region is complementary. Based on the conclusions, the paper puts forward the idea of switching operation modes: switch to the U‐VSG mode when the grid strength weakens and switch to the PQ‐VSG mode when greater, so that the inverter can keep stable in a wider range of grid strength. Therefore, the characterization method of the switching boundary with hysteresis properties is proposed. Then the improved recursive least squares (RLS) algorithm is introduced to identify the power grid impedance online without additional injected disturbance, based on which the adaptive multi‐mode smooth switching control strategy is proposed. Finally, the effectiveness of the analysis and the control strategy are verified by simulations. [ABSTRACT FROM AUTHOR]

High-energy lithium-ion batteries (LIBs) have been actively pursued for practical applications in advanced electric vehicles and large-scale energy storage systems. The silicon (Si) material has been considered as a promising anode candidate due to its impressive lithium storage capacity, but is facing the challenge to ameliorate its cycling and rate performance. We here report a structure integration strategy to overcome major issues of poor capacity retention and slow kinetics during the lithium storage of Si anode, through in situ embedding Si nanoparticles into V 2 C MXene nanosheets. The MXene-supported Si@V 2 C nanocomposite anode reveals significantly enhanced cycling stability and improved lithium storage kinetics compared to that of the pristine Si anode. A high capacity exceeding to 430 mAh g−1 can be retained for 150 cycles at 200 mA g−1 current density. In addition, the conductive MXene supporter has been demonstrated to facilitate lithiation/delithiation processes for the Si by enhancing the charge transfer kinetics, as it is demonstrated by in situ electrochemical impedance spectroscopic (EIS) and Galvanostatic Intermittent Titration Technique (GITT) measurements. Findings from this work may inspire feasible structural designs for the practical deployment of MXene composited Si anode materials for next-generation lithium-ion batteries. [Display omitted] • Si@V 2 C composite anode was explored using V 2 C MXene as supporting substrate with enhanced Si stability performance. • A high capacity of 430 mAh g−1 can be retained for 150 cycles at 200 mA g−1 current density. • The V 2 C MXene can provide improved electronic conductivity and structural support of the Si anode during cycling. [ABSTRACT FROM AUTHOR]

Comprehensive Summary: Ammonia (NH3) is one of the most important industrial feedstocks in the fields of fertilizers, drugs, explosives, ordnance, commercial cleanings, and so on. However, the features of ammonia such as high toxicity and corrosivity, and difficulty in handling would inevitably increase the risk of environmental damage and the deterioration of natural/public lands. Although sorts of solid adsorbents such as metal oxides, zeolites, organic polymers, activated carbons, and metal organic frameworks have been applied in NH3 capture, they still show low uptake capacity, low affinities, and instability. Herein, we developed the first case of a highly stable sulfuric acid covalent organic framework (COF), namely TpBD‐(SO3H)2, as NH3 capturer, in which sulfonic acid sites can strongly interact with NH3 molecules, and enhance the performance of NH3 sorption. As a result, TpBD‐(SO3H)2 shows high chemical stability under strong acid and water conditions, an important merit for the potential application in harsh environment. And it also exhibits high ammonia capacity of 11.5 mmol·g−1 at 298 K and 1.0 bar, making it one of the best in all chemically stable NH3 adsorbents up to date. This work thus develops sulfuric acid COF materials as a new platform for ammonia capture and storage. [ABSTRACT FROM AUTHOR]

Our study developed the one-step catalytic cracking conceptual design using a two-stage riser reactor (OSCO). Molecular-level process models and multi-objective optimization strategies are also carried out. Results show that the OSCO process exhibits superior techno-economic, society, people's livelihood, and environmental performance. [Display omitted] • A novel process is proposed to crack naphtha, kerosene, diesel and heavy oil in the two-stage riser reactor efficiently. • A novel integration model of mixed fraction structure and molecular level is proposed. • The multi-objective optimization strategies using systematic solution algorithm are performed. • The novel process shows superior techno-economic, society, people's livelihood, and environmental performance. With the demand for vehicle fuels (i.e., gasoline and diesel) is expected to decline soon, crude oil to chemical technology exhibits great potential to drive the next industry transition. This megatrend has led to studies on maximizing the production of low-carbon petrochemicals at the cost of fuels, which requires aggressive ways of converting oil into chemicals in a clean and efficient pattern. Herein, we proposed a novel process, termed OSCO, to crack naphtha, kerosene, diesel and heavy oil in a two-stage riser reactor efficiently, which can perform several refining procedures in the two-stage riser reactor vessel. A novel integration model of mixed fraction structure and molecular level is proposed. The multi-objective optimization strategies are also carried out to solve the optimization problem. As a result, the OSCO process can stably convert untreated heavy Daqing crude oil into light olefins with total yields of ethylene and propylene over 33 wt%, which also exhibits superior techno-economic, society, people's livelihood, and environmental performance. These insights may have a positive pushing role in engineering design, process intensification, and the optimization of direct catalytic cracking of crude oil. [ABSTRACT FROM AUTHOR]

Incompatible cross-platform detection technologies adopted for different medical scenarios has caused several problems in the clinical detection of disease biomarkers. Here, we developed a unified platform with hierarchical performance for biomarker detection. A hexagonal star-nanostructured DNAzyme was constructed. It shows excellent catalytic activity towards the deposition of polydopamine, which is capable of presenting colorimetric signals directly and is also scalable to present fluorescent and electrochemical signals by conjugating with quantum dots. This scalable detection system is validated for the detection of both nucleic acid biomarkers (miRNAs) and protein biomarkers (carcinoembryonic antigen and platelet-derived growth factor). Results show that the detection system can adapt to the current colorimetric, fluorescent and electrochemical equipment, possess the advantage of high efficiency and low-cost, and present hierarchical performance in terms of operability and sensitivity, making it possible to verify the results in a unified system and to switch the detection methods according to different scenarios. [Display omitted] • The unified platform showed excellent advantages in efficiency and cost of biomarker detection. • A nanostructured DNAzyme was constructed to realize efficient deposition of dopamine. • The scalable platform is validated for the detection of both nucleic acid and protein biomarkers. [ABSTRACT FROM AUTHOR]

Background: The development of diabetes vascular calcification (VC) is tightly associated with the inhibition of vascular smooth muscle cell (VSMC) autophagy. Previously, our team found that miR-32-5p (miR-32) promotes macrophage activation, and miR-32 is expressed at higher level in the plasma of patients with coronary calcification. However, whether miR-32 mediates the function of macrophages in type 2 diabetes (T2D) VC is still unclear.Methods: Wild-type (WT) and miR-32-/- mice were used in this study. qRT-PCR and western blotting were used to analyze gene expression. Flow cytometry was used to analyze the influence of glucose concentration on macrophage polarization. Nanoparticle tracking analysis (NTA), transmission electron microscopy, and confocal microscopy were used to identify macrophage extracellular vehicles (EVs). Immunofluorescence, in situ hybridization (ISH), immunohistochemistry, and alizarin red staining were used to analyze the influence of macrophage EVs on autophagy and calcification of the aorta of miR-32-/- mice. A luciferase assay was used to analyze the effect of miR-32 on myocyte enhancer factor 2D (Mef2d) expression. Co-IP combined with mass spectrometry (MS) and transcriptome sequencing was used to analyze the signalling pathway by which Mef2d acts in VSMC autophagy.Results: We found that high glucose conditions upregulate miR-32 expression in macrophages and their EVs. Importantly, macrophages and their EVs promote VSMC osteogenic differentiation and upregulate miR-32 expression in VSMCs. Moreover, miR-32 mimics transfection promoted osteogenic differentiation and inhibited autophagy in VSMCs. In vitro and in vivo experiments showed that Mef2d is the key target gene of miR-32 that inhibits VSMC autophagy. Furthermore, MS and transcriptome sequencing found that cGMP-PKG is an important signalling pathway by which Mef2d regulates VSMC autophagy. In addition, after T2D miR-32-/- mice were injected with macrophage EVs via the caudal vein, miR-32 was detected in aortic VSMCs of miR-32-/- mice. Moreover, autophagy was significantly inhibited, and calcification was significantly enhanced in aorta cells.Conclusions: These results reveal that EVs are the key pathway by which macrophages promote T2D VC, and that EVs miR-32 is a key cause of autophagy inhibition in VSMCs. [ABSTRACT FROM AUTHOR]

Soil moisture (SM) is an important land-surface parameter. Although microwave remote sensing is recognized as one of the most appropriate methods for retrieving SM, such retrievals often cannot meet the requirements of specific applications because of their coarse spatial resolution and spatiotemporal data gaps. A range of general models (GMs) for SM analysis topics (e.g., gap-filling, forecasting, and downscaling) have been introduced to address these shortcomings. This work presents a novel strategy (i.e., optimized wavelet-coupled fitting method (OWCM)) to enhance the fitting accuracy of GMs by introducing a wavelet transform (WT) technique. Four separate GMs are selected, i.e., elastic network regression, area-to-area regression kriging, random forest regression, and neural network regression. The fitting procedures are then tested within a downscaling analysis implemented between aggregated Global Land Surface Satellite products (i.e., LAI, FVC, albedo), Thermal and Reanalysis Integrating Medium-resolution Spatial-seamless LST, and Random Forest Soil Moisture (RFSM) datasets in both the WT space and the regular space. Then, eight fine-resolution SM datasets mapped from the trained GMs and OWCMs are analyzed using direct comparisons with in situ SM measurements and indirect intercomparisons between the aggregated OWCM-/GM-derived SM and RFSM. The results demonstrate that OWCM-derived SM products are generally closer to the in situ SM observations, and better capture in situ SM dynamics during the unfrozen season, compared to the corresponding GM-derived SM product, which shows fewer time changes and more stable trends. Moreover, OWCM-derived SM products represent a significant improvement over corresponding GM-derived SM products in terms of their ability to spatially and temporally match RFSM. Although spatial heterogeneity still substantially impacts the fitting accuracies of both GM and OWCM SM products, the improvements of OWCMs over GMs are significant. This improvement can likely be attributed to the fitting procedure of OWCMs implemented in the WT space, which better captures high- and low-frequency image features than in the regular space. [ABSTRACT FROM AUTHOR]

The concentration of uranium in the rock sample was 35.0 μg/g, the concentration ratio of CO2 and O2 injected was 1:1, the autoclaves pressure was 0.02 MPa. The uranium leaching rate varied from 28.70 to 37.97%, and when the concentration of HCO3− is lower, the output rate of U is significantly increased as it increases, when its concentration exceeds the threshold value, U’s output concentration is no longer infinitely increased. Calcite and dolomite were saturated and precipitated during the leaching process due to the high initial pH; with the injection of CO2, calcite and dolomite remained near- or under-saturated and did not precipitate. [ABSTRACT FROM AUTHOR]

[Display omitted] • A rational coating-integrated-into-synthesis design was used to prepare surface Ti-enriched NMC811 material. • The Ti substitute has a unique tri-valence (Ti3+) in a gradient surface distribution. • The surface Ti-enriched NMC811has high cationic ordering both in the bulk and surface. • Theoretical simulations certify enhanced stability of lattice oxygen for the NMC811#Ti material. • The NMC811#Ti cathode shows improved cycling performance and thermal/ storage stabilities. High-Ni cathodes are being intensely pursued worldwide for electric vehicles and other energy-dense applications due to their high capacity and low cost. However, structural instabilities during electrochemical cycling and when subjected to thermal treatment have been the major issues hindering their practical deployment. We here report a rational design of coating-integrated-into-synthesis protocol for fabricating surface Ti-enriched LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811#Ti) material. The coating to intermediates is crucial to obtain high structural ordering, both in the bulk and surface of high-Ni cathodes, and the Ti substitute has a unique tri-valence (Ti3+) in a gradient surface distribution. The simulations of projected density of states in the atomistic understanding further certify significantly enhanced stability of lattice oxygen for the NMC811 through such a Ti3+-based structure reinforcement. Consequently, the NMC811#Ti cathode delivers a high capacity up to 200 mAh g−1 at 0.1 C, along with superior stabilities during air-storage and thermal treatment (up to 297 °C at the fully charged state under differential scanning calorimetric measurements). The corresponding NMC811#Ti||graphite full cell exhibits a desired 83.6 % capacity retention after 1000 cycles at 0.5 C in a voltage range of 2.8–4.3 V. This work demonstrates a delicate surface reinforcement to stabilize high-Ni cathodes for long-life and safe lithium-ion batteries. [ABSTRACT FROM AUTHOR]

Li‐ion hybrid supercapacitors (LHSCs) are intensely studied due to their favorable power densities. However, combined higher energy density materials, particularly anodes, are desirably sought. Herein, a defect‐dominating structure protocol is reported. Specifically, two visible structural defects, i.e., crystal vacancy and lattice distortion have been introduced in situ in ultrafine niobium nitride (NbN) monocrystals that are integrated into a carbon (C) framework. Highly reversible Li‐ion storage capacities up to 540 mAh g−1 are demonstrated in such a NbN@C composite anode, together with excellent rate capability and cycling stability. An extra vacancy‐induced capacity contribution of the defective NbN component is evidenced by first‐principles density functional theory (DFT) simulations in contrast to perfect modeling. Coupling with an activated carbon (AC) cathode, the NbN@C//AC cell can deliver balanced energy and power densities of 53.8 Wh kg−1 and 7818 W kg−1 at 4 A g−1, and retain a desired energy density of 56.1 Wh kg−1 after 10 000 cycles at 1 A g−1. Findings from this study, particularly the demonstrated defects‐induced extra capacity of pseudocapacitive materials, may inspire new structural material designs of LHSCs. [ABSTRACT FROM AUTHOR]

Rapid urbanization has brought about many problems in urban environments, including the deterioration of the thermal environment, which greatly affects the sustainable development of cities and the health of urban residents. Therefore, a comprehensive and thorough study of the thermal environment is necessary. In this study, quantitative and qualitative analyses of the interannual and seasonal variation of the thermal environment in the urban area of Chongqing were conducted using a combination of equal sector analysis, mathematical statistics, and principal component analysis. In addition, the mechanism by which multiple integrated human and natural factors affect the urban thermal environment in different seasons was explored. The thermal environment of the land surface has a clear spatial correlation with built-up areas. From 2010 to 2020, the Liangjiang New Area and the western high-tech zone were the main areas of thermal environment area expansion. From 2010 to 2020, a decrease in the area of low-temperature zones and an increase in the area of high-temperature zones were the main trends. In particular, during the summer of 2020, the low-temperature zones almost disappeared, and the area of high-temperature zones was nearly twice as large as in the other seasons. The combined influence of multiple factors on surface temperature has certain seasonal characteristics. The slope, elevation, normalized water body index, fractional vegetation cover, normalized imperviousness index, and nighttime light intensity were the main factors affecting the surface temperature, whereas landscape pattern indicators, as well as the population and points of interest (POI) density, had a low influence. The strength of the combined influence of these multiple factors of the different seasons exhibited the following order: winter > spring > summer > autumn. [ABSTRACT FROM AUTHOR]

[Display omitted] • Novel, potent and effective EZH2 degraders were developed. • Compound P4 can effectively induce EZH2 protein degradation and inhibit breast cancer cell growth. • Compound P4 can significantly decrease the degree of H3K27me3 in MDA-MB-231 cell line, induce apoptosis and G 0 /G 1 phase arrest in Pfeiffer and MDA-MB-231 cell lines. • Compound P4 significantly inhibited the migratory and invasive capacity of MDA-MB-231 cells at micromolar concentrations in a dose-dependent manner. • Adequate metabolic stability in vitro. EZH2 (enhancer of zeste homolog 2) is one of the most important histone methyltransferases (HMTs), and overexpression of EZH2 can lead to proliferation, migration and angiogenesis of tumor cells. But most of EZH2 inhibitors are only effective against some hematologic malignancies and have poor efficacy against solid tumors. Here, we report the design, synthesis, and evaluation of highly potent proteolysis targeting chimeric (PROTACs) small molecules targeting EZH2. We developed a potent and effective EZH2 degrader P4 , which effectively induced EZH2 protein degradation and inhibited breast cancer cell growth. Further studies showed that P4 can significantly decrease the degree of H3K27me3 in MDA-MB-231 cell line, induce apoptosis and G 0 /G 1 phase arrest in Pfeiffer and MDA-MB-231 cell lines. Therefore, P4 is a potential anticancer molecule for breast cancer treatment. [ABSTRACT FROM AUTHOR]

Here, four normalized difference water index (NDWI) variants, i.e., NDWI(860,970), NDWI(860,1240), NDWI(860,1640), and NDWI(1240,1640) are generated from the corn-oriented PROSAIL radiative transfer model. It is found that, instead of the linear relationship derived in previous studies, corn canopy water content (CWC) is best approximated as an exponential function of NDWI. Following the analysis of the PROSAIL-generated results, a newly optimized NDWI-based scheme is proposed for estimating corn CWC according to variations in the performance of the four NDWI variants under different CWC conditions. Validation results based on independent field data from the SMEX02, HiWATER2012, and Baoding2018 field experiments verify that this optimized NDWI-based corn CWC estimating scheme has a higher accuracy ($R = 0.87\,\,\pm \,\,0.03$ , RMSE = 0.2068 ± 0.0145 kg/m2) than existing NDWI-based strategies for corn CWC retrieval. The feasibility of retrieving corn vegetation water content (VWC) based on the optimized NDWI-based scheme is also investigated, and the superiority of the optimized NDWI-based scheme for retrieving corn VWC is assessed. By comparing with four other NDWI-based corn VWC estimating methods, as well as the corn VWC parameterization scheme applied in the SMAP soil moisture algorithm, it is shown that our optimized NDWI-based scheme has the best VWC estimation accuracy, with the highest $R$ of 0.89 ± 0.02 and the lowest RMSE of 0.7179 ± 0.0555 kg/m2. [ABSTRACT FROM AUTHOR]

Deformable thermoelectrics have great potential in self‐powered flexible or hetero‐shaped electronics. The exceptional room‐temperature plasticity recently discovered in several inorganic semiconductors makes it possible to develop new thermoelectric (TE) materials with both high performance and intrinsic deformability. Nonetheless, all the known plastic or ductile TE materials are n‐type semiconductors. It is urgent to explore p‐type counterparts for device design and fabrication. In this study, the first p‐type plastic inorganic TE material is reported. Via alloying Cu in n‐type plastic Ag2S0.7Se0.3 to modulate the charged crystal defects, (Ag1−xCux)2S0.7Se0.3 (x = 0.7–0.8) can simultaneously realize good plasticity and p‐type conduction. Particularly, (Ag0.2Cu0.8)2S0.7Se0.3 with a hexagonal structure shows a maximum zT of 0.42 at 800 K. Via the introduction of Cu deficiencies, the good plasticity is well maintained while the maximum zT is greatly enhanced to 0.95 at 800 K, a record‐high value for plastic TE materials. This study is expected to accelerate the development of plastic TE semiconductors and full‐inorganic deformable TE devices for the application in hetero‐shaped power generators. [ABSTRACT FROM AUTHOR]

The environmental pollution caused by waste plastics and their potential of resource recovery are receiving increasing attention. In this study, a molecular level kinetic model was established to simulate the polypropylene pyrolysis based on the SOL method, Poisson distribution model and genetic algorithm, which was simplified and effective without the introduction of extensive chemical databases and stiff differential equations. The automatic generation of complex reaction network was based on the representation of species and reactions at molecular level and the design of 14 reaction rules consistent with the mechanism. The model prediction achieved good agreement with experimental data affected by the primary and secondary reactions, verifying the generalizability of the models. The model prediction according to the kinetic parameters provided guidance for the pyrolysis experiments. In general, the molecular-level model behaves exquisite in the evaluation, validation, and prediction, and can gain an insight into the pyrolysis of polymers. • A molecular level kinetic model with automatic reaction network generation is established for polypropylene pyrolysis. • The automatic network generation is based on the Poisson distribution model, the SOL method and the design of reaction rules. • This model achieves excellent agreement with experimental data and can predict pyrolysis performance in more details. • The important role of temperature on the pyrolysis and the competition of two scissions are quantified by this model. [ABSTRACT FROM AUTHOR]

[Display omitted] • The I 2 nanotraps were used by introducing adjacent IBSs and LBSs on the skeleton. • The absorbent shows high I 2 uptake capacity (37 wt%) among all COF materials. • IBSs and LBSs synergistically promote iodine adsorption. Covalent organic frameworks have been recognized as promising porous materials for the radioactive iodine capture. However, most COFs often suffer from low adsorption capacity under practical conditions (typically ≥ 150 °C, ≤ 150 ppmv I 2) due to the lack of strong binding sites and low affinity toward iodine, which restricts their application in industrial relevant conditions. Here, we develop a strategy of constructing highly efficient I 2 nanotraps by manipulating two kinds of adsorption sites (ionic binding sites and Lewis binding sites) located at adjacent spatial positions, thereby realizing the synergistic binding toward I 2. The obtained I 2 nanotrap 4F-iCOF-TpBpy-I- delivers a remarkable I 2 uptake capacity of 37 wt% at 150 °C and 150 ppmv of I 2 , which illustrate a record-high value for all COFs reported so far. This work opens a new avenue for the rational design of COF materials toward highly efficient I 2 capture and related application. [ABSTRACT FROM AUTHOR]

α-MgAgSb is considered as a potential near-room-temperature thermoelectric material in virtue of its excellent electrical properties, ultralow lattice thermal conductivity and abundant constituent elements. However, it is hard to obtain high-quality phase pure α-MgAgSb due to its complex phase transition and high reactivity of element Mg, which cloaks material's intrinsic thermoelectric performance. Herein, through adopting a tantalum-sealing melting technique, we achieved highly-quality pure α-MgAgSb with large grain size and less oxygen content, as compared with our ball milled samples. The as-synthesized tantalum-sealing melted α-MgAgSb, without element doping or alloying, exhibited intrinsically low thermal conductivity, large weighted mobility, and high carrier concentration closes to the optimum range. Eventually, we attained a maximum thermoelectric figure of merit zT value of 1.3 at around 500 K in the tantalum-sealing melted α-MgAgSb. The average power factors and average zT values are also as high as 25 μW cm−1 K−2 and 1.1 respectively in the low-temperature range of (300 - 550) K, both of which rank as top values among the known materials. This study not only sheds new light on the understanding of intrinsic properties of α-MgAgSb but also demonstrates its great promise for harvesting low-grade waste heat. Record-high average power factor of 25 μW cm−1 K−2 and average zT of 1.1 were achieved in the melted α-MgAgSb sythesized by the tantalum-sealing melting technique. [Display omitted] [ABSTRACT FROM AUTHOR]

Urban impervious surfaces area (ISA) and green space (GS), two primary components of urban environment, are pivotal in detecting urban environmental quality and addressing global environmental change issues. However, the current global mapping of ISA and GS is not effective enough to accurately delineate in urban areas due to the mosaicked and complex structure. To address the issue, the hierarchical architecture principle and subpixel metric method were applied to map 30 m global urban ISA and GS fractions for the years 2015 and circa 2020. We use random forest algorithms for retrieval of the Normalized Settlement Density Index and Normalized Green Space Index from Landsat images using Google Earth Engine. The correlation coefficients of global urban ISA and GS fractions were all higher than 0.9 for 2015 and circa 2020. Our results show global urban ISA and GS areas in circa 2020 were 31.19 × 104 km2 and 17.16 × 104 km2, respectively. The novel ISA and GS fractions product can show potential applications in assessing the effects of urbanization on climate, ecology, and urban sustainability. [ABSTRACT FROM AUTHOR]

Keywords: defect engineering; flexible electronics; plastic inorganic semiconductors; thermoelectrics EN defect engineering flexible electronics plastic inorganic semiconductors thermoelectrics 1 1 1 06/21/21 20210617 NES 210617 In article number 2100883, Pengfei Qiu, Tian-Ran Wei, Xun Shi, and co-workers develop the first p-type plastic inorganic thermoelectric material. Thermoelectrics: p-Type Plastic Inorganic Thermoelectric Materials (Adv. Defect engineering, flexible electronics, plastic inorganic semiconductors, thermoelectrics. [Extracted from the article]