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The Southern Indian Ocean is a major reservoir for rapid carbon exchange with the atmosphere, plays a key role in the world’s carbon cycle. To understand the importance of anthropogenic CO2 uptake in the Southern Indian Ocean, a variety of methods have been used to quantify the magnitude of the CO2 flux between air and sea. The basic approach is based on the bulk formula—the air-sea CO2 flux is commonly calculated by the difference in the CO2 partial pressure between the ocean and the atmosphere, the gas transfer velocity, the surface wind speed, and the CO2 solubility in seawater. However, relying solely on wind speed to measure the gas transfer velocity at the sea surface increases the uncertainty of CO2 flux estimation. Recent studies have shown that the generation and breaking of ocean waves also significantly affect the gas transfer process at the air-sea interface. In this study, we highlight the impact of windseas on the process of air-sea CO2 exchange and address its important role in CO2 uptake in the Southern Indian Ocean. We run the WAVEWATCH III model to simulate surface waves in this region over the period from January 1st 2002 to December 31st 2021. Then, we use the spectral partitioning method to isolate windseas and swells from total wave fields. Finally, we calculate the CO2 flux based on the new semiempirical equation for gas transfer velocity considering only windseas. We found that after considering windseas’ impact, the seasonal mean zonal flux (mmol/m2·d) increased approximately 10%-20% compared with that calculated solely on wind speed in all seasons. Evolution of air-sea net carbon flux (PgC) increased around 5.87%-32.12% in the latest 5 years with the most significant seasonal improvement appeared in summer. Long-term trend analysis also indicated that the CO2 absorption capacity of the whole Southern Indian Ocean gradually increased during the past 20 years. These findings extend the understanding of the roles of the Southern Indian Ocean i

The Southern Indian Ocean is a major reservoir for rapid carbon exchange with the atmosphere, plays a key role in the world’s carbon cycle. To understand the importance of anthropogenic CO2 uptake in the Southern Indian Ocean, a variety of methods have been used to quantify the magnitude of the CO2 flux between air and sea. The basic approach is based on the bulk formula—the air-sea CO2 flux is commonly calculated by the difference in the CO2 partial pressure between the ocean and the atmosphere, the gas transfer velocity, the surface wind speed, and the CO2 solubility in seawater. However, relying solely on wind speed to measure the gas transfer velocity at the sea surface increases the uncertainty of CO2 flux estimation. Recent studies have shown that the generation and breaking of ocean waves also significantly affect the gas transfer process at the air-sea interface. In this study, we highlight the impact of windseas on the process of air-sea CO2 exchange and address its important role in CO2 uptake in the Southern Indian Ocean. We run the WAVEWATCH III model to simulate surface waves in this region over the period from January 1st 2002 to December 31st 2021. Then, we use the spectral partitioning method to isolate windseas and swells from total wave fields. Finally, we calculate the CO2 flux based on the new semiempirical equation for gas transfer velocity considering only windseas. We found that after considering windseas’ impact, the seasonal mean zonal flux (mmol/m2·d) increased approximately 10%-20% compared with that calculated solely on wind speed in all seasons. Evolution of air-sea net carbon flux (PgC) increased around 5.87%-32.12% in the latest 5 years with the most significant seasonal improvement appeared in summer. Long-term trend analysis also indicated that the CO2 absorption capacity of the whole Southern Indian Ocean gradually increased during the past 20 years. These findings extend the understanding of the roles of the Southern Indian Ocean i

© The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fairall, C. W. W., Yang, M., Brumer, S. E. E., Blomquist, B. W. W., Edson, J. B. B., Zappa, C. J. J., Bariteau, L., Pezoa, S., Bell, T. G. G., & Saltzman, E. S. S. Air-Sea trace gas fluxes: direct and indirect measurements. Frontiers in Marine Science, 9, (2022): 826606, https://doi.org/10.3389/fmars.2022.826606., The past decade has seen significant technological advance in the observation of trace gas fluxes over the open ocean, most notably CO2, but also an impressive list of other gases. Here we will emphasize flux observations from the air-side of the interface including both turbulent covariance (direct) and surface-layer similarity-based (indirect) bulk transfer velocity methods. Most applications of direct covariance observations have been from ships but recently work has intensified on buoy-based implementation. The principal use of direct methods is to quantify empirical coefficients in bulk estimates of the gas transfer velocity. Advances in direct measurements and some recent field programs that capture a considerable range of conditions with wind speeds exceeding 20 ms-1 are discussed. We use coincident direct flux measurements of CO2 and dimethylsulfide (DMS) to infer the scaling of interfacial viscous and bubble-mediated (whitecap driven) gas transfer mechanisms. This analysis suggests modest chemical enhancement of CO2 flux at low wind speed. We include some updates to the theoretical structure of bulk parameterizations (including chemical enhancement) as framed in the COAREG gas transfer algorithm., This work, and the contributions of MY and TB, is supported by the UK Natural Environment Research Council’s ORCHESTRA (Grant No. NE/N018095/1) and PICCOLO (Grant No. NE/P021409/1) projects, and by the European Space Agency’s AMT4OceanSatFlux project (Grant No. 4000125730/18/NL/FF/gp). CF and BB are funded by the National Oceanic and Atmospheric Administration’s Global Ocean Monitoring and Observing program (http://data.crossref.org/fundingdata/funder/10.13039/100018302). CZ was funded by the National Science Foundation (CJZ: OCE-2049579, Grants OCE-1537890 and OCE-1923935). Funding for HiWinGS was provided by the US National Science Foundation grant AGS-1036062. The Knorr-11 and SOAP campaigns were supported by the NSF Atmospheric Chemistry Program (Grant No. ATM-0426314, AGS-08568, -0851472, -0851407 and -1143709).

© The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fairall, C. W. W., Yang, M., Brumer, S. E. E., Blomquist, B. W. W., Edson, J. B. B., Zappa, C. J. J., Bariteau, L., Pezoa, S., Bell, T. G. G., & Saltzman, E. S. S. Air-Sea trace gas fluxes: direct and indirect measurements. Frontiers in Marine Science, 9, (2022): 826606, https://doi.org/10.3389/fmars.2022.826606., The past decade has seen significant technological advance in the observation of trace gas fluxes over the open ocean, most notably CO2, but also an impressive list of other gases. Here we will emphasize flux observations from the air-side of the interface including both turbulent covariance (direct) and surface-layer similarity-based (indirect) bulk transfer velocity methods. Most applications of direct covariance observations have been from ships but recently work has intensified on buoy-based implementation. The principal use of direct methods is to quantify empirical coefficients in bulk estimates of the gas transfer velocity. Advances in direct measurements and some recent field programs that capture a considerable range of conditions with wind speeds exceeding 20 ms-1 are discussed. We use coincident direct flux measurements of CO2 and dimethylsulfide (DMS) to infer the scaling of interfacial viscous and bubble-mediated (whitecap driven) gas transfer mechanisms. This analysis suggests modest chemical enhancement of CO2 flux at low wind speed. We include some updates to the theoretical structure of bulk parameterizations (including chemical enhancement) as framed in the COAREG gas transfer algorithm., This work, and the contributions of MY and TB, is supported by the UK Natural Environment Research Council’s ORCHESTRA (Grant No. NE/N018095/1) and PICCOLO (Grant No. NE/P021409/1) projects, and by the European Space Agency’s AMT4OceanSatFlux project (Grant No. 4000125730/18/NL/FF/gp). CF and BB are funded by the National Oceanic and Atmospheric Administration’s Global Ocean Monitoring and Observing program (http://data.crossref.org/fundingdata/funder/10.13039/100018302). CZ was funded by the National Science Foundation (CJZ: OCE-2049579, Grants OCE-1537890 and OCE-1923935). Funding for HiWinGS was provided by the US National Science Foundation grant AGS-1036062. The Knorr-11 and SOAP campaigns were supported by the NSF Atmospheric Chemistry Program (Grant No. ATM-0426314, AGS-08568, -0851472, -0851407 and -1143709).

The past decade has seen significant technological advance in the observation of trace gas fluxes over the open ocean, most notably CO2, but also an impressive list of other gases. Here we will emphasize flux observations from the air-side of the interface including both turbulent covariance (direct) and surface-layer similarity-based (indirect) bulk transfer velocity methods. Most applications of direct covariance observations have been from ships but recently work has intensified on buoy-based implementation. The principal use of direct methods is to quantify empirical coefficients in bulk estimates of the gas transfer velocity. Advances in direct measurements and some recent field programs that capture a considerable range of conditions with wind speeds exceeding 20 ms-1 are discussed. We use coincident direct flux measurements of CO2 and dimethylsulfide (DMS) to infer the scaling of interfacial viscous and bubble-mediated (whitecap driven) gas transfer mechanisms. This analysis suggests modest chemical enhancement of CO2 flux at low wind speed. We include some updates to the theoretical structure of bulk parameterizations (including chemical enhancement) as framed in the COAREG gas transfer algorithm.

Reducing uncertainties in the air–sea CO2 flux calculations is one of the major challenges when addressing the oceanic contribution in the global carbon balance. In traditional models, the air–sea CO2 flux is estimated using expressions of the gas transfer velocity as a function of wind speed. However, other mechanisms affecting the variability in the flux at local and regional scales are still poorly understood. The uncertainties associated with the flux estimates become particularly large in heterogeneous environments such as coastal and marginal seas. Here, we investigated the air–sea CO2 exchange at a coastal site in the central Baltic Sea using nine years of eddy covariance measurements. Based on these observations we were able to capture the temporal variability of the air–sea CO2 flux and other parameters relevant for the gas exchange. Our results show that a wind-based model with similar pattern to those developed for larger basins and open sea condition can, on average, be a good approximation for k. However, in order to reduce the uncertainty associated to these averages and produce reliable short-term k estimates, additional physical processes must be considered. Using a normalized gas transfer velocity, we identified conditions associated to enhanced exchange (large k values). During high and intermediate wind speeds (above 6–8 m s−1),conditions on both sides of the air–water interface were found to be relevant for the gas exchange. Our findings further suggest that at such relatively high wind speeds, sea spray is an efficient mechanisms for air–sea CO2 exchange. During low wind speeds (<6 m s−1), water-side convection was found to be a relevant control mechanism. The effect of both sea spray and water-side convection on the gas exchange showed a clear seasonality with positive fluxes (winter conditions) being the most affected.

Carbon is essential to the Earth’s system functioning, playing a major role in physical and biogeochemical processes in the atmosphere, the terrestrial biosphere, and the oceans. The concentration of carbon-based greenhouse gases in the atmosphere, such as carbon dioxide (CO2) and methane (CH4), has been increasing since the industrial era. Therefore, assessing the redistribution of these greenhouse gases between the Earth’s reservoirs has become essential for understanding the current climate system and modelling future climate scenarios. The oceans are a component of the global carbon cycle, and their role as sinks and sources of greenhouse gases has significant implications for the Earth’s climate. The gas exchange between the atmosphere and the ocean is driven by the concentration difference in these two reservoirs. However, the turbulent processes in the layers adjacent to the ocean surface control the efficiency of the transport. This thesis investigates mechanisms controlling the air–sea gas exchange using direct measurements of CO2 and CH4 fluxes from the Östergarnsholm station in the Central Baltic Sea. The gas exchange of both gases is found to have a strong variability at time scales from sub-hourly to inter-annual. The region is found to be a net source of CH4, with both the concentration gradient and wind as controlling mechanisms. In the case of the CO2 fluxes, the variability is strongly modulated by local processes such as sea spray and water-side convection, as well as precipitation. Interestingly, an asymmetric effect is observed, with these processes enhancing the upward transport of CO2 but not the downward flux. Furthermore, a model-based sensitivity analysis of the gas transfer velocity is performed to evaluate the effect of the forcing mechanisms on the air-sea gas exchange at a regional scale. The results show that water-side convection, precipitation, and surfactants strongly modulate the spatio-temporal variability of the CO2 fluxes in the, BONUS INTEGRAL Project

Carbon is essential to the Earth’s system functioning, playing a major role in physical and biogeochemical processes in the atmosphere, the terrestrial biosphere, and the oceans. The concentration of carbon-based greenhouse gases in the atmosphere, such as carbon dioxide (CO2) and methane (CH4), has been increasing since the industrial era. Therefore, assessing the redistribution of these greenhouse gases between the Earth’s reservoirs has become essential for understanding the current climate system and modelling future climate scenarios. The oceans are a component of the global carbon cycle, and their role as sinks and sources of greenhouse gases has significant implications for the Earth’s climate. The gas exchange between the atmosphere and the ocean is driven by the concentration difference in these two reservoirs. However, the turbulent processes in the layers adjacent to the ocean surface control the efficiency of the transport. This thesis investigates mechanisms controlling the air–sea gas exchange using direct measurements of CO2 and CH4 fluxes from the Östergarnsholm station in the Central Baltic Sea. The gas exchange of both gases is found to have a strong variability at time scales from sub-hourly to inter-annual. The region is found to be a net source of CH4, with both the concentration gradient and wind as controlling mechanisms. In the case of the CO2 fluxes, the variability is strongly modulated by local processes such as sea spray and water-side convection, as well as precipitation. Interestingly, an asymmetric effect is observed, with these processes enhancing the upward transport of CO2 but not the downward flux. Furthermore, a model-based sensitivity analysis of the gas transfer velocity is performed to evaluate the effect of the forcing mechanisms on the air-sea gas exchange at a regional scale. The results show that water-side convection, precipitation, and surfactants strongly modulate the spatio-temporal variability of the CO2 fluxes in the, BONUS INTEGRAL Project

Carbon is essential to the Earth’s system functioning, playing a major role in physical and biogeochemical processes in the atmosphere, the terrestrial biosphere, and the oceans. The concentration of carbon-based greenhouse gases in the atmosphere, such as carbon dioxide (CO2) and methane (CH4), has been increasing since the industrial era. Therefore, assessing the redistribution of these greenhouse gases between the Earth’s reservoirs has become essential for understanding the current climate system and modelling future climate scenarios. The oceans are a component of the global carbon cycle, and their role as sinks and sources of greenhouse gases has significant implications for the Earth’s climate. The gas exchange between the atmosphere and the ocean is driven by the concentration difference in these two reservoirs. However, the turbulent processes in the layers adjacent to the ocean surface control the efficiency of the transport. This thesis investigates mechanisms controlling the air–sea gas exchange using direct measurements of CO2 and CH4 fluxes from the Östergarnsholm station in the Central Baltic Sea. The gas exchange of both gases is found to have a strong variability at time scales from sub-hourly to inter-annual. The region is found to be a net source of CH4, with both the concentration gradient and wind as controlling mechanisms. In the case of the CO2 fluxes, the variability is strongly modulated by local processes such as sea spray and water-side convection, as well as precipitation. Interestingly, an asymmetric effect is observed, with these processes enhancing the upward transport of CO2 but not the downward flux. Furthermore, a model-based sensitivity analysis of the gas transfer velocity is performed to evaluate the effect of the forcing mechanisms on the air-sea gas exchange at a regional scale. The results show that water-side convection, precipitation, and surfactants strongly modulate the spatio-temporal variability of the CO2 fluxes in the, BONUS INTEGRAL Project

Carbon is essential to the Earth’s system functioning, playing a major role in physical and biogeochemical processes in the atmosphere, the terrestrial biosphere, and the oceans. The concentration of carbon-based greenhouse gases in the atmosphere, such as carbon dioxide (CO2) and methane (CH4), has been increasing since the industrial era. Therefore, assessing the redistribution of these greenhouse gases between the Earth’s reservoirs has become essential for understanding the current climate system and modelling future climate scenarios. The oceans are a component of the global carbon cycle, and their role as sinks and sources of greenhouse gases has significant implications for the Earth’s climate. The gas exchange between the atmosphere and the ocean is driven by the concentration difference in these two reservoirs. However, the turbulent processes in the layers adjacent to the ocean surface control the efficiency of the transport. This thesis investigates mechanisms controlling the air–sea gas exchange using direct measurements of CO2 and CH4 fluxes from the Östergarnsholm station in the Central Baltic Sea. The gas exchange of both gases is found to have a strong variability at time scales from sub-hourly to inter-annual. The region is found to be a net source of CH4, with both the concentration gradient and wind as controlling mechanisms. In the case of the CO2 fluxes, the variability is strongly modulated by local processes such as sea spray and water-side convection, as well as precipitation. Interestingly, an asymmetric effect is observed, with these processes enhancing the upward transport of CO2 but not the downward flux. Furthermore, a model-based sensitivity analysis of the gas transfer velocity is performed to evaluate the effect of the forcing mechanisms on the air-sea gas exchange at a regional scale. The results show that water-side convection, precipitation, and surfactants strongly modulate the spatio-temporal variability of the CO2 fluxes in the, BONUS INTEGRAL Project

Reducing uncertainties in the air–sea CO2 flux calculations is one of the major challenges when addressing the oceanic contribution in the global carbon balance. In traditional models, the air–sea CO2 flux is estimated using expressions of the gas transfer velocity as a function of wind speed. However, other mechanisms affecting the variability in the flux at local and regional scales are still poorly understood. The uncertainties associated with the flux estimates become particularly large in heterogeneous environments such as coastal and marginal seas. Here, we investigated the air–sea CO2 exchange at a coastal site in the central Baltic Sea using nine years of eddy covariance measurements. Based on these observations we were able to capture the temporal variability of the air–sea CO2 flux and other parameters relevant for the gas exchange. Our results show that a wind-based model with similar pattern to those developed for larger basins and open sea condition can, on average, be a good approximation for k. However, in order to reduce the uncertainty associated to these averages and produce reliable short-term k estimates, additional physical processes must be considered. Using a normalized gas transfer velocity, we identified conditions associated to enhanced exchange (large k values). During high and intermediate wind speeds (above 6–8 m s−1),conditions on both sides of the air–water interface were found to be relevant for the gas exchange. Our findings further suggest that at such relatively high wind speeds, sea spray is an efficient mechanisms for air–sea CO2 exchange. During low wind speeds (<6 m s−1), water-side convection was found to be a relevant control mechanism. The effect of both sea spray and water-side convection on the gas exchange showed a clear seasonality with positive fluxes (winter conditions) being the most affected.

Carbon is essential to the Earth’s system functioning, playing a major role in physical and biogeochemical processes in the atmosphere, the terrestrial biosphere, and the oceans. The concentration of carbon-based greenhouse gases in the atmosphere, such as carbon dioxide (CO2) and methane (CH4), has been increasing since the industrial era. Therefore, assessing the redistribution of these greenhouse gases between the Earth’s reservoirs has become essential for understanding the current climate system and modelling future climate scenarios. The oceans are a component of the global carbon cycle, and their role as sinks and sources of greenhouse gases has significant implications for the Earth’s climate. The gas exchange between the atmosphere and the ocean is driven by the concentration difference in these two reservoirs. However, the turbulent processes in the layers adjacent to the ocean surface control the efficiency of the transport. This thesis investigates mechanisms controlling the air–sea gas exchange using direct measurements of CO2 and CH4 fluxes from the Östergarnsholm station in the Central Baltic Sea. The gas exchange of both gases is found to have a strong variability at time scales from sub-hourly to inter-annual. The region is found to be a net source of CH4, with both the concentration gradient and wind as controlling mechanisms. In the case of the CO2 fluxes, the variability is strongly modulated by local processes such as sea spray and water-side convection, as well as precipitation. Interestingly, an asymmetric effect is observed, with these processes enhancing the upward transport of CO2 but not the downward flux. Furthermore, a model-based sensitivity analysis of the gas transfer velocity is performed to evaluate the effect of the forcing mechanisms on the air-sea gas exchange at a regional scale. The results show that water-side convection, precipitation, and surfactants strongly modulate the spatio-temporal variability of the CO2 fluxes in the, BONUS INTEGRAL Project

Reducing uncertainties in the air–sea CO2 flux calculations is one of the major challenges when addressing the oceanic contribution in the global carbon balance. In traditional models, the air–sea CO2 flux is estimated using expressions of the gas transfer velocity as a function of wind speed. However, other mechanisms affecting the variability in the flux at local and regional scales are still poorly understood. The uncertainties associated with the flux estimates become particularly large in heterogeneous environments such as coastal and marginal seas. Here, we investigated the air–sea CO2 exchange at a coastal site in the central Baltic Sea using nine years of eddy covariance measurements. Based on these observations we were able to capture the temporal variability of the air–sea CO2 flux and other parameters relevant for the gas exchange. Our results show that a wind-based model with similar pattern to those developed for larger basins and open sea condition can, on average, be a good approximation for k. However, in order to reduce the uncertainty associated to these averages and produce reliable short-term k estimates, additional physical processes must be considered. Using a normalized gas transfer velocity, we identified conditions associated to enhanced exchange (large k values). During high and intermediate wind speeds (above 6–8 m s−1),conditions on both sides of the air–water interface were found to be relevant for the gas exchange. Our findings further suggest that at such relatively high wind speeds, sea spray is an efficient mechanisms for air–sea CO2 exchange. During low wind speeds (<6 m s−1), water-side convection was found to be a relevant control mechanism. The effect of both sea spray and water-side convection on the gas exchange showed a clear seasonality with positive fluxes (winter conditions) being the most affected.

Reducing uncertainties in the air–sea CO2 flux calculations is one of the major challenges when addressing the oceanic contribution in the global carbon balance. In traditional models, the air–sea CO2 flux is estimated using expressions of the gas transfer velocity as a function of wind speed. However, other mechanisms affecting the variability in the flux at local and regional scales are still poorly understood. The uncertainties associated with the flux estimates become particularly large in heterogeneous environments such as coastal and marginal seas. Here, we investigated the air–sea CO2 exchange at a coastal site in the central Baltic Sea using nine years of eddy covariance measurements. Based on these observations we were able to capture the temporal variability of the air–sea CO2 flux and other parameters relevant for the gas exchange. Our results show that a wind-based model with similar pattern to those developed for larger basins and open sea condition can, on average, be a good approximation for k. However, in order to reduce the uncertainty associated to these averages and produce reliable short-term k estimates, additional physical processes must be considered. Using a normalized gas transfer velocity, we identified conditions associated to enhanced exchange (large k values). During high and intermediate wind speeds (above 6–8 m s−1),conditions on both sides of the air–water interface were found to be relevant for the gas exchange. Our findings further suggest that at such relatively high wind speeds, sea spray is an efficient mechanisms for air–sea CO2 exchange. During low wind speeds (<6 m s−1), water-side convection was found to be a relevant control mechanism. The effect of both sea spray and water-side convection on the gas exchange showed a clear seasonality with positive fluxes (winter conditions) being the most affected.

Reducing uncertainties in the air–sea CO2 flux calculations is one of the major challenges when addressing the oceanic contribution in the global carbon balance. In traditional models, the air–sea CO2 flux is estimated using expressions of the gas transfer velocity as a function of wind speed. However, other mechanisms affecting the variability in the flux at local and regional scales are still poorly understood. The uncertainties associated with the flux estimates become particularly large in heterogeneous environments such as coastal and marginal seas. Here, we investigated the air–sea CO2 exchange at a coastal site in the central Baltic Sea using nine years of eddy covariance measurements. Based on these observations we were able to capture the temporal variability of the air–sea CO2 flux and other parameters relevant for the gas exchange. Our results show that a wind-based model with similar pattern to those developed for larger basins and open sea condition can, on average, be a good approximation for k. However, in order to reduce the uncertainty associated to these averages and produce reliable short-term k estimates, additional physical processes must be considered. Using a normalized gas transfer velocity, we identified conditions associated to enhanced exchange (large k values). During high and intermediate wind speeds (above 6–8 m s−1),conditions on both sides of the air–water interface were found to be relevant for the gas exchange. Our findings further suggest that at such relatively high wind speeds, sea spray is an efficient mechanisms for air–sea CO2 exchange. During low wind speeds (<6 m s−1), water-side convection was found to be a relevant control mechanism. The effect of both sea spray and water-side convection on the gas exchange showed a clear seasonality with positive fluxes (winter conditions) being the most affected.

The past decade has seen significant technological advance in the observation of trace gas fluxes over the open ocean, most notably CO2, but also an impressive list of other gases. Here we will emphasize flux observations from the air-side of the interface including both turbulent covariance (direct) and surface-layer similarity-based (indirect) bulk transfer velocity methods. Most applications of direct covariance observations have been from ships but recently work has intensified on buoy-based implementation. The principal use of direct methods is to quantify empirical coefficients in bulk estimates of the gas transfer velocity. Advances in direct measurements and some recent field programs that capture a considerable range of conditions with wind speeds exceeding 20 ms-1 are discussed. We use coincident direct flux measurements of CO2 and dimethylsulfide (DMS) to infer the scaling of interfacial viscous and bubble-mediated (whitecap driven) gas transfer mechanisms. This analysis suggests modest chemical enhancement of CO2 flux at low wind speed. We include some updates to the theoretical structure of bulk parameterizations (including chemical enhancement) as framed in the COAREG gas transfer algorithm.