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The forward-backward (FB) approximation as applied to semiclassical initial value representations (SCIVR’s) has enabled the practical application of the SCIVR methodology to systems with many degrees of freedom. However, to date a systematic representation of the exact quantum dynamics in terms of the FB-SCIVR has proven elusive. In this paper, we provide a new derivation of a forward-backward phase space SCIVR expression (FBPS-SCIVR) derived previously by Thompson and Makri [Phys. Rev. E 59, R4729 (1999)]. This enables us to represent quantum correlation functions exactly in terms of a series whose leading order term is the FBPS-SCIVR expression. Numerical examples for systems with over 50 degrees of freedom are presented for the spin boson problem. Comparison of the FBPS-SCIVR with the numerically exact results of Wang [J. Chem. Phys. 113, 9948 (2000)] obtained using a multiconfigurational time dependent method shows that the leading order FBPS-SCIVR term already provides an excellent approximation. [ABSTRACT FROM AUTHOR]

The issue of adequate describing a gas of complex particles, composed of an even number of fermions, as point bosons is studied in alkali metals. In the low-density approximation we obtain the equation for the complex order parameter [uppercase_phi_synonym](r1, r2) representing the wave function of atoms with taking into account the internal motion of the valence electrons. For superfluid systems formed by particles with internal degrees of freedom, this equation replaces the Gross-Pitaevskii equation. It is shown that, in general, exchange effects should be considered in the same approximation as effects of the direct interaction of atoms with each other. In particular, in the case of only the Coulomb interaction the neglect of exchange effects leads to qualitatively incorrect results. The problem of spontaneous polarization in superfluid systems is studied. The expression for the electric polarization of the inhomogeneous superfluid system is obtained. [ABSTRACT FROM AUTHOR]