151. Analysis of di-methyl ether production routes: Process performance evaluations at various syngas compositions.
- Author
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Luu, Minh Tri, Milani, Dia, Wake, Matthew, and Abbas, Ali
- Subjects
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METHYL ether synthesis , *SYNTHESIS gas , *MOLAR mass , *CARBON sequestration , *CARBON dioxide , *HEATING - Abstract
This paper investigates direct di-methyl ether (DME) production based on dry methane reforming (DMR-to-DME) and on bireforming (BiR-to-DME). Technically, DMR-to-DME is preferred to BiR-to-DME because the former produces synthesis gas (syngas) with a hydrogen to carbon monoxide molar ratio (H 2 /CO) of 1 which is the ideal ratio for DME synthesis. Whereas the latter produces a H 2 /CO close to 2 and consequently suffers from two apparent drawbacks: (1) lack of the so-called ‘synergy effect’ – a feature that enhances DME yield when operating at H 2 /CO close to 1, and (2) generation of a high heat capacity by-product (H 2 O) which makes DME recovery energy intensive. In this paper, we find that those two disadvantages actually enhance the performance of BiR compared to DMR across a range of performance metrics. Although the presence of water increases the cooling/heating duty and the distillation columns’ reboiler duty in the BiR route, more heat released from DME synthesis reactor can be utilized in the reboilers to make BiR techno-economically compatible. To assess the sustainability of DMR and BiR, evaluations are carried out against an existing industrial scale DME production route (auto-thermal-reforming (ATR)). By utilizing the carbon in the CO 2 from an attached post-combustion carbon capture plant, DMR and BiR can save 22.3% methane feed uptake on average compared to the ATR process, which results in the DMR and BiR reducing CO 2 emissions by at least 6.5% on average. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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