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• The potential of microorganisms in olive trees in southern Brazil is still a gap. • Beneficial microorganisms can improve seedling growth and resistance to stress. • Each species of microorganism had its beneficial potential affected by pH. • The inoculant species can be adjusted according to the soil condition. The benefits of plant growth-promoting microorganisms to increase productivity have been demonstrated in various crops. Little is known about their potential in olive orchards in southern Brazil, whose naturally acidic soils are intensively limed for olive production. The present study investigated the effect of four inoculations (no inoculation, inoculation of the bacterium Azospirillum brasilense , inoculation of the fungus Trichoderma harzianum and inoculation of the fungus Trichoderma virens) at different levels of soil liming on the development of olive seedlings. The results showed that the microorganisms T. virens, T harzianum, and A. brasilense, but especially T. virens , when applied to the soil, promoted increased growth in height, diameter, and total dry mass yield of young olive trees, especially in conditions of lower soil acidity, with increases of 92, 34 and 33 % respectively, compared to the soil without inoculation. Less acidic environments, more favorable for olive tree development, enhanced the positive effect of these microorganisms. The microorganisms also mitigated the effects in potentially more stressful conditions, as observed by the higher concentration of photosynthesizing pigments, the reduction in hydrogen peroxide content, and the reduction in antioxidant enzyme activities in leaves and roots, in soil pH below that recommended for olive cultivation. [ABSTRACT FROM AUTHOR]

• Plasmodiophora brassicae is an obligate biotrophic protest and plasmodiophorid in the eukaryotic kingdom of Rhizaria. • P. brassicae can infect almost all species of Brassicaceae, resulting in yield and quality losses. • The use of beneficial endophytic fungi is a possible promising strategy for suppression/controlling club root disease. Clubroot, as a major disease and severe threat to cruciferous crops, is caused by the pathogen Plasmodiophora brassicae Woronin. The pathogen is an obligate biotrophic protist and plasmodiophorid in the eukaryotic kingdom of Rhizaria. P. brassicae can infect almost all species of family Brassicaceae, resulting in yield and quality losses of these important oil and vegetable producing crops worldwide. Resting spores of the pathogen can persist in soil for more than 18 years and can easily be transmitted through a number of agencies, including infected transplants and animals. Furthermore, resting spores can rapidly increase with continuous cropping system devastating both protected vegetables and infected fields. Cruciferous crops such as Canola and others are of enormous importance, as they are important source of vegetable oil for human and industrial lubricants, where mineral oils are inappropriate. Several strategies are in practice such as adjustment of soil pH, soil liming, controlling the soil environment and changes in hormonal levels etc. for suppression and/or controlling clubroot disease. But these are conventional techniques impractical under most circumstances and insufficient for controlling the disease. Thus, the use of fungi could be a possible promising strategy for suppression/controlling clubroot disease in economically important plants. This review summarizes the historical background of clubroot, current knowledge about its pathogen life cycle, its host range, problems in controlling the spreading of disease as well as the recent attempts for suppression/controlling the pathogen via beneficial endosymbiont fungi. [ABSTRACT FROM AUTHOR]

Continuous monitoring of soil quality is vital to understand the effects and to identify best management practices for sustainable agroecosystems. This study focuses on evaluating the soil quality and crop yield sustainability in a long-term maize-wheat cropping system experiment spanning 47 years. Physical, chemical, and biological soil quality indicators were assessed at two soil depths (0–0.15 m and 0.15–0.30 m) under eleven fertilizer and amendment regimes i.e., 50 % NPK, 100 % NPK, 150 % NPK, 100 % NPK + Zn, 100 % NPK+ hand weeding, 100 % NP, 100 % N, 100 % NPK + farmyard manure (FYM), 100 % NPK(S), 100 % NPK + lime and control, laid out in a completely randomized block design. Principal component analysis (PCA) was employed to select a minimum data set (MDS) of indicators for soil quality assessment, followed by weighted additive approach to calculate the soil quality index (SQI). Results showed that balanced dose of NPK fertilizers, in combination with FYM or lime, enhanced average wheat grain yield by 39.9 and 29.4 % over sole 100 % NPK fertilizers, respectively. Treatment 100 % NPK + FYM recorded a significant improvement in aggregate stability, available nutrients, microbial biomass over control and 100 % NPK. The highest value of SQI (0–0.15 m) was recorded in 100 % NPK + FYM (0.99), followed by 100 % NPK + lime (0.86) and lowest in 100 % N (0.41). Omission of NPK, PK, K and S from fertilizer regime caused a decline of respective 33, 39, 22 and 6 % in the SQI, whereas, all the treatments recorded a decline in SQI in sub-surface layer. The average contribution of MDS towards the SQI of 0–0.15 and 0.15–0.30 m depth was labile carbon (LC) (30 %) > microbial biomass N (MBN) (28 %) > mean weight diameter (MWD) (17 %) > pH (16 %) > available K (6 %) and LC (33 %) > N mineralization (24 %) > MWD (22 %) > pH (21 %), respectively. The SQI positively correlated with average grain yield and SYI, highlighting the importance of soil quality for sustainable crop production. This research underscores the significance of continuous soil quality monitoring and use of balanced fertilization, organic manure and lime in maintaining soil health and crop productivity in agroecosystems. • Balanced NPK fertilizers with FYM or lime increased the wheat yield by 39.9 and 29.4 %, respectively. • Continuous urea application rendered the soil unproductive. • Labile carbon was the major contributor towards the soil quality index. • Soil quality index correlated positively with grain yield and sustainable yield index. [ABSTRACT FROM AUTHOR]

Soil acidity is the most limiting factor for agricultural yield and sustainability in acid soils. Liming is the management practice recommended for reducing soil acidity and increasing the availability of macronutrients, but it can also lead to reduction in the availability of cationic micronutrients when applied at high rates. The aim of this study was to evaluate the effect of application of high rates of limestone, incorporated in the 0–0.40 m soil layer, on nutrient availability and their relation to cumulative grain yield in an annual crop production system. Three experiments were set up in 2017 with six liming rates (0, 3, 6, 9, 12, and 15 Mg ha−1), with incorporation in the 0–0.40 m layer. Soil and leaf samples were collected for determination of macro- and micronutrient concentration in the leaves. Regression and linear correlation analyses were used to evaluate the effect of the application rates on the availability of nutrients and on cumulative yield in soybean, maize, dry bean (common bean) wheat crops over three crop years. The micronutrient that showed the greatest reduction in level in the soil through liming was Fe, in contrast with Zn, which was not affected. The concentrations of micronutrients in soybean and common bean leaves were more sensitive to the effect of deep liming than the levels in the soil, and reductions were observed in the concentrations of B, Fe, Mn, and Zn; however, they remained at suitable levels according to regional standards. Thus, even with the reductions in the availability of the micronutrients brought about by incorporation of higher doses of limestone (≥ 9 Mg ha−1), the cumulative grain yields showed an increase in accordance with liming rates, with the optimal dosage from 8.77 to 12.6 Mg ha−1, depending on the site. The main factors that had positive correlation with yield were soil pH and the macronutrients concentration in the leaves, which generally increased along with the liming rates. • Micronutrients availability to plants reduces with increasing limestone doses incorporated at 0.40 m. • The concentrations of macronutrients in the leaves increased with increasing limestone rates incorporated at 0.40 m. • There is a positive correlation with grain yield and soil pH and macronutrient concentration in leaves. • Accumulated grain yield increases with increasing limestone rates incorporated at 0.40 m. [ABSTRACT FROM AUTHOR]

Plant functional traits can serve as indicators of plant resource-use strategies in response to environmental changes. Plants growing in acidified soil exhibit conservative traits and limit growth, but there is still little known about changes in above- and belowground functional traits and their coordination under alleviation of soil acidification. Here, we conducted a pot experiment on raising soil pH by liming in Chinese fir (Cunninghamia lanceolata) saplings in southern China. The experiment involved in two degrees of acidified soil (Mild, pH = 4.3; Severe, pH = 3.6) and three liming treatments: Control (CK, 0), low liming treatment (L, 1000 kg CaO hm−2) and high liming treatment (H, 4000 kg CaO hm−2). We measured 22 above- and belowground functional traits of Chinese fir including allocation, morphological, photosynthetic, and chemical traits to assess their response to liming. The results show that liming enhanced aboveground mass fraction and total leaf area (TLA), and reduced construction cost (lower C concentration). However, specific leaf area (SLA), nutrient concentrations of N and P, and photosynthetic rate (Pn) remained unchanged. These results suggest that aboveground components exhibited acquisitive strategies in response to liming with greater TLA and lower construction cost. Moreover, liming reduced root mass fraction (RMF), increased specific root length (SRL), specific root area (SRA), and root N and Ca nutrient concentrations. These results suggest that belowground components also exhibited acquisitive strategies through constructing longer and thinner roots with greater metabolic rates. Our findings show that liming shifts above- and belowground resource-use strategies of Chinese fir from conservative to acquisitive. These changes in functional traits support the ability of Chinese fir to grow rapidly in response to alleviation of soil acidification. Our research not only contributes to a deeper understanding of plant adaptation mechanisms in the face of environment changes but also provides valuable insights for improving carbon sequestration of plantations in subtropical China. • 22 functional traits of Chinese fir were measured to assess their response to liming. • Liming elevated total leaf area and reduced leaf construction cost. • Liming elevated specific root length, specific root area and root N concentration. • Liming shifts resource-use strategies of Chinese fir towards acquisitive. [ABSTRACT FROM AUTHOR]

[Display omitted] • In soil, adsorption of FA is limited by the binding to external surfaces of nano-aggregates. • The overall adsorption of FA is pH independent and has a relatively low affinity. • In acid soils, FA prefers direct interaction with soil oxide particles, releasing phosphate. • NOM-oxide interaction can be reduced by soil liming, decreasing the solubility of oxyanions. • A dual-phase model is developed to describe the release of PO 4 upon FA addition. For more insight into the interaction of natural organic matter (NOM) with metal (hydr)oxides and oxyanions, the adsorption of added fulvic acid (FA) and the corresponding release of phosphate (PO 4) were studied for a series of agricultural soils (∼0 – 25 cm), strongly varying in soil properties. Interpretation of the data with surface complexation modeling using the NOM-CD model applied in a dual-phase mode shows that the adsorption of added FA, in contrast to PO 4 , is restricted to the external surfaces of nano-aggregates. The adsorption is relatively weak and pH-independent, due to its competition with the native NOM of the organo-mineral phase. At low pH, the functional groups of both added FA and native NOM shift in the interface towards the soil oxide surfaces, making both a good competitor for adsorbed phosphate, resulting in a higher amount of phosphate being released. With an increase in pH, the competition becomes weaker. As a result, more phosphate is bound and less is released when FA is added. Our surface complexation modeling points to the existence of organo-mineral nano-aggregates with sizes of >∼10 – 270 nm, which depends on the total reactive surface area of the soil. Our findings imply that organic amendments containing FA equilibrate with only a portion of the total reactive surface area. In acidic soils, the addition of such organic amendments will be more effective in solubilizing phosphate, which is beneficial from a plant nutrition perspective, but simultaneously it may also contribute more to environmental eutrophication. [ABSTRACT FROM AUTHOR]

[Display omitted] • 5 RDs neutralise 500 up to 10 000 mmol H+/kg, variation in mineralogy and target pH. • Automatic titration (pH stat) estimates pH-dependent dissolution rates and slopes. • Novel soil-RD suspension estimates fast/slow pools of acid neutralising capacity. • Low and high doses (12 Mg/ha, 340 Mg/ha) for validation in 2 year soil-RD mesocosm. • Mechanistic model using pH stat and soil-RD suspension predicts mesocosm soil pH. The ongoing acidification of soil poses a significant threat to the proper functioning of various ecosystems worldwide. Silicate rock dusts (RD) are increasingly amended to acid soils to restore their pH, but the acid neutralising capacity (ANC) and dissolution rate of these products are highly variable and lack proper assessment protocols. It is expected that pH-dependent RD ANCs and dissolution rates dictate the pH increase in soils depending on the initial pH and pH buffer power of the soil. This study addressed these questions by comparing and validating three accelerated weathering tests for their capacity to predict the gradual liming effects in a two-year outdoor mesocosm. Five commercial RDs (two basalts, phonolite, foidite, and trachy-andesite) were tested in four acidified forest soils varying in initial pH, in texture and associated pH buffer power. First, RD dissolution was measured in aqueous batch renewal systems during one year at various starting pH (3.5, 4.5, and 5.5) and constant temperatures (20 °C, 37 °C, and 65 °C). These showed that the ANCs of RDs exhibit a fast fraction (half-life < 1 day) followed by a slower fraction. Second, titration tests of RDs at fixed solution pH, i.e., pH stat , performed between pH 3.5 and 4.5 revealed surface normalised dissolution rates that decreased factors 10–100 per unit pH increase, the slope depending on the RD's mineralogy. Indeed, the rate ranking of observed surface area normalised dissolution rates confirmed that of literature-based values, weighed by the XRD-derived mineralogical fractions. Third, lime-calibrated agitated soil-RD suspension tests were conducted for two months, illustrating the dependency of RD ANC on soil context, and yielding ANCs that were factor 2–5 times larger than in the batch renewal test because of pH buffering effects of soil particulates. Finally, an outdoor soil mesocosm on the four acid soils amended with RDs at 12 Mg/ha and 340 Mg/ha was established and soil pH was monitored for 2 years. The observed pH trends corresponded well for both the low dose (R2 a = 0.67) and the high dose (R2 a = 0.93) with model predictions made using the pH- and temperature-dependent RD dissolution rates (pH stat test) and the soil pH buffer power and RD slow ANC-fraction (soil-RD suspension test). This model predicts half-lives of RD dissolution ranging between <1 month to >100 years depending on the starting pH of the soil, its pH buffer power, the RD mineralogy (XRD based) and its specific surface area. This study shows that the dissolution and ANC of RD can be most pragmatically predicted with a series of lime-calibrated soil-RD suspension tests of maximally two months. [ABSTRACT FROM AUTHOR]

Liming materials are widely applied to alleviate soil acidification and increase rice yield in acidic soils, but their effects on nitrogen (N) use efficiency are still unclear. Here, we conducted a field-, pot-, and micro-plot experiment to investigate how the application of slaked lime (i.e., Ca(OH) 2) affects the fate of chemical fertilizer-N and straw-N in a double rice cropping system. In the field experiment, liming increased grain yield and N uptake by an average of 9.0% and 10.6%, respectively. In contrast, CaCl 2 application did not affect rice yield and N uptake, suggesting that the effects of lime application were not related to the addition of Ca2+. Results from a 15N tracer experiment (i.e., 15N-labeled urea and straw) indicated that liming reduced N uptake from fertilizer (−5.7%), but increased N uptake from straw (+31.3%). Liming also reduced soil retention of both urea- and straw-N and increased their loss rates. Taken together, our results indicate that although liming increases rice yield and N uptake, it lowers the use efficiency of fertilizer N and facilitates N losses. In addition, our results emphasize the need for long-term studies on the impact of liming on soil N dynamics in paddy soils. • Liming of an acidic rice paddy soil increased both rice yield and N uptake. • Addition of Ca2+ did not affect rice yield and N uptake. • Liming reduced N uptake from fertilizer but increased that from straw. • Liming reduced soil retention of both urea- and straw-N and increased their loss rates. [ABSTRACT FROM AUTHOR]

The solubility of cadmium (Cd) in soil and its transfer to plants are influenced by soil pH. While increasing soil pH reduces Cd solubility and accumulation in rice plants grown in acidic soils, its effect on Cd accumulation in vegetables remains inconclusive. Here, we investigated the impact of soil pH on Cd accumulation in dicotyledonous vegetables and elucidated the underlying molecular mechanisms. Soils collected from various locations were supplemented with varying quantities of lime to achieve soil pH values of around 5.0, 6.0, 7.0, and 8.0. Raising soil pH from around 5.0 to 8.0 markedly decreased extractable Cd. However, increasing soil pH tended to promote shoot Cd accumulation in dicotyledonous vegetable species including lettuce, pakchoi, and Chinese cabbage, and the model dicotyledonous plant Arabidopsis thaliana. Conversely, soil pH increase resulted in a monotonic decrease in rice Cd accumulation. In our hydroponic experiments, we discovered that iron (Fe) deficiency substantially increased Cd uptake and accumulation in dicotyledonous plants but not in rice. Increasing soil pH reduced soil Fe availability and induced the Fe transporter gene IRT1 expression in dicotyledonous vegetables roots, which led to an increase in IRT1-mediated Cd uptake and subsequently increased Cd accumulation as soil pH increases. A comprehensive model incorporating extractable Cd and root IRT1 expression better explained Cd accumulation in vegetable shoots. The application of 50 mg/kg of Fe fertilizer in neutral or alkaline soils resulted in a significant reduction in Cd accumulation by 34–58% in dicotyledonous vegetables. These findings reveal that increasing soil pH has two opposite effects, decreasing soil Cd availability while promoting Cd uptake through IRT1 upregulation, reconciling the inconsistency in its effect on Cd accumulation in dicotyledonous plants. Our findings provide important insights for understanding the factors affecting Cd uptake in plants and offer a practical solution to mitigate Cd contamination in vegetables. [Display omitted] • Elevating soil pH increases Cd accumulation in lettuce, pakchoi, and cabbage. • Fe-deficiency increases IRT1-mediated Cd uptake by dicotyledonous vegetables. • Fe-transporter gene IRT1 is responsible for Cd uptake in dicotyledonous vegetables. • Applying Fe fertilizer can decrease Cd accumulation in dicotyledonous vegetables. [ABSTRACT FROM AUTHOR]

• Lime input significantly decreased topsoil exchangeable potassium (EK) content. • The initial EK and acidic degrees were the key factors of effect on EK decrease. • Liming enhances the excavate and uptake of subsoil EK by crop roots in Ultisol. • Soil Ca, Al, and initial EK jointly regulate the Ultisol K availability after liming. Potassium (K) is the most commonly neglected macronutrient in global change, especially in acidified areas. Lime is a typical management to eliminate soil acidification in agroecosystem soils; however, its impact on soil K dynamics remains inconsistent under different acidic environments. Here, we combine a meta-analysis based on 407 observations from 89 papers and a long-term experiment to investigate the effect and main driving factors of liming on soil K change. The meta-analysis showed that lime application significantly reduced topsoil exchangeable K (EK) content by an average of 4.8% globally. The decrease in topsoil EK content due to liming depended on various soil properties, crop types, fertilizer regimes, and experiment types. Boosted regression tree analysis showed that initial soil exchangeable K (IEK) and pH were the main factors affecting soil EK change under the lime application. The field experiment results further evidence that the decrease of soil EK after the lime application was mainly due to increased K uptake by the crop, and EK transformed to non-exchangeable K (NEK). The application of lime has a greater impact on reducing subsoil EK content at a higher IEK thresholds. Soil EK showed a significant negative relationship with exchangeable calcium (Ca) and a significant positive relationship with exchangeable aluminum (Al). Redundancy analysis revealed that K input (KI), IEK, lime, Ca, Al, pH, and exchangeable magnesium significantly affected the K in soil and crops. The partial least squares path model showed that lime application and IEK levels combined indirectly influence soil K (EK and NEK) by directly affecting soil Ca and Al, K uptake, and K balances. The findings highlight the importance of the lime effect on K management in globally adverse environmental agroecosystems and indicate the key role of initial soil EK levels and acidification degree for regulating crops to excavate the subsoil potassium when subjected to liming. [ABSTRACT FROM AUTHOR]

The dual role of biochar for inhibiting soil acidification induced by nitrification was determined through two-step incubation experiments in this study. Ca(OH) 2 or biochar was added respectively to adjust soil pH to the same values (pH 5.15 and 5.85), and then the amended soils were incubated in the presence of urea for 70 days. The results showed that compared with Ca(OH) 2 treatment, both rice straw biochar and peanut straw biochar inhibited the decrease in soil pH and the increase in exchangeable acidity during the incubation. The application of biochars suppressed soil nitrification during the incubation, and thus reduced 7.5 mmol kg−1 and 1.4 mmol kg−1 protons released from nitrification compared to Ca(OH) 2 treatments. Compared with Ca(OH) 2 treatment, the ammonia-oxidizing bacteria population size was decreased by 8% and 12% in rice straw biochar and peanut straw biochar treatments respectively, which was the main responsibility for the inhibited nitrification after biochar application. In addition, the application of rice straw biochar and peanut straw biochar increased soil pH buffering capacity (pHBC) respectively by 22% and 32%. The increased pHBC played the main role (75%) in inhibiting the acidification of the soil amended with peanut straw biochar, while the rice straw biochar inhibited soil acidification mainly through suppressing nitrification during the incubation. Overall, compared with lime application, biochars can inhibit soil acidification caused by urea application through suppressing the nitrification process and improving the resistance of soils to acidification. The crop residue biochars presented a longer-lasting effect on ameliorating acidic soils than mineral lime. Image 1 • Biochar played a dual role in inhibiting soil acidification from nitrification. • Biochar decreased proton release through suppressing soil nitrification. • Biochar increased soil pH buffering capacity and the resistance to acidification. • Biochar would be a better option to ameliorate acidic soils than liming. [ABSTRACT FROM AUTHOR]

• Surface liming reduced soil acidity down to −60 cm one year after its application. • Liming increased soybean grain yield by 9%, but it had no effect on cereal crops. • The lime reactivity had no effect on crop grain yield. • Gypsum did not increase crop grain yield in this moderate acidic Oxisol. • Combined application of gypsum and lime did not benefit crop yields. The low solubility of lime (CaCO 3) and the absence of soil disturbance in fields under no-tillage (NT) may diminish the effectiveness of surface liming to reduce exchangeable Al3+ (toxic to plants) and increase the base saturation in deep soil layers. However, the effects of subsurface soil acidity can be attenuated by applying agricultural gypsum (CaSO 4 ⋅2H 2 O), which is more soluble than lime, and thus, can leached bases (exchangeable Ca2+, Mg2+ and K+) and S-SO 4 2− to deeper soil layers as well as decrease Al3+ toxicity to plants. Therefore, gypsum can be applied individually or in combination with lime. Herein, we conducted a field experiment aiming to evaluate short- (1 year) and long-term (11 years) effects of surface liming and gypsum application on the chemical properties of the 0.00–0.10, 0.10–0.20, 0.20–0.40 and 0.40–0.60 m soil layers and also on crop yield of 22 crop seasons (i.e., 10 soybean, 3 maize, 4 white oat, 3 wheat and 2 barley crops). The study was performed in a clayey Typic Hapludox of moderate acidity managed under NT for more than 25 years in Guarapuava, Paraná State, southern Brazil. Three soil surface-applied lime strategies were tested in order to raise base saturation to 70%, namely: (a) 4.62 Mg ha–1 rate of lime of low effective calcium carbonate equivalent (ECCE = 75%); (b) 3.47 Mg ha–1 rate of lime with a high ECCE value (101%); and (c) the same rate of high-ECCE lime split in three applications (i.e., 1/3 at the start of experiment; 1/3 after 1 year and 1/3 after 2 years). A control treatment without liming was also conducted. The liming strategies were combined with four rates of agricultural gypsum (i.e., 0, 3, 6 and 9 Mg ha–1) applied at the start of the experiment. Our findings did not reveal synergistic effect of lime and gypsum on soil chemical properties nor on crop yield. Gypsum resulted in very slight gains in grain yield (4% on average) and limited to just 25% of cereal (corn and winter cereals) crop seasons. On the other hand, liming increased soybean yields by 14% in 40% of crop seasons. Gypsum was more efficient than lime in raising exchangeable Ca2+ levels up to −0.60 m in the short term; however, lime promoted greater reduction of soil acidity and had a more marked residual effect on exchangeable Ca2+ contents than gypsum. The liming strategies did no promote substantial differences in crop yield, but low-ECCE lime sustained better soil chemical condition to plant growth for a longer period. Surface liming efficiently reduced subsurface acidity in a moderately acidic Oxisol managed under NT even in the short-term, promoting increments on soybean crop yields. In this case, the application of gypsum rates did not bring additional benefits to soil or plant yield. [ABSTRACT FROM AUTHOR]

• Liming has been recognized to be beneficial for soil physical properties. • The physical resilience of a soil is related to its structural stability. • It may take several years to develop a sustainable structure system. Liming is a well-established practice to ameliorate acidic soils worldwide. However, the role of liming in soil structure formation and its relation to the nitrogen cycling is only little explored. We hypothesized that improved physical and mechanical soil properties, which are directly linked to soil structure, lead to lower nitrogen losses in an agricultural system. Water holding capacity, total pore volume, bulk density, hydraulic conductivity, shear stress and pre-compression stress were quantified in the topsoil of three surveys located in Germany on different soil types: Eutric Gleyic Cambisol (Loamic) (Magdeburg, Saxony-Anhalt), Haplic Luvisol (Neubrandenburg, Mecklenburg-Western Pomerania) and Eutric Cambisol (Loamic) (Puch, Bavaria). The field experiments were arranged in a Randomized Complete Block Design and treated with two different rates of lime (calcium carbonate). Furthermore, three rates of nitrogen in form of urea or calcium ammonium nitrate were applied every year. Liming significantly increased the pH, plant available water capacity, total pore volume and decreased bulk density in the soils six months after application, but twelve months after lime application the soil structure collapsed again causes by ploughing and chiseling. We, therefore, assume a positive influence of lime application on soil physical parameters, if tillage is excluded at least initially. On the other hand, our results from the shear stress parameters and the pre-compression stress values indicate that their changes need time and we assume that it may take several years to develop a sustainable structure system. [ABSTRACT FROM AUTHOR]

Upon insertion of biomass into a boiler, the material is incinerated, generating heat for the system. The combustion of biomass in the boiler produces ash, which is comprised of inorganic and mineral components that possess the potential for usage as a soil amendment. This study aimed to evaluate the efficacy of utilizing bottom ash from a Eucalyptus wood panels company, either partially or wholly replacing liming, for Eucalyptus planting. Chemical, physical and morphological characterizations of the ash and chemical characterization of the soil were carried out. An experiment was set up for the development of clonal Eucalyptus (3 ×2 m spacing), using different concentrations of ash and/or lime in the soil. The chemical characterization of ash was considered safe for use in agriculture, according to current legislation in Brazil (Normative Instruction SDA, n° 27). The diameter above ground and height of the seedlings were evaluated during twelve months in the field. In all treatments, elements such as copper and zinc presented concentrations within the limit parameters for soil, set by the government agency, CETESB. The findings indicate the feasibility of partially or fully replacing liming with ash, thereby promoting a more sustainable integration of circular economy into forest-based industries' energy generation processes. • The above ground height and diameter of eucalyptus were not harmed by ash addition. • Heavy metal content in ash conformed to soil amendment safety standards. • Soil chemical constituents were within the limits set by Brazilian regulations. • Bottom ash supplied Ca and Mg, thus working as a liming substitute. [ABSTRACT FROM AUTHOR]

Crop yield gains and improvements in surface and subsurface soil chemical properties are evident when agricultural lime and gypsum are used in high-acidity soils. However, there is scarce information on the effects of lime and gypsum application on no-till tropical soils previously treated with these additives (low-acidity soils). The duration of the effects of lime applied to the soil surface varies according to lime rate, product characteristics, soil conditions, and water and thermal regimes. Such residual effects influence the timing of lime reapplication. This study aimed to investigate the effects of surface application of agricultural lime and gypsum on soil chemical properties, soybean and second-crop corn yields, and lime residual contents. The experiment was conducted on a Red Latosol with a very clayey texture in Floresta, Paraná, Brazil. Four rates of dolomitic lime (0.0, 2.6, 5.4, and 8.1 Mg ha−1) and agricultural gypsum (0, 4, 8, and 12 Mg ha−1) were used. The experimental design was a randomized complete block with subplots and four replications. The experiment lasted for four soybean seasons and three second-crop corn seasons. At 6, 12, 24, and 36 months after treatment, soil samples were collected from the 0.00–0.05, 0.05–0.10, 0.10–0.20, 0.20–0.30, 0.30–0.40, and 0.40–0.60 m layers for chemical analysis. No significant interaction effects were observed on soil chemical properties. Liming resulted in soil alkalization, with a consequent reduction in Al3+ and an increase in Ca, Mg, base saturation, and pH. Residual lime was not detected in layers deeper than 0.05 m, suggesting a lack of physical movement of particles in the soil pore space. Residual lime was detected on surface soil (0.00–0.05 m) up to 36 months after application, demonstrating the low reactivity of lime on no-till soils. At 6 months after gypsum application, there was an increase in Ca2+ levels up to the 0.6 m layer, whereas Mg2+ levels were reduced throughout the soil profile for up to 36 months. In no-till soybean–second-crop corn rotation systems, use of agricultural gypsum alone did not provide consistent effects on crop yield and reduced foliar Mg contents. Under the studied conditions of low acidity, liming did not produce significant differences in crop yield but improved soil chemical properties for plant growth under no-till. • Residual lime was restricted to the 0.05 m layer. • Lime remained on the soil surface for up to 36 months after application. • Agricultural gypsum increased calcium content up to 0.6 m depth for 6 months. • Lime and gypsum application increased corn yield in some seasons. • Soybean yield did not improve with lime and reduced with gypsum in the first season. [ABSTRACT FROM AUTHOR]

• Study on toughness of fiber reinforced lime soil in different stress states. • Analysis of soil toughness from aspects of energy, deformation and strength. • Toughening mechanism of rice straw fiber on lime stabilized soil. Lime-stabilized soil used for subgrade is prone to brittle damage under loading because of low toughness. Based on this phenomenon, the toughening effects of anticorrosive rice straw fibers on the lime-stabilized soil and its internal mechanism have been studied in this paper. Different fiber contents (0.2 wt%, 0.6 wt%, 1.0 wt%) and fiber lengths (0–10 mm, 10–20 mm, 20–30 mm) were studied. Three-point bending tests, unconfined compressive strength tests and triaxial compression tests were conducted on the rice straw fiber-reinforced lime soil. Energy absorption, deformation index, and brittleness index were evaluated under flexure, compression, and shear. The toughness change from energy, deformation, and strength was studied based on these. The toughening mechanism of fiber reinforcement was analyzed from the mechanism of fiber-soil interaction, the energy absorption threshold of the damage process, the damage pattern of specimens and the length of the crack propagation path. The results showed that with the increase in fiber content and fiber length, the energy absorption and deformation index of the damage process increased while the brittleness index decreased. The brittle damage pattern was improved, and the toughness increased. The fibers connect the soil particles on both sides of the fracture surface through the bridging effect, form a three-dimensional reinforcement network to restrict the soil particle movement and consume a lot of energy during the interaction with soil, which causes the increase in the energy absorption threshold of soil. Thus, the toughness of the lime-stabilized soil is improved. [ABSTRACT FROM AUTHOR]

Soil acidity limits crop growth and yield all over the world. Low grain yields is usually associated with poor soil fertility; however, little attention has been given to the nitrogen-based fertilizer use efficiency in soils managed with lime. Given the current scenario of uncertainties regarding the availability and prices of fertilizers, our study aimed to understand how maize intercropped with ruzigrass and soybean plants develop in long-term soils managed with lime rates, and what the fate of the 15N–labeled ammonium sulfate [(15NH 4) 2 SO 4 ] applied in the soil-plant system. The treatments consisted of four dolomitic lime rates applied to the soil surface [control, half the recommended lime rate (½ RLR), full recommended lime rate (1 RLR) and double the recommended lime rate (2 RLR)]. The higher lime rate (2 RLR) improved fertility, carbon and nitrogen stocks in the soil profile, and grain and/or stover production of maize, ruzigrass and soybean. As a consequence, maize and ruzigrass recovered a high amount of 15N-fertilizer. On the other hand, soybean recovered less 15N-fertilizer, regardless of treatment, but a greater amount was found in acidic soils. At the end of the maize and soybean growth cycles, our results showed that in 2 RLR-amended soil, the 15N unrecovered was 71% lower than control. Finally, our results suggested that the use of low lime rates (½ RLR) may increase the 15N losses potential to deep layers, whereas low amounts of 15N were found in the subsoil when higher lime rates were applied. Soil acidity management through higher lime rates leads, over time, to increased soil fertility, resulting in a favorable environment for plant growth and the use of nitrogen fertilizers. In this way, it is possible to obtain a more productive and less costly agricultural system, and with less potential to pollute the environment. • Soil fertility increases after long-term liming with higher lime rates. • The 15N-fertilizer recovery by crops is proportional to the soil fertility level. • Low lime rates increased the concentration of 15N-fertilizer in deep soil layers. • The higher 15N recovery leads to higher yields and lower N-fertilizer losses. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • Liming and organic fertilizer increased soil pH and decreased Al concentration. • Microbial communities were altered by lime and organic fertilizer. • Soil organic carbon and microbial activities were promoted by organic fertilizer. • Organic fertilizer may enhance synergistic microbial interactions. • Organic fertilizer, not heavy lime alone, effectively increased banana growth. Abstract Low soil pH and low soil organic matter content are major factors limiting banana production in acid soils. A pot experiment was conducted to determine whether liming or organic fertilizer is effective in mediating banana growth and soil health. The experiment comprised an unamended control and two treatments, lime and OF (organic fertilizer) and sampling was conducted twice, 65 and 280 days after planting. Soil nutrient concentrations, soil microbial communities and enzyme activities, and banana biomass and nutrient uptake were determined. As expected, the application of lime or organic fertilizer significantly increased soil pH and mineral nutrient concentrations and decreased Al3+ concentration. At both harvests an increase in bacterial and fungal diversity in the lime treatment and a shift in the soil bacterial and fungal communities did not translate into increased plant biomass. Organic fertilizer application significantly increased soil organic carbon content and enzyme activities, root length density down the soil profile, plant biomass and nutrient uptake compared to the lime treatment and the control. Changes in the soil microbial community in the organic fertilizer treatment compared to the control followed the same direction as in the lime treatment. However, the relative abundances of Actinobacteria and Ascomycota increased significantly 280 days after planting and potential pathogenic fungi including Fusarium decreased. Our results indicate that heavy liming alone may not be a viable approach to overcome the growth limiting factors in banana production on acid soils. In addition to the increased soil organic matter and nutrient availability, organic fertilizer may prime microbial activities and act as biologically active agent and/or enhance synergistic interactions within the soil microbiome in enhancing plant biomass. Increased soil biological activities after organic fertilizer application emphasize the importance of soil health in promoting the yield of banana crops. [ABSTRACT FROM AUTHOR]

Abstract Growing quantities of biomass ashes are currently produced worldwide due to the increasing consumption of biomass in energy applications. The disposal of biomass ash in landfills is costly and leads to the loss of valuable resources. Biomass ash has important macro-nutrient contents and relevant soil liming capacity, and can be recycled to soils, thus contributing to biomass-to-energy process integration and a sustainable energy production. Although the EU Thematic Strategy for Soil Protection has highlighted the importance of promoting soil amelioration through nutrient recycling and some Member States have already recognised biomass-ash value in a context of circular economy, recycling of this material at the EU level and the potential use of ash-based material in fertilisers is still not properly framed by the EU regulatory framework. Adequate regulation for biomass ash from the energy sector is recognised of most importance as a driving force towards implementation of correct management and valorisation of ash as a raw material. This review provides a discussion on biomass ash properties and related EU regulations, notably the Waste Framework Directive and the Fertilisers Regulation, which are relevant for implementing a strategy for valorisation of biomass ash for soil amelioration purposes. Steps needed to provide the biomass ash with an appropriate end-of-waste and/or by-product status were identified. Key product and process aspects to enable the inclusion of biomass ash in the list of materials that can be used as fertilisers or as ingredients of soil fertilisers in the scope of the revised Fertilisers Regulation were discussed. Quality and safety standards to be harmonised at the EU level, as well as necessary revisions of the risk assessment framework were also discussed here. [ABSTRACT FROM AUTHOR]

Abstract An 18-year field experiment was conducted on a highly acidic soil in the mixed farming zone of south-eastern Australia. The experiment was a fully phased design with three major treatment contrasts: perennial systems versus annual systems; unlimed versus limed treatments; and permanent pasture versus pasture-crop rotations. The hypotheses tested in this study were that a) perennial systems would be less acidifying than annual systems, and b) surface liming would lead to amelioration of subsurface soil acidity over time. Results showed that there was no significant difference in soil pH in terms of acidification rate and amelioration rate between perennial and annual systems, thus we rejected the first hypothesis. However, both perennial and annual systems did acidify or re-acidify soil. The re-acidification rate was at least 0.09 pH units per year in the 0–0.10 m depth under the limed treatment. The acidification rate was 0.005 pH units per year in the 0.10–0.20 m depth under the unlimed treatment. The vigorous lime regime of maintaining pH ≥5.5 (measured in 0.01 M CaCl 2) in the 0–0.10 m depth increased soil pH in the 0.10–0.20 m depth at a rate of the 0.04 pH units per year, hence we accepted the second hypothesis. There was clear evidence of alkali movement vertically over time, but it was confined within the top 0.30 m depth over the 18-year period of experiment. It is recommended that soil should be limed regularly to maintain pH ≥5.5 to keep the system productive and sustainable. Highlights • Both perennial and annual systems acidify soil in depths at a similar rate. • Surface liming can alleviate subsurface (below 0.10 m) soil acidity. • Soil re-acidification rate is 0.09 pH units per year in the 0–0.10 m depth. • Soil acidity amelioration rate is 0.04 pH unit per year in the 0.10–0.20 m depth. • Soil should be limed regularly to maintain pH ≥5.5 to keep the system productive and sustainable. [ABSTRACT FROM AUTHOR]

Abstract The hierarchical organization of aggregates in soil is responsible for the presence of inter and intra-aggregate pores. This research aimed to investigate effects of soil surface liming, considering lime rates of 0, 10 and 15 t ha−1, on the intra-aggregate porous system of soil aggregates with equivalent diameters of 2–4 and 1–2 mm, from 0 to 10 (A) and 10 to 20 cm (B) soil layers. These aggregates were selected by the wet sieving method carried out for determination of the mean weight diameter. Synchrotron-based computed microtomography (μCT) of aggregates was analyzed in terms of porosity, connectivity, tortuosity, and fractal dimension. Additionally, X-ray fluorescence was used to evaluate the elemental composition of the soil aggregates. All liming effects were concentrated at layer A, where calcium percentage was elevated in aggregates from 1–2 mm class as compared to those from 2–4 mm class. Accordingly, the physical parameters studied were generally more affected in the case of smaller aggregates (1–2 mm). Liming decreased total porosity, increased tortuosity of pores, and decreased fractal dimension for 1–2 mm aggregates, which was in line with the fact that larger pores were replaced by smaller ones in 1–2 mm aggregates, as found via both quantitative and qualitative analyses. On the other hand, liming did not affect pore connectivity under any of the circumstances. Highlights • Surface liming improved soil aggregation by increasing the mean weight diameter. • Smaller soil aggregates present higher percentage of calcium due to liming. • Liming effects on soil physical properties were stronger for smaller aggregates. • In these small aggregates, liming decreased porosity and increased tortuosity. • Liming provided a more homogeneous intra-aggregate pore space. [ABSTRACT FROM AUTHOR]

Abstract Agricultural liming materials are broadly utilized in the world to ameliorate soil acidity. Crushed limestone (CaCO 3) and dolomite (MgCO 3 ·CaCO 3) are most common liming materials. The CO 2 emission coefficient was proposed as 0.12 Mg C per Mg for CaCO 3 by the Intergovernmental Panel on Climate Change (IPCC), which indicates that 100% of C in CaCO 3 is eventually released to the atmosphere in the form of CO 2. However, this assumption appears unlikely based on current knowledge of the very low solubility of CaCO 3 and carbonate transport through soil. To develop the direct CO 2 emission factor from the C-containing liming materials applied in moderately acidic soil, CaCO 3 was applied in a typical temperate upland soil at different levels (0–2 Mg ha−1 yr−1), and the CO 2 emission rates were determined using the closed chamber method for two years. The direct CO 2 emission factor from CaCO 3 was estimated using 13CO 2 fluxes from 13C-CaCO 3 applied soils. Approximately 0.026 Mg C per Mg of CaCO 3 was emitted as CO 2 from CaCO 3 in cropping lands. This value was much lower than the IPCC default value (0.12 Mg C per Mg of CaCO 3). The current CO 2 emission coefficient was comparable with the United States Environmental Protection Agency (EPA) emission factor (0.046 Mg C per Mg of CaCO 3) from the agricultural field. If the EPA emission factor from the ocean (0.013 Mg C per Mg of CaCO 3) is added to the currently developed CO 2 emission factor of the inner agricultural field, the total CO 2 emission factor from lime may be close to 0.039 Mg C per Mg of CaCO 3 in the selected upland soil. Therefore, we propose that the current IPCC guideline value of the CO 2 emission factor from lime should be revised as 0.039 Mg C per Mg of CaCO 3 for Korean upland soils. Highlights • IPCC proposed 0.12 Mg CO 2 -C per Mg CaCO 3 as the CO 2 emission factor from CaCO 3 in soil. • 0.026 Mg CO 2 -C per Mg CaCO 3 was emitted from CaCO 3 during maize cultivation. • EPA estimated 0.013 Mg CO 2 -C per Mg CaCO 3 of CO 2 emission factor released from agricultural field. • CO 2 emission factor of CaCO 3 should be revised with 0.039 Mg CO 2 -C per Mg CaCO 3 in Korean upland soil. [ABSTRACT FROM AUTHOR]

The cropping systems of northern Idaho and eastern Washington are dominated by a cereal-based (winter wheat) rotation that is exclusively rainfed. Following the green revolution, the productivity of wheat increased dramatically with semi-dwarf varieties and inexpensive synthetic fertilizers. However, long-term and frequent use of ammonium-based nitrogen fertilizers has resulted in the gradual acidification of fields in the region, with reduced productivity and symptoms of aluminum toxicity in some locations. A micronized liquid formulation of lime (calcium carbonate) was evaluated at three locations to mitigate soil acidification in comparison to a no-lime control. To examine how liming affects bacterial community structure, soil samples were taken in the spring in wheat and pea rotations 7 and 19 months after lime application, DNA was extracted and the V1-V3 portion of the 16S rRNA gene was amplified and sequenced with Illumina MiSeq. pH was only increased ∼0.2–0.3 units in most locations, and liming only had a significant effect on bacterial community composition at one location (Pullman). Liming had no consistent or significant effect on community richness or diversity. Location had a stronger effect on communities than liming or crop rotation, but some specific taxa increased in relative abundance in response to liming, including the families Cytophagaceae and Flavobacteriaceae (Phylum Bacteroidetes), A4b (Phylum Chloroflexi), and Opitutaceae (Phylum Verrucomicrobia). A number of operational taxonomic units (OTU) in Chitinophagaceae and Xanthomonadaceae were increased by liming at the Pullman location, which had 3–4 X more OTUs affected by liming than the other locations. Streptomycetaceae and Oxalobacteraceae were more abundant in root zone soil of wheat than pea. In conclusion, there was a strong interaction between liming and location in determining soil bacterial composition, but specific components of the bacterial community responded to even minimal increases in soil pH. [ABSTRACT FROM AUTHOR]

Soils under continuous no-till (NT) often produce stratified soil acidification due to fertilizer placement and subsequent lack of mixing. Because aluminum (Al) becomes more bioavailable with lower soil pH, Al toxicity is an emerging problem in many soils throughout the Palouse region in the dryland cropping areas of the inland Pacific Northwest of the United States. When various lime materials are surface applied to NT soils, the depth to which these materials may impact soil pH, available Al, and microbial community response has not been explored in the fine-silty soils of this arid region. The objectives of the current study were to: (1) determine if soil sampling at small, discrete depth increments captures stratification of chemical and microbial properties in NT soils and (2) evaluate the impacts of two types of surface-broadcast lime on Al availability and microbial community composition at each depth interval. In April 2014 and 2015 (6 mo and 18 mo after liming), soil samples were collected at 2-cm depth increments and analyzed for soil pH and metals bioavailability, as well as microbial community composition using terminal restriction fragment length polymorphism analysis. In 2015, surface soil (0–2 cm) pH increased from 4.6 in untreated control to 6.6 in limed plots, and KCl-extractable Al decreased from approximately 50 mg kg −1 to below 10 mg kg −1 in the 2–4 cm depth of soil. The surface soil microbial community composition changed significantly in response to lime application, and was highly correlated with soil pH and Al concentrations. No significant effects of treatment were detected when data were pooled across the 10 cm depth. The 2-cm sampling increments provided statistically significant resolution in soil chemical stratification and related shifts in microbial community composition, revealing different effects at different depths. We are able to conclude from this study that (1) A finely resolved, spatially explicit sampling design is necessary to capture soil chemical stratification complexity within a variety of variables, and microbial community response over time; and (2) Surface application of lime in Palouse NT systems will take >18 mo to be effective at depths below 6 cm. [ABSTRACT FROM AUTHOR]

The rate and method of lime application modify soil chemical attributes, but the re-acidification process after liming remains poorly understood in the long-term. This study aimed to assess the long-term effect of surface and incorporated liming on shifting soil use from native grassland of South Brazilian Campos to no-tillage system (NTS) for grain production in a highly acidic sandy-loam Ultisol. In 1994, an experiment in a randomized block with split plot design and four replications was installed in Southern Brazil. The main plot consisted of lime application method (surface or incorporation by soil tillage), while the subplots were lime rates (0.0, 2.0, 8.5 and 17.0 Mg ha −1 ), corresponding, approximately, to 0, 1/8, 1/2, and 1 fold the recommended dose to rise soil pH to 6.0 in the 0–20 cm soil layer. The 2 Mg ha ‒1 treatment had reapplication every two years until soil accumulated 8 Mg ha ‒1 of lime. In October 2006 and 2012 (i.e., 12 and 18 years after lime application), soil samples were collected at every centimeter from 1 to 10 cm depth, every 2.5 cm from 10 to 25 cm, every 5 cm from 25 to 50 cm and 50 to 60 cm. The chemical attributes related to soil acidity were evaluated. Even after 18 years of lime application, the re-acidification process recovered only 50% of the exchangeable Al and 30% of the potential acidity compared to native soil. Lime incorporation before NTS adoption proved to be more rapid and efficient to mitigate soil acidity than surface liming, and it is suitable for correction of deep-layered soil acidity in the soil profile. Surface lime application induced a lower alkalinization front in the soil profile, and even after 18 years there was no neutralization of total exchangeable Al in the 10–20 cm layer. [ABSTRACT FROM AUTHOR]

Chemical fertilizer application is a common agronomic practice to improve crop productivity and liming is often used to counteract the soil acidification caused by long-term fertilization; however, it is unclear whether liming will counteract the effect of long-term fertilization on soil bacterial community structure and its co-occurrence pattern. Here, we examined the influence of long-term fertilization (NPKS) and liming (L) on soil bacterial community structure and its co-occurrence networks by sequencing 16S rRNA gene amplicons. Our results showed that liming counteracted the influence of long-term fertilization on soil pH, but not on soluble organic carbon (SOC) and electrical conductivity (EC). Long-term fertilization affected the abundance of Acidobacteriia, Deltaproteobacteria and Gammaproteobacteria in the 0–10 cm soil, and that of Deltaproteobacteria, Gammaproteobacteria and Gemmatimonadetes in the 10–20 cm soil; whereas liming affected the abundance of Acidobacteriia, Gammaproteobacteria, and Chloracidobacteria in the 0–10 cm soil and that of Deltaproteobacteria in the 10–20 cm soil. The bacterial community structure in soils with the NPKS-L treatment was different from that with other treatments, and was mainly affected by SOC, EC, and NO 3 − concentration. The link numbers in bacterial co-occurrence networks were decreased by long-term fertilization or liming alone, but were increased by the NPKS-L treatment. Notwithstanding the fact that liming alleviates fertilization-induced soil acidification, this study indicates that liming did not counteract the effect of long-term fertilization on soil bacterial community structure and its co-occurrence pattern, hence cannot recuperate the soil microbial functionality that is changed by long-term fertilization. [ABSTRACT FROM AUTHOR]

[Display omitted] • No-liming decreased approximately 30% of P use efficiency in CT and NT systems. • The use of NT increased P use efficiency by about 10–12% compared to the CT system. • NT without lime resulted in the highest P legacy but was non-accessible due to high Al3+. • Soil P forms and P use efficiency in NT and occasional tillage systems were similar. • Liming with soil incorporation effects persists for four decades, enhancing P use by crops. Liming combined with no-tillage (NT) can increase the efficiency of P use by accumulating soil P in more available forms and improving root exploration due to the absence of toxic Al3+. This study aimed to evaluate the long-term effect of different combinations of soil tillage managements and liming in a subtropical Oxisol on the accumulation of P forms, legacy P index, and P use efficiency. A long-term experiment was used, established in 1987 testing (i) conventional tillage with lime (lime-CT) and control (control-CT), (ii) NT with lime (lime-NT) and control (control-NT), and (iii) occasional tillage with lime (lime-OT). The NPK fertilization was the same for all treatments. The accumulated grain yield and P use efficiency of 56 crops between 1987 and 2019 were evaluated. In 2019, soil samples were collected in the 0–5, 5–10, and 10–20 cm layers and submitted to a sequential chemical fractionation of P, P indexes, and soil acidity parameters. The results reveal that is necessary to correct acidity to increase crop yields and P use efficiency, regardless of the soil management used. This increase is enhanced when soil acidity correction by liming is combined with the use of conservation systems such as NT. Furthermore, after liming with incorporation, liming can be done on the soil surface, without the need to repeat the operation of lime incorporation, ensuring high efficiency of P use even after more than four decades. [ABSTRACT FROM AUTHOR]

Liming with 'structure lime', comprising approximately 80–85% ground limestone and 15–20% slaked lime, has been promoted in subsidised environmental schemes in Sweden since 2010 to increase clay aggregate stability and mitigate particulate phosphorus losses to surface waters. To date, approximately 65,000 ha have been structure-limed. Apart from stabilising aggregates, liming may also improve other physical properties, such as soil strength. This study examined the effect of increasing application rate (0–16 t ha-1) of structure lime on soil strength, approximated by horizontal (draught requirement) and vertical (penetrometer resistance) measurements, in eight field soils (clay content 26–38%) to which structure lime had been applied two, three, four or six years previously. Draught requirement when cultivating with a multipurpose cultivator significantly decreased (by 11%) with the highest application rate of structure lime (16 t ha-1) compared with an unlimed control. This reduced the wheel power requirement by 7.1 kW and diesel consumption by 1.2–1.4 L ha-1, and lowered CO 2 emissions by 3–4 kg ha-1. To clarify the general effect of structure liming, the mean value of all limed treatments was compared with that of the unlimed control. This showed that structure liming in general significantly reduced the draught requirement (by 7%). However, penetrometer resistance measurements revealed no significant effects of structure liming and no relation between draught requirement and penetrometer resistance measurements. Overall, the results indicate that structure liming can reduce fuel consumption, due to easier soil tillage, and thus lower CO 2 emissions. • Cultivator draught requirement was measured in structure limed field trials. • A towing eye with sensors that can measure forces in three directions was used. • Structure liming reduced horizontal draught requirement by 7%. • Reductions corresponded to decreases of 1.2–1.4 L diesel ha-1 and 3–4 kg CO 2 ha-1. • Structure liming did not affect penetrometer resistance in this study. [ABSTRACT FROM AUTHOR]

The new EU regulations on maximum levels of cadmium (Cd) in cacao products sparked research on countermeasures to reduce Cd concentrations in cacao beans. This study was set up to test the effects of soil amendments in two established cacao orchards (soil pH 6.6 and 5.1) in Ecuador. Soil amendments included: 1) agricultural limestone at 2.0 and 4.0 Mg ha−1 y−1, 2) gypsum at 2.0 and 4.0 Mg ha−1 y−1 and 3) compost at 12.5 and 25 Mg ha−1 y−1, all amendments were applied at the surface during two subsequent years. Lime application increased the soil pH by one unit down to 20 cm depth. On the acid soil, leaf Cd concentrations decreased by lime application and the reduction factor gradually rose to 1.5 after 30 months. No effects of liming or gypsum on leaf Cd was found in the pH neutral soil. Compost application in the pH neutral soil reduced leaf Cd concentration with factor 1.2 at 22 months but that effect was absent at 30 months after application. Bean Cd concentrations were unaffected by any of the treatments at 22 months after application (acid soil) or 30 months (pH neutral soil) suggesting that any treatment effects on bean Cd might be even more delayed than in leaves. Soil columns experiments in the laboratory showed that mixing lime with compost largely enhanced the depth of lime penetration compared to lime only. Compost + lime reduced 10−3 M CaCl 2 extractable Cd in soil without lowering extractable Zn. Our results suggest that soil liming has the potential to lower Cd uptake in cacao in the long term in acid soils and that the compost + lime treatment should be tested at field scale to accelerate the effects of the mitigation. [Display omitted] • Soil amendments significantly reduced Cd in leaves but not cacao beans in long-term field experiments. • Surface lime application increased soil pH only at the first 15 cm soil layer. • The lowest leaf Cd concentrations occurred during the flowering/filling stage of cacao. • Compost and gypsum effects on elemental leaf composition were inconsistent over time. • Lime + compost applications are advocated for future research as compost increases lime penetration into the soil profile. [ABSTRACT FROM AUTHOR]

• Silicate-containing amendments increased calcium and available silicate contents. • Silicate-containing amendments moderately increased soil fertility. • Silicate and lime co-application increased the relative change in soil fertility. • Long-term application of silicate and lime reduced C stratification. • Carbon stocks reduced in lime and silicate amended soils. Most agricultural soils are unproductive due to soil acidity which limits crop growth and yield. To ameliorate soil acidity constraints and enhance the ecosystem services the soil renders to achieve optimum crop yields, lime, and silicate are mostly used. However, there are few studies reporting the impacts of the combined application of silicate and lime on soil properties, soil fertility and carbon stocks and stratification in long-term experiments. This study evaluated the impacts of the combined application of silicate and lime on soil fertility indicators (pH, soil organic matter (SOM), available phosphorus, exchangeable potassium, magnesium, and calcium, and available SiO 2), carbon stratification and stocks in comparison to sole lime and sole silicate applied to a Fluvaquentic Eutrudepts over a 67-year period. Each treatment's rate of application was calculated to raise the soil pH to 6.5. Incorporation of the treatments increased the soil pH by 1.30, 1.22, and 1.35 folds in the sole silicate, sole lime, and combined silicate and lime-treated soils, respectively, relative to the baseline soil pH (5.5). The combined application of silicate and lime resulted in significant decreases in C stratification and C stocks. The significant reduction in the C stocks in the silicate and lime-treated soils implies that its long-term application could potentially reduce carbon sequestration and increase the carbon footprint of rice cultivation. This information is crucial to develop sustainable soil management interventions to curtail the environmental footprint in rice paddy ecosystems. Comparatively, the combined silicate and lime treatment caused an increase in the relative change of soil fertility by 65.7% and the average annual growth rate in the soil fertility improvement by 0.0115, as compared to the untreated soil. Among the soil variables, soil pH, exchangeable calcium, and available silicate contributed most to the variation the soil fertility. The obtained results could serve as a guide in revising the lime and silicate fertilization programs instituted by the Korean Government and reviewing national soil fertility management systems in temperate paddy ecosystems. [ABSTRACT FROM AUTHOR]

In this study, effects of soil pulverization level on resilient modulus of lime stabilized soils were studied through extensive laboratory testing. Resilient modulus tests were carried on both non-freeze and thaw and freeze and thaw samples. California Bearing Ratio (CBR) tests were also carried out. The soil used was a high plasticity soil. The soil was pulverized in two different soil pulverization levels, both of which complied with the relevant soil pulverization criteria. Resilient modulus tests were carried out on unstabilized and 4%, 6% and 9% hydrated lime stabilized samples. Curing days were 7, 28 and 56 days respectively. One group of samples were tested for resilient modulus after curing duration was completed, while the other group of samples were measured for resilient modulus after freeze and thaw cycles were applied according to ASTM D. 560-03 (2015). For non-freeze and thaw conditions, resilient modulus and soaked CBR values showed that soil pulverization level affected the resilient modulus and CBR values significantly and fine soil pulverization revealed higher resilient modulus and CBR values compared to coarse pulverization. Resilient modulus values were stress state dependent. Freeze and thaw cycles decreased the resilient modulus for all samples, while lime stabilized samples retained at higher resilient modulus values compared to unstabilized samples. The tests showed the importance of using higher lime contents and extended curing as well as fine soil pulverization for increased freeze and thaw resistance. Under freeze and thaw conditions, coarse soil pulverization could only be partially compensated using higher lime contents, which means significant higher environmental and economic costs. The data showed that if severe freeze and thaw cycles are anticipated in the region, construction planning for lime stabilized pavements should be carried out so that minimum two months of curing can occur beforehand. P wave velocities were measured on some selected samples using an ultrasound equipment and it was shown that they were capable of reflecting the trend in mechanical properties and therefore there is a potential that they can be used as index properties for lime stabilized soils. The results of this study highlight that soil pulverization level in lime stabilized soils is as important as lime content and therefore should be given enough consideration in field construction. Otherwise targeted soil properties cannot be achieved in the field. [ABSTRACT FROM AUTHOR]

Human-managed grasslands receive significant inputs of fertilizing materials, which can greatly influence soil biological processes associated with the cycling of nitrogen (N), including microbial nitrification. Here we specifically address how soil ammonia oxidizing archaea (AOA) and ammonia oxidizing bacteria (AOB) respond to 23 years of different management practices in a permanent grassland experiment. We found that AOB amoA gene copy numbers were significantly higher in limed soils (associated with greater pH values) whereas AOA amoA gene copy numbers were higher in grazed grasslands. The chronic addition of inorganic N fertilizer in the form of ammonium nitrate (either applied alone or in combination with other macro-nutrients) greatly contributed to increase AOB abundance. Our study brings evidence of how soil-nitrifying communities can differently respond to the long-term effect of animal (i.e. rabbit) grazing and to repeated applications of nutrient (e.g. NH 4 NO 3 ) and non-nutrient (i.e. CaCO 3 ) fertilizing materials. [ABSTRACT FROM AUTHOR]

The effects of increasing pH on the adsorption and extractability of Si in two Si-deficient Australian sugarcane soils was investigated and the effects of increasing rates of fertilizer Si (as blast furnace slag) on pH and extractable Si were also examined. Equilibrium studies showed that maximum adsorption of Si by the two soils occurred in the pH range 9–10. When soil pH was increased from 5.0 to 6.5, subsequent adsorption of Si by the two soils, as measured by adsorption isotherms, increased. After incubation with progressive lime additions there was a decline in CaCl 2 − extractable Si due to its increased adsorption and an increase in acid (H 2 SO 4 − and acetic acid)-extractable (mainly adsorbed) Si. The increase in acid extractable Si was greater than the decrease in CaCl 2 − extractable Si suggesting a supply from an additional source. Alkali (Na 2 CO 3 and Tiron)-extractable Si decreased greatly with increasing pH suggesting dissolution of the amorphous (mainly biogenic) pool of silica was occurring with increasing pH. When increasing rates of slag were incubated with the soils, pH, CaCl 2 − and acid- extractable Si were all increased because upon dissolution slags release both silicic acid and OH − ions. There was, therefore, a positive relationship between extractable Si and soil pH. However, Na 2 CO 3 − and Tiron-extractable Si decreased with increasing slag rates (and increasing soil pH) suggesting dissolution of the biogenic pool of soil Si. It was concluded that future research needs to examine the desorption potential of adsorbed Si and the effects of liming on dissolution of the biogenic pool of soil silica under field conditions. [ABSTRACT FROM AUTHOR]

Cadmium (Cd) accumulation in rice is strongly controlled by liming, but information on the use of liming to control Cd accumulation in rice grown in slightly acidic soils is inconsistent. Here, pot experiments were carried out to investigate the mechanisms of liming on Cd accumulation in two rice varieties focusing on two aspects: available/exchangeable Cd content in soils that were highly responsive to liming, and Cd uptake and transport capacity in the roots of rice in terms of Cd accumulation-relative gene expression. The results showed that soil availability and exchangeable iron, manganese, zinc and Cd contents decreased with increased liming, and that genes related to Cd uptake ( OsNramp5 and OsIRT1 ) were sharply up-regulated in the roots of the two rice varieties. Thus, iron, manganese, zinc and Cd contents in rice plants increased under low liming applications but decreased in response to high liming applications. However, yield and rice quantities were only slightly affected. These results indicated that Cd accumulation in rice grown in slightly acidic soils presents a contradictory dynamic equilibrium between Cd uptake capacity by roots and soil Cd immobilisation in response to liming. The enhanced Cd uptake capacity under low liming dosages increases risks to human health. [ABSTRACT FROM AUTHOR]

Common grassland management practices include animal grazing and the repeated addition of lime and nutrient fertilizers to soils. These practices can greatly influence the size and distribution of different soil aggregate fractions, thus altering the cycling and storage of carbon (C) and nitrogen (N) in grassland soils. So far, very few studies have simultaneously addressed the potential long-term effect that multiple management practices might have on soil physical aggregation. Here we specifically ask whether and how grazing, liming and nutrient fertilization might influence C and N content (%) as well as C and N pools of different soil aggregate fractions in a long-term grassland experiment established in 1991 at Silwood Park, Berkshire, UK. We found that repeated liming applications over 23 years significantly decreased the C pool (i.e. g C Kg − 1 soil) of Large Macro Aggregate (LMA > 2 mm) fractions and increased C pools within three smaller soil aggregate fractions: Small Macro Aggregate (SMA, 250 μm–2 mm), Micro Aggregate (MiA, 53–250 μm), and Silt Clay Aggregate (SCA < 53 μm). Soil C (and N) accrual in smaller fractions was mainly caused by positive liming effects on aggregate fraction mass rather than on changes in soil C (and N) content (%). Liming effects could be explained by increases in soil pH, as this factor was significantly positively related to greater soil C and N pools of smaller aggregate fractions. Long-term grazing and inorganic nutrient fertilization had much weaker effects on both soil aggregate-fraction mass and on soil C and N concentrations, however, our evidence is that these practices could also contribute to greater C and N pools of smaller soil fractions. Overall our study demonstrates how agricultural liming can contribute to increase C pools of small (more stable) soil fractions with potential significant benefits for the long-term C balance of human-managed grassland soils. [ABSTRACT FROM AUTHOR]

Full denitirifcation of NO 3 − to N 2 is most likely when soil pH is elevated and oxygen levels are low. In the period immediately following urine deposition, soil pH and dissolved organic carbon (DOC) concentrations rapidly increase, coupled with O 2 consumption - conditions conducive to denitrification and gaseous N-loss - yet the potential for rapid denitrification during this early period post urine deposition has received little attention. In addition, recent research has shown that the amount of DOC (and N) released as pH increases is affected by the valence of the accompanying base cation, with monovalent cations releasing more. Liming has been used to positively influence N 2 O/(N 2 O + N 2 ) ratios in the later stages of N-transformations post urine deposition, yet the relative amounts of DOC (and N) released is likely to be affected in the presence of divalent Ca 2+ potentially lowering N-transformation potential. Soil pH in anaerobic microcosms was adjusted to values between 4.5 and 9.5 using either Ca(OH) 2 as a liming agent, or KOH as an analog of urine derived NH 4 OH. After 16 h incubation, up to ∼6800 μg g −1 of DOC and ∼480 μg g −1 of dissolved organic nitrogen (DON) was solubilized by KOH amendment which was ∼10-fold higher than Ca(OH) 2 ammendment, while NH 4 + and NO 3 − increased to concentrations well above native soil concentrations. In Ca(OH) 2 amended microcosms, denitrification enzyme activity (DEA) assays produced a maximum of 875 ng N 2 O-N g −1 h −1 at pH 7.2 with respiration rates <10 μg CO 2 -C g −1 h −1 . In contrast, DEA and respiration continually climbed in KOH amended microcosms with rates up to 4798 ng N 2 O-N g −1 h −1 and 47 μg CO 2 -C g −1 h −1 at pH 8.7 and 8.9, respectively. By using KOH as proxy for NH 4 OH derived from urea hydrolysis, this research has shown that rapid denitrification could occur shortly after urine deposition along with substantial DOC and DON solubilisation and N-mineralisation. However, elevated soil pH combined with excess Ca 2+ from liming might actually suppress denitrification potential. We propose that excess Ca 2+ affects how soil microbes access and process DOC and DON at elevated pH, with Ca 2+ acting to stabilize DOC and DON. Our results emphasize that although liming promotes soil conditions conducive to denitrification, DEA can be markedly affected by base type and prevailing soil chemical conditions. [ABSTRACT FROM AUTHOR]

Natural grasslands are important reservoirs of animal and plant biodiversity and provide several ecosystem services, through the action of soil microorganisms. The increased demand for food, energy, and cattle activity has led to the conversion of natural grasslands to cultivated systems. However, the consequences of this conversion for soil microbial diversity and ecosystem functioning are yet to be discovered. Here, we used the 16 S rRNA amplicon sequencing and a large set of soil and environmental variables to understand the possible effects of natural grasslands to cultivated pasture conversion on the soil microbial structure, composition, diversity, and functions. The study areas followed a gradient of increasing soil disturbance intensity, as follows: Natural grassland (NG), Improved-natural grassland (IG), Perennial-cultivated pasture (PP), and Annual-cultivated pasture (AP). Natural grassland conversion to managed and cultivated pastures decreased the abundances of Acidobacteria and Verrucomicrobia, while increased α-, γ-, and δ-Proteobacteria, Gemmatimonadetes, Bacteroidetes, Patescibacteria, and Latescibacteria. The predicted functional profiles have also changed, as functions like 'cellulolytic and symbionts/parasites' decreased after natural to cultivated pastures conversion, while 'nitrogen respiration', 'sulfur respiration', and 'aromatic compound degradation' functions increased. Aboveground plant diversity decrease influenced belowground microbial diversity. The main drivers of diversity, composition, and functional potential are associated with soil attributes affected by liming, like aluminum complexation. In conclusion, we have found taxonomic and functional differences between natural and managed grasslands (NG and IG, respectively) and cultivated pastures (PP and AP), with consequences for management strategies and biodiversity conservation priorities. [Display omitted] • Pasture management intensification shifts soil microbiome diversity and composition. • Liming rules soil microbial diversity and functions changes across pastures. • Forage diversity also drives soil microbial diversity and functional potential. [ABSTRACT FROM AUTHOR]

Chemical action as an anthropogenic factor in soil formation was suggested 50 years ago as a part of the metapedogenetic process. Initially, agricultural practices such as irrigation with saline water and soil liming by natural carbonated earth materials (marling) were considered as examples of chemical contamination that alter soil properties. Over the years, however, new anthropogenic substances have emerged, and their disposal on the land surface, whether intentionally or by accident, is acting as another metapedogenetic factor, leading to formation of contemporary soils with altered properties. In this context, potential transformation of natural soils may occur as a result of exposure to engineered nanomaterials (ENMs). Due to the relatively small amounts used to date, and their size and associated chemical properties, the impact of ENMs on soil may be questioned. We argue here, however, that ENMs disposed on the land surface are irreversibly retained in the soil matrix, accumulating over time and becoming a metapedogenetic factor. In support of this hypothesis, we present examples from the literature which demonstrate that deposition of carbon-based and metal-based ENMs may cause, under specific conditions, changes to the matrix and properties of soil constituents and formation of contemporary anthropogenic soils. These examples reconfirm the hypothesis that chemicals are a factor in anthropogenically-induced metapedogenesis. [ABSTRACT FROM AUTHOR]

No tillage (NT) has been associated to increased N 2 O emission from poorly drained agricultural soils. This is the case for soils with a low permeable Bt horizon, which generates a perched water layer after water addition (via rainfall or irrigation) over a long period of time. Moreover, these soils often have problems of acidity and require liming application to sustain crop productivity; changes in soil pH have large implications for the production and consumption of soil greenhouse gas (GHG) emissions. Here, we assessed in a split-plot design the individual and interactive effects of tillage practices (conventional tillage (CT) vs. NT) and liming (Ca-amendment vs. not-amendment) on N 2 O and CH 4 emissions from poorly drained acidic soils, over a field experiment with a rainfed triticale crop. Soil mineral N concentrations, pH, temperature, moisture, water soluble organic carbon, GHG fluxes and denitrification capacity were measured during the experiment. Tillage increased N 2 O emissions by 68% compared to NT and generally led to higher CH 4 emissions; both effects were due to the higher soil moisture content under CT plots. Under CT, liming reduced N 2 O emissions by 61% whereas no effect was observed under NT. Under both CT and NT, CH 4 oxidation was enhanced after liming application due to decreased Al 3 + toxicity. Based on our results, NT should be promoted as a means to improve soil physical properties and concurrently reduce N 2 O and CH 4 emissions. Raising the soil pH via liming has positive effects on crop yield; here we show that it may also serve to mitigate CH 4 emissions and, under CT, abate N 2 O emissions. [ABSTRACT FROM AUTHOR]

A significant area in Brazil is covered with degraded pasturelands, which could be more appropriately used under no-till system. These soils are highly acid and physically fragile, and then there is a need to identify a better liming strategy that will improve the establishment of no-till systems. We hypothesized that the surface application of lime would be more efficient to alleviate soil acidity on degraded pastureland soils. A 4-year field trial examined the effect of a lime application (4.8 Mg ha −1 ) that had either been incorporated (0–20 cm) or surface-applied to an acid sandy loam Oxisol, originally under degraded pasture in Southern Brazil. Control treatments (no-lime) were applied with and without soil disturbance. A black oat ( Avena strigosa Schreb) – soybean ( Glycine max L. Merrill) cropping sequence was used for 4 years after no-till establishment. Soil chemical attributes, plant nutrient uptake, black oat dry biomass production and soybean grain yield were assessed. Soil acidity amelioration was achieved either by incorporating the lime or applying it onto the soil surface. Lime incorporation resulted in a faster neutralization reaction, whereas surface-applied lime provided longer lasting soil profile benefits. At 0–5 cm layer, both tillage treatments, especially with lime application, provided lower soil organic carbon levels than no-till treatments, with or without lime application, until the second year. These differences in soil organic carbon levels were not observed at the end of evaluation, after 4 years, probably because the residual tillage effect disappeared. Over time, the soil organic carbon levels at 5–10 cm layer were slightly increased or maintained close to the initial level, regardless of treatment. Overall, the plants responded to lime application, with an increase by 35% on soybean yield, regardless of the application method. Surface liming provided better economic returns than incorporated liming. Lime incorporation is not recommended in degraded lands due to the risks of SOC losses with soil disturbance and rapid pH increase. Despite of high soil acidity before no-till cultivation, the surface application of lime was the best alternative for alleviating soil acidity when establishing a no-till system on degraded pastureland. [ABSTRACT FROM AUTHOR]

Dredged sediment soil (DSS) is a type of soil that cannot be directly used for construction due to its hard and strong characteristics in dry conditions and its lose and weak characteristics in wet conditions. Several feasible engineering treatments to improve its properties include stabilization. The dredged sediment soil sample was collected from Lam Glumpang, Banda Aceh. This research aims to determine the shear strength and compressibility of lime-stabilized dredged sediment soil. Various physical and mechanical laboratory experiments were performed on both treated and untreated dredged sediment soil. In addition, scanning electron microscopy was used to examine the morphological change of stabilized dredged sediment soil with lime treatment (SEM). This experiment was carried out by mixing the soil and lime in different ratios of 2%, 4%, 6%, and 8% of the dry weight of the soil. According to AASHTO, the soil is classified as an A-4(8) soil type and according to the USCS, it is classified as an inorganic silt soil type (ML). Findings demonstrate that after lime stabilization, the shear strength and compressibility of dredged sediment soil gradually increased. The combination internal friction angle and cohesion value indicated that the shear strength of the soil was enhanced with the addition of lime up to 6% but then declined with the addition of lime to 8%. In addition, the study of micrographs indicates that the formation of aggregate particles has a substantial effect on the increase in shear strength and compressibility of treated dredged sediment soil. • Combinations of dredged sediment soil significantly develop a cementitious material. • Formation of aggregates has increase shear strength and compressibility parameters of treated soil. • Pozzolanic activity of lime on dredged sediment soil has shown the improvement shear strength and compressibility parameters. • Dredged sediment soil stabilized with lime has the potential to be used as an alternative subgrade construction material. [ABSTRACT FROM AUTHOR]

• Liming and labile C addition interacted to affect N 2 O emission. • Liming reduced N 2 O emission by 13–28% compared to unlimed soil following labile C addition. • Liming reduced the Q 10 of N 2 O following labile C addition. • Labile C addition facilitated denitrification. • N 2 O emission was positively related to (nirK + nirS)/(nosZI + nosZII) ratio and NO 3 − consumption. Lime has been widely applied for ameliorating soil acidification, potentially improving soil fertility and crop production. However, the long-term effects of liming and its interaction with carbon (C) availability on the emission and temperature sensitivity (Q 10) of greenhouse gas nitrous oxide (N 2 O) from acidic arable soil are not well understood. Here, the limed and unlimed acidic soils collected from a long-term field trial, amended with and without glucose as labile C, were incubated at 15℃ and 25℃ to investigate the responses of the emission and Q 10 of N 2 O and the underlying mechanisms. Results showed that liming had no effect on N 2 O emission without labile C addition. While after labile C addition, N 2 O emissions were 13–28% lower in the limed relative to unlimed soils, indicating that the mitigation effect of liming on N 2 O emission can mainly be seen when labile C (e.g., from rhizodeposition) is highly available in soils. High temperature did not affect N 2 O emissions from soil without labile C addition, but greatly increased N 2 O emissions after labile C addition with significantly lower Q 10 of N 2 O in the limed (1.23) relative to unlimed soils (1.48). These results suggested that liming could decrease the Q 10 of N 2 O emission in the presence of labile C. Elevated soil pH by liming caused increases in the abundances of N 2 O reductase genes (nosZI and nosZII) over nitrite reductase genes (nirK and nirS), thus significantly lowering (nirK + nirS)/(nosZI + nosZII) ratio compared to the unlimed soil, particularly after labile C addition. Soil N 2 O emissions were strongly positively related to the nirK abundance, (nirK + nirS)/(nosZI + nosZII) ratio, and NO 3 − consumption after labile C addition, indicating that denitrification was mostly responsible for N 2 O emission. Concluding, long-term liming could potentially reduce N 2 O emission and its Q 10 via decreased (nirK + nirS)/(nosZI + nosZII) ratio in acidic soils in the presence of labile C. [ABSTRACT FROM AUTHOR]

In paddy soils, plant availability of phosphorus (P) increases during the flooding period due to the reductive dissolution of iron (Fe)-bearing minerals on which P is sorbed. Soil chemical properties are a determining factor of P availability and are subject to change after prolonged paddy rice cultivation. The purpose of this study was to evaluate the effects of long-term application of rice straw compost and slaked lime on changes in soil chemical properties, particularly focusing on the increase in available P under reductive conditions. The rice cultivation experiment was launched in 1926 to clarify the effects of mineral fertilizer (NPK), rice straw compost, and slaked lime application on soil properties. The amount of P solubilized under reductive conditions was evaluated by the difference in the P extracted by the Bray II method with and without reductive treatment of the soil. Continuous application of NPK mineral fertilizer without slaked lime resulted in higher amounts of aluminum extracted by acid ammonium oxalate and P extracted by the Bray II method until the 92nd cropping, while the increase in the proportion of available P under reductive conditions was low. In contrast, the amounts of Fe extracted by acid ammonium oxalate and P solubilized under reductive conditions were higher with increasing application of compost. The application of the compost caused strongly reductive conditions in the soil during the flooding period, and the dissolution of P in the Fe-bound fraction was facilitated. However, excessive application of compost led to the dissolution of high amounts of Fe-bound P, resulting in a loss of Fe and P from the cultivated soil. These results suggest that excessive application of rice straw compost and no application of slaked lime may cause a decrease in available P in paddy soils. [ABSTRACT FROM AUTHOR]

The selection of an appropriate soil tillage system for improving yields and longevity is an important decision in sugarcane cultivation. In the present study, the effects of different soil tillage systems and methods of applying lime on sugarcane stalk and sugar yield performance as well as soil fertility parameters were evaluated throughout the sugarcane crop cycle. The experiments were established in two locations in April 2015 and conducted until August 2019, corresponding to a total of 4 growing seasons. A field study with a randomized block design was established with four replicates considering 4 treatments: conventional soil tillage system (CT), deep strip-tillage system (DT) and modified deep strip-tillage system (MDT), all with the same lime rate; and a standard treatment (control, CT without liming). Immediately after harvesting plant cane (18 months (mo) after planting), first ratoon (30 mo after planting), second ratoon (42 mo after planting) and third ratoon (54 mo after planting), soil samples were collected from a depth of 0.0–1.00 m, stratified every 0.2 m. Leaf material was sampled during the period of full vegetative growth. Analyses of soil chemical fertility, leaf concentrations of elements, and sugarcane yield components were performed. MDT was found to correct soil acidity most efficiently, mainly due to the positioning of the lime application. Under high aluminum saturation (AS), especially in deeper layers, deep lime placement was more effective and resulted in the best distributions of calcium (Ca2+) and magnesium (Mg2+), the highest base saturation (BS) and the lowest AS compared with the other treatments. Lime application was more important than the tillage system for improving the sucrose concertation and total recoverable sugar (TRS), whereas the tillage system affected the stalk yield and, consequently, the yield of sugar. Compared with DT and CT, the average stalk yield was 4.1% and 9.4% higher, respectively, under MDT at Macatuba and 6.3% and 15.3%, higher, respectively, under MDT at Piraju. Similarly, MDT improved average sugar yield by 3.7% and 10.4% at Macatuba and 6.1% and 16.3% at Piraju. Overall, long-term assessments, which are important for semi-perennial crops like sugarcane, showed that the both deep strip-tillage were most effective. • Strip-tillage system is an innovative soil tillage for sugarcane plantation. • Deep liming placement is important to reach longevity for sugarcane ratoons in highly weathered clayey soils. • Soil fertility is enhanced by deep liming placement. • Sugar and stalk yield is affected by the relation of lime application and tillage systems. [ABSTRACT FROM AUTHOR]

Hydrochar is produced through a process called hydrothermal carbonization (HTC) and constitutes a carbon-rich solid material with different remarkable applications. This study investigated the effects of wood ash on the physicochemical and morphological properties of biosludge-derived hydrochar in pelleted form relevant to the use of the pellets as a soil nutritional and liming agent and as a biofuel source. The hydrochar was mechanically compressed into uniformly-sized pellets under applied pressures of 4 and 8 kN after blending with varying percentages of wood ash in the order 0, 20 and 50%. The pure and blended pellets were characterized to determine the impact of wood ash on key properties, correlated to the two applications mentioned above. Results demonstrated a strong relationship between key features of the pellets and ash proportion. The wood ash-blended hydrochar pellets showed good hydrophobicity as a consequence of increased contents of alkali and alkaline earth metals, but were low in aromatic functional groups compared to the pure hydrochar pellet. Furthermore, the heating value of the pure hydrochar pellet was about 4% higher than that of its parent material and indicates that this pellet has the capacity to serve as a source of energy. The study generally reveals that blending hydrochar produced from biosludge under HTC conditions with up to 20%–50% of wood ash and mechanically compressing into homogeneous pellets has promising potential for a nutrient-rich material that can enhance soil fertility. • Sludge was used to produce hydrochar (HC) at temperature 200 °C via a HTC process. • Multi linear regression facilitates better understanding of HC pellets properties. • Strong correlation exists between key features of HC pellets and ash proportion. • The pellets with 50% ash contained the highest level of alkali and alkaline metals. • The HC pellet revealed potential to be used for soil and energy purposes. [ABSTRACT FROM AUTHOR]

The relationship between farmland bird populations and agricultural intensification has been well studied. However, the impact of variation in soil conditions and soil management is an exception, especially in upland (sub-alpine) farming systems. In this study, we examined the relationships between liming history, soil pH and patterns of foraging by Northern Lapwing, Vanellus vanellus , chicks in order to test the potential utility of soil amendment as a conservation intervention for shorebirds nesting in agricultural grasslands. Limed fields had higher soil pH than unlimed fields, and soil pH declined with the number of years since a field was last limed. The most important predictor of total earthworm abundance was soil organic matter with very few earthworms in peats of very high organic matter content. However, there was a marked additive effect of soil pH with earthworms more than twice as abundant at high (pH 6.0) as at the low (pH 3.5) extremes of soil pH recorded in the study. Specifically, at Lapwing chick foraging locations, the density of Allolobophora chlorotica , an acid-intolerant species of earthworm found just below the surface of the soil, was significantly higher than at randomly selected locations. These results suggest that liming helped to maintain breeding habitat quality for Lapwings and other species dependent on earthworms. This is of conservation significance in upland agricultural grasslands in the UK, where there has been a long-term reduction in agricultural lime use since the mid-20th century. Field-scale trials of liming would be valuable to test whether targetted amendment of soil pH in agriculturally improved grasslands could retain an important role in conservation management for shorebirds in upland landscapes where geology, high rainfall, and leaching tend to acidify soils over time. [ABSTRACT FROM AUTHOR]

Albic material is a widespread soil diagnostic material. The genesis of albic materials is known to be very sensitive to changes in environmental conditions resulting from natural or anthropic driving forces. Common agricultural practices like liming or drainage improvement are able to change the nature or the intensity of albic material genesis. The direction and the amplitude of such changes have however remained controversial because of a lack of quantitative approaches. In this paper, the intensity of the genesis of albic material was quantified in one forested Retisol and compared to those previously quantified in two limed and cropped soils sampled respectively far from and close to a drain line. Liming practices were found to decrease the intensity of the genesis of albic material by two thirds with reference to natural soil evolution under forest. Contrastingly, artificial drainage improvement initiated the development of physically-driven albic material genesis due to translocation of soil particles but without significant implication of any reduction process. The observed increase in the intensity of albic material genesis after artificial improvement was higher in the immediate vicinity of drains than was its decrease after liming applications. It was however the reverse for the rest of the soil between the drains. As a result, the overall effect of cultivation was a slowdown of the genesis of albic horizons by comparison to the natural evolution under forest. Such changes in both the nature and the intensity of albic material genesis clearly demonstrated that i) numerous genetic pathways may be simultaneously or successively active at a particular location, and ii) anthropic driving-forces like agricultural practices may be a way to favour one particular genetic pathway at the expense of another. [ABSTRACT FROM AUTHOR]

Soil pH plays a critical role in determining the overall rate of several important processes in the agricultural nitrogen cycle. During denitrification, the activity of nitrous oxide reductase (N 2 O-R) is reduced at low pH. This effect has led to suggestions that soil pH adjustment via liming to enhance the activity of this enzyme might be a viable agricultural greenhouse gas mitigation strategy by enhancing the reduction of N 2 O in the soil to climatically inert N 2 . We assessed the effect of liming on the apparent activity of N 2 O-R by measuring the denitrification end products, N 2 O and N 2 , in a series of short-term anaerobic incubations. We compared a weakly-buffered fluvial soil and a well-buffered, volcanic soil under different incubation temperatures and in the presence or absence of a ∼600 kg ha −1 cow urine-N amendment. Our results indicated that the liming effect was heavily modulated by soil type, temperature, and urine amendment. Liming (at rates of 1.5 and 3.0 t ha −1 for the volcanic soil and at rates of 5 and 10 t ha −1 for the fluvial soil) caused pH increases of between 0.43 and 1.25 pH units. The highest reductions in N 2 O in the fluvial soil occurred when the 1.5 t ha −1 rate was used in the fluvial soils under urine addition and at the higher temperature. The combined flux of N 2 O + N 2 did not change with liming. However, an interaction of soil type and urine amendment caused large differences in the partitioning of the denitrification end-products between N 2 O and N 2 – an effect that overwhelmed the relatively modest effects of liming. When the soils were amended with urine-N, the resulting denitrification gases from the volcanic soil were mostly in the form of N 2 O (60–77%), whereas in the fluvial soil the denitrification products were mostly in the form of N 2 and a much smaller portion were in the form of N 2 O (11–45%). Nevertheless, we found liming-induced enhancements of N 2 O-R of 15–20% (P < 0.05) in urine-amended, fluvial soil. We suggest some possible mechanisms that would explain such large differences in the N 2 O/(N 2 O + N 2 ) product ratio. [ABSTRACT FROM AUTHOR]

Short-term potential carbon (C) and nitrogen (N) mineralization of soil organic matter and belowground plant litter was determined in the top soil layer of a sandy soil of a short-rotation coppice (SRC) and the effect of addition of lime, mineral nitrogen and poplar roots was determined. Lime addition was equivalent to 1.2 mg CaCO 3 g − 1 , mineral N and root litter were added corresponding to 6.8 μg N g − 1 and 13.8 mg roots g − 1 soil respectively. Partitioning of carbon dioxide (CO 2 ) derived from lime and soil organic matter (SOM) was calculated by using stable isotope analysis of the CO 2 . In addition, particulate organic matter (POM) as well as microbial biomass carbon and nitrogen were analyzed after 51 days of incubation. Addition of lime decreased CO 2 derived from organic matter in all treatments, but the level of decrease varied with N and root litter addition. Microbial biomass C and N increased with N addition in soil without root litter but decreased with root litter, nevertheless an immobilization of mineral N was especially high in soil amended with root litter. Particulate organic matter (POM) decreased by 41% of its dry weight in root litter amended soil. Liming decreased decomposition of POM in these soils, whereas no effect was observed after addition of mineral nitrogen or mineral nitrogen and lime. These results show that liming has the potential to decrease C mineralization of humified organic matter as well as plant residues and that decreased mineralization of organic matter occurred after liming, even if mineral N was added. [ABSTRACT FROM AUTHOR]

Lignin markers in humic acids (HA, the alkali-soluble, acid-insoluble soil organic matter fraction) molecular features are explored to assess the extent to which plant biomacromolecules are progressively transformed by humification processes leading to stable C-forms in soils. Humic acids extracted from a collection of mountain calcimorphic soils from Sierra María-Los Vélez Natural Park (Southeastern Spain) under different use and management practices were studied in detail by visible and infrared (FT-IR) spectroscopies and analytical pyrolysis (Py-GC/MS). The HAs display a more or less marked lignin pattern defined by characteristic methoxyphenol assemblages released after pyrolysis that are associated to a typical infrared pattern including absorption frequencies bands at 1510, 1460, 1420, 1270, 1230 and 1030 cm −1 . This variability in the HA spectroscopic and pyrolytic patterns was used as a source of molecular-level surrogates to establish the balance between complementary mechanisms of soil C sequestration i.e., a selective preservation of lignin associated to raw organic matter and other plant-inherited macromolecules, or alternative mechanisms involving microbial breakdown or plant precursors and its condensation with microbial metabolites. We found that HAs in which the lignin signature was comparatively less marked also show high optical density values suggesting unsubstituted, condensed aromatic units and a chaotic organic structure, pointing to the presence of highly resilient carbon forms. Upon analytical pyrolysis, one group of HAs produced major yields of methoxyl-lacking aromatics (alkylbenzenes and alkylphenols), and poor yields of alkyl compounds, which suggest efficient cleavage of biomacromolecules and the occurrence of active microbial synthesis and condensation processes. In fact, these HAs also displayed broadband IR spectra, and visible spectra showing high optical density and polynuclear quinoid chromophors considered of fungal origin. Other group of HAs yielded upon pyrolysis conspicuous series of methoxyphenols and well-defined alkyl series (alkanes, alkenes and fatty acids). The IR spectra also displayed clear lignin and amide bands, as well as intense 2920 cm −1 band and a low optical density, indicative of a marked aliphatic character. This latter is interpreted as the result of recent diagenetic alteration processes of young organic matter and suggests that C sequestration mechanisms in these soils are mainly based on the stabilization of HAs from plant biomacromolecules and aliphatic structures. These differential lignin alteration patterns indicate that HAs are responsive to soil C sequestration mechanisms, which in the studied soils seem to relay upon microtopographical features rather than to changes in soil use and management. [ABSTRACT FROM AUTHOR]