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Your search keyword '"Bhargava, Gaurav"' showing total 1 results
Start Over Author "Bhargava, Gaurav" Topic ring formation (chemistry) Publication Year Range Last 50 years Publisher royal society of chemistry
1 results on '"Bhargava, Gaurav"'

1. Palladium-catalyzed [3C + 2C + 2C] cycloaddition of enynylidenecyclopropanes: efficient construction of fused 5-7-5 tricyclic systemsThis article is part of a ChemComm ‘Catalysis in Organic Synthesis’ web-theme issue showcasing high quality research in organic chemistry. Please see our website (http://www.rsc.org/chemcomm/organicwebtheme2009) to access the other papers in this issue.Electronic supplementary information (ESI) available: Experimental procedures and spectroscopic data of previously unknown reaction products. CCDC 748242. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b919258a

Author

Bhargava, Gaurav, Trillo, Beatriz, Araya, Marisel, López, Fernando, Castedo, Luis, and Mascareñas, José L.

Subjects
*RING formation (Chemistry), *PALLADIUM catalysts, *PROPANE, *CATALYSIS, *ORGANIC synthesis, *ALKYNES, *ALKENES, *CYCLIC compounds
Abstract

We report a Pd-catalyzed intramolecular [3C + 2C + 2C] cycloaddition between alkylidenecyclopropanes, alkynes and alkenes. The method provides synthetically relevant 5-7-5 tricyclic structures, with good chemoselectivity and complete diastereoselectivity. [ABSTRACT FROM AUTHOR]

Published
2010
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