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To support the transformation to clean low carbon technologies, there is a demand for critical metals such as nickel. Awaruite is a less common nickel-bearing mineral with unique properties and responses to mineral separation. This paper presents the findings of a flotation study to recover awaruite from the Baptiste ultramafic deposit, located in central British Columbia, Canada. Nickel recoveries of up to 65% at the rougher stage were obtained with xanthate as a collector at a pH level of 4.5. Awaruite flotation was shown to be highly dependent on the slurry pH. At weakly acidic conditions, the awaruite surface is activated through the dissolution of the passivation layer formed during grinding in alkaline conditions. Desliming was shown to reduce the acid consumption required to maintain the pH, probably by removing the highly reactive serpentine slimes generated during grinding. Rougher, followed by cleaner stages of flotation, showed that a high-grade concentrate can be produced with up to 45% nickel, 1.3% cobalt, 0.7% copper and negligible concentrations of penalty elements, such as arsenic, lead, and selenium, among others. A nickel flotation concentrate from an awaruite deposit is a promising feedstock for not only stainless-steel production but also for clean energy technologies. [ABSTRACT FROM AUTHOR]

Block and panel caving mines are increasingly being proposed for the excavation of massive ore-bodies located at depth. The lack of selectivity associated with the mining methods results in both ore and waste being caved and transported through material handling systems to the surface for processing and waste rock disposal. Sensor-based sorting systems provide an opportunity to automate the discrimination between ore grades and rock types, providing an enhanced level of selectivity for ore control and thereby improving mine productivity. To evaluate the potential to add value to a caving operation, a sensor-based ore sorting study, incorporating bulk and particle sorting systems, was carried out for the New Afton block cave mine. Results showed that rock from the copper-gold porphyry deposit is amenable to prompt gamma neutron activation analysis, and to X-ray fluorescence sensors. A conceptual flowsheet, where both technologies are used as separate unit operations, was evaluated. Test samples of varying copper head grades allowed an ore value calculation method to be developed based on the integration of continuous bulk sorting and particle sorting. The calculation method can be applied to block models of a future cave at New Afton and used to evaluate the change in the economic footprint. It was found that the concept demonstrated an improvement in the net smelter return of excavated material. [ABSTRACT FROM AUTHOR]

[Display omitted] • Awaruite passivates in neutral and alkaline media. • Awaruite readily floats in acidic media with xanthate. • Xanthate chemisorbs and oxidizes at the awaruite surface in acidic media. Awaruite is a native nickel–iron alloy (Ni 3 Fe), found in serpentinized ultramafic rocks, that has gained interest as a possible source of nickel. FPX Nickel is advancing a very large awaruite deposit in central British Columbia, Canada, on which this work is based. To date there is limited information available regarding the flotation conditions to selectively concentrate awaruite from gangue minerals in serpentinite ores. The aim of this work was to investigate the floatability of awaruite in different solution conditions with a xanthate collector. Awaruite readily floated in acidic solution with a xanthate collector but not in neutral and alkaline solutions. Voltammograms on awaruite indicated that the alloy shows an active passive transition behaviour in acidic solution and passive behaviour in neutral and alkaline solutions. The passivation layer formed in neutral and alkaline solutions showed to inhibit the interaction between xanthate and awaruite surface. Infrared spectra on awaruite showed the presence of xanthate compounds attached to the surface in acidic condition at potentials higher than the reversible potential of xanthate/dixanthogen. Based on experimental results, it was postulated that xanthate chemisorbs on awaruite and then it oxidizes to form dixanthogen. Also, it was demonstrated that when passivated, awaruite quickly activates in acidic solution, good flotation performance was achieved with 10 min of conditioning, and similar performance was obtained after 30 min of conditioning. This work serves as a confirmation that is possible to float awaruite using xanthate, a well-known collector that offers selectivity over oxides and silicate minerals, which are the main gangue minerals in serpentinite ores. [ABSTRACT FROM AUTHOR]