29 results on '"Lei, Yan"'
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2. Crystal structure of (E)-N′-benzylidene-1-methyl-4-nitro-1H-pyrrole-2-carbohydrazide
- Author
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Zhijun Wang, Chengyong Zhou, Lei Yan, and Jinglin Wang
- Subjects
crystal structure ,pyrrole-2-carbohydrazide ,aroylhydrazones ,hydrogen bonding ,π–π interactions ,Crystallography ,QD901-999 - Abstract
In the title compound, C13H12N4O3, the dihedral angle between the planes of the pyrrole and benzene rings is 7.47 (1)°. In the crystal, molecules are arranged in sheets lying parallel to (101). Neighbouring sheets are linked by N—H...O hydrogen bonds, weak π–π [centroid–centroid distance between the pyrrole rings = 3.765 (11) Å] and C—H...π interactions, forming a three-dimensional structure.
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- 2014
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3. Synthesis, characterization and X-ray crystal structures of oxidovanadium(V) and dioxidomolybdenum(VI) complexes derived from 2-bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide.
- Author
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Lei, Yan, Yang, Qiwen, Bai, Yang, and Tan, Yao
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CRYSTAL structure , *X-rays , *SCHIFF bases , *SINGLE crystals , *HYDROGEN bonding , *COMPLEX ions - Abstract
A new oxidovanadium(V) complex, [VOL(OEt)(EtOH)] (1), and a new dioxidomolybdenum(VI) complex, [MoO2L(OH2)] (2), where L is the dianionic form of 2-bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide, have been synthesized and structurally characterized by physico-chemical methods and single crystal X-ray determination. X-ray analysis indicates that the V and Mo ions in the complexes are in octahedral coordination. Crystal structures of the complexes are stabilized by hydrogen bonds. The catalytic property for epoxidation of styrene by the complexes was evaluated. Both complexes have effective catalytic properties for the epoxidation of styrene, with conversions over 76% and selectivities over 92%. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
4. Synthesis and Crystal Structures of 4-Chloro-N′-(4-hydroxy-3-nitrobenzylidene)benzohydrazide monohydrate and 4-Chloro-N′-(4-hydroxy-3-methoxybenzylidene)benzohydrazide monohydrate
- Author
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Lei, Yan, Li, Ting-Zhen, Fu, Chuan, Guan, Xiao-Lin, and Tan, Yao
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- 2011
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5. Advanced BaLi2Ti6O14 Anode Fabricated via Lithium Site Substitution by Magnesium
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Haoxiang Yu, Peng Li, Yaoyao Wu, Miao Shui, Xiaoting Lin, Shangshu Qian, Nengbing Long, Jie Shu, and Lei Yan
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Materials science ,Renewable Energy, Sustainability and the Environment ,Magnesium ,General Chemical Engineering ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,Crystal structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Anode ,Ion ,Storage material ,Chemical engineering ,chemistry ,Environmental Chemistry ,Lithium ,Particle size ,0210 nano-technology - Abstract
Advanced Na- and Mg-doped BaLi2Ti6O14 anodes in the form of BaLi1.9M0.1Ti6O14 (M = Na, Mg) are successfully fabricated and evaluated as lithium storage materials for rechargeable lithium-ion batteries. The effects of Na- and Mg-dopings on the crystal structure, surface morphology and electrochemical behavior are investigated for BaLi2Ti6O14. The results show that both Na and Mg elements are successfully introduced into the Li site, and they do not alter the basic structure of BaLi2Ti6O14. The resulting BaLi1.9M0.1Ti6O14 (M = Na, Mg) exhibit significant improvements on the electrochemical performance in terms of the rate capability and cycle performance. Especially for BaLi1.9Mg0.1Ti6O14, it can deliver an initial charge capacity of 111.7 mAh g–1 at 5C. After 200 cycles, it still can maintain a reversible capacity of 90.1 mAh g–1 with the capacity retention of 80.7%. The enhanced electrochemical properties can be attributed to the reduced particle size, decreased charge transfer resistance and enhanced ion...
- Published
- 2016
6. Sr0.95In0.05Li2Ti6O14: A high performance lithium host material
- Author
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Haoxiang Yu, Peng Li, Jie Shu, Yanyu Zhang, Lei Yan, Nengbing Long, Shangshu Qian, Miao Shui, and Xiaoting Lin
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Materials science ,Renewable Energy, Sustainability and the Environment ,Diffusion ,Doping ,Analytical chemistry ,Energy Engineering and Power Technology ,chemistry.chemical_element ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Anode ,Host material ,chemistry ,Lithium ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Electronic conductivity ,0210 nano-technology - Abstract
Via Sr-site substitution, a series of Sr 0.95 M 0.05 Li 2 Ti 6 O 14 (M z+ = Na + , Cu 2+ , In 3+ ) are prepared as anode materials for lithium-ion batteries. It is found that the introduction of Na + , Cu 2+ or In 3+ into the crystal lattice can reduce the charge-transfer resistance and improve the lithium-ion diffusion coefficient of SrLi 2 Ti 6 O 14 . Especially for In 3+ -doping, it exhibits more obvious effect on these improvements. Furthermore, the substitution of Sr 2+ by In 3+ can also enhance the electronic conductivity via inducing a reduction of an equivalent number of Ti cations from Ti 4+ to Ti 3+ . As a result, Sr 0.95 In 0.05 Li 2 Ti 6 O 14 shows the best cycle and rate properties among all as-prepared samples. In addition, in-situ observation also proves that Sr 0.95 In 0.05 Li 2 Ti 6 O 14 is a zero-strain lithium storage compound during charge/discharge process. As a result, it delivers a lithium storage capacity of 136.4 mAh g −1 at 200 mA g −1 , 126.3 mAh g −1 at 400 mA g −1 and 121.0 mAh g −1 at 600 mA g −1 . In contrast, SrLi 2 Ti 6 O 14 only presents a charge capacity of 138.3 mAh g −1 at 200 mA g −1 , 120.3 mAh g −1 at 400 mA g −1 and 111.3 mAh g −1 at 600 mA g −1 . Therefore, In 3+ -doping is an effective method to enhance the electrochemical properties of SrLi 2 Ti 6 O 14 .
- Published
- 2016
7. Synthesis, crystal structure, density functional theory calculations, and antimicrobial activity of silver(I) complex derived from 2‐aminobenzothiazole ligand.
- Author
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Jiang, Jian‐Hong, Lei, Yan‐Hua, Ou, Yang‐Hao, Li, Xu, Pi, Yi‐Yuan, Ye, Li‐Juan, Li, Qiang‐Guo, and Li, Chuan‐Hua
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DENSITY functional theory , *TRICLINIC crystal system , *CRYSTAL structure , *LIGANDS (Chemistry) , *SCHIFF bases , *ELEMENTAL analysis , *SILVER , *COORDINATION compounds - Abstract
Reaction of silver nitrate with 2‐aminobenzothiazole (abbreviated as Habt) in methanol at 45°C gave mononuclear complex of formula [Ag (Habt)2]NO3•CH3OH. The structure of the complex was characterized by infrared (IR) spectra, single crystal X‐ray diffraction, and elemental analysis. X‐ray diffraction analysis indicated that the title complex was crystallized in the triclinic crystal system with space group P–1, in which silver(I) ion was coordinated to two 2‐aminobenzothiazole ligands through the benzothiazol nitrogen atom. Theoretical study of the complex was carried out by density functional theory (DFT) B3LYP method. The antimicrobial effects of the ligand and its silver(I) complex were evaluated by bio‐microcalorimetry on the growth of Schizosaccharomyces pombe (S. pombe). Some quantitative metabolic parameters, such as growth rate constant (k), maximum heat power (Pmax), inhibition ratio (I), and half inhibition concentration (IC50), were derived from the metabolic power–time curves of S. pombe growth. The half inhibition concentration (IC50) of the ligand was calculated to be 2.58 × 10−3 mol L−1. The complex could strongly influence the lag phase of S. pombe. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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8. Construction of lanthanide coordination polymers based on mixed terpyridyl and dicarboxylate ligands: Syntheses, structures and luminescent properties
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Huai-Ming Hu, Lei Yan, Shi He, Chao Bai, Li-Li Xue, and Bing Xu
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Lanthanide ,chemistry.chemical_classification ,Adipic acid ,Oxalic acid ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Coordination complex ,Inorganic Chemistry ,chemistry.chemical_compound ,Crystallography ,chemistry ,Materials Chemistry ,Ceramics and Composites ,Carboxylate ,Physical and Theoretical Chemistry ,Isostructural ,Terpyridine ,0210 nano-technology - Abstract
Reaction of hydrated lanthanide (III) nitrates and 4’-(3-carboxyphenyl)-4,2′:6′,4″-terpyridine (HL) under hydrothermal conditions in the presence of auxiliary ligands afforded four series of lanthanide coordination polymers, [Ln2(L)2(ox)2(H2O)2]n (Ln = Sm (1), Eu (2)), [Ln(L)(glu)]n (Ln = Eu (3)), [Ln(L)(adip)(H2O)]n (Ln = Pr (4), Sm (5)), [Ln2(L)2(1,3-bdc)2]n (Ln = Pr (6), Nd (7), Sm (8), Eu (9)), where H2ox, H2glu, H2adip and H2(1,3-bdc) denote oxalic acid, glutaric acid, adipic acid and benzene-1,3-dicarboxylic acid, which have been characterized by elemental analysis, IR and single crystal X-ray diffraction. Compounds 1 and 2 possess similar structures and display a two dimensional 6-connected hxl net ground on loop-like binuclear Ln2 units with the (36·46·53) topology. Compound 3 presents a fascinating 3D framework with paddle-wheel units, which exhibits a 2-nodal (3,10)-connected 3,10-T9 net with (418·624·83)(43)2 topology. Isostructural compounds 4 and 5 exhibit a (3,6)-connected kgd net with (43)2(46·66·83) topology. Isomorphous 6–9 feature a 3D (3,10)-connected 3,10-T9 net with (418·624·83)(43)2 topology. The structural diversity adequately demonstrate the abundant coordination chemistry of carboxylate terpyridine derivatives and the coordination geometries of LnIII ions, as well as the effects of introducing auxiliary ligands. Moreover, detailed discussion toward the photoluminescence and thermal stabilities of 1–9 were also conducted.
- Published
- 2020
9. Morphological, electrochemical and in-situ XRD study of LiNi0.6Co0.2Mn0.1Al0.1O2 as high potential cathode material for rechargeable lithium-ion batteries
- Author
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Lei Yan, Nengbing Long, Shangshu Qian, Haoxiang Yu, Peng Li, Jie Shu, Minghe Luo, Miao Shui, and Xiaoting Lin
- Subjects
Diffraction ,Materials science ,Mechanical Engineering ,Doping ,Metals and Alloys ,chemistry.chemical_element ,Mineralogy ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Ion ,Structural change ,chemistry ,Chemical engineering ,Mechanics of Materials ,Materials Chemistry ,Lithium ,Particle size ,0210 nano-technology - Abstract
By using a simple high temperature solid state reaction, LiNi0.6Co0.2Mn0.1Al0.1O2 is prepared via Ni site dual substitution with Mn and Al. Structural observation reveals that the as-prepared sample can be indexed to an α-NaFeO2 type single phase with R-3m space group. Morphology and particle size investigations present that Mn and Al co-doped LiNi0.8Co0.2O2 is composed of micro-sized secondary particles (5–20 μm) agglomerated from highly packed primary particles (1–2 μm). Charge–discharge tests demonstrate that LiNi0.6Co0.2Mn0.1Al0.1O2 can reversibly react with lithium between 2.5 and 4.9 V with a high discharge capacity of 202.0 mAh g−1. This favorable electrochemical performance is attributed to the stable crystal structure after Mn and Al dual doping. This quasi-reversible structural change is also proved by in-situ X-ray diffraction study in this work.
- Published
- 2016
10. Enhanced electrochemical properties of Mg2+ doped Li2Na2Ti6O14 anode material for lithium-ion batteries
- Author
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Mengmeng Lao, Xiaoting Lin, Nengbing Long, Miao Shui, Shangshu Qian, Lei Yan, Haoxiang Yu, Peng Li, and Jie Shu
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Materials science ,Rietveld refinement ,General Chemical Engineering ,Doping ,Inorganic chemistry ,chemistry.chemical_element ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,Anode ,Ion ,chemistry ,Phase (matter) ,Lithium ,0210 nano-technology - Abstract
A series of Mg 2+ doped Li 2 Na 2 Ti 6 O 14 in the form of Li 2-x Mg x Na 2 Ti 6 O 14 (x = 0.0, 0.05, 0.1, 0.15, 2.0) are successfully synthesized via a solid-state method. Phase structure and surface morphology analyses show that all samples maintain high purity and low dose of Mg 2+ doping does not change the crystal structure and surface morphology of Li 2 Na 2 Ti 6 O 14 . According to the Rietveld refinement result, it is known that Mg 2+ takes the tetrahedral 8i sites shared with Li + in the structure. Galvanostatic charge/discharge tests demonstrate that Li 1.95 Mg 0.05 Na 2 Ti 6 O 14 exhibits higher reversible capacity (264.6 mAh g −1 ) and better cycling performance (capacity retention of 82.7% after 50 cycles) than other materials. Even cycled at high current density of 500 mA g −1 , Li 1.95 Mg 0.05 Na 2 Ti 6 O 14 still provides the specific capacity of 167.4 mA g −1 after 100 cycles, indicating that low dose of Mg 2+ doping can effectively improve the lithium storage capability of Li 2 Na 2 Ti 6 O 14. The enhanced electrochemical properties are contributed to the improved electronic conductivity and ionic diffusion coefficient of Li 2 Na 2 Ti 6 O 14 via Mg 2+ doping. Besides, the lithiation/delithiation behavior of Li 1.95 Mg 0.05 Na 2 Ti 6 O 14 is also studied by homemade in-situ X-ray diffraction device, which reveals that Li 1.95 Mg 0.05 Na 2 Ti 6 O 14 exhibits high structural and electrochemical reversibility as lithium storage material.
- Published
- 2016
11. Zinc and aluminum complexes derived from 2, 4-N, N′-disubstituted 1, 3, 5-triazapentadienyl ligands: Synthesis, characterization and catalysis of the ring-opening polymerization of rac-lactide
- Author
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Dan Tian, Lei Yan, Meisu Zhou, Qianwen Xie, and Hongbo Tong
- Subjects
Lactide ,Stereochemistry ,Chemistry ,Ligand ,Tetrahedral molecular geometry ,chemistry.chemical_element ,Zinc ,Crystal structure ,Triclinic crystal system ,Medicinal chemistry ,Ring-opening polymerization ,Catalysis ,Inorganic Chemistry ,chemistry.chemical_compound ,Materials Chemistry ,Physical and Theoretical Chemistry - Abstract
Bis(1,3,5-triazapentadienate)zinc complexes [N(Ph)C(R)NC(R)N(SiMe3)]2Zn (R = NMe2, 1; 1-piperidino, 2) and (1,3,5-triazapentadienate)aluminum dichloride [N(Ph)C(NMe2)NC(NMe2)N(SiMe3)]AlCl2·C9H18N6 (3) were synthesized and structurally characterized by X-ray crystallography and spectroscopic techniques. The X-ray structures of 1–3 showed that they crystallize in the triclinic system and prefer coordination to the zinc and aluminum centers via the terminal N atoms of the NCNCN ligand backbone, affording tetrahedral geometry. The catalytic properties of 1 and 2 were evaluated.
- Published
- 2015
12. Zinc(II) and Nickel(II) Complexes Based on Schiff Base Ligands: Synthesis, Crystal Structure, Luminescent and Magnetic Properties
- Author
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Zhiliang Liu, Yu-Fei Ji, Lei Yan, Xiaoting Qin, Yanqin Wang, Shuai Ding, and Yanfei Gao
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Schiff base ,Denticity ,Stereochemistry ,chemistry.chemical_element ,Crystal structure ,Zinc ,Inorganic Chemistry ,chemistry.chemical_compound ,Nickel ,Crystallography ,chemistry ,Transition metal ,Zinc Cluster ,Azide - Abstract
Three new phenolate oxygen bridged transition metal complexes [Zn3(HL1)3(μ3-CH3O)]·(ClO4)2(H2O)3 (1), [Ni2(HL1)2(μ1,1-N3)(o-vanillin)]·H2O (2), [Ni3(HL2)2(PhCOO)2(PhCOOH)2(EtOH)2] (3) have been synthesized by metal ions and potentially multidentate Schiff base ligands (H2L1 = 2-((1-hydroxy-2-methylpropan-2-ylimino) methyl)-6-methoxyphenol; H3L2 = (E)-1-((2-hydroxy-3-methoxy-benzylidene)amino)ethane-1,2-diol). All the three complexes 1, 2, and 3 have been characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction studies. Crystal structures reveal that complex 1 is a trinuclear incomplete cubane-like zinc cluster whereas complex 2 is a dinuclear nickel complex bridged by azide, and compound 3 is a trinuclear nickel complex. The luminescent property for complex 1 and magnetic behaviors for complexes 2 and 3 have been investigated.
- Published
- 2013
13. Crystal structure and magnetic properties of two dinuclear iron(III) complexes with multidentate Schiff-base ligands
- Author
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Zhiliang Liu, Cai-Ming Liu, Lei Yan, Yu-Fei Ji, and Shuai Ding
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Schiff base ,Denticity ,Chemistry ,Metal ions in aqueous solution ,Inorganic chemistry ,Crystal structure ,Magnetic susceptibility ,Ion ,chemistry.chemical_compound ,Crystallography ,Octahedral molecular geometry ,Materials Chemistry ,Antiferromagnetism ,Physical and Theoretical Chemistry - Abstract
Two dinuclear iron(III) compounds, [Fe2(HL1)2(L1)2] · MeOH (1) and [Fe2(μ- )3] (2) [L1 = N-(2-hydroxypropyl)(3-methoxysalicylaldimine) and = 1,2-bis(2-hydroxybenzylidene) hydrazine], have been synthesized and characterized. Structural analysis of 1 shows that the six-coordinate Fe(III)'s are linked by two alkoxo oxygen atoms from two Schiff-base ligands to form a rectangular arrangement of metal ions and oxygen atoms. The distance of these two Fe(III) ions is 3.2122(8) A. In 2, three Schiff-base ligands coordinate two Fe(III) ions in a tetradentate mode; each iron is six coordinate with octahedral geometry. The Fe–Fe distance is 3.9304(10) A. Magnetic susceptibility (2–300 K) indicates an antiferromagnetic interaction between the two oxygen-bridged Fe(III) ions with J = −13.6 cm−1 for 1.
- Published
- 2011
14. Crystal structures and luminescence of two cadmium(II) polymers constructed from aromatic polycarboxylate and bis(1,2,4-triazol-1-yl)methane ligands
- Author
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Lei Yan, Shang-Yuan Liu, and Li Tian
- Subjects
chemistry.chemical_classification ,Inorganic chemistry ,Supramolecular chemistry ,Polymer ,Crystal structure ,Fluorescence ,Methane ,Coordination complex ,Isophthalic acid ,Crystallography ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Physical and Theoretical Chemistry ,Luminescence - Abstract
Two new coordination compounds, {[Cd2(btrm)(ip)2(H2O)2] · 2H2O} n (1) and {[Cd2(btrm)(hip)2(H2O)4] · 3H2O} n (2) (btrm = bis(1,2,4-triazol-1-yl)methane, H2ip = isophthalic acid, H2hip = 5-hydroxy isophthalic acid), have been synthesized and structurally characterized. Compound 1 is a 3-D network with CdSO4 topology. Compound 2 contains 1-D ladder structures, which are interconnected by classical hydrogen-bonding interactions (O–H ··· O) to lead to 3-D supramolecular architectures. Luminescence was performed on 1 and 2, both of which showed strong fluorescent emissions in the solid state at room temperature.
- Published
- 2011
15. Crystal structure of [1-(2,6-diiso-propyl-phen-yl)-2,4-bis-(di-methyl-amino)-5-tri-methyl-silyl-1,3,5-tri-aza-penta-dienyl-κ(2) N (1),N (5)](tri-phenyl-phosphane-κP)copper(I)
- Author
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Lei Yan, Hongbo Tong, Feiguang Li, and Meisu Zhou
- Subjects
crystal structure ,Coordination sphere ,Crystallography ,Silylation ,Ligand ,Chemistry ,chemistry.chemical_element ,triazapentadienyl ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,Bioinformatics ,Medicinal chemistry ,Copper ,Data Reports ,Bond length ,Delocalized electron ,Molecular geometry ,triazapentadienyl ,QD901-999 ,copper(I) complex ,General Materials Science - Abstract
The title complex, [Cu(C21H38N5Si)(C18H15P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe3(Dipp = 2,6-diisopropylphenyl), Me2NCN, CuCl and PPh3. The CuIatom has a distorted trigonal–planar coordination sphere. The triazapentadienyl ligand acts as a κ2-donor. The N—Cu—N bond angle is 95.88 (14)°. In the triazapentadienyl fragment, the C—N bond lengths are in the range 1.328 (5)–1.349 (5) Å, which indicates delocalization of the π-electrons in the NCNCN system.
- Published
- 2015
16. Fabrication and Characterization of AlxCoFeNiCu1−x High Entropy Alloys by Laser Metal Deposition
- Author
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Frank W. Liou, Yunlu Zhang, Lei Yan, Sreekar Karnati, and Xueyang Chen
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high entropy alloy ,elemental powder ,laser metal deposition ,010302 applied physics ,Materials science ,High entropy alloys ,Alloy ,Metallurgy ,chemistry.chemical_element ,02 engineering and technology ,Surfaces and Interfaces ,Crystal structure ,engineering.material ,021001 nanoscience & nanotechnology ,Microstructure ,01 natural sciences ,Surfaces, Coatings and Films ,Corrosion ,chemistry ,Aluminium ,0103 physical sciences ,Vickers hardness test ,Materials Chemistry ,engineering ,0210 nano-technology ,Electron backscatter diffraction - Abstract
High entropy alloys are multicomponent alloys that have at least five different principal elements as alloying elements. Each of these elements has an atomic percentage between 5% and 35%. Typically, they form body-centered cubic (bcc) or face-centered cubic (fcc) structure and are known to possess excellent mechanical properties, corrosion resistance, excellent electric and magnetic properties. Owing to their excellent corrosion and wear resistance, researchers are focusing on employing these materials as coatings. In this research, Laser Metal Deposition (LMD) was used to fabricate AlxCoFeNiCu1−x (x = 0.25, 0.5, 0.75) high entropy alloys from elemental powder based feedstocks. Thin wall claddings fabricated via LMD were characterized by a variety of techniques. Data from X-ray Diffraction (XRD) and Electron Back Scatter Diffraction (EBSD) suggested that with increase in Al content and decrease in Cu content, a change in crystal structure from a predominantly fcc to a combined fcc and bcc structure can be observed. The microstructure of the material was observed to be columnar dendritic. Data from standard less EDS analysis showed that the dendritic phase was Fe and Co enriched while the matrix was Cu and Al enriched in all the considered high entropy alloy fabrications. The Vickers hardness data was used to estimate the mechanical properties of these deposits. Results also showed that with the increase in aluminum content, AlxCoFeNiCu1−x displayed higher hardness. The high hardness values imply potential applications in wear resistant coatings.
- Published
- 2017
17. 4-(o-Methoxyphenyl)-1,3,4,4a,5,6,7,8a-octahydro-2H-pyrano[2,3-d]pyrimidine-2-thione
- Author
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Lei Yan, Yuanjiang Pan, and Yulin Zhu
- Subjects
Pyrimidine ,Stereochemistry ,education ,Intermolecular force ,Cyclohexane conformation ,Biginelli reaction ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,Ring (chemistry) ,chemistry.chemical_compound ,chemistry ,Pyran ,General Materials Science ,Benzene ,human activities - Abstract
The title compound, C14H18N2O2S, which was obtained from an extended Biginelli reaction, contains a pyran ring with a chair conformation, a pyrimidine ring with a half-chair conformation and a benzene ring. The crystal structure is stabilized by an intermolecular hydrogen-bond network.
- Published
- 2005
18. 4-p-Tolyl-1,3,4,4a,5,6,7,8a-octahydro-2H-pyrano[2,3-d]pyrimidin-2-one
- Author
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Lei Yan, Yulin Zhu, and Yuanjiang Pan
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Pyrimidine ,Stereochemistry ,Cyclohexane conformation ,Intermolecular force ,Biginelli reaction ,General Chemistry ,Crystal structure ,Condensed Matter Physics ,Ring (chemistry) ,chemistry.chemical_compound ,chemistry ,Pyran ,General Materials Science ,Benzene - Abstract
The title compound, C14H18N2O2, which was obtained from an extended Biginelli reaction, contains a pyran ring with a chair conformation, a pyrimidine ring with a half-chair conformation and a benzene ring. The crystal structure is stabilized by an intermolecular hydrogen-bond network involving both NH groups and the carbonyl group.
- Published
- 2005
19. Synthesis and crystal structures of copper, nickel and zinc complexes derived from 2-((2-(pyrrolidin-1-yl)ethylimino)methyl)phenol with antimicrobial activity.
- Author
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Tan, Yao and Lei, Yan
- Subjects
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ZINC compounds , *SCHIFF bases , *COPPER crystals , *CRYSTAL structure , *ANTI-infective agents , *ESCHERICHIA coli - Abstract
Five new copper(II), nickel(II) and zinc(II) complexes derived from 2-((2-(pyrrolidin-1-yl)ethylimino)methyl)phenol were synthesized and structurally characterized. Single crystal X-ray analysis indicates that the Cu atoms in the tetranuclear complexes 1 and 2 are in a square pyramidal coordination, the Ni atoms in the trinuclear complexes 3 and 4 are in an octahedral coordination and the Zn atom in the mononuclear complex 5 is in a tetrahedral coordination. In vitro bacterial viability revealed that the copper and zinc complexes have effective antimicrobial activity against B. subtilis , S. aureus , E. coli and P. fluorescens , and general activity against the fungal strains C. albicans and A. niger. [Display omitted] Five new copper(II), nickel(II) and zinc(II) complexes, [Cu 4 Cl 2 (μ 1,1 -N 3) 4 (DMF) 2 ] (1), [Cu 4 Br 2 (μ 1,1 -N 3) 4 (DMF) 2 ] (2), [Ni 3 L 2 (CH 3 COO) 4 ]CH 3 OH (3), [Ni 3 L 2 (CH 3 COO) 2 (μ 1,1 -N 3) 2 (CH 3 OH) 2 ] (4) and [Zn(LH)I 2 ]CH 3 OH (5), were designed and successfully synthesized using the Schiff base ligand 2-((2-(pyrrolidin-1-yl)ethylimino)methyl)phenol (HL). All the synthesized complexes were characterized using different physico-chemical and spectroscopic methods, like elemental analysis, infrared spectra and single crystal X-ray diffraction. The X-ray structural analysis showed that the Cu atoms in the tetranuclear complexes 1 and 2 are in a square pyramidal coordination, the Ni atoms in the trinuclear complexes 3 and 4 are in an octahedral coordination and the Zn atom in the mononuclear complex 5 is in a tetrahedral coordination. The Schiff base ligand was coordinated to the metal atoms through the phenolate oxygen, imino nitrogen and/or pyrrolidine nitrogen atoms. The biological study indicated that the copper and zinc complexes have interesting antimicrobial activity against B. subtilis , S. aureus , E. coli and P. fluorescens , with MIC values of 0.6–2.3 μmol/L. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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20. Improved stoichiometry and photoanode efficiency of thermally evaporated CdS film with quantum dots as precursor
- Author
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Dongluo Yang, Qiuquan Guo, Jun Yang, Libo Fan, Lei Yan, Ming Li, Haifeng Zhao, Peng Wang, Zhi Zheng, and Hongpei Han
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Materials science ,chemistry.chemical_element ,Bioengineering ,Nanotechnology ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,7. Clean energy ,01 natural sciences ,chemistry.chemical_compound ,General Materials Science ,Electrical and Electronic Engineering ,Mechanical Engineering ,General Chemistry ,021001 nanoscience & nanotechnology ,Microstructure ,Cadmium sulfide ,0104 chemical sciences ,chemistry ,Chemical engineering ,Mechanics of Materials ,Quantum dot ,Atomic ratio ,0210 nano-technology ,Tin ,Stoichiometry ,Indium - Abstract
Good stoichiometry of cadmium sulfide (CdS) film facilitates its application in photovoltaic devices; however, traditional thermal evaporation usually results in a Cd-deficient CdS film at a low-substrate temperature. In this study, Cd-rich CdS quantum dots (QDs) were synthesized by a facile co-precipitation method and used as the precursor to thermally evaporate CdS film on indium tin oxide-coated glass (ITO/glass). As a consequence, the stoichiometry of CdS film was greatly improved with atomic ratio of Cd to S restored to unity. More importantly, the newly developed CdS film, with its rod-like surface microstructure, acted as an efficient photoanode in a photoelectrochemical (PEC) cell. Its properties, including surface morphology and roughness, crystal structure, chemical composition, film thickness, energy-level structure and photosensitivity, are studied in detail.
- Published
- 2015
21. Crystal structure of (E)-N′-benzylidene-1-methyl-4-nitro-1H-pyrrole-2-carbohydrazide
- Author
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Chengyong Zhou, Lei Yan, Jinglin Wang, and Zhijun Wang
- Subjects
crystal structure ,pyrrole-2-carbohydrazide ,Hydrogen bond ,π–π interactions ,General Chemistry ,Crystal structure ,Dihedral angle ,Carbohydrazide ,hydrogen bonding ,Condensed Matter Physics ,Bioinformatics ,Data Reports ,lcsh:Chemistry ,Crystal ,chemistry.chemical_compound ,Crystallography ,lcsh:QD1-999 ,chemistry ,π–π interactions ,Nitro ,aroylhydrazones ,General Materials Science ,Benzene ,Pyrrole - Abstract
In the title compound, C13H12N4O3, the dihedral angle between the planes of the pyrrole and benzene rings is 7.47 (1)°. In the crystal, molecules are arranged in sheets lying parallel to (101). Neighbouring sheets are linked by N—H...O hydrogen bonds, weak π–π [centroid–centroid distance between the pyrrole rings = 3.765 (11) Å] and C—H...π interactions, forming a three-dimensional structure.
- Published
- 2014
22. Synthesis, X-ray structural characterization, and catalytic property of binuclear oxidovanadium(V) complex with 2,4-dibromo-6-(5-methylamino-[1,3,4]thiadiazol-2-yl)phenol.
- Author
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Lei, Yan and Yang, Qiwen
- Subjects
- *
PHENOL , *X-rays , *PHENOXIDES , *CATALYTIC oxidation , *SPACE groups - Abstract
A novel binuclear oxidovanadium(V) complex [V2O2(μ-O)L2(OEt)2], where L is the deprotonated form of 2,4-dibromo-6-(5-methylamino-[1,3,4]thiadiazol-2-yl)phenol (HL), was prepared by the reaction of 2-(3,5-dibromo-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide (HL') and VO(acac)2 in ethanol. The ligand L' underwent a cyclization during the coordination, to form a new ligand L. Structure of the complex was characterized by physicochemical methods and single-crystal X-ray determination. Crystal of the complex crystallizes in hexagonal space group R-3, with a = b = 33.302(3) Å, c = 15.308(2) Å, α = β = 90°, γ = 120°, V = 14702(3) Å3, Z = 18, R1 = 0.0823, wR2 = 0.2064, S = 1.011. X-ray analysis indicates that the V atom in the complex is in an octahedral coordination environment, constructed by the phenolate O and thiadiazol N atoms of L, one oxido O atom, one bridging O atom, and one deprotonated ethanol O atom. The distance between the two V atoms is 3.365(1) Å. The complex has an effective catalytic property for the oxidation of several olefins. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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23. Synthesis and crystal structures of zinc complexes derived from N,N'-bis(4-bromosalicylidene)-1,3-propanediamine with antimicrobial activity.
- Author
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Lei, Yan, Yang, Qiwen, Li, Guodong, and Tan, Yao
- Subjects
- *
ZINC compounds , *SCHIFF bases , *ZINC crystals , *CRYSTAL structure , *ANTI-infective agents , *ZINC compounds synthesis , *ESCHERICHIA coli - Abstract
Four new zinc(II) complexes derived from the bis-Schiff base ligand N,N' -bis(4-bromosalicylidene)-1,3-propanediamine have been synthesized and structurally characterized by elemental analysis, infrared spectra, as well as single crystal X-ray diffraction. X-ray analysis indicates that the Zn atoms in the complexes are in octahedral, tetrahedral and square pyramidal coordination. In vitro bacterial viability revealed that the complexes have effective antimicrobial activities against B. subtilis , S. aureus , E. coli and P. fluorescens. [Display omitted] A series of new zinc(II) complexes, [Zn 2 Cl 2 L(MeOH) 2 ] (1), [Zn 4 Cl 2 L 2 (N 3) 2 ] (2), [Zn 4 Br 2 L 2 (N 3) 2 ] (3) and [Zn 4 I 2 L 2 (N(CN) 2) 2 ] (4), where L is the dianionic form of N,N' -bis(4-bromosalicylidene)-1,3-propanediamine, have been synthesized and structurally characterized by elemental analysis, infrared spectra, as well as single crystal X-ray diffraction. X-ray analysis indicates that the Zn atoms in the dinuclear complex 1 are in octahedral and tetrahedral coordination, while in the tetranuclear complexes 2 , 3 and 4 are in square pyramidal and tetrahedral coordination. In vitro bacterial viability revealed that the complexes have effective antimicrobial activities against B. subtilis , S. aureus , E. coli and P. fluorescens , while weak activities against the fungal strains C. albicans and A. niger. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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24. Synthesis, X-Ray Structural Characterization, and Catalytic Property of a Manganese (II) Complex With 2-Bromo-6-[(3-cyclohexylammoniopropylimino)methyl]phenolate and Thiocyanate Ligands.
- Author
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Yang, Qiwen, Lei, Yan, and Wang, Pu
- Subjects
- *
CHEMICAL synthesis , *MOLECULAR structure , *MANGANESE , *METAL complexes , *PHENOXIDES , *THIOCYANATES , *LIGAND analysis - Abstract
A new manganese(II) complex [MnL2(NCS)2]·2H2O with the Schiff base ligand derived from 3-bromosalicylaldehyde withN-cyclohexylpropane-1,3-diamine has been synthesized and structurally characterized by physicochemical methods and single-crystal X-ray determination. The crystal of the complex crystallizes in monoclinic space groupC2/c, witha= 24.749(2),b= 7.2957(7),c= 26.183(4) Å,β= 118.70(2)°,V= 4171.6(8) Å3,Z= 4,R1= 0.0893,wR2= 0.2305, GOOF = 1.084. X-ray analysis indicates that the complex is a mononuclear manganese species, which possesses crystallographic inversion center symmetry. The Mn atom, lying on the inversion center, is coordinated in an octahedral coordination by two phenolate O and two imine N atoms from two Schiff base ligands, and two thiocyanate N atoms. The catalytic property for epoxidation of styrene by the complex has also been tested. [ABSTRACT FROM PUBLISHER]
- Published
- 2014
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- View/download PDF
25. Synthesis, X-Ray Structural Characterization, and Catalytic Property of Dioxomolybdenum(VI) Complexes With N’-(3-Bromo-2-hydroxybenzylidene)-2-hydroxybenzohydrazide and N’-(5-Chloro-2-hydroxybenzylidene)-4- nitrobenzohydrazide.
- Author
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Lei, Yan, Yang, Qiwen, Chen, Gangcai, and Yang, Qingling
- Subjects
- *
COMPLEX compounds synthesis , *X-ray crystallography , *CRYSTAL structure , *MOLYBDENUM catalysts , *METAL complexes , *HYDRAZIDES , *ALDEHYDES - Abstract
Two new dioxomolybdenum(VI) complexes [MoO2(Bhbz) (CH3OH)] (1) and [MoO2(Cnbz)(CH3OH)] (2) with the benzohydrazone ligands H2Bhbz and H2Cnbz derived from 5-chlorosalicylaldehyde with 4-nitrobenzohydrazide and 3-bromosalicylaldehyde with 2-hydroxybenzohydrazide, respectively, have been synthesized and structurally characterized by physicochemical methods and single crystal X-ray determination. The crystal of (1) crystallizes in triclinic space groupP-1, witha= 8.0014(9),b= 9.6294(10),c= 11.4204(12) Å,α= 89.193(2),β= 87.833(2),γ= 89.110(2)°,V= 879.11(16) Å3,Z= 2,R1= 0.0464,wR2= 0.1185,S= 1.051. The crystal of (2) crystallizes in monoclinic space groupP21/c, witha= 7.4108(3),b= 18.7901(7),c= 12.6293(5) Å,β= 104.4850(10)°,V= 1702.72(12) Å3,Z= 4,R1= 0.0236,wR2= 0.0576,S= 1.061. X-ray analysis indicates that the structures of both complexes are similar to each other. The molybdenum atom in each complex is in an octahedral coordination environment, constructed by two oxo groups and NO2donor set of the ligand, and one methanol O atom. The complexes have effective catalytic property for the oxidation of several olefins. [ABSTRACT FROM PUBLISHER]
- Published
- 2014
- Full Text
- View/download PDF
26. The First Observationof One-Dimensional Naphthalenediimidato-BasedTransition-Metal Coordination Polymers: Syntheses, Crystal Structuresand Properties.
- Author
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Tao, Tao, Lei, Yan-Hua, Peng, Yu-Xin, Wang, Ying, Huang, Wei, Chen, Zhao-Xu, and You, Xiao-Zeng
- Subjects
- *
NAPHTHALENE , *COORDINATION polymers , *TRANSITION metals , *CRYSTAL structure , *MOLECULAR self-assembly , *CARBOXYLIC acids - Abstract
Metal-directed assembly of naphthalene-1,4,5,8-tetracarboxylicacid (NTA) with different transition-metal salts in the presence ofammonia results in a series of one-dimensional metalânaphthalenediimidato(MâNDI) coordination polymers with the formulas of {[Ag(NDI)](NH4)}n(P1), [Zn(NDI)(NH3)2]n(P2), [Cd(NDI)(NH3)2]n(P3), [Co(NDI)(NH3)2]n(P4) and [Ni(NDI)(NH3)2]n(P5), respectively.It is worthwhile to mention that the 1D straight-line NDIâAg(I)coordination polymer P1is formed stepwise from a dinuclearNDIâAg(I) intermediate [Ag2(NDI)(NH3)2] (2AgNDI), where ammonia serves as a stabilizingreagent of Ag(I) ion and a weak base to remove the protons of NDIH2simultaneously. Furthermore, P1exhibits semiconductingproperties in the solid state which may originate from its all-parallel-alignedpacking structure (AAAA) which is different from the common ABAB packingmode for P2âP5and 2AgNDI. In addition, theoretic computational studies as well as X-ray photoelectronspectrometer spectra on P1and 2AgNDIhavealso been carried out. [ABSTRACT FROM AUTHOR]
- Published
- 2012
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27. Synthesis and X-Ray Structural Characterization of Dioxomolybdenum(VI) Complexes with 2'-(5-Chloro-2-hydroxybenzylidene)isonicotinohydrazide and 2'-(2-Hydroxy-3-methoxybenzylidene)isonicotinohydrazide.
- Author
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Lei, Yan and Fu, Chuan
- Subjects
- *
COMPLEX compounds synthesis , *MOLECULAR structure , *METAL complexes , *ISONIAZID , *LIGANDS (Chemistry) , *ALDEHYDES , *MOLYBDENUM compounds , *X-ray crystallography - Abstract
Two new dioxomolybdenum(VI) complexes, [MoO2 (Cinh)(CH3OH)] (1) and [MoO2(Minh)(CH3OH)] (2), with the isonicotinohydrazone ligands H2Cinh and H2Minh derived from isonicotinohydrazide with 5-chlorosalicylaldehyde and 3-methoxysalicylaldehyde, respectively, have been synthesized and structurally characterized by physico-chemical methods and single crystal X-ray determination. The crystal of (1) crystallizes in triclinic space group P-1, with a = 6.553(2), b = 10.737(4), c = 12.907(4) Å, α = 68.021(2), β = 83.788(3), γ = 75.072(3)°, V = 813.6(5) Å3, Z = 2, R1 = 0.0291, wR2 = 0.0617, S = 1.044. The crystal of (2) crystallizes in monoclinic space group P21/n, with a = 6.792(2), b = 30.259(4), c = 7.920(3) Å, β = 93.703(3)°, V = 1624.3(8) Å3, Z = 4, R1 = 0.0501, wR2 = 0.1250, S = 1.087. X-ray analysis indicates that the structures of both complexes are similar to each other. The molybdenum atom in each complex is in an octahedral coordination environment, constructed by two oxo groups and NO2 donor set of the isonicotinohydrazone ligand, and one methanol O atom. [ABSTRACT FROM AUTHOR]
- Published
- 2011
- Full Text
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28. New cobalt(II) Schiff base complex: Synthesis, characterization, DFT calculation and antimicrobial activity.
- Author
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Jiang, Jian-Hong, Lei, Yan-Hua, Li, Xu, Pi, Yiyuan, Zhu, He, Li, Qiang-Guo, and Li, Chuan-Hua
- Subjects
- *
SCHIFF bases , *COBALT , *SPACE groups , *CRYSTAL structure , *X-ray diffraction - Abstract
[Display omitted] • A new cobalt(II) complex was synthesized and characterized. • Theoretical studies using DFT calculations. • The bioactivity of cobalt(II) complex was assessed by bio-microcalorimetry. • The complex displayed much stronger antibacterial activity than Schiff base. • Some thermokinetic parameters (k , P max , t G and Q total) were derived. A new cobalt(II) Schiff-base complex [Co(L) 2 ] was prepared by using equivalent molar of Schiff-base ligand [HL=(E)- N '-(2-hydroxy-3-methoxybenzylidene)isonicotinohydrazide] and CoCl 2 ·6H 2 O. The structure of the complex was characterized by single-crystal X-ray diffraction, IR, ESI-MS, elemental analysis and DFT method. X-ray crystal structure analysis showed that the complex crystallized in space group Pbca, with two symmetry-independent molecules. The experimental vibrational bands(IR) have been discussed and assigned based on DFT calculations. The antibacterial activity of Schiff base and its complex against S. pombe were assessed by bio-microcalorimetry at 32 °C. Some thermokinetic parameters (k , P max, t G and Q total) were derived from the metabolic power–time curves, and their quantitative relationship with the concentration were analyzed. The half inhibition concentration (IC 50) of Schiff base and its complex were calculated to be 1.18 × 10−2 mol L−1 and 1.07 × 10−3 mol L−1, respectively. The inhibition effect of the complex showed much stronger than that of Schiff base. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
29. Highly-toughened biodegradable poly(L-lactic acid) composites with heat resistance and mechanical-damage-healing ability by adding poly(butylene adipate-co-butylene terephthalate) and carbon nanofibers.
- Author
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Sun, De-xiang, Gu, Ting, Qi, Xiao-dong, Yang, Jing-hui, Lei, Yan-zhou, and Wang, Yong
- Subjects
- *
CARBON nanofibers , *SELF-healing materials , *POLYESTERS , *BUTENE , *CRYSTAL structure , *PHOTOTHERMAL effect , *PHOTOTHERMAL conversion - Abstract
[Display omitted] • The ternary composites containing PLLA, PBAT and CNFs were prepared. • PBAT and CNFs assembled into the "mutton kebab"-like structure during processing. • CNFs induced the epitaxial crystallization of PLLA on the surface of CNFs. • Highly-toughened, high heat resistant and self-healing properties were achieved. Biodegradable poly(L -lactic acid) (PLLA) based blend composites with excellent toughness exhibit comprehensive applications and they can be substitute for the common polyolefin and polyester based composites. To date, various strategies have been developed to enhance the toughness of the PLLA based blends or composites. Here, carbon nanofibers (CNFs) incorporated PLLA/poly(butylene adipate-co-butylene terephthalate) (PBAT) blend composites were investigated. The crystallinity of the PLLA matrix were precisely tailored through annealing treatment. Interestingly, CNFs and PBAT particles self-assembled into the "mutton kebab"-like structure during processing. In addition, the annealing treatment facilitated the epitaxial crystallization of PLLA on the surface of CNFs that were not covered by PBAT due to the excellent heterogeneous nucleation effect of CNFs. Consequently, with the addition of 1 wt% CNFs and tailoring the blend composite with the PLLA crystallinity of about 32.6%, the impact strength of the composite was increased by 270% from 10.0 kJ/m2 to 37.0 kJ/m2. The toughening mechanisms were mainly connected with the greatly strengthened interfacial interaction between PLLA matrix and PBAT particles by CNFs through CNFs bridging effect and CNFs inducing PLLA crystallization, facilitating the transfer of stress under the load condition, especially at high PLLA crystallinity. Furthermore, it was found that CNFs exhibited outstanding photothermal conversion effect, which could endow the blend composites with mechanical-damage-healing ability. This work not only reveals the role of crystalline structure in toughening of the PLLA-based blend composites but also paves an effective way to prepare super-toughened, biodegradable, heat resistant and mechanical-damage-healing PLLA-based composites via tailoring the crystalline structure of the matrix. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
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