8 results on '"Zhu, Xiaofei"'
Search Results
2. Graphene oxide wrapped Fe2O3 as a durable anode material for high-performance lithium-ion batteries.
- Author
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Li, Henan, Zhu, Xiaofei, Sitinamaluwa, Hansinee, Wasalathilake, Kimal, Xu, Li, Zhang, Shanqing, and Yan, Cheng
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GRAPHENE oxide , *FERRIC oxide , *LITHIUM-ion batteries , *CHARGE storage diodes , *MECHANICAL behavior of materials - Abstract
Ferric oxide has demonstrated as a promising anode candidate for lithium ion batteries (LIBs) due to large charge storage capacity, but its high cost, low Coulombic efficiency, and unstable solid-electrolyte interphase remain to be a technical challenge. Here, we report a flexible interleaved hybrid in which Fe 2 O 3 nanoparticles were encapsulated by graphene oxide layers (Fe 2 O 3 /GO) using facile freeze-drying approach as anode for LIBs. Within this flexible interleaved structure, GO layers act as flexible but mechanically strong buffer to accommodate volume expansion and reduce associated stress in Fe 2 O 3 nanoparticles, thereby maintaining mechanical integrity and increasing the cycling life of batteries. With the synergistic effects from Fe 2 O 3 and GO, this hybrid not only promotes fast mass transfer and shortens the diffusion path of the Li ions but also forms a stable solid electrolyte interface, contributing improved Coulombic efficiency in the first few cycles. The Fe 2 O 3 /GO hybrid as anode for LIBs exhibited a reversible specific capacity of ca. 890 mAh g −1 after 50 cycles at 1 C (1005 mA g −1 ) and 405 mAh g −1 after 1000 cycles at 10 C rate. Furthermore, a full-cell battery with a LiFePO 4 cathode also showed high Coulombic efficiency and good capacity retention capability. Mechanical properties and impedance spectroscopy tests were performed to confirm the mechanism in superior rate and electrochemical stability. The conclusions are considered to be very useful for design of Li batteries with improved mechanical performance. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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3. Controlled synthesis of partially reduced graphene oxide: Enhance electrochemical determination of isoniazid with high sensitivity and stability.
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Zhu, Xiaofei, Xu, Jingkun, Duan, Xuemin, Lu, Limin, Zhang, Kaixin, Yu, Yongfang, Xing, Huakun, Gao, Yansha, Dong, Liqi, Sun, Hui, and Yang, Taotao
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GRAPHENE oxide , *ISONIAZID , *ELECTROCHEMICAL sensors , *VOLTAMMETRY , *CHEMICAL sample preparation , *CHEMICAL reduction - Abstract
Electrochemically reduced graphene oxide (ERGO) based voltammetric sensors have drawn considerable attentions due to their simple preparation process and outstanding electrochemical properties. While quite a lot of work suffers from problems in terms of sensitivity and cycling stability. Here, we demonstrate that the reduction extent of ERGO displays a crucial role in enhancing sensitivity and preventing electrode fouling. To illustrate this, partially reduced and relatively complete reduced ERGO films were prepared via the electrochemical method. The reduction extent was controlled by performing cyclic voltammetry with varieties of reduction cycle numbers. Results indicated that partially reduced ERGO film with 5 reduction cycle numbers (ERGO 5 ) showed the highest sensitivity towards electrochemical oxidation of isoniazid (INZ) among all the ERGO films with different reduction extents, and acquired better electrode stability as compared with ERGO 15 . Under the optimal conditions, the peak currents on ERGO 5 modified electrode increased linearly with the concentrations of INZ in the range of 0.09–100 μM. The detection limit of INZ reached 15 nM (S/N = 3). The present work has a guidance meaning in developing ERGO based sensors for detecting other electroactive analytes. [ABSTRACT FROM AUTHOR]
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- 2015
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4. Efficient synthesis of graphene–multiwalled carbon nanotubes nanocomposite and its application in electrochemical sensing of diethylstilbestrol.
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Zhu, Xiaofei, Lu, Limin, Duan, Xuemin, Zhang, Kaixin, Xu, Jingkun, Hu, Dufen, Sun, Hui, Dong, Liqi, Gao, Yansha, and Wu, Yao
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DIETHYLSTILBESTROL , *GRAPHENE oxide , *ELECTROCHEMICAL sensors , *MULTIWALLED carbon nanotube synthesis , *VOLTAMMETRY , *GROWTH factors , *ANIMAL culture - Abstract
Herein, a sensitive voltammetric method for the determination of diethylstilbestrol (DES), illegally used as a growth promoter in animal husbandry, was developed using electrochemically reduced graphene oxide–multiwalled carbon nanotubes (ERGO–MWCNTs) modified electrode. The incorporated multiwalled carbon nanotubes (MWCNTs) served as electrical conducting wires, which could facilitate the electrochemical reduction of graphene oxide (GO). Compared to either electrochemically reduced graphene oxide (ERGO) or MWCNTs, integrating these nanostructures resulted in a strong synergistic effect between the two materials consequently leading to a superior hybrid material with higher activity for the electro-oxidation of DES. The electron transfer coefficient ( α ), the standard rate constant ( k s ), electrochemically effective surface area ( A ) and the saturating absorption capacity ( Г s ) were calculated. Under the optimized conditions, ERGO–MWCNTs modified electrode exhibited better linearity than either ERGO or MWCNTs over ranges from 0.01 to 40 μM with the detection limit of 3 nM ( S / N = 3). Moreover, the proposed method was successfully applied to determine DES in real sample and satisfactory results were obtained. The results showed that the modified electrode exhibits an excellent catalytic activity, good sensitivity and reproducibility. [ABSTRACT FROM AUTHOR]
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- 2014
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5. A new electrochemical sensor based on carboimidazole grafted reduced graphene oxide for simultaneous detection of Hg2 + and Pb2 +.
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Xing, Huakun, Xu, Jingkun, Zhu, Xiaofei, Duan, Xuemin, Lu, Limin, Zuo, Yinxiu, Zhang, Youshan, and Wang, Wenmin
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ELECTROCHEMICAL sensors , *IMIDAZOLES , *GRAPHENE oxide , *MERCURY , *METAL ions , *HEAVY metals - Abstract
Herein, an electrochemical sensor was developed for detecting heavy metal ions by using a carboimidazole grafted reduced graphene oxide (reduced graphene oxide-NH-carboimidazole, abbreviated as RGO-NH-Ci) modified electrode. The morphology of RGO-NH-Ci material was characterized by scanning electron microscopy (SEM). The electrochemical behaviors of the RGO-NH-Ci modified electrode toward heavy metal ions, including Hg 2 + and Pb 2 + , were investigated with differential pulse anodic stripping voltammetry (DPASV). Compared with pure reduced graphene oxide (RGO), RGO-NH-Ci modified electrode showed improved analytical performance in detecting the two metal ions owing to the strong complexing capacity of Ci and the presence of the amino groups. The detection limits were estimated to be 0.2 nM and 3.0 nM for Hg 2 + and Pb 2 + , respectively, under the optimized conditions. The developed method was also employed to detect the Hg 2 + and Pb 2 + in real water samples, and satisfactory results were obtained. [ABSTRACT FROM AUTHOR]
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- 2016
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6. Poly(3,4-ethylenedioxythiophene) nanorods/graphene oxide nanocomposite as a new electrode material for the selective electrochemical detection of mercury (II).
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Zuo, Yinxiu, Xu, Jingkun, Zhu, Xiaofei, Duan, Xuemin, Lu, Limin, Gao, Yansha, Xing, Huakun, Yang, Taotao, Ye, Guo, and Yu, Yongfang
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NANORODS , *GRAPHENE oxide , *NANOCOMPOSITE materials , *ELECTRODES , *MERCURY - Abstract
Abstracts Development of selective methods for the detection of mercury (Hg 2+ ) has received tremendous attention in modern chemical research due to its health hazard and persistence in environment. In this paper, the electrochemical determination of Hg 2+ at trace level based on poly(3,4-ethylenedioxythiophene) nanorods/graphene oxide nanocomposite modified glassy carbon electrode (PEDOT/GO/GCE) is reported. PEDOT/GO nanocomposite has been proposed via a simple liquid–liquid interfacial polymerization approach. Scanning electron microscopy (SEM) and transmission electron microscope (TEM) were employed to characterize the morphology and structure of the as-prepared PEDOT/GO. The results revealed that PEDOT with a nanorods-like structure anchored on the surface of GO nanosheets, which could enhance the electro-active sites of the nanocomposite. Differential pulse stripping voltammetry (DPSV) was applied to determine low concentrations of Hg 2+ on PEDOT/GO/GCE. Experimental conditions, including accumulation time, pH values and deposition potential were optimized. In optimal conditions, a good linear relationship was found between peak currents and the concentration of Hg 2+ in 10.0 nM-3.0 μM range. The detection limit was estimated to be 2.78 nM at a signal-to-noise ratio of 3. Finally, the applicability for Hg 2+ determination in tap water samples was successfully demonstrated. [ABSTRACT FROM AUTHOR]
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- 2016
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7. Poly(3,4-ethylenedioxythiophene) nanorods grown on graphene oxide sheets as electrochemical sensing platform for rutin.
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Zhang, Kaixin, Xu, Jingkun, Zhu, Xiaofei, Lu, Limin, Duan, Xuemin, Hu, Dufen, Dong, Liqi, Sun, Hui, Gao, Yansha, and Wu, Yao
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POLYTHIOPHENES , *NANORODS , *GRAPHENE oxide , *LIQUID-liquid interfaces , *ELECTROCHEMICAL sensors , *RUTIN - Abstract
Hierarchical nanocomposites of poly(3,4-ethylenedioxythiophene) nanorods array on graphene oxide nanosheets (PEDOT/GO) were synthesized via a liquid–liquid interfacial polymerization method. The synthesized composites were characterized by using Fourier transform infrared (FTIR) and Raman spectroscopic studies, and their morphology was analyzed by transmission electron microscopy (TEM). Characterization and surface morphology results indicated that PEDOT with a nanorods-like structure successfully anchored on the surface of GO sheets, which could enhance the electro-active sites of the nanocomposites. Then the obtained PEDOT/GO nanocomposites were utilized to modify glassy carbon electrode and designed for the trace level sensing of rutin. Electrochemical results revealed that the PEDOT/GO nanocomposites modified electrode exhibited larger oxidation peak currents of rutin than pure PEDOT and GO owing to the synergistic effect of GO and PEDOT nanorods. Under optimized conditions, the anodic peak current was linear to the concentration of rutin in the range from 0.004 to 60 μM with the detection limit of 0.00125 μM. To further validate its possible application, the proposed method was successfully used for the determination of rutin in pharmaceutical formulations with satisfactory results. [ABSTRACT FROM AUTHOR]
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- 2015
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8. Copper nanoparticle/graphene oxide/single wall carbon nanotube hybrid materials as electrochemical sensing platform for nonenzymatic glucose detection.
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Yang, Taotao, Xu, Jingkun, Lu, Limin, Zhu, Xiaofei, Gao, Yansha, Xing, Huakun, Yu, Yongfang, Ding, Wanchuan, and Liu, Zhen
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COPPER compounds , *NANOPARTICLE synthesis , *GRAPHENE oxide , *SINGLE walled carbon nanotubes , *ELECTROCHEMICAL sensors , *GLUCOSE , *CHEMICAL sample preparation - Abstract
Cu nanoparticle/graphene oxide/single walled carbon nanotube (CuNP/GO/SWCNT) composites were prepared by a facile electrodeposition method and used for constructing nonenzymatic glucose sensor. Scanning electron microscopy (SEM) and Raman spectroscopy were employed to characterize the morphology and structures of the samples. The electrocatalytic performance of CuNP/GO/SWCNT composites towards glucose oxidation was studied by cyclic voltammetry (CV) and current–time measurements. Electrochemical results indicated that CuNP/GO/SWCNT electrode exhibited a higher electrocatalytic activity towards the oxidation of glucose than CuNP, CuNP/GO and CuNP/SWCNT electrodes. This was because the GO/SWCNT composite as substrate material not only possessed excellent conductivity, but also provided large surface area for the high loading of the CuNPs. Meanwhile, the good dispersibility, independent and multi-layer structure of CuNP, could enhance the charge-transport properties, and afford more active sites for the catalytic oxidation of glucose. Under the optimized conditions, the sensor showed a high sensitivity of up to 930.07 μA mM − 1 cm − 2 , with a wide linear range of 1 μM to 4.538 mM and a low detection limit of 0.34 μM (S/N = 3). It also exhibited excellent stability, reproducibility, selectivity, and reliable measurement in real human blood samples. All of these excellent properties made the CuNP/GO/SWCNT composite material promising for the development of effective nonenzymatic glucose sensors. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
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