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In this study, we present new zircon U-Pb and Hf isotope data and geochemical analyses for Jurassic igneous rocks from the southern Zhangguangcai Range, NE China. In the context of our new U/Pb data together with other published data (n = 165), we recognize three major magmatic pulses in the eastern Songnen Block during the Jurassic: earliest Jurassic (200–195 Ma), late Early Jurassic (183–175 Ma) and early Late Jurassic (ca. 163 Ma). According to the petrological classification scheme, rocks are divided into two categories of andesite and I-type granitoids. Generally, Early Jurassic monzogranites have more evolved compositions with SiO2, Al2O3, and K2O+Na2O concentrations of 67–74 wt.%, 13.28–17.04 wt.% and 7.25–9.31 wt.%, respectively than Late Jurassic granodiorite. Early Jurassic andesite has SiO2, Al2O3, Na2O+K2O contents of 54.64–56 wt.%, 17.27–17.44 wt.% and 3.47–4.06 wt.%, respectively with low Mg# values of 0.18–0.26. In addition, all samples show enrichment in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depletion in high strength field elements (HSFEs, such as Nb, Ta, P and Ti) and low Sr/Y and (La/Yb)N ratios, all of which are characteristic of arc-type magmatic signatures. In view of the Hf isotope signatures, these rocks show high initial 176Hf/177Hf ratios (0.282711–0.283069) corresponding to positive εHf(t) values (+0.39 to +13.66) and Neoproterozoic two-stage model ages (1154–550 Ma). In summary, the geochemical results suggest that the primary magmas of Jurassic granitoids were derived from variable degrees of partial melting of juvenile lower crust, whereas Early Jurassic andesite was derived from the partial melting of mantle wedge peridotite metasomatized by hydrous melts from subducting sediments and/or oceanic crust. The Jurassic arc-type magmatism in the eastern Songnen Block indicates that the Mudanjiang oceanic plate was still subducting in the Jurassic. [ABSTRACT FROM AUTHOR]

Magmatic and metasomatic rock suites can be commonly found in active convergent margins as the suprasubduction zone mantle wedge is usually impregnated by melts and fluids. Here we present petrologic, whole-rock geochemical and zircon U-Pb and Lu-Hf data from metamorphic intermediate-mafic and ultramafic rocks in central Jilin Province, NE China, to constrain the Early Paleozoic tectonic evolution of the southeastern margin of the Xing'an-Mongolia Orogenic Belt. Lithologically, the meta-igneous rocks are composed of plagioclase-actinolite, meta-allgovite, tremolitized pyroxenite, and serpentinized peridotite. Geochronological results indicate that the protoliths of the meta-igneous rocks formed during the Early–Middle Ordovician (474–466 Ma). Geochemical features suggest that the rocks are calc-alkaline and transitional-series rocks relatively enriched in large-ion lithophile and light rare earth elements and depleted in high field strength and heavy rare earth elements, implying that they formed in a supra-subduction zone environment. Additionally, the protoliths of the plagioclase-actinolites, which display an affinity for sanukites, resulted from an equilibrium reaction between mantle peridotite and slab melts derived from the partial melting of subducting sediments during early-stage subduction; the meta-allgovite rocks were likely derived from a juvenile depleted lithospheric mantle that was metasomatized by subduction-related fluids; the ultramafic rocks are magmatic cumulates formed in a suprasubduction zone mantle wedge. Furthermore, the meta-allgovite rocks display both arc-like and MORB-like geochemical characteristics, suggesting an intra-continental back-arc basin setting. These features, combined with the presence of the abundance of zircon xenocrysts with Neoproterozoic–Paleozoic ages, as well as the results of previous studies, reflect that a small-scale and limited back-arc basin, which was related to the northward subduction of the Paleo-Asian oceanic plate, probably existed close to the Songnen-Zhangguangcai Range Massif during the Early–Middle Ordovician. [ABSTRACT FROM AUTHOR]

In the Upper Ediacaran Dengying Formation of the Sichuan Basin, the presence of abundant, well-preserved microbial carbonates provides a unique opportunity to study Precambrian paleoceanography and microbial carbonate origins. Particularly, the underexplored coated grain dolostones of this formation, characterized by distinct microbially induced fabrics and intragranular dissolution, offer crucial insights for understanding late Ediacaran microbial mineralization and diagenetic sequences. Utilizing selected typical samples, we conducted detailed petrographic and geochemical analyses, revealing a dynamic interplay between microbial processes and sedimentary dynamics. We observe the coexistence of constructive micrite envelopes with microbially induced fabrics such as clots and laminations, highlighting microbial biomineralization's key role in fabric formation. The sedimentary dynamics critically determines the formation processes of the coated grains: low-energy settings foster grain agglomeration and consolidation through clot precipitation between grains, while high-energy settings favor smaller grains binding to microbial mats. Geochemically, micrite envelopes play an essential role in preserving distinct rare earth element (REE) signatures. The weak negative Ce anomalies and positive Eu anomalies within these envelopes point to a suboxic to anoxic depositional environment, directly indicative of the microenvironmental conditions conducive to microbial mineralization processes. Furthermore, our study sheds light on the structural evolution of coated grains with hollow nuclei, proposing that their internal pore formations are influenced by both mineral instability and selective dissolution by meteoric freshwater. These findings not only provide fresh insights into complex diagenetic processes in the Dengying Formation but also substantially advance our understanding of early microbial life and environmental adaptations during the Precambrian. • Revealed the relationship between micrite envelopes and microbially induced fabrics • Proposed a novel formation mechanism for coated grain dolostone in the Dengying Fm. • Investigated the diverse environmental responses of microbiolite fabrics • Established micrite envelopes as dependable records of seawater REE compositions [ABSTRACT FROM AUTHOR]