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Unitary Association Method (UAM) analyses of conodont faunas from 28 sections spanning the biggest Phanerozoic end-Permian mass extinction and significant global environmental and ecosystem perturbations during the succeeding Early Triassic are presented. Based on 72 conodont species, 26 Unitary Association Zones (UAZs) are established for the latest Permian to earliest Middle Triassic of South China. These UAZs provide quantitative high-resolution tools to correlate sequences in the Early Triassic of South China and to compare and test high-resolution conodont biostratigraphy based on interval conodont zones developed over the past three decades. Our quantitative analyses provide insights on ongoing debates relating to the First Appearance Datum (FAD) of the conodont Hindeodus parvus which is used to place and subsequently correlate the "Golden Spike" defining the base of the Triassic (Permian-Triassic Boundary) at the base of Bed 27c at the GSSP Meishan D Section. Previous proposals that suggested potential earlier occurrences of H. parvus below its FAD at Meishan section are not supported by our results. In deep water sections, the First Occurrence (FO) of H. parvus lies at the base of UAZ 5 at the Bianyang section while it lies within UAZ 6 at the Meishan section. This indicates that the earliest occurrence of H. parvus in South China is in the Bianyang section but this conclusion needs further testing due to the reliance on "spot" data by the UAM. Anomalously high occurrences of Hindeodus in the Mingtang section (close to the Bianyang section) further suggests that the Bianyang-Mingtang area may have provided a temporally extended habitable zone for anchignathodontid conodonts. Stage boundaries currently proposed or established using interval conodont zones locate within or between UAZs and are difficult to correlate with carbon isotope curves. UAZs are useful in helping to define GSSPs by recognizing which correlations are most robust and in the selection of the most appropriate species and level for GSSPs. [ABSTRACT FROM AUTHOR]

The age and timing of the Permian-Triassic mass extinction have been difficult to determine because zircon populations from the type sections are typically affected by pervasive lead loss and contamination by indistinguishable older xenocrysts. Zircons from nine ash beds within the Shangsi and Meishan sections (China), pretreated by annealing followed by partial attack with hydrofluoric acid, result in suites of consistent and concordant uranium/lead (U/Pb) ages, eliminating the effects of lead loss. The U/Pb age of the main pulse of the extinction is 252.6 +/- 0.2 million years, synchronous with the Siberian flood volcanism, and it occurred within the quoted uncertainty.