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Wastewater treatment plants (WWTPs) receive wastewater from various sources. Despite wastewater treatment aiming to remove contaminants, microplastics persist. Plastic surfaces are quickly colonized by microbial biofilm ("plastispheres"). Plastisphere communities are suggested to promote the spread and survival of potential human pathogens, suggesting that the transfer of plastispheres from wastewater to the environment could pose a risk to human and environmental health. The study aimed to identify pathogens in wastewater plastispheres, specifically food-borne pathogens, in addition to characterizing the taxonomic diversity and composition of the wastewater plastispheres. Plastispheres that accumulated on polypropylene (PP), polyvinyl chloride (PVC), and high-density polyethylene propylene (HDPE) surfaces exposed to raw and treated wastewater were analyzed via cultivation methods, quantitative reverse transcription PCR (RT‒qPCR) and 16S rRNA amplicon sequencing. RT‒qPCR revealed the presence of potential foodborne pathogenic bacteria and viruses, such as Listeria monocytogenes, Escherichia coli, norovirus, and adenovirus. Viable isolates of the emerging pathogenic species Klebsiella pneumoniae and Acinetobacter spp. were identified in the plastispheres from raw and treated wastewater, indicating that potential pathogenic bacteria might survive in the plastispheres during the wastewater treatment. These findings underscore the potential of plastispheres to harbor and disseminate pathogenic species, posing challenges to water reuse initiatives. The taxonomic diversity and composition of the plastispheres, as explored through 16S rRNA amplicon sequencing, were significantly influenced by the wastewater environment and the duration of time the plastic spent in the wastewater. In contrast, the specific plastic material did not influence the bacterial composition, while the bacterial diversity was affected. Without efficient wastewater treatment and proper plastic waste management, wastewater could act as a source of transferring plastic-associated pathogens into the food chain and possibly pose a threat to human health. Continued research and innovation are essential to improve the removal of microplastics and associated pathogenic microorganisms in wastewater. [ABSTRACT FROM AUTHOR]

Highway stormwater (HSW) runoff is among the environment's most important sources of microplastics. This study aimed to characterize via vibrational spectroscopy and quantify SMPs (small microplastics < 100 µm) in HSW runoff from a trafficked highway entering a facility equipped with a filtration system and in those flowing out to the receiving water body near agricultural activities. Samples of the inlet runoff (from the highway) and outlet runoff (the discharge into the environment) were collected in different periods to investigate potential seasonal and spatial differences. The sampling, methodology, and analysis were thoroughly carried out to quantify and simultaneously identify SMPs via Micro-FTIR to obtain a specific novel dataset to assess the environmental quality of highway pollution. A significant difference between inlet and outlet samples was reported; the highest abundance in inlet samples was 39813 ± 277 SMPs L.1 (SW10 IN; average length of 77 µm), while the highest one in outlet samples was 15173 ± 171 SMPs L−1 (SW10 OUT; SMPs' average length of 63 µm). Polyamide 6 (PA 6) and High-Density Polyethylene (HDPE) were predominant. Our results show that these HSW treatment plants, designed for managing regulated pollutants, can intercept SMPs, improving the quality of HSW runoff discharged into the environment. [ABSTRACT FROM AUTHOR]

Polyethylene is the single largest volume polymer produced globally using Ziegler-type catalysts. Numerous modifications have been reported in search of a better catalyst that can control molecular weight, polydispersity, and branching. In our attempts to identify a suitable imine thiophene-ligated chromium complex, we examined 9 different titanium complexes computationally. The DFT investigations considered barriers for insertion, propagation, and termination by β-H elimination or chain transfer, and identified N-(4-methoxyphenyl)-2-phenyl-1-(thiophen-2-yl)ethan-1-imine(L9) as the most suitable ligand. Subsequently, L9 was prepared in good yield (70%) by condensing 2-phenyl-1-(thiophen-2-yl)ethan-1-one with 4-methoxyaniline. Ligand L9 was treated with early transition metal precursors (Ti, Cr, Zr) to generate a homogenous catalyst. The identity of these catalysts was unambiguously ascertained using a combination of NMR, ICP, FT-IR, UV-Vis spectroscopy, and ESI-MS. The performance of L9-ligated titanium complex [Cat.1] was examined in ethylene polymerization using MMAO as a co-catalyst. Insertion of ethylene was tracked using high-pressure NMR experiments and Cat.1 was found to be active in the polymerization. Ethylene polymerization conditions were optimized to obtain high activity and molecular weight polyethylene. The chromium complex [Cat.2] outperformed the Ti and Zr-derived catalysts with the highest TOF of 6294 mol of PE/mol of Cr/h. Cat.2 produced high molecular weight, high-density polyethylene. SYNOPSIS TOC: Rational designing and synthesis of imine thiophene-ligated Ti, Cr, and Zr-complexes and their performance in ethylene polymerization is presented. [ABSTRACT FROM AUTHOR]

This paper presents the obtaining and characterization of blends based on high-density polyethylene (HDPE) and plasticized starch. In addition to plasticized starch (28.8% w/w), the compositions made also contained other ingredients, such as polyethylene-graft-maleic anhydride as a compatibilizer, ethylene propylene terpolymer elastomer, cross-linking agents, and nanoclay. Plasticized starch contains 68.6% w/w potato starch, 29.4% w/w glycerin, and 2% w/w anhydrous citric acid. Blends based on HDPE and plasticized starch were made in a Brabender Plasti-Corder internal mixer at 160 °C, and plates for testing were obtained using the compression method. Thermal analyses indicate an increase in the crystallization degree of the HDPE after the addition of plasticized starch. SEM micrographs indicate that blends are compatibilized, with the plasticized starch being well dispersed as droplets in the HDPE matrix. Samples show high hardness values (62–65° ShD), good tensile strength values (14.88–17.02 N/mm2), and Charpy impact strength values (1.08–2.27 kJ/m2 on notched samples, and 7.96–20.29 kJ/m2 on unnotched samples). After 72 h of water immersion at room temperature, mixtures containing a compatibilizer had a mass variation below 1% and water absorption values below 1.7%. Upon increasing the water immersion temperature to 80 °C, the sample without the compatibilizer showed a mass reduction of −2.23%, indicating the dissolution of the plasticized starch in the water. The samples containing the compatibilizer had a mass variation of max 8.33% and a water absorption of max 5.02%. After toluene immersion for 72 h at room temperature, mass variation was below 8%. [ABSTRACT FROM AUTHOR]

High-density polyethylene (HDPE) has emerged as a promising alternative to fiber-reinforced plastic (FRP) for small vessel manufacturing due to its durability, chemical resistance, lightweight properties, and recyclability. However, while thermoplastic polymers like HDPE have been extensively used in gas and water pipelines, their application in large, complex marine structures remains underexplored, particularly in terms of joining methods. Existing techniques, such as ultrasonic welding, laser welding, and friction stir welding, are unsuitable for large-scale HDPE components, where extrusion welding is more viable. This study focuses on evaluating the impact of key process parameters, such as the preheating temperature, hot air movement speed, and nozzle distance, on the welding performance of HDPE. By analyzing the influence of these variables on heat distribution during the extrusion welding process, we aim to conduct basic research to derive optimal conditions for achieving strong and reliable joints. The results highlight the critical importance of a uniform temperature distribution in preventing defects such as excessive melting or thermal degradation, which could compromise weld integrity. This research provides valuable insights into improving HDPE joining techniques, contributing to its broader adoption in the marine and manufacturing industries. [ABSTRACT FROM AUTHOR]

Valorization of potential thermoplastic waste is an effective strategy to address resource scarcity and reduce valuable thermoplastic waste. In this study, new ecofriendly biomass-derived wood polymer composites (WPCs) were produced from three different types of recycled polyethylene (PE) municipal waste, namely linear low-density polyethylene (LLDPE), medium-density polyethylene (MDPE), or high-density polyethylene (HDPE), and their blend with equal composition (33/33/33 by wt.%). Bamboo particle reinforcement derived from indigenous Ethiopian lowland bamboo (LLB), which had never been utilized before in a WPC formulation, was used as the dispersed phase. Before utilization, recycled LLDPE, MDPE, and HDPE were carefully characterized to determine their chemical compositions, residual metals, polycyclic aromatic hydrocarbons, and thermal properties. Similarly, the fundamental mechanical properties of the WPCs, such as tensile strength, modulus of elasticity, flexural strength, modulus of rupture, and unnotched impact strength, were evaluated. Finally, the thermal stability and interphase coupling efficiency of maleic-anhydride-grafted polypropylene (MAPP) were carefully investigated. WPCs formulated by melt-blending either of the recycled PEs or the blend of recycled PE with bamboo particles showed significant improvement due to MAPP enhancing interfacial adhesion and thermally induced crosslinking, despite inherent immiscibility. These results were confirmed using Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The formulated WPCs may promote PE waste cascading valorization, offering sustainable alternatives and maximizing LLB utilization. Furthermore, comparison with well-known standards for polyolefin-based WPCs indicated that the prepared WPCs can be used as alternative sustainable building materials and related applications. [ABSTRACT FROM AUTHOR]

The nuclear radiation shielding materials are having a great importance in reactor shielding, nuclear laboratories, radiation sources storage, as well as in space radiation shielding. The experimental methods are time consuming, facility dependent, as well as costly affair in order to manufacture the shielding materials. The alternative approach is to use nuclear transport codes such as GEANT, MCNP, PHITS, FLUKA for nuclear radiation shielding application. The present work is planned to study the prediction capabilities of transport code for calculation of shielding parameters using two different radiation transport codes and comparison with experimental results. The simulation measurements were carried out by Monte Carlo analysis, 241Am–Be neutron source & neutron dosimeter, and High Density Polyethylene (HDPE) were modeled using MCNP 6 and PHITS 3.22 codes. Subsequently, experimental neutron dose rates were measured after different thickness of HDPE samples using live 241Am–Be neutron source and NRF31 dosimeter. The study shows a good agreement between the experimental and simulated results which suggest that the simulation method can be used for the optimization of new shielding composites. [ABSTRACT FROM AUTHOR]

Rabbit facilities are systems that pneumatically transport a sample carrier (known as a rabbit) to and from a radiation source. However, trace impurities in the polyethylene (PE) rabbit may interfere with measurements of short-lived isotopes. Activated impurities with short half-lives as 28Al interfere with the fission product γ-ray, therefore the rabbit cannot be measured immediately. Neutron activation analysis was performed on various PE samples obtained from different manufacturers and the highest quality PE was used to fabricate a high-purity PE rabbit. The impurities identified in the PE study were 27Al, 48Ca, 37Cl, 50Cr, 65Cu, 127I, 26Mg, 55Mn, and 30Si. [ABSTRACT FROM AUTHOR]

Polymer composites with low dielectric properties and excellent radio transparency are essential for high signal transmission rates and high device integration. However, creating dielectric polymer composites with high radio transparency is a challenging task. This work presents comparative results of studying the dielectric loss, permittivity and radio transparency of composite materials, such as aramid-epoxy composite (AEC), glass fiber (GF), carbon fiber reinforced plastic (CFRP), and ultra-high molecular weight high-density polyethylene (UHMWPE). Based on the experimental results, the following transmission percentages were established for various materials: CFRP – 2.45%, AEC – 79.43%, UHMWPE – 80.16%, and GF – 78.88%. The dielectric loss tangent angle of carbon fiber is significantly higher compared to other polymer composites, UHMWPE exhibits the lowest tangent angle values, and AEC and GF have stable and low dielectric loss. The obtained polymer composites demonstrated low dielectric permittivity values: AEС 2.9, UHMWPE 2.56, and GF 3.64. [ABSTRACT FROM AUTHOR]

The propagation of pressure waves in water pipes is frequency dependent, which leads to these waves experiencing a frequency-dependent wave speed and attenuation, resulting in wave dissipation and dispersion. The effect is much more significant and complex in plastic pipes than in metal pipes, which makes most wave-based pipe condition assessment techniques ineffective for plastic pipes. In this paper, a new technique is developed to calibrate the frequency-dependent wave speed and attenuation for pressurized water pipes. Persistent hydraulic waves induced by a side-discharge valve are used as excitation. Pressure responses are measured using two pressure sensors, and a paired-impulse response function (paired-IRF) is determined through a deconvolution process. The transfer function between the two sensors is determined using the main spike in the paired-IRF trace, which contains the information on the wave propagation characteristics. The frequency-dependent wave speed and attenuation are then derived from the transfer function. The proposed new technique is validated by both numerical simulations and laboratory experiments. Three pipe configurations are considered in the experiments: (1) a high-density polyethylene (HDPE) pipe in the air; (2) an HDPE pipe buried in sand; and (3) a copper pipe in the air. The frequency-dependent wave speed and attenuation are calibrated for all three configurations and the results are distinctive from each other. [ABSTRACT FROM AUTHOR]

Geosynthetics are widely used in reinforced soil engineering because of their excellent performance. Currently, an increasing number of researchers are studying the fabrication of geosynthetics with both reinforcement functions and sensing abilities. Sensor-enabled piezoelectric geobelts (SPGBs) have great potential in the field of integrated soil reinforcement monitoring because of their ability to reinforce and sense soil. In this paper, polymer-based SPGBs that can be batch extruded were successfully prepared using high-density polyethylene (HDPE), polyolefin elastomer (POE), carbon black (CB), and piezoelectric ceramics (PZT), and the preparation rate of SPGBs was substantially improved. Laboratory tensile tests were conducted to test the strain–stress–impedance–voltage signals of SPGB in the tensile process at 45 different ratios. The results showed that the piezoelectric strain constant (d33) of SPGBs was up to 10.5 pC/N. The tensile strength and breaking strain of SPGBs reached their maximum values of 14 MPa and 26.37%, respectively, at 65% PZT content. During the tensile test, the SPGB normalized impedance increased with increasing strain, and there was a significant sudden increase at the time of damage. An empirical formula for strain-normalized impedance, which can be used to calculate the strain of SPGBs quantitatively, was established. The SPGB output voltage rapidly increased and then decreased with increasing strain, and two characteristic points can be used as warning signs to qualitatively describe the change of SPGBs. The results of this study can provide a design basis for the batch preparation of SPGBs in engineering. [ABSTRACT FROM AUTHOR]

The investigation of new composite materials possessing low weight but not at the expense of their mechanical performance is of great interest in terms of reducing energy consumption in many industrial applications. This study is focused on the nanomechanical characterization of high-density polyethylene (HDPE)-based composite specimens modified with equal loadings of graphene nanoplatelets (GNPs) and/or multiwall carbon nanotubes (MWCNTs). Quasi-static nanoindentation analysis revealed the impact of the carbon nanofillers on the receiving of nanocomposites with higher nanohardness and reduced modulus of elasticity, reaching values of 0.146 GPa and 3.57 GPa, respectively. The role of the indentation size effect in elastic polymer matrix was assessed by applying three distinct peak forces. Nanoscratch experiments depicted the tribological behavior of the composite samples and inferred the influence of the carbon nanofillers on the values of the coefficient of friction (COF). It seems that the incorporation of 4 wt% GNPs in the polymer structure improves the scratch resistance of the material, resulting in a higher value of the exerted lateral force and therefore leading to the detection of a higher coefficient of friction at scratch of 0.401. A considerable pile-up response of the scratched polymer specimens was observed by means of in-situ SPM imaging of the tested surface sample area. The sway of the carbon nanoparticles on the composite pile-up behavior and the effect of the pile-up on the measured friction coefficients have been explored. [ABSTRACT FROM AUTHOR]

In this paper, the nonlinear mechanical properties for flexible pipe were obtained through mechanical property tests. Then a multi-scale coupled finite element model was established based on ABAQUS and CATIA in order to accurately simulate the force problems in the winding process of plastic pipe reinforced by cross helically winding steel wires (PSP). The mechanical responses of the PSP during the winding process were simulated effectively on the premise of ensuring calculation accuracy and time efficiency. Besides, the influences of traction force, drum diameter and steel wire number were investigated. The results show that the sectional ovality of high-density polyethylene (HDPE) layer enhances linearly with the increase of traction force and steel wire number, but decreases nonlinearly with the increase of drum diameter; the maximum Mises stress for steel wires increases with the augment of traction force, but decreases with the increase of drum diameter and steel wire number. [ABSTRACT FROM AUTHOR]

This study investigates the mechanical, thermal, and water absorption properties of high-density polyethylene (HDPE) composites filled with barley straw and varying amounts of waste rubber. The research aims to develop sustainable materials that repurpose agricultural and industrial waste while addressing resource scarcity and waste management challenges. Composites were prepared using a twin-rotor mixer and hydraulic press, with waste rubber content varying from 0 to 20 wt%. Mechanical properties were evaluated through tensile testing, thermal behavior was analyzed using TGA, DTG, and DSC, and long-term water absorption was measured. Results show that increasing waste rubber content from 0 to 20% led to a decrease in tensile strength (11.3 to 8.9 MPa) and tensile modulus (1760 to 790 MPa), while relative extension increased (2.4–5.9%). Thermal analysis revealed a slight reduction in onset degradation temperature (270 °C to 240 °C) and increased char residue (8–18%) with higher rubber content. Water absorption decreased significantly, from 12 to 13% to 6–7% after 600 h of immersion, as waste rubber content increased. These findings demonstrate that incorporating waste rubber into HDPE/barley straw composites results in materials with enhanced flexibility and water resistance at the cost of some strength and stiffness. In conclusion, the results of this study offer a clear pathway for the development of sustainable polymer composites that have broad potential applications across industries like construction, marine infrastructure, automotive, and packaging. By replacing traditional, resource-intensive materials with eco-friendly alternatives, these composites not only provide functional benefits but also support global efforts toward sustainable development and environmental conservation. [ABSTRACT FROM AUTHOR]

Upcycling is emerging as a crucial strategy for enhancing the value of polymers, driving the transition toward a circular material economy. In this study, we present a facile chemical method for converting high-density polyethylene (HDPE) waste into valuable long-chain dicarboxylic acids (LCDCAs) via a key enabling unsaturated double-bond formation step. That is, we propose introducing unsaturation points in HDPE using commercially available heterogeneous catalysts (e.g. Pt/Al2O3). The unsaturation level through C＝C double bond formation is around 10%, as confirmed by FTIR, Raman and X-ray photoelectron spectroscopy. A process of microwave-assisted oxidation is demonstrated to break down the dehydrogenated HDPE into a mixture of aliphatic diacids. This approach enhances the recyclability and value of HDPE by the transformation of polymer waste into bifunctional monomers for potentially novel polyester synthesis. This process offers a sustainable and value-added alternative to conventional recycling methods. While further optimizations are needed, initial estimates of the E-factor and sEF provide promising indicators of the potential environmental benefits of this upcycling approach. [ABSTRACT FROM AUTHOR]

Introduction: Food spoilage and pathogenic bacteria on food-contact surfaces, especially biofilm-forming strains, can transfer to meats during processing. The objectives of this study were to survey the bacterial communities of beef cuts that transfer onto two commonly used food-contact surfaces, stainless steel (SS) and high-density polyethylene (HDPE) and identify potentially biofilm-forming strains. Methods: Top round, flank, chuck, and ground beef were purchased from 3 retail stores. SS and HDPE coupons (approximately 2cm × 5cm) were placed on beef portions (3h, 10°C), after which, the coupons were submerged halfway in PBS (24h, 10°C). Bacteria from the beef cuts and coupon surfaces (n = 3) were collected, plated on tryptic soy agar plates and incubated (5 days, 25°C). Bacterial isolates were identified by 16S rRNA gene amplicon sequencing and assayed for biofilm formation using a crystal violet binding (CV) assay (72h, 10°C). Additionally, beef and coupon samples were collected for bacterial community analysis by 16S rRNA gene amplicon sequencing. Results and discussion: Sixty-one of 972 beef isolates, 29 of 204 HDPE isolates, and 30 of 211 SS isolates were strong biofilm-formers (Absorbance>1.000 at 590 nm in the CV assay). Strong-binding isolates identified were of the genera Pseudomonas, Acinetobacter, Psychrobacter, Carnobacterium, and Brochothrix. Coupon bacterial communities among stores and cuts were distinct (p < 0.001, PERMANOVA), but there was no distinction between the communities found on HDPE or SS coupons (p > 0.050, PERMANOVA). The bacterial communities identified on the coupons may help determine the communities capable of transferring and colonizing onto surfaces, which can subsequently cross-contaminate foods. [ABSTRACT FROM AUTHOR]

The widespread use of low-density polyethylene (LDPE) and high-density polyethylene (HDPE) plastics has resulted in a large amount of waste plastic that requires appropriate disposal or reuse. One potential solution is to use them in the modification of asphalt concrete (AC) mixtures for more sustainable highways. To study this possibility, permanent deformation and dynamic modulus (DM) of the LDPE and HDPE modified AC mixtures was investigated by conducting flow number (FN), flow time (FT) and DM tests on Superpave gyratory compacted specimens. Machine learning models; multi-layer perceptron (MLP), radial basis function neural network (RBFNN), generalized regression neural network (GRNN) and support vector machine (SVM) were used to predict the DM on the basis of frequency and temperature parameters. The model's performance was gauged by analyzing the root mean square error, mean relative error, and coefficient of determination. The study findings revealed that the LDPE and HDPE modified AC mixtures provide 2.07 times and 1.27 times better resistance to permanent deformation, respectively, than their counterpart. It was also found that the LDPE and HDPE modified AC mixtures have 2.1 times and 1.4 times higher DM values, respectively, than the Control AC mixtures. Among the machine learning models, MLP (R2 = 0.98) showed best accuracy in predicting DM and thus is recommended to be used in similar studies due to its robustness. Additionally, the feature importance analysis revealed that frequency has the highest impact on DM predictions, followed by temperature and the inclusion of the LDPE. [ABSTRACT FROM AUTHOR]

Water molecules in vapor can exchange with gaseous water molecules sticking to surfaces of sampling tubing, and exchange rates are unique for each water isotopologue and tubing material. Therefore, water molecules on tubing walls take some time to reach isotopic equilibrium with a new vapor isotopic signal. This creates a memory effect that is observed as attenuation time for signal propagation in continuous stable water vapor isotope measurement systems. Tubing memory effects in δ D and δ18 O measurements can limit the ability to observe fast changes, and because δD and δ18 O memory are not identical, this introduces transient deuterium excess (D-excess, defined as δD-8×δ18O) artifacts in time-varying observations. To our knowledge, a comprehensive performance comparison of commonly used tubing material water exchange properties in laser-based measurement systems has not been published. We compared how a large isotopic step change propagated through five commonly used tubing materials for water isotopic studies – perfluoroalkoxy (PFA), fluorinated ethylene propylene (FEP), polytetrafluoroethylene (PTFE), high-density polyethylene (HDPE), and copper – at two different temperatures and an airflow rate of 0.635 L min−1 through approximately 100 ft (30.5 m) of 1/4 in. (6.4 mm) outer diameter (o.d.) tubing. All commonly used tubing materials performed similarly to each other in terms of attenuation times, reaching δ18 O-location-adjusted δD and δ18 O 95 % completion in less than 45 s, with slight variations based on temperature. PFA does appear to perform slightly better than the other materials, although memory metric differences are small. A tubing material commonly used in the early 2000s but reported to have memory effects on δD , Dekabon, was also tested at ambient temperature and changing humidities. The Dekabon isotopic equilibrium was not reached until nearly an hour after source transition, much later than H2O mixing ratios equilibrated. Bev-A-Line XX (used in some soil O2 and CO2 gas studies) was also tested at ambient temperature, but it did not approach isotopic equilibrium until after nearly 6 h of testing. Therefore, we cannot recommend the use of Bev-A-Line XX or Dekabon in water vapor isotope applications. Source transition from heavy to light or from light to heavy affected isotopic transition speed only in experiments where H2O ppmv was changing. While a shorter tubing lengths and smaller inner diameters shorten the delay of signal propagation through the tubing, they did not greatly change the attenuation curves under these conditions for the current commonly used tubing materials tested. However, in Dekabon, attenuation curves were greatly extended with increased tubing length. Our results show that the commonly used plastic tubing materials tested were not inferior to copper in terms of isotopic memory under these conditions, and they are easier to work with and are less expensive than copper. [ABSTRACT FROM AUTHOR]

Herein, silicon nitride (Si3N4) was the selected additive to be examined for its reinforcing properties on high-density polyethylene (HDPE) by exploiting techniques of the popular material extrusion (MEX) 3D printing method. Six different HDPE/Si3N4 composites with filler percentages ranging between 0.0–10.0 wt. %, having a 2.0 step, were produced initially in compounds, then in filaments, and later in the form of specimens, to be examined by a series of tests. Thermal, rheological, mechanical, structural, and morphological analyses were also performed. For comprehensive mechanical characterization, tensile, flexural, microhardness (M-H), and Charpy impacts were included. Scanning electron microscopy (SME) was used for morphological assessments and microcomputed tomography (μ-CT). Raman spectroscopy was conducted, and the elemental composition was assessed using energy-dispersive spectroscopy (EDS). The HDPE/Si3N4 composite with 6.0 wt. % was the one with an enhancing performance higher than the rest of the composites, in the majority of the mechanical metrics (more than 20% in the tensile and flexural experiment), showing a strong potential for Si3N4 as a reinforcement additive in 3D printing. This method can be easily industrialized by further exploiting the MEX 3D printing method. [ABSTRACT FROM AUTHOR]

Biomass composites are ever-increasing in agricultural engineering. This study aims to enhance the mechanical properties and aging resistance of bamboo-plastic composites (BPC), in order to realize the environmental friendliness and application of its pallet products. Firstly, three ratios of bamboo fiber (BF) and high-density polyethylene (HDPE) were used to prepare the BPC. Then mechanical property tests were conducted to determine the optimal ratio of BF to HDPE. Among them, nano-TiO2 was widely used to enhance the performance of plant fiber/thermoplastic polymer composites, due to its chemical inertness, anti-aging, anti-bacterial properties, and non-toxic nature. An organic-inorganic co-modification was also employed to enhance the BPC properties for strong compatibility with bamboo fiber and plastic matrix. Nano-SiO2 was coated onto nano-TiO2 to prepare SiO2@TiO2 nanoparticles for the high dispersion and aging resistance of TiO2 . Nano-SiO2@TiO2 modified BPC (KH550-ST-BPC) was prepared using the silane coupling agent KH550 as a reinforcing agent by a spray coating. The properties were evaluated to compare the mechanical properties, SEM images, and UV aging properties of BPC before and after modification. In addition, ANSYS Workbench software was used to perform the finite element analysis of BPC integrated pallets before and after modification, in order to verify the application performance of reinforced BPC pallets. The results indicated: 1) The bending and tensile properties of BPC shared an increasing trend with the increase of bamboo fiber content. The optimal mechanical properties of BPC were obtained at a 5:5 mass ratio of BF to HDPE, with a 38.34% increase in the bending strength and a 62.19% increase in the bending modulus, compared with the 3:7 ratio. The tensile strength and modulus increased by 14.95% and 101.18%, respectively. SEM images revealed that there was a smoother interface for BPC55, which was better consistent with the mechanical test. 2) The bending and tensile strength of BPC were enhanced by 31.11% and 11.86%, respectively, in the modified nano KH550-SiO2@TiO2, while the bending and tensile modulus were enhanced by 52.27% and 21.92%, respectively. The interfacial gaps of modified BPC were significantly reduced in the SEM images, indicating the strong bonding between the bamboo fibers and HDPE. The KH550-SiO2@TiO2 was introduced to fill the interface gaps for the BPC compatibility, which was better consistent with the mechanical property test. 3) The surface morphology revealed that KH550-SiO2@TiO2 modified BPC maintained better color stability for the high resistance to UV aging. While the unmodified BPC showed significant color fading after 1 200 h UV irradiation aging. Colorimetric analysis confirmed that the color stability of KH550-ST-BPC was significantly better during UV aging, with a color aberration change value 77.79% lower than before. 4) Finite element analysis indicated that the modified BPC pallet exhibited the better-bending properties and load-bearing capacity, with a 27.36% reduction in the maximum deformation under the rated load and a 23.41% reduction under the ultimate load in stacking simulation. These research findings can provide a strong reference for the application of nano-SiO2@TiO2 reinforced BPC as logistics turnover units. [ABSTRACT FROM AUTHOR]

Accurate detection and characterisation of defects in high-density polyethylene (HDPE) materials are important for the safety of industrially critical structures. Ultrasonic non-destructive evaluation (UNDE) has proven to be a powerful tool for detecting and characterising defects in engineered materials. However, efficient and high-precision defect imaging in these highly attenuating materials remains a significant challenge for UNDE. Least-squares reverse time migration (LSRTM) offers the potential to reconstruct high-precision images of reflectivity. Yet, the conventional LSRTM iteratively updates the reflectivity model by minimising the data residuals, making it computationally expensive. In this paper, an efficient ultrasonic LSRTM algorithm within a deep learning framework is proposed. Building upon this, a generative adversarial network (GAN) is integrated to further enhance the reconstruction results by reducing artefacts in the images. Simulation and experimental results show that the proposed ultrasonic LSRTM-GAN can generate high-quality images, effectively enabling precise defect detection in HDPE. [ABSTRACT FROM AUTHOR]

It has been known that plastics with undegradability and long half‐times have caused serious environmental and ecological issues. Considering the devastating effects, the development of efficient plastic upcycling technologies with low energy consumption is absolutely imperative. Catalytic hydrogenolysis of single‐use polyethylene over Ru‐based catalysts to produce high‐quality liquid fuel has been one of the current top priority strategies, but it is restricted by some tough challenges, such as the tendency towards methanation resulting from terminal C−C cleavage. Herein, we introduced Ru nanoparticles supported on hollow ZSM‐5 zeolite (Ru/H‐ZSM‐5) for hydrocracking of high‐density polyethylene (HDPE) under mild reaction conditions. The implication of experimental results is that the 1Ru/H‐ZSM‐5 (~1 wt % Ru) acted as an effective and reusable bifunctional catalyst providing higher conversion rate (82.53 %) and liquid fuel (C5−C21) yield (62.87 %). Detailed characterization demonstrated that the optimal performance in hydrocracking of PE could be attributed to the moderate acidity and appropriate positively charged Ru species resulting from the metal‐zeolite interaction. This work proposes a promising catalyst for plastic upcycling and reveals its structure‐performance relationship, which has guiding significance for catalyst design to improve the yield of high‐value liquid fuels. [ABSTRACT FROM AUTHOR]

The waste of polymeric materials in our society is increasing year after year, generating a serious pollution problem. One way to deal with this waste problem is to recycle and reuse these materials. This process of recovery of used plastic materials aims to minimise their impact on the environment and reduce the energy consumption required for the generation of new consumer products. Recycling companies that recover these plastic materials must take into account some aspects such as transparency and colour, cleanliness, size, odour and sorting. One of the major disadvantages in accepting these recycled materials in the production processes is their odour, which in some cases causes the rejection of materials with comparable mechanical characteristics. High-density polyethylene, HDPE, is one of the polymeric wastes generated in the packaging industry. The aim of this work is to eliminate the bad odour of HDPE from waste collection plants for application in the recovery and reuse industry. HDPE supplied by a recycling company was washed, characterised and processed, and the odour was analysed by gas chromatography at each stage and by olfactory panel. In view of the results, it was observed that the washing processes managed to reduce the odour. Likewise, the processing of this waste by extrusion and injection managed to further reduce this effect, even eliminating some of the components responsible for odour by treating the samples with acetone and then extruding and injecting these samples. These results have a direct application in the packaging industry with significant shares of recycled material. [ABSTRACT FROM AUTHOR]

Metallization of polymers is a modern technique used to improve their properties by coating them with conductive, lightweight surfaces, enabling their use in many electronic and communications applications. This study examines the effect of corrosion of a copper layer deposited on two polymeric substrates, high-density polyethylene (HDPE) and acrylonitrile butadiene styrene (ABS), by flame thermal spraying. Pull off test shows the adhesion strengths between the Cu coating layers and the HDPE and ABS substrates were 1.42 and 1.94 MPa, respectively. The contact angles for the HDPE and ABS were 57.227 and 36.422ο, respectively, indicating that the ABS substrate is more wettable than the HDPE substrate. A corrosion test of the coated substrates was conducted at 27±1 °C in a solution of 3.5% NaCl. The corrosion rate was 2.763×10-2 mm/year for Cu on HDPE and 1.361×10-2 mm/year for Cu on ABS. The corrosion rate of Cu on HDPE is greater than that of Cu on ABS, indicating that the Cu coating layer on the ABS substrate is denser and less porous than that on the HDPE substrate. The corrosion products for the corroded Cu layer on HDPE were NaCl, NaOH, Cu5Zn8 and CuCl, whereas those for the corroded Cu on ABS were CuCl and Cu(OH)2. [ABSTRACT FROM AUTHOR]

The current study explores the fabrication of 3D printing filament using waste glass powder (WGP) and high-density polyethylene (HDPE) thermoplastic aiming to enhance the mechanical properties and sustainability of the composite material. The matrix and filler were blended in varying weight ratios (HDPE: WGP) of 100:0, 95:5, 90:10, 85:15, and 80:20 to prepare a raw material for filament extrusion. The filament of diameter 1.65 ± 0.05 mm diameter was extruded. Thereafter, a chemical and thermo-mechanical characterization of extruded filament was conducted. Fourier-transform infrared spectroscopy (FTIR) analysis confirmed the successful integration of WGP into the HDPE matrix, while X-ray diffraction (XRD) examination revealed alterations in crystallinity attributed to WGP reinforcement. Thermogravimetric Analyzer (TGA) analysis demonstrated enhanced thermal stability upon WGP incorporation, which is attributed to its role as a thermal barrier. Tensile test exhibit 45.41% and 17.22% increase in yield stress and ultimate tensile stress for 90:10 composition ratio, respectively. Moreover, including waste glass powder in HDPE, thermoplastic composite offers a sustainable solution for repurposing glass waste, thereby reducing the volume of glass destined for landfills or incineration. Potential applications of this composite filament include its use in construction, automotive, and packaging industries through 3D printing, where improved mechanical properties and sustainability are highly valued. [ABSTRACT FROM AUTHOR]

Microplastic pollution is an emerging stressor of concern to coral reef ecosystems, which are already threatened by additional global and local level anthropogenic stressors. The effects of ingesting microplastics alone on corals have been well studied, but the effects of the chemical composition of these particles have been understudied. Many microplastic-associated chemicals are endocrine disrupters potentially posing a threat to organismal reproduction. Therefore, the goal of this study was to determine if differences exist between the effects of microplastics themselves and microplastic leachate on Montipora capitata fertilization due to changes in fatty acid quantity and composition. Assays were conducted two years in a row which exposed M. capitata gamete bundles to either one of four types of recently manufactured, virgin microspheres (nylon, polypropylene, high-density polyethylene, or low-density polyethylene) at three concentrations (50, 100, or 200 particles/L) or microplastic leachates, presumably including plastic additives from these microspheres. Gamete fertilization was not impacted by microplastic particles themselves, but some of the microplastic leachate treatments with the same polymer type significantly reduced fertilization rates for M. capitata. Additionally, a total of 17 fatty acids were seen in both years, but neither fatty acid quantity nor composition correlated with observed declines in fertilization. Instead, fertilization and fatty acid data independently varied by concentration and polymer type, likely due to the presence of different chemicals. This study is the first to directly test the toxicity of microplastic leachate to coral reproduction. These findings show that microplastic-associated chemicals are an important stressor affecting successful coral fertilization and fatty acid quantity and composition and provide evidence for the negative effects of microplastic leachate to coral reproduction. Thus, plastic additives could pose an additional threat to coral replenishment and persistence in coral reef ecosystems. [ABSTRACT FROM AUTHOR]

In this study, a small‐sized shredder machine equipped with spiral oriented double‐edged rotating and fixed blades was utilized to shred high‐density polyethylene (HDPE) waste. The performance of the shredder machine was determined based on the recycling and shredding efficiency, the percentage of retention, and the wear of its rotating and fixed blades. The wear of the blades was examined using an optical microscope, a scanning electron microscope, an energy dispersive x‐ray, and an x‐ray diffraction. High recycling (~95 %–98 %) and shredding (~66 %–70 %) efficiency, and low percentage of retention (~1.2 %–4.1 %) indicated a reliable performance of the shredder machine. The rotating blade exhibited higher wear at the back end, compared to the front end for the fixed blade. The wear of the blades was due to scratching and edge chipping. Formation of iron oxides during shredding did not cause significant changes in the hardness of the blades. Based on the evaluation, cost‐effective and time saving maintenance of the shredder blades could be achieved by gradual maintenance starting from the blade exhibited high wear. [ABSTRACT FROM AUTHOR]

Enhancing the degradability of polyethylene plastics could provide a potential solution to the overwhelming crisis of plastic waste. Conventional studies have focused on the degradation of polyethylene thin films. This study investigated UV-induced photo-degradation according to ASTM D5208-14 in polyethylene sheets with thicknesses ranging from 0.4 to 1.2 mm. The impacts of sample thickness, metal pro-oxidants, polyethylene resin types and foaming were explored through the characterization of the carbonyl index, molecular weight, tensile properties and crystallinity. As pro-oxidants, single iron or manganese stearate demonstrated a concentration-dependent trend in accelerating the photo-degradation of polyethylene sheets. The thickness, foaming and resin type—such as low-density polyethylene (LDPE) and high-density polyethylene (HDPE)—significantly impacted the rate of photo-oxidation. Thick polyethylene sheets (1.2 mm) exhibited a heterogenous and depth-dependent degradation profile. As the photo-degradation progressed, the enhanced crystallinity, reduced UV transmittance and formation of crosslinks were able to prevent further oxidative cleavage of the polyethylene chain. This study investigated the time course and factors affecting the photo-degradation of polyethylene sheets, which could provide insights into the formulation design of photo-degradable polyethylene plastics. [ABSTRACT FROM AUTHOR]

This study uses an extrusion process to formulate blends based on recycled high-density and high-molecular-weight polyethylene (recHDPE, recHMWPE) for the manufacture of rainwater drainage pipes. The main objective of this project is to investigate the effects of incorporating graphene on the mechanical, thermal, and stress-cracking resistance properties of the recycled HDPE and HMWPE blends. Also, it aims to demonstrate that the addition of graphene may enable the use of different recycled polymers without compromising their properties. The effects of adding two amounts of graphene (0.5 and 1%) to recycled blends on the tensile and flexion properties, stress crack resistance (SCR) (using a notched crack ligament stress (NCLS) test), thermal behavior (using a differential scanning calorimeter (DSC) and a rheological plastometer) were investigated. The experimental results showed a significative enhancement when adding graphene in the SCR, some tensile properties (elongation at break and tensile strength), and flexural modulus. However, physical characterization showed that the samples containing 0.5% graphene exhibited lower crystallinity compared to the reference and, for the blend with 1% graphene, the fluidity also decreased for the blend filled with the graphene compared to the reference blend without any filler. [ABSTRACT FROM AUTHOR]

The influence of carbon nano fiber (CNF) along with organically modified nanoclay (OMMT) on the final properties of high density polyethylene (HDPE) hybrid nanocomposites has been investigated. The hybridized nanocomposites were prepared in a twin screw extruder by melt mixing to achieve better dispersion. The effect of nano fillers on the mechanical, thermal, rheological, and morphological properties has been reported. The incorporation of OMMT along with CNF slightly improved the mechanical properties of the resultant hybrid nanocomposite due to the good adhesion between the filler and matrix. On the other hand, as shown in DSC results, increasing reinforcing filler quantity has no significant influence on the thermal properties such as melting and crystallization temperatures. Thermogravimetric analysis (TGA) results have shown that increasing filler content in the hybrid nanocomposite matrix has enhanced drastically the thermal stability of the neat HDPE. Similarly, the rheological behavior of the hybrid system showed significant increase in the viscosity due to the synergetic effect. A marginal increase in moduli and complex viscosity was observed in the hybrid system, while loss tangent was found to be decreased due to the increase in the stiffness. The morphological features of nanocomposites were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The nanoscale images showed the well dispersion of filler nanoparticles without any prominent aggregation, which further indicates the compatibilizing ability of nanofillers within the HDPE matrix. [ABSTRACT FROM AUTHOR]

The effect of UVC (254 nm) treatment on the mould-free shelf-life of par-baked wholemeal, rye and six-grain bread was examined. Currently, these breads are par-baked, wrapped in high-density polyethylene (HDPE)-foil and transported or stored at room temperature for a couple of days before being full-baked and sold/consumed. Generally, after five days, these breads show signs of mould spoilage. A shelf-life increase in one or more days would already offer immense economical and logistic benefits for the baker or retailer. In this study, the parameters fluence rate (irradiation intensity), fluence (UV dose), distance to the UV-lamp (DTL) and number of layers of a common wrapping HDPE-foil (20 µm) were diversified. The breads were subjected to a UVC treatment (0–2502 mJ/cm²), packed and stored at room temperature for a period of 15 days (21.5 ± 0.8 °C). Similar as for the breads, agar plates with mould spores of Aspergillus niger, Aspergillus montevidensis and Penicillium roqueforti were UVC treated (0–1664 mJ/cm²) and checked daily for visible mould growth during 15 days (25 °C). Aspergillus niger showed the strongest resistance towards UVC, a fluence of 800 mJ/cm² was needed to inhibit growth during 15 days of storage, whereas for P. roqueforti and A. montevidensis, respectively, UV levels of 291 and 133 mJ/cm² were found sufficient. Furthermore, the shelf-life of wholemeal, rye and six-grain bread can be prolonged from 5 to 6, 8 and 9 days, respectively, using 2502 mJ/cm². The effect of higher UVC dosage on shelf-life reached a maximal level and was strongly impacted by the wide spread on data of mould-free shelf-life. The main factors influencing the potential of UV decontamination were the rough bread surface, differences in DTL, the possibility of post-contamination and UV permeability of packaging materials. [ABSTRACT FROM AUTHOR]

Vitrimers have emerged as a prominent research area in the field of polymer materials. Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures, while the impact of chemical structure on aggregate structure of vitrimers, particularly during polymer processing, remains insufficiently investigated. The present study employed commercial maleic anhydride-grafted-high density polyethylene (M-g-HDPE) as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process. Through chemical structure characterization, morphology observation, thermal and mechanical properties investigation, as well as aggregate structure analysis, this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing. A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing, resulting in a lower orientation of the PE chains. However, lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation. The uneven morphology of fiber-shaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding, which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure. [ABSTRACT FROM AUTHOR]

To manufacture, feature and analyze the potential of materials to be used as raw material for drug delivery systems for the treatment of overactive bladder. Four distinct mixtures of oxybutynin and polymers ethylene vinyl acetate (EVA) and high-density polyethylene (PE) were prepared via compression molding and hot melt extrusion. The materials were characterized regarding their physicochemical and mechanical properties as well as drug release potential. Promising results were obtained in which the release of oxybutynin was observed for more than 250 days from both EVA and HDPE matrices. The obtained data demonstrate it is possible to manufacture HDPE- and EVA-based samples with the incorporation of oxybutynin, and the EVA samples presented an adequate release profile. The results are promising for the development of an intravesical device with drug delivery, especially because super dose risk is extinguished when considering the release from a monolithic release system. [ABSTRACT FROM AUTHOR]

Plastic products are used in large quantities. However, the fact that plastics do not degrade in nature for many years causes environmental pollution. Addressing this issue, the study focuses on recycling the widespread high-density polyethylene (HDPE) plastic waste. In this study, HDPE waste was collected randomly from the environment, mirroring real-world scenarios. Then, the waste was transformed into granules. Afterward, washing and drying processes were carried out. HDPE filaments of different linear densities were successfully produced from the waste plastic granules. Tensile tests revealed that the breaking strength of the filaments from waste plastic was lower than that of virgin HDPE filaments, highlighting the challenges of recycling. Hybrid yarns were formed by twisting the filaments with cotton yarn to improve the mechanical properties of the filaments from waste plastic. Remarkably, statistical analysis demonstrated that the breaking load values of the hybrid yarns from waste plastic were statistically equivalent to those made from virgin polymer. This outcome indicated that the hybrid yarns made from waste HDPE plastic were as strong as those made from virgin HDPE polymer. In addition, both hybrid yarns exhibited a breaking load 36% higher than the reference extra-twisted cotton yarn. The hybrid yarn formation made filaments produced from waste plastic a valuable component of the high-strength hybrid yarn. Overall, this study shows that recycling HDPE plastics can lead to the production of high-strength hybrid yarns, which can contribute to reducing plastic waste pollution. [ABSTRACT FROM AUTHOR]

Plastic pollution is an emergent global issue in freshwater and marine ecosystems. Microplastics enter waterways from a variety of sources, although the relative importance of point and nonpoint sources for a given watershed is not well understood. To determine whether medium-sized wastewater treatment plants are significant sources of microplastics to rivers draining into Lake Erie, we measured microplastic loads up- and downstream of two wastewater treatment plants in southeastern Michigan State (USA). We detected a significant increase in the microplastic load downstream from the wastewater treatment plant discharging into the Lower Rouge River, but not downstream from the one discharging into the Huron River. However, the background microplastic load was tenfold higher in the Huron River compared to the Lower Rouge River, likely obscuring our ability to detect the wastewater treatment plant as a point source. We found a positive relationship between river discharge and microplastic load in the Huron River, which drains a larger watershed area at the effluent discharge point than the Lower Rouge site, suggesting that watershed sources may be more important over larger spatial scales. We also performed experiments to test the effects of plastic on stream biofilm function to better understand how plastic pollution alters stream metabolism. Biofilms grown on high-density polyethylene and polypropylene had significantly lower metabolic diversity and metabolic response, respectively. Overall, our findings indicate that attention should be directed to both point and nonpoint sources to reduce microplastic pollution and that plastics may negatively affect the function of stream biofilm communities. [ABSTRACT FROM AUTHOR]

Full‐field optical experimental techniques such as Digital Image Correlation (DIC) enable measurement of information‐rich heterogeneous strain states. The aim of Material Testing 2.0 is to capitalise on this and design experimental setups for efficient material characterisation using inverse identification techniques such as the Virtual Fields Method (VFM). In that case, however, a priori knowledge of the constitutive model is required, which sometimes is not a trivial task. This limitation can be overcome by identifying multiple constitutive models using the same DIC strain fields and comparing their performance. In this work, we present a methodology to evaluate model performance and compare different constitutive models based on quantitative metrics. DIC experiments were performed on an S‐shaped high density polyethylene test sample under uniaxial load. The heterogeneous DIC strain fields were used in combination with the VFM to identify parameters of hyperelastic constitutive models with increasing complexity. Two deterministic metrics, the equilibrium gap indicator (EGI) and the reconstructed axial force ratio (RAFR), were defined and used to compare the performance of these constitutive models. The impact of spatial smoothing on DIC strain fields was studied by calculating the EGI and RAFR using a digital twin of the DIC experiments. EGI and RAFR metrics provide complementary information regarding the material behaviour, and both are necessary to make an informed choice. In this case study, hyperelastic constitutive models were found not to capture the material stiffness well in the small strain regime. A linear‐elastic contribution exponentially decaying with the equivalent shear stress was added to the hyperelastic models and the corresponding model parameters identified using the VFM. The elastic‐hyperelastic constitutive models were found to perform better than their purely hyperelastic counterparts. [ABSTRACT FROM AUTHOR]

• Waste coffee pods (CP) were treated using a two-stage pyrolysis process. • A microwave-assisted pyrolysis process was employed for treating waste CP. • Catalytic reforming of evolved gas yielded 76 % (by volume) hydrogen at 900 °C. • Microwave and catalysis-assisted pyrolysis process can be a solution to upcycling. Plastic waste poses a critical environmental challenge for the world. The proliferation of waste plastic coffee pods exacerbates this issue. Traditional disposal methods such as incineration and landfills are environmentally unfriendly, necessitating the exploration of alternative management strategies. One promising avenue is the pyrolysis in-line reforming process, which converts plastic waste into hydrogen. However, traditional pyrolysis methods are costly due to inefficiencies and heat losses. To address this, for the first time, our study investigates the use of microwave to enhance the pyrolysis process. We explored microwave pyrolysis for polypropylene (PP), high-density polypropylene (HDPE), and waste coffee pods, with the latter primarily comprising polypropylene. Additionally, catalytic ex-situ pyrolysis of coffee pod pyrolysis over a nickel-based catalyst was investigated to convert the evolved gas into hydrogen. The single-stage microwave pyrolysis results revealed the highest gas yield at 500 °C for HDPE, and 41 % and 58 % (by mass) for waste coffee pods and polypropylene at 700 °C, respectively. Polypropylene exhibited the highest gaseous yield, suggesting its readiness for pyrolytic degradation. Waste coffee pods uniquely produced carbon dioxide and carbon monoxide gases because of the oxygen present in their structure. Catalytic reforming of evolved gas from waste coffee pods using a 5 % nickel loaded activated carbon catalyst, yielded 76 % (by volume) hydrogen at 900 °C. These observed results were supported by elemental balance analysis. These findings highlight that two-stage microwave and catalysis assisted pyrolysis could be a promising method for the efficient management of waste coffee pods, particularly for producing clean energy. [ABSTRACT FROM AUTHOR]

This paper presents a novel methodology for assessing water vapour transmission rates (WVTRs) through geomembranes across a wide temperature range, from 20 °C to 90 °C. This expands upon the existing ASTM E96 standard, limited to temperatures up to 32 °C. The study focused on 1.5 mm thick high-density polyethylene (HDPE) and polyvinyl chloride-ethylene interpolymer alloy (PVC-EIA) geomembranes. The WVTR results—0.15 g/m2h at 25 °C for PVC-EIA and 0.02 g/m2h at 30 °C for HDPE—align closely with values reported in existing literature for similar geomembranes at lower temperatures, validating the methodology proposed in this study. Under elevated temperatures, the WVTR of PVC-EIA increased significantly to 4.7 g/m2h at 90 °C, while HDPE showed a slower increase, reaching only 0.4 g/m2h at the same temperature. This disparity is attributed to polymer composition and behaviour differences under high temperatures. This study's methodology provides a dependable approach for accurately measuring WVTR, including high temperatures relevant to various applications where such data is currently lacking. • Geomembranes are increasingly used in the energy sector where high temperatures prevail. • Means of measuring water vapour transmission rates (WVTRs) at high temperatures is lacking. • Existing ASTM E96 can only be used up to 32°C and does not cater for high temperatures. • Novel methodology is introduced to measure water vapour transmission rates at high temperatures. [ABSTRACT FROM AUTHOR]

Two copolymer polyethylenes of raised temperature resistance (PE-RT) were used to analyze their basic properties and molecular structure, including their basic physical properties, molecular weight and distribution, molecular chain structure, and aggregation structure of the product; the crystallization kinetics and other properties differences are also discussed. The results showed that the basic physical properties of the two resins were similar, but there were still some differences in molecular structure. The molecular weight of PE-RT-1 was slightly lower in the range of 500,000–1,000,000 molecular weight, and slightly higher in the range of <500,000 molecular weight than PE-RT-2. The crystallization capacity of the crystallizable part of PE-RT-2 was slightly better than that of PE-RT-1. The comonomer (1-butene) content and polymer branching degree of PE-RT-2 were higher than those of PE-RT-1. The crystallinity of PE-RT-1 products was higher than that of PE-RT-2, and the lattice structure of PE-RT-1 was more complete and had good heat resistance. In addition, the butene content of PE-RT-2 with high molecular weight was higher than those of PE-RT-1, which was more conducive to the generation of tie molecules. [ABSTRACT FROM AUTHOR]

The rapid spread of the use of high-density polyethylene (HDPE) pipes is due to the wide variety of methods for connecting them. This study keeps pace with the developments of butt fusion welding of HDPE pipes by exploring the relationship between the performance of the weld joints by studying ultimate tensile strength and exploring the joint welding profiles by studying the shape of the joint at the outer surface of the pipe (height and width of the joint cap) and the shape of the joint at the internal surface (height and width of the joint root). Welding pressure, heater temperature, stocking time, and cooling time were the parameters for the welding process. Regression was analyzed using ANOVA, and an ANN was used to analyze the experimental results and predict the outputs. Two optimization techniques (pattern search and genetic algorithm) were applied to obtain the ideal operating conditions and compare their performance. The results showed that pattern search and genetic algorithms can determine the optimal output results and corresponding welding parameters. In comparison between the two methods, pattern search has a limited relative advantage. The optimal values for the obtained outputs revolved around a tensile strength of 35 MPa (3.45 and 4.5 mm for the cap and root heights, and 8 and 6.98 mm for the cap and root widths, respectively). When comparing the effects of welding parameters on the results, welding pressure had the best effect on tensile strength, and plate surface temperature had the most significant effect on the welding profile geometries. [ABSTRACT FROM AUTHOR]

Ballistic helmets are individual pieces of armor equipment designed to protect a soldier's head from projectiles and fragments. Although very common, these helmets are responsible for several casualties due to their significant back face deformation and low ballistic resistance to projectiles. Therefore, to enhance helmet performance, studies have focused on the development of new materials and new ballistic protection solutions. The purpose of this study was to develop and evaluate a new ballistic solution using thermoplastic-based matrices. The first matrix was based on high-density polyethylene (HDPE). The second matrix was based on HDPE modified with exfoliated montmorillonite (MMT). The main manufacturing processes of a thermoplastic-based ballistic helmet are presented, along with its ballistic performance, according to the National Institute of Justice (NIJ) standard 0106.01 and an investigation of its failure mechanisms via a non-destructive technique. All the helmets resulted in level III-A ballistic protection. The postimpact helmets were scanned to evaluate the back face deformation dimensions, which revealed that the global cone deformation was deeper in the HDPE than in the HDPE/MMT helmet. The failure analysis revealed an overall larger deformation area in the HDPE and HDPE/MMT helmet delamination zones in the regions with a large radius of curvature than in the zones with the lowest radius, which is in accordance with previous simulations reported in the literature. [ABSTRACT FROM AUTHOR]

Reintroducing recycled plastics into production processes can lead to irreversible degradation and changes in their properties, thereby limiting their recycling potential to a finite number of loops. This study investigates the impact of process-induced degradation resulting from multiple reprocessing cycles on specific material properties and aims to establish structure–property relationships. Four different polyolefins, including two polypropylenes, high-density polyethylene, and low-density polyethylene, were selected for the study. The materials underwent extrusion, pelletizing, injection molding, and milling before being reintroduced into the reprocessing cycle. This sequence of processing steps was repeated six times on each material. Various characterization techniques, including high-temperature gel permeation chromatography, melt mass flow rate, parallel-plate rheology, differential scanning calorimetry, gas chromatography–mass spectrometry, and optical defect control system, were performed to evaluate the molecular structure, rheological behavior, thermal stability, and the resulting contaminants and defects after each reprocessing step. The reprocessing of polypropylene resulted in a gradual decrease in the average molecular weights accompanied by a shift to lower viscosities and higher melt mass flow rates, whereas the polyethylene grades showed the opposite trend with a less pronounced effect in high-density polyethylene. The volatile organic compounds rose in polypropylene and sank in polyethylene after reprocessing. Additionally, all four materials exhibited an increase in degradation-related defects based on optical defect analysis. [ABSTRACT FROM AUTHOR]

Microplastics (MPs), measuring less than 5 mm, have been causing environmental concerns in aquatic ecosystems, and less work has been done in indoor environments, where humans spend most of their lives. This finding revealed a diverse range of MPs within indoor house dust samples. These MPs encompassed fibres, fragments, foams, pellets and films. Due to the ubiquity of textile-based items, fibres are the most common indoor MP. The MPs have different colours like black, red, blue, yellow, white and brown. The study revealed there were substantial differences in MP sizes across different households. The average size range was 178.87–3713.99 µm. One hundred eighteen particles were identified as MPs. The study identified 22 types of MPs, shedding light on these materials' extensive sources and applications in everyday household items. MPs in indoor environments raise concerns about potential human exposure and underscore the need for further research into their health implications. The MPs found in most indoor house samples were low-density polyethylene, polyethylene, polypropylene, polyamide, polyvinyl chloride, high-density polyethylene and polystyrene. Carbon, nitrogen, fluorine, sodium, sulphur, potassium, calcium, zinc, oxygen and magnesium were the common elements in all indoor house dust samples. Compared with the active sampling, slightly more work has been done on the indoor house dust samples. [ABSTRACT FROM AUTHOR]

The Golmud-Korla Railway in the Gobi area faces operational challenges due to sand hazards, caused by strong and variable winds. This study addresses these challenges by conducting wind tunnel tests to evaluate the protective benefits of High Density Polyethylene (HDPE) board sand fences, focusing on their orientation relative to various wind directions (referred to as 'wind angle'). This study found that the size of the low-velocity zone on the leeward side of the sand fences (LSF) expanded with an increase in the wind angle (WA). At 1H (the height of the sand fence) and 2H positions on the LSF, the wind speed profiles (WSP) exhibited a segmented logarithmic growth, constrained by Z = H at varying WAs. The efficacy of the sand fence in obstructing airflow escalated as WA increased. The size of the WA has a significant impact on the protective efficiency of HDPE board sand fences. Furthermore, compared to typical sandy surfaces, the rate of sand transport across the Gobi surface diminishes more slowly with height, attributed to the gravel's rebound effect. This phenomenon allows some sand particles to bypass the fences, rendering them less effective at blocking wind and trapping sand than in sandy environments. This paper offers scientific evidence supporting the practical use and enhancement of HDPE board sand fences in varied wind conditions. [ABSTRACT FROM AUTHOR]

The effect of thermal-oxidative ageing on in-isolation and in-soil stiffness is investigated for two high-density polyethylene (HDPE) and two polyester (PET) geogrids when incubated in an oven at 90°C. It is shown that the in-isolation and in-soil stiffness of three out of the four geogrids decreased during the 4-month ageing time with a faster degradation of the two PET geogrids. In contrast, one of the HDPE geogrids examined with thicker rib showed slower degradation compared to the PET counterparts. It is also shown that a geogrid might have a higher unaged stiffness, but less aged stiffness compared to another geogrid made of the same polymer type. It is suggested that the ageing approach used in this study could be adopted for the selection of geogrids based on their long-term stiffness for structures such as reinforced embankments or mechanically stabilized earth walls that require a long service life. Moreover, results indicate that the stiffness improvement factor for PET geogrids decreases with ageing time. On the contrary, the stiffness improvement factor of the HDPE geogrid increases with time and hypothetically might keep increasing followed by a sudden drop to zero at full degradation of the geogrid. [ABSTRACT FROM AUTHOR]

The aim of this paper is to determine the effect of polymer density, correlated to the comonomer content, and nanosilica addition on the mechanical and Environmental Stress Cracking Resistance (ESCR) characteristics of high‐density polyethylene (HDPE). In this regard, five HDPE samples with similar Melt Flow Index (MFI) and molar mass but various densities were acquired from a petrochemical plant. Two polymerization reactors work in series and differ only in the amount of 1‐buene comonomer fed to the second reactor. To ascertain the microstructure of the studied samples, GPC and SSA (successive self‐nucleation and annealing) analyses were accomplished. All samples resulted having similar characteristics but slightly various SCB/1000 C=7.26–9.74 (SCB=Short Chain Branching). Consequently, meanwhile studied HDPEs reveal similar notched impact and stress at yield values, the tensile modulus, stress‐at‐break, and elongation‐at‐break tend to demonstrate different results with the SCB content. More significantly, ESCR characteristic varied considerably with SCB/1000 C extent, so that higher amount of SCB acknowledged advanced ESCR. Notably, blending HDPE sample containing higher amount of SCB/1000 C, with 3 wt.% of chemically modified nanosilica enhanced ESCR characteristic by 40 %. DFT (Density Functional Theory) calculations unveiled the role of the comonomer, quantitatively by binding energies and qualitatively by Non Covalent Interaction (NCI) plots. [ABSTRACT FROM AUTHOR]

Highlights Microfibrillated cellulose (MFC) was uniformly dispersed in high‐density polyethylene (HDPE) using a large amount of surfactant, and composites were prepared after removing the surfactant at different contents. The structural, morphological, thermal, and tensile properties of these composites were systematically investigated. The results demonstrated an asymptotic relationship between the amount of surfactant removed and the number of removal cycles. A negative linear correlation was observed between the surfactant content and the tensile strength, tensile modulus, and storage modulus at −20 °C of the composites, while a positive linear correlation was found with the loss modulus at −20 °C. Excessive surfactant adversely affected the dispersion of MFC, as well as the mechanical properties and thermal stability of the composites. However, when the surfactant content was below 2.8%, its impact on the composite properties was minimal, and the tensile strength, modulus, and thermal stability of the composites were significantly improved compared to neat HDPE. These findings indicate that surfactant pretreatment is an effective strategy for dispersing MFC in non‐polar polymers, and controlling the surfactant content in the final product can effectively tailor the properties of the resulting composites. Confirms the relationship between surfactant content and MFC/HDPE composite properties. Surfactant content showed an asymptotic relationship with removal cycles. Surfactant content and mechanical properties exhibited a negative linear correlation. Surfactant content and thermal stability exhibited a negative relationship. Surfactant content had minor impact when below 2.8%. [ABSTRACT FROM AUTHOR]

Heptene‐graphitic nanoplatelets (HtGNP) serve as a filler for high density polyethylene (HDPE), generated through a mechanochemical reaction involving graphite and 1‐heptene. Various analyses indicate the efficient exfoliation of graphite into HtGNP, characterized by exceptional traits. Consequently, HtGNP & HDPE_5 nanocomposites, produced via the solution process, exhibit significantly increased tensile strength and Young's modulus, boasting corresponding increases of 27.7% and 13.7% compared to pure HDPE. Thus, owing to their outstanding performance, HtGNP emerges as a promising option in the form of a novel reinforcing additive for various hydrocarbon polymers. [ABSTRACT FROM AUTHOR]

As an abundant commodity, coffee production generates significant scraps and by-products, increasing the potential pollution hazards. Circular economy and bioeconomy can help valorize Spent Coffee Grounds (SCGs), e.g., as fillers in polymer-based composites using conventional manufacturing, i.e., injection molding. Large-format additive manufacturing with pellet extruders offers a further option for new applications, reducing costs for the valorization of biomass waste. However, its use in this context remains unexplored, especially for applications with complex geometries or critical overhangs. This work investigates new biomass waste-based materials for large-format additive manufacturing with direct feeding extrusion, fabricating self-supported complex overhang geometries through nonplanar slicing. The thermal, rheological, and mechanical properties of three novel polymer-based pellet compounds with post-industrial SCGs, i.e., injection molding grade polylactic acid/SCGs, recycled low-density polyethylene/SCGs, and high-density polyethylene/SCGs, were herein investigated to evaluate their printability, defining their extrusion temperatures (190 °C and 170 °C). Results showed suitable viscosity ranges (133.6–839.7 Pa∙s) and accurate tensile values comparable with literature, e.g., ~ 1–3% minimum relative standard deviations (polylactic acid/SCGs), or conventional manufacturing, e.g., elastic moduli of 107.4 MPa (recycled low-density polyethylene/SCGs) and 587 MPa (high-density polyethylene/SCGs). Their use with large-format 3D printers was assessed thanks to nonplanar samples with complex overhang geometries, reaching a maximum curvature angle of 32° and fabricating overhangs up to 25° without supports. According to the tests, especially polylactic acid/SCGs, a bio-based compound, and recycled low-density polyethylene/SCGs, a fully recycled material, can be used for large-format 3D printing applications with complex geometries, e.g., furniture, interior, and exhibition design. This work paves the way for new materials for large-format additive manufacturing, reducing the need for 3D printing grade feedstock, cutting costs and consumption from filament processing, and fostering material waste reduction practices. [ABSTRACT FROM AUTHOR]

In this paper, three types of horizontal ground heat exchangers (GHEs) such as U-tube, spiral, and slinky were numerically analyzed to investigate their thermal performance in cooling mode for 7 days of continuous operation with specific boundary conditions where a rectangular trench of 5 m in length, 2 m in width, and 5 m in depth served as the basis for the modeling of each heat exchanger. The pipe material was selected to be high density polyethylene for higher durability and corrosion resistance, as well as the soil and working fluid, which were clay and water. To confirm the accuracy of simulation results and reduce the computational time, a mesh independence test was performed, and simulation models were validated. There were four types of modifications, and in all of the cases, slinky GHE has better thermal performance. For instance, the heat exchange rate per unit trench length of slinky GHE was 20.72 W/m, which is higher than U-tube and spiral tube with a heat exchange rate of 9.75 and 13.62 W/m, which is of maximum 53% and 28% than U tube GHE, respectively, for the same pipe wall thickness and different material volumes of U-tube, spiral, and slinky GHEs. The pressure drop of slinky GHE is also higher (maximum 87% higher than U tube). To balance the heat exchange rate and pressure drop, the thermal performance capability (TPC) was examined. The slinky GHE has the highest thermal performance capability for all the cases. From the energy balance point, the TPC valued a maximum of 1.72 for the same material volume and different pipe wall thickness. The effectiveness was investigated to examine the heat exchange rate with different ground temperatures, and the slinky GHE showed higher effectiveness than spiral and U-tube GHEs. Finally, the thermal performance of slinky horizontal GHE was examined with different trench lengths to investigate the excavation work reduction with reduced trench length. With the decrease in trench length, the heat exchange rate and excavation work also decreased. The heat exchange rate of slinky horizontal GHEs with trench lengths of 1.5 and 1 m remained better than that of spiral and U-tube horizontal GHEs with a trench length of 3.5 m. [ABSTRACT FROM AUTHOR]