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The interpenetrating connection of icosahedra network (ICOIN) was termed as structural skeleton, which could quantify the strength and ductility of MGs. The impact of different rejuvenation methods on medium-range order (MRO) alterations was rarely studied. This work employed molecular dynamics simulations to examine the difference in MRO evolution of metallic glasses treated by recovery annealing and thermal-pressure treatment during uniaxial tension. All of the specimens obtain enhanced ductility due to improved potential energy. During tension, ICOI of all rejuvenated specimens exhibits an increased destruction rate and a decreased transformation rate. However, there are some converse characteristics in the specimens under different rejuvenation methods. The rejuvenated specimens treated by recovery annealing exhibit increased free volume and decreased ICOIN density. After thermal-pressure treatment, the rejuvenated specimens demonstrated decreased free volume and enhanced ICOIN density. During tension, the enhancement of icosahedral free volume in specimens treated by thermal pressure largely decreased the ICOIN density, thereby increasing the ductility. After tension, the rejuvenated specimens under high pressure have a significant reduction in ICOIN density compared to those under recovery annealing. The significance of this work is to accurately regulate the ICOIN density of rejuvenated specimens.

Profound reliance of the building and construction sector on cement exacerbates its immense carbon footprint, accounting for a substantial portion of worldwide emissions. In this paper, we investigate the possibilities of in-situ carbon capture and sequestration to eliminate spatial constraints from a chamber confined curing solution via CO2 and steam integrated 3D concrete printing. The presented technology involves a two-step extrusion-based system that sequesters captured CO2 directly into concrete prior deposition at the nozzle printhead, so as to achieve artificially accelerated carbonation reactions with enhancement of mechanical properties. Accordingly, samples subjected to in-situ CO2 and steam integration showed increases of up to 50.0 % 3D printability, 36.8 % compressive strength, and 45.3 % flexural strength compared to control at its respective curing conditions. The results of said approach demonstrated 38.2 % increase in bulk carbon uptake compared to accelerated carbonation confined curing methods, offering an alternative pathway towards decarbonized construction with 3DCP.

The phytochemical investigation of the methanol extract of the seeds of Magydaris pastinacea afforded two undescribed benzofuran glycosides, furomagydarins A-B (1, 2), together with three known coumarins. The structures of the new isolates were elucidated after extensive 1D and 2D NMR experiments as well as HR MS. Compound 1 was able to inhibit the COX-2 expression in RAW264.7 macrophages exposed to lipopolysaccharide, a pro-inflammatory stimulus. RT-qPCR and luciferase reporter assays suggested that compound 1 reduces COX-2 expression at the transcriptional level. Further studies highlighted the capability of compound 1 to suppress the LPS-induced p38MAPK, JNK, and C/EBPβ phosphorylation, leading to COX-2 down-regulation in RAW264.7 macrophages.

Among reinforcement methods for 3D concrete printing (3DCP) structures, steel cable reinforcement and reinforced concrete confined by 3DCP formwork (RC-3DPF) methods offer high design freedom and automation. However, the former lacks reinforcement in directions perpendicular to the printing direction, and the latter cannot satisfy constructional requirements. This paper proposed a hybrid approach: the steel rebar reinforced concrete column confined by the steel cable reinforced 3DCP permanent formwork (RC-SC-3DPF). Axial compression tests and theoretical analysis were conducted to study axial performances. Test results showed steel cables and fibres added to 3DCP formwork benefit RC-SC-3DPF structural performances. With a steel cable confinement ratio above 0.534%, RC-SC-3DPF outperforms the traditional case. Steel fibre, compared to PVA fibre, demonstrates greater potential for RC-SC-3DPF due to improved axial load resistance and reduced ductility loss. A theoretical model, based on experimental results, existing standards, and M&T model, was developed to effectively evaluate RC-SC-3DPF structural behaviour.

This study explores the innovative use of 3D robotic spray for applying self-sensing cementitious coating, emphasising its potential for multifunctional smart concrete applications. The effects of spray parameters on the performance of self-sensing cementitious composites were investigated by systematically examining the impact of nozzle travel speed, air injection pressure, nozzle standoff distance, and spray direction on the self-sensing coating. In-depth analyses were conducted on mechanical strength, coating adhesion properties, and sensing performance. Micro-CT was performed to investigate the coating's inherent porosity. This study evaluated the sensing performance of the coatings by analysing their piezoresistive behaviour under cyclic compression and bending. Furthermore, it demonstrated the coating's capacity for real-time structural health monitoring by evaluating its performance under compressive and bending stresses until failure. This research underscores the significant impact of spray parameters on optimising the sensing capabilities of the self-sensing spray coating, highlighting its potential for advanced real-time structural health monitoring.

Achieving net carbon neutrality is a global goal toward mitigating climate change presumed consequences. The building and construction sector, responsible for approximately 40 % of greenhouse gas emissions, requires innovative zero-carbon technologies. This paper investigates the synergistic potential of combining 3D concrete printing (3DCP) and carbon capture and sequestration (CCS) to advance net carbon neutrality in construction. By implementing different CO2 spraying regimes, this study demonstrates improved carbon dioxide (CO2) uptake and the crystallinity of precipitated calcium carbonate (CaCO3). The findings indicate that the method's effectiveness heavily relies on appropriate printing parameters and curing conditions. Chamber-cured samples exhibit the highest CO2 uptake but the lowest mechanical strength, while ambient-cured samples show the opposite trend. It is also important to note that the duration of CO2 exposure in this study was relatively short, resulting in limitations in both CO2 uptake and strength gain. Nevertheless, this study highlights the potential of synergistically combining 3DCP and CCS technologies for net carbon neutrality, emphasizing the critical role of the construction sector in achieving global emission reduction targets.

Cementitious materials incorporating recycled crumb rubber have become a common sustainable resolution in diverse building environments to achieve various functions in terms of lightweight, ductility, as well as energy absorption. This study explored the 3D printed rubberised cementitious composites (3DPRC) in two aspects: examining the effects of crumb rubber pretreatment conditions on compressive properties; conducting experimental and numerical analysis on the acoustic dissipation characteristics of 3DPRC. Fine crumb rubber granules (3-5 mm) replaced 10%, 20%, and 30% of river sand in the composites. Uniaxial compression tests indicated that the compressive strength of 3DPRC decreased with the increase of crumb rubber content and introduced anisotropic behaviour. Impedance tube tests were conducted to evaluate the sound absorption and insulation capabilities of 3DPRC. An optimal Noise Reduction Coefficient (NRC) of 0.35 was achieved with 30% crumb rubber. The sound insulation properties depend strongly on the mass density and porosity of the 3DPRC. Additionally, it is proved that the volume of built-in air gap has positive effects on both sound absorption and insulation properties. The results from Finite Element Method (FEM) numerical simulations correlated well with experimental data, proving the efficiency of the simulation and validating the experimental results.

The polarization dependence of directional couplers (DC) formed by silicon-on-insulator (SOI) slot waveguides was studied, and its applications as highly efficient polarization beam splitters (PBSs) and polarization-independent directional couplers (PIDCs) were investigated. The coupling lengths for the quasi-TE and quasi-TM modes may vary with the waveguide geometry due to structural birefringence; thus numerical simulations of the coupling effects in the directional couplers with different aspect ratios and waveguide spacing were conducted to obtain the optimal design parameters for high efficiency as well as compact device size. The lengths of the coupling regions of the designed PBS and PIDC are 47.61 and 23.13 [micro]m, respectively, and they delivered good performance, with an extinction ratio greater than 20 and 1 dB bandwidth larger than 100 nm. The tolerance of fabrication error in the practical device is also discussed. [c] 2010 Optical Society of America OCIS codes: 060.1810, 130.3120, 130.5440.

We show, to the best of our knowledge, the first simulation result of the strong plasmonic field coupling and enhancement at the Ag/Si interface of a silver core/protruded silicon shell nanocylinder by using the finite-element method. The strong plasmon field, with a slow effective phase velocity accumulated at the Ag/Si interface, which results from the large effective index of the surface plasmon due to the nearly identical real parts with opposite signs of the permittivities of silver and silicon at 633 nm, is analyzed. When the silicon shell has shallow protrusions of proper periodicity to meet the phase matching condition between the incident light and the surface plasmon wave at the Ag/Si interface, a higher scattered electric field and a higher sensitivity to the refractive index change of the surrounding medium can be achieved. Furthermore, a feasible implementation of the core-shell nanocylinder design concept is studied and discussed. OCIS codes: 240.6680, 250.5403.

A hexagonal nanostructure formed by seven core shell nanocylinders filled with different dielectric cores is investigated. The surface plasmon resonance in such a hexagonal nanostructure under conditions of different illumination wavelengths, dielectric cores, angles of incidence, and thicknesses of silver shells is studied by use of the finite element method. Simulation results show that the resonant wavelength is redshifted as the dielectric constant and the size of the core increase. The peak resonant wavelength and the local field enhancement are approximately proportional to the radius of the dielectric core. Additionally, the surface plasmon field excited by TM-polarized light at the incident angle of [theta] = 15[degrees] is exactly a linear combination of those excited at incident angles of [theta] = 0[degrees] and 30[degrees], confirming the linear nature of the surface plasmon resonance in a nanostructure formed by linear media. OCIS codes: 240.6680, 250.5403.

Abstract When a transformable B2 precipitate is embedded in an amorphous matrix, it is often experimentally observed that the crystalline-amorphous interface not only serves as an initiation site for the martensitic transformation due to local stress concentrations, but also as an inhibitor to stabilize the transformation, the latter being attributed to the “confinement effect” exerted by the amorphous matrix, according to the Eshelby solution. These two seemingly incongruous factors are examined in this study using molecular dynamics simulations from an atomic interaction perspective. An innate strain gradient in the vicinity of the crystalline-amorphous interface is identified. The actual interface, the compressive/dilatative transition, and the interfacial maximum strain are investigated to differentiate from the conventional “interface” located within a distance of a few nanometers. Our innate interfacial elastic strain field model is applicable for the design of materials with a higher degree of martensitic transformation and controllable stress concentration, even in cryogenic environments.

The advantage of 3DCP technologies is the ability to fabricate free-form structures. However, printing openings in concrete structures are limited by the presence of overhanging sections. While various 3D printing and additive manufacturing technologies have established methods for handling overhangs with temporary supports, many existing techniques for 3D concrete printing still rely on wooden planks and corbelling, which restrict the design flexibility and slope angles. The objective of this study is to develop a removable and sustainable support material with high printability performance. This support material serves as temporary support for overhang sections in 3D-printed structures and can be removed once the primary concrete has hardened sufficiently. This study observed that increasing the recycled glass content in the mixture raises both the dynamic and static yield stresses, with only mixtures containing up to 60% recycled glass remaining pumpable. Optimization of the mixture design aimed to balance high flowability and buildability, and the results indicated that a mixture with 60% recycled glass content is optimal. The effectiveness of the optimized support material was validated through the successful printing of a structure featuring a free-form opening and overhang section.

This article identifies key features of the strategy concept as a basis for reviewing existing theories of strategy. It also provides an agenda for future research. The article argues that there is a decision hierarchy in a firm, and defines strategy as the highest-level decision in the hierarchy. Consequently, strategy has to exhibit what may be called three features of dominance: vertical dominance, horizontal dominance, and dynamic dominance. A vertically dominant strategy is one that determines, directly or indirectly, other decisions of a firm. A horizontally dominant strategy seeks to optimize the value of the firm according to some criteria. Dynamic dominance implies that strategy should affect the subsequent decisions of a firm over a relevant period of time. With few exceptions, existing theories of strategy are issue-oriented and focus largely on horizontal dominance. More research should, therefore, be directed towards vertical and dynamic dominance criteria. If a comprehensive theory of strategy which satisfies the three dominance features cannot be developed, it is suggested that development should be directed towards integrating behavioural and economic approaches. (Reprinted by permission of the publisher.)

A study was done to analyze joint ventures of multinational corporations when they serve a host market. Models were constructed to evaluate the effects of profit sharing, cost reductions, risk reductions and competition reductions on the profits from such ventures. The models show that multinational corporations from joint ventures when there is strong competition and operational risks are present. The level of significant costs determine the choice between mutinational corporations and subsidiaries. Finally, multiple licensing is done when there are many local companies.

Any technological innovation changes the economic market and consequently, firm competition. Optimal timing should be considered before firms react to technological change because it may have adverse effects in the long run. Continuous technological improvement creates and changes asymmetry between firms. Strategy planners should weigh the advantages and disadvantages of technological investments in choosing whether to replace or retain existing technology.

ABSTRACTAs global CO2 concentrations rise, there is a pressing need for sustainable alternatives in the construction sector as many countries are striving to attain net carbon neutrality. Integrating carbon capture and sequestration (CCS) technologies directly into 3D concrete printing offer a promising solution to reduce the carbon footprint in the construction sector. This paper investigates a novel printing technique involving the purging of pressurised CO2 gas was demonstrated and the various process parameters were evaluated for its effectiveness in promoting carbon sequestration. Results show that the carbon-sequestrated sample has a 15% increase in carbon uptake as compared to the control sample. The method can be complementary to existing sequestration technologies, facilitating large-scale carbon sequestration without chamber size limitations. Nevertheless, further research and development are necessary to optimise the various printing parameters and achieve a more balanced and efficient integration of carbon capture and sequestration technologies with 3DCP.

Abstract Background Aging degrades the balance and locomotion ability due to frailty and pathological conditions. This demands balance rehabilitation and assistive technologies that help the affected population to regain mobility, independence, and improve their quality of life. While many overground gait rehabilitation and assistive robots exist in the market, none are designed to be used at home or in community settings. Methods A device named Mobile Robotic Balance Assistant (MRBA) is developed to address this problem. MRBA is a hybrid of a gait assistive robot and a powered wheelchair. When the user is walking around performing activities of daily living, the robot follows the person and provides support at the pelvic area in case of loss of balance. It can also be transformed into a wheelchair if the user wants to sit down or commute. To achieve instability detection, sensory data from the robot are compared with a predefined threshold; a fall is identified if the value exceeds the threshold. The experiments involve both healthy young subjects and an individual with spinal cord injury (SCI). Spatial Parametric Mapping is used to assess the effect of the robot on lower limb joint kinematics during walking. The instability detection algorithm is evaluated by calculating the sensitivity and specificity in identifying normal walking and simulated falls. Results When walking with MRBA, the healthy subjects have a lower speed, smaller step length and longer step time. The SCI subject experiences similar changes as well as a decrease in step width that indicates better stability. Both groups of subjects have reduced joint range of motion. By comparing the force sensor measurement with a calibrated threshold, the instability detection algorithm can identify more than 93% of self-induced falls with a false alarm rate of 0%. Conclusions While there is still room for improvement in the robot compliance and the instability identification, the study demonstrates the first step in bringing gait assistive technologies into homes. We hope that the robot can encourage the balance-impaired population to engage in more activities of daily living to improve their quality of life. Future research includes recruiting more subjects with balance difficulty to further refine the device functionalities.