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The Groundwater Ubiquity Score (GUS) is widely used to indicate the relative leachability of pesticides based on the soil half-life and the adsorption partition coefficient. In this manuscript, we derive mathematically the Theoretical Groundwater Ubiquity Score (TGUS) that, based on considerations of the preferential movement of pesticides to groundwater and a first-order pesticide degradation model, leads to a similar function as the GUS model. In the preferential flow model, movement to groundwater is fast, and the adsorption partition coefficient is thus not used for calculating the travel time to the groundwater (as it is in the advective-dispersive equation) but rather only determines the distribution of the pesticide between the water and soil phases. Both the GUS and TGUS models well predict the groundwater contamination of the originally studied pesticides for rainfall event(s) that caused pesticide leaching from 30 days after application. The theoretically derived Groundwater Ubiquity Score (TGUS) shows, in accordance with experimental evidence, that for leaching events shortly after spraying, the mass lost to (and resulting concentration in) groundwater is inversely related to the adsorption partition coefficient and not necessarily to the GUS index.

The highlands serve as water towers for the blue water in the surrounding area, with often insufficient rainfall for rainfed crops. The population is growing in the highlands, changing the hydrology and blue and green water availability. One of the changes that affect the highlands of Ethiopia is the rapidly expanding areas of small patches of eucalyptus on farmers fields. This manuscript aims to sort through the limited available literature and develop a water balance model as a starting point to discuss how hydrology is affected by increased acreage of eucalyptus in the highlands. We find some evidence in the literature that patches of eucalyptus during the dry phase may withdraw water from the subsoil up to twice the rate of evapotranspiration when the soil water is not limited. Since saturation excess generates surface runoff in the subhumid and humid highlands, water withdrawn during the dry phase should be made up before the area with eucalyptus becomes hydraulically active. The amount of water that can be removed from storage by eucalyptus is greater in areas with a long dry monsoon phase than in temperate climates for the same increase in trees. We also found, as expected, that the eucalyptus water balance model, as developed in this paper, was not valid for areas in semi-arid and arid regions. Soil crusting and water repellency might induce infiltration excess runoff. A tentative implication is that since most blue water is produced in the areas with the highest rainfall, eucalyptus in subhumid and humid monsoon regions will affect the blue water supply downstream but not the plant available green water although shading will decrease yield in the immediate surroundings of the eucalyptus trees.

Finding effective ecosystem services (ESS) management practices to counteract land degradation and poverty is becoming increasingly urgent in the Ethiopian highlands, where livelihood security is strongly dependent on local ESS, particularly those provided by water and soil. In this paper, we test the effects of widely implemented soil and water conservation (SWC) interventions on storm flow and sediment concentration in the Debre Mawi watershed (representative of watersheds in the upper Blue Nile basin and Ethiopian highlands). The SWC interventions were tested with a Parameter Efficient Distributed (PED) model. The PED model simulates saturation excess runoff from degraded and saturated valley bottoms, and base and interflow from hillsides. The model was calibrated with observed runoff and sediment data in a 95-ha subcatchment. We found that the PED model simulated the discharge and soil loss well by decreasing the proportion of degraded lands due to installing SWC practices. The results show that four years after the implementation of SWC practices, the infiltration of rainwater was improved in 53% of the degraded lands. Thus, installing SWC practices on hillsides where infiltration is limited is most beneficial and will result in greater water availability during the dry phase, especially in locations where volcanic dikes block the lateral flow. [ABSTRACT FROM AUTHOR]

Effective watershed planning requires an understanding of the hydrology. In the humid tropical monsoon climates and especially in volcanic highland regions such as the Ethiopian Highlands, the understanding of watershed processes is incomplete. The objective is to better understand the hydrology of the volcanic regions in the humid highlands by linking the hillslope processes with the discharge at the outlet. The Ene-Chilala watershed was selected for this study. The infiltration rate, piezometric water levels and discharge from two nested sub watersheds and at the watershed outlet were measured during a four-year period. Infiltration rates on the hillsides exceeded the rainfall intensity most of the time. The excess rain recharged a perched hillside aquifer. Water flowed through the perched aquifer as interflow to rivers and outlet. In addition, saturation excess overland flow was generated in the valley bottoms. Perched water tables heights were predicted by summing up the recharge over the travel time from the watershed divide. Travel times ranged from a few days for piezometers close to the divide to 40 days near the outlet. River discharge was simulated by adding the interflow from the upland to overland flow from the saturated valley bottom lands. Overland flow accounted only for one-fourth of the total flow. There was good agreement between predicted and observed discharge during the rain phase therefore the hillslope hydrologically processes were successfully linked with the discharge at the outlet.

Ash plays an important role in controlling runoff and erosion processes after wildfire and has frequently been hypothesised to clog soil pores and reduce infiltration. Yet evidence for clogging is incomplete, as research has focussed on identifying the presence of ash in soil; the actual flow processes remain unknown. We conducted laboratory infiltration experiments coupled with microscope observations in pure sands, saturated hydraulic conductivity analysis, and interaction energy calculations, to test whether ash can clog pores (i.e. block pores such that infiltration is hampered and ponding occurs). Although results confirmed previous observations of ash washing into pores, clogging was not observed in the pure sands tested, nor were conditions found for which this does occur. Clogging by means of strong attachment of ash to sand was deemed unlikely given the negative surface charge of the two materials. Ponding due to washing in of ash was also considered improbable given the high saturated conductivity of pure ash and ash-sand mixtures. This first mechanistic step towards analysing ash transport and attachment processes in field soils therefore suggests that pore clogging by ash is unlikely to occur in sands. Discussion is provided on other mechanisms by which ash can affect post-fire hydrology. Journal compilation

Hydraulic fracturing is expanding rapidly in the US to meet increasing energy demand and requires high volumes of hydrofracking fluid to displace natural gas from shale. Accidental spills and deliberate land application of hydrofracking fluids, which return to the surface during hydrofracking, are common causes of environmental contamination. Since the chemistry of hydrofracking fluids favors transport of colloids and mineral particles through rock cracks, it may also facilitate transport of in situ colloids and associated pollutants in unsaturated soils. We investigated this by subsequently injecting deionized water and flowback fluid at increasing flow rates into unsaturated sand columns containing colloids. Colloid retention and mobilization was measured in the column effluent and visualized in situ with bright field microscopy. While

The prediction of colloid transport in unsaturated porous media in the presence of large energy barrier is hampered by scant information of the proportional retention by straining and attractive interactions at surface energy minima. This study aims to fill this gap by performing saturated and unsaturated column experiments in which colloid pulses were added at various ionic strengths (ISs) from 0.1 to 50 mM. Subsequent flushing with deionized water released colloids held at the secondary minimum. Next, destruction of the column freed colloids held by straining. Colloids not recovered at the end of the experiment were quantified as retained at the primary minimum. Results showed that net colloid retention increased with IS and was independent of saturation degree under identical IS and Darcian velocity. Attachment rates were greater in unsaturated columns, despite an over 3-fold increase in pore water velocity relative to saturated columns, because additional retention at the readily available air-associated interfaces (e.g., the air-water-solid [AWS] interfaces) is highly efficient. Complementary visual data showed heavy retention at the AWS interfaces. Retention by secondary minima ranged between 8% and 46% as IS increased, and was greater for saturated conditions. Straining accounted for an average of 57% of the retained colloids with insignificant differences among the treatments. Finally, retention by primary minima ranged between 14% and 35% with increasing IS, and was greater for unsaturated conditions due to capillary pinning.

In the northeastern United States (U.S.), watersheds and ecosystems are impacted by nonpoint source pollution (NPS) from agricultural activity. Where agricultural fields coincide with runoff-producing areas-so called hydrologically sensitive areas (HSA)-there is a potential risk of NPS contaminant transport to streams during rainfall events. Although improvements have been made, water management practices implemented to reduce NPS pollution generally do not account for the highly variable, spatiotemporal dynamics of HSAs and the associated dynamics in NPS pollution risks. This paper presents a prototype for a web-based HSA prediction tool developed for the Salmon Creek watershed in upstate New York to assist producers and planners in quickly identifying areas at high risk of generating storm runoff. These predictions can be used to prioritize potentially polluting activities to parts of the landscape with low risks of generating storm runoff. The tool uses real-time measured data and 24-48 h weather forecasts so that locations and the timing of storm runoff generation are accurately predicted based o present-day and future moisture conditions. Analysis of HSA predictions in Salmon Creek show that 71% of the largest storm events between 2006 and 2009 were correctly predicted based on 48 h forecasted weather data. Real-time forecast of HSAs represents an important paradigm shift for the management of NPS in the northeastern U.S. © 2013 by the authors.

Soil erosion decreases soil fertility of the uplands and causes siltation of lakes and reservoirs; the lakes and reservoirs in tropical monsoonal African highlands are especially affected by sedimentation. Efforts in reducing loads by designing management practices are hampered by lack of quantitative data on the relationship of erosion in the watersheds and sediment accumulation on flood plains, lakes and reservoirs. The objective of this study is to develop a prototype quantitative method for estimating sediment budget for tropical monsoon lakes with limited observational data. Four watersheds in the Lake Tana basin were selected for this study. The Parameter Efficient Distributed (PED) model that has shown to perform well in the Ethiopian highlands is used to overcome the data limitations and recreate the missing sediment fluxes. PED model parameters are calibrated using daily discharge data and the occasionally collected sediment concentration when establishing the sediment rating curves for the major rivers. The calibrated model parameters are then used to predict the sediment budget for the 1994-2009 period. Sediment retained in the lake is determined from two bathymetric surveys taken 20 years apart whereas the sediment leaving the lake is calculated based on measured discharge and observed sediment concentrations. Results show that annually on average 34 t/ha/year of sediment is removed from the gauged part of the Lake Tana watersheds. Depending on the up-scaling method from the gauged to the ungauged part, 21 to 32 t/ha/year (equivalent to 24-38 Mt/year) is transported from the upland watersheds of which 46% to 65% is retained in the flood plains and 93% to 96% is trapped on the flood plains and in the lake. Thus, only 4-7% of all sediment produced in the watersheds leaves the Lake Tana Basin.

The absence of a basin-wide apportionment agreement on using the Nile River equitably has been a long-standing source of disagreement among Nile riparian states. This study introduces a new approach that the riparian states can consider that quantifies the Nile River's apportionment. The approach includes (1) developing a basin-wide database of indicators representative of the United Nations Watercourse Convention (UNWC) relevant factors and circumstances, (2) developing an ensemble of indicator weighting scenarios using various weighting methods, and (3) developing six water-sharing methods to obtain a range of apportionments for Egypt, Sudan, Ethiopia and the group of the White Nile Equatorial States for each weighting scenarios. The results illustrate a relatively narrow range of country-level water apportionments, even though some individual factor weights vary from 3% to 26%. Considering the entire Nile River, the water apportionment for Ethiopia ranges from 32% to 38%, Sudan and South Sudan from 25% to 33%, Egypt from 26% to 35%, and the Equatorial States from 5% to 7%. We trust that the six proposed equitable water-sharing methods may aid in fostering basin-wide negotiations toward a mutual agreement and address the dispute over water sharing. [ABSTRACT FROM AUTHOR]

Drainage of paved and unpaved roads has been implicated as a major contributor of overland flow and erosion in mountainous landscapes. Despite this, few watershed models include or have tested for the effect roads have on discharge and sediment loads. Though having a model is an important step, its proper application and attention to distinct landscape features is even more important. This study focuses on developing a module for drainage from a road and tests it on a nested watershed (Shanko Bahir) within a larger previously studied site (Debre Mawi) that receives overland flow contributions from a highly compacted layer of soil on an unpaved road surface. Shanko Bahir experiences a sub-humid monsoonal climate and was assessed for the rainy seasons of 2010, 2011, and 2012. The model chosen is the Parameter Efficient Distributed (PED) model, previously used where saturation-excess overland flow heavily influences discharge and sediment concentration variation, though infiltration-excess occasionally occurs. Since overland flow on unpaved surfaces emulates Hortonian flow, an adjustment to the PED model (the developed module) advances possible incorporation of both flow regimes. The modification resulted in similar modeling performance as previous studies in the Blue Nile Basin on a daily basis (NSE = 0.67 for discharge and 0.71 for sediment concentrations). Furthermore, the road while occupying a small proportion of the sub-watershed (11%) contributed importantly to the early discharge and sediment transport events demonstrating the effect of roads especially on sediment concentrations. Considerations for the dynamic erodibility of the road improved sediment concentration simulation further (NSE = 0.75). The results show that this PED modeling framework can be adjusted to include unpaved compacted surfaces to give reasonable results, but more work is needed to account for contributions from gullies, which can cause high influxes of sediment.