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Start Over Author "Che, Cheng" Publication Year Range More than 50 years ago
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2. Synthesis and abnormal reactions of a cholestadienyliron tricarbonyl cation

Author

Che-Cheng Huang and Howard Alper

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Addition reaction, Tetrafluoroborate, chemistry, Nucleophile, Organic Chemistry, Materials Chemistry, Cationic polymerization, Organic chemistry, Physical and Theoretical Chemistry, Biochemistry
Abstract

Cholesta-1,3-diene- and cholesta-2,4-dieneiron tricarbonyls each react sluggishly with triphenylmethyl tetrafluoroborate to form the same cationic complex. Treatment of the latter with a variety of nucleophiles results in elimination rather than the normally observed addition reaction.

Published
1973

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