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1. THE REACTION OF DICHLORODIETHOXYSILANE WITH ISOPRENE IN THE PRESENCE OF MAGNESIUM

Author

Daiyo Terunuma, Satoshi Hatta, and Tsunao Araki

Subjects
chemistry.chemical_compound, Chemistry, Magnesium, Yield (chemistry), Sodium, Inorganic chemistry, chemistry.chemical_element, Organic chemistry, General Chemistry, Isoprene
Abstract

Dichlorodiethoxysilane was treated with isoprene in the presence of magnesium in THF. It was found that new silacyclopentene derivatives i.e., 1,1-diethoxy-3-methyl-1-silacyclopentene-3(1), and 2,7-dimethyl-5-silaspiro[4.4]nonadiene-2,7(2), were produced in good yields, while sodium was used instead of magnesium in the reaction 2 was obtained in a low yield.

Published
1974
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