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This paper utilized the hydrothermal method and freeze-drying technology to prepare the macroscopic aerogel structure and powder structure of MOF-808/RGO. Through comparative analysis of aspects such as photocatalytic CO 2 reduction performance, electron transfer efficiency, macroscopic structure, and microstructure, it has been discovered that aerogel structure can provide favorable conditions for mass transfer of CO 2 and water molecules, and light propagation. The introduction of RGO successfully captures electrons and the reduction reaction occurs on the surface of the material. [Display omitted] • Macroscopic aerogel and powder structures of the MOF-808/RGO composite photocatalysts were fabricated separately and used for comparison. • The photocatalytic performance of the MOF-808/RGO macroscopic aerogels in reducing CO 2 to CO was approximately 16 times that of MOF-808 and 12 times that of RGO. • The aerogel structure provides an abundance of pore structures within the material. • The presence of the aerogel structure successfully enhanced the photothermal and photoelectric conversion efficiencies of the composite photocatalysts. Three-dimensional (3D) macroscopic aerogels have emerged as a critical component in the realm of photocatalysis. Maximizing the integration of materials can result in enhanced efficiency and selectivity in photocatalytic processes. In this investigation, we fabricated MOF-808/reduced graphene oxide (RGO) 3D macroscopic aerogel composite materials employing the techniques of hydrothermal synthesis and freeze-drying. The results revealed that the macroscopic aerogel material exhibited the highest performance in CO 2 reduction to CO, particularly when the concentration of RGO was maintained at 5 mg mL−1. In addition, we synthesized powder materials of MR-5 composite photocatalysts and conducted a comparative analysis in terms of photocatalytic CO 2 reduction performance and electron transfer efficiency. The results show that the macroscopic aerogel material boasts a high specific surface area, an abundant internal pore structure, and increased active sites. These attributes collectively enhance light energy utilization, and electron transfer rates, thereby, improving photothermal and photoelectric conversion efficiencies. Furthermore, we conducted in-situ FT-IR measurements and found that the M/R-5 aerogel exhibited the best CO 2 adsorption capacity under a CO 2 flow rate of 10 mL min−1. The density functional theory results demonstrate the correlation between the formation pathway of the product and the charge transfer pathway. This study provides useful ideas for realizing photocatalytic CO 2 reduction of macroscopic aerogel materials in gas–solid reaction mode. [ABSTRACT FROM AUTHOR]

Insufficient active sites at the hydrophilic grassy CuO electrode tend to produce H 2 in electrochemical CO 2 reduction reaction. To enhance the intrinsic catalytic activity, a metal-oxide heterogeneous interface was created via interfacial engineering modulation by loading Pd on CuO. The CuO/Pd electrode exhibited excellent electrochemical CO 2 reduction performance, with 54% Faraday efficiency at −0.65 V for CH 3 OH. [Display omitted] • The active site of the grass-like hydrophilic CuO electrode was verified to be oxide-derived Cu by the transition in wettability. • Pd loading on CuO by interfacial engineering both satisfies the reduction of CuO to Cu and also contributes to the increase of active sites. • The interfacial effect between CuO and Pd appreciably reduces the work function of CuO to promote CO 2 reduction. • The FE of CH 3 OH reach up to 54 % at −0.65 V over CuO/Pd-2. Copper-based catalysts have been extensively investigated in electrochemical carbon dioxide (CO 2) reduction to promote carbon products generated by requiring multiple electron transfer. However, hydrophilic electrodes are unfavourable for CO 2 mass transfer and preferentially hydrogen (H 2) evolution in electrochemical CO 2 reduction. In this paper, a hydrophilic cupric oxide (CuO) electrode with a grassy morphology was prepared. CuO-derived Cu was confirmed as the active site for electrochemical CO 2 reduction through wettability modulation. To enhance the intrinsic catalytic activity, a metal-oxide heterogeneous interface was created by engineering modulation at the interface, involving the loading of palladium (Pd) on CuO (CuO/Pd). Both the electrochemically active area and the electron transfer rate were enhanced by Pd loading, and significantly the reduced work function further facilitated the electron transfer between the electrode surface and the electrolyte. Consequently, the CuO/Pd electrode exhibited excellent excellent performance in electrochemical CO 2 reduction, achieving a 54 % Faraday efficiency at −0.65 V for methanol (CH 3 OH). The metal-oxide interfacial effect potentially improves the intrinsic catalytic activity of hydrophilic CuO electrodes in electrochemical CO 2 reduction, providing a conducive pathway for optimizing hydrophilic oxide electrodes in this process. [ABSTRACT FROM AUTHOR]

[Display omitted] • Co 2 N C with diatomic pair sites was successfully prepared. • Co 2 N C exhibited much faster degradation kinetic rate than Co 1 N C. • More ROS were generated by the catalysis of Co 2 N C. • DFT calculation further revealed the enhanced activity of Co 2 sites. A novel strategy for better catalytic performance in terms of precisely tuning the metal atom number of active centers is gradually getting attention. In this paper, the Co atom pair sites on N -doped porous carbon was engineered. The binuclear Co 2 site structure was identified by aberration-corrected scanning transmission electron microscopy and X-ray absorption spectroscopy. As expected, the Co 2 N C display an outstanding Fenton-like catalysis activity in tetracycline degradation with turnover frequency exceeding 0.91 min−1 that is approximately 4 times higher than the conventional CoN 4 site. The EPR tests indicated that the ROS strength stimulated by the binuclear site was much stronger than that of single site. Theoretical density functional theory calculations reveal that the optimized adsorption configuration is the O1 of peroxymonosulfate (PMS) interacting with two Co atoms, leading to stronger interaction effect and electron transfer for PMS comparing to single atom sites. [ABSTRACT FROM AUTHOR]

[Display omitted] • The adsorption energies of CO 2 on the surface oxygen vacancies of different crystalline In 2 O 3 were calculated using DFT. • The effect of the spatial distributions of two active components on the CO 2 hydrogenation to aromatics was studied. • The acidity of catalyst under different spatial distributions was studied through NH 3 -TPD. In tandem catalysts, not only good synergy between the two active components is required, but also the precise control of the spatial distribution between the two active components of metal oxides and zeolite is crucial for the migration and conversion of reaction intermediates in the direct conversion of CO 2 to hydrocarbons. The correlation between the metal and the acidic site of zeolite has traditionally been simplified as "the closer, the better". However, it should be noted that this principle only holds true for a portion of tandem catalysts. Therefore, this paper studied the effect of different crystalline In 2 O 3 (cubic phase, hexagonal phase, and mixed cubic/hexagonal phase) and sheet HZSM-5 zeolite tandem catalysts on the activity of CO 2 hydrogenation reaction under different spatial distribution. The generalized gradient approximation (GGA) of density functional theory (DFT) were used to simulate the adsorption energy of CO 2 by oxygen vacancy on c-In 2 O 3 (1 1 1) and h-In 2 O 3 (1 0 4) planes, it was found that O v1 on c-In 2 O 3 (1 1 1) and O v4 on h-In 2 O 3 (1 0 4) had the strongest adsorption energy for CO 2. In addition, it has been observed that the proximity of the two active components (e.g., during mortar mixing) results in decreased catalytic performance. This is due to the migration of metal In, which neutralizes the acid sites of zeolites and leads to inefficient conversion of methanol reaction intermediates to aromatics. As a result, CO 2 conversion and aromatic selectivity are decreased. [ABSTRACT FROM AUTHOR]

Carbon dioxide (CO 2) emissions constitute the primary contribution to global climate change. Synthetic CO 2 fixation represents an exceptionally appealing and sustainable method for carbon neutralization. Unlike the limitations of chemical catalysis, biological CO 2 fixation displays high selectivity and the ability to operate under mild conditions. The superfamily of amidohydrolases has demonstrated the ability to synthesize a range of aromatic monocarboxylic acids. However, there is a scarcity of reported carboxylases capable of synthesizing aromatic dicarboxylic acids. Among these, 4-hydroxyisophthalic acid holds significant potential for applications across various fields, yet no enzyme has been reported for its synthesis. In this study, we developed for the first time that exhibits starting activity in fixing CO 2 to synthesize 4-hydroxyisophthalic acid. Furthermore, we have devised a computational strategy that effectively enhances the catalytic activity of this enzyme. A focused library comprising only 13 variants was generated. Experimental validation confirmed a threefold improvement in the carboxylation activity of the optimal variant (L47M). The computational enzyme design strategy proposed in this paper demonstrates broad applicability in developing carboxylases for synthesizing other aromatic dicarboxylic acids. This lays the groundwork for leveraging biocatalysis in industrial synthesis for CO 2 fixation. • Demonstration that carboxylase can synthesize aromatic dicarboxylic acid by fixing CO 2. • 5-Carboxyvanillate carboxylase was found to catalyze the synthesis of 4-HIPA. • Develop an enzyme design strategy combing energy optimization and MD simulation. • The designed variant exhibited a 3-fold increase in carboxylation activity. [ABSTRACT FROM AUTHOR]

In this paper, we propose a multi-RREH (Remote Renewable Energy Hub) based optimization framework. This framework allows a valorization of CO 2 using carbon capture technologies. This valorization is grounded on the idea that CO 2 gathered from the atmosphere or post combustion can be combined with hydrogen to produce synthetic methane. The hydrogen is obtained from water electrolysis using renewable energy. Such renewable energy is generated in RREH, which are locations where RE is cheap and abundant (e.g., solar PV in the Sahara Desert, or wind in Greenland). We instantiate our framework on a case study focusing on Belgium and 2 RREH, and we conduct a techno-economic analysis under uncertainty. This analysis highlights, among others, the interest in capturing CO 2 via Post Combustion Carbon Capture (PCCC) rather than only through Direct Air Capture (DAC) for methane synthesis in RREH. By doing so, a notable reduction of 10% is observed in the total cost of the system under our reference scenario. In addition, we use our framework to derive a carbon price threshold above which carbon capture technologies may start playing a pivotal role in the decarbonation process of our industries. • We demonstrate PCCC technology potential for reducing RREH's CH4 production cost. • We derive a carbon price threshold for crucial industrial decarbonization. • An uncertainty analysis has been carried out on the reference scenario. [ABSTRACT FROM AUTHOR]

Exploring whether informal environmental regulations (INER) can achieve carbon reduction in the context of pollution reduction and carbon reduction, as well as how to achieve carbon reduction, can help solve the dual failures of the market and government in environmental protection. Based on the polycentric governance theory and considering the characteristics of social subject environmental participation, the Stackelberg game is used to demonstrate the impact mechanism of INER on CO 2. In addition, using the panel data of China's 30 provinces from 2003 to 2018, this paper validates the effectiveness of INER by Pooled Ordinary Least Square (POLS) and threshold panel model. Then, the mediating effect model is used to test the mechanism of INER's effect on carbon reduction. The results show that corruption is not conducive to CO 2 reduction. The reduction effect of INER on CO 2 exhibits heterogeneity with changes in other non-greenhouse gas pollutants. While INER effectively reduces local corruption, its more substantial indirect impact on CO 2 reduction is prominent when levels of other pollutants are lower. Comparative analysis reveals that there are still biased governance behaviors to cope with INER's pressure in some regions nowadays. The findings show that for countries facing the dual task of pollution control and carbon reduction, the key to leveraging the supervisory role of INER should be focused on mitigating information asymmetry caused by the characteristics of CO 2. Therefore, in the process of environmental protection, the public environmental participation system should be improved, and the process of disclosing polluters' carbon information should be accelerated. • Polluters may adopt strategic carbon reduction behaviors. • Other pollutants influence the impact of INER on CO 2. • When other pollutants are low, INER significantly reduce CO 2 by constraining corruption. • Some regions still have biased governance behaviors to cope with INER's pressure. [ABSTRACT FROM AUTHOR]

The present paper compared, through life cycle assessment (LCA), the production of aviation biofuel from two hydrothermal routes of microalgae cultivated in wastewater. Hydrothermal liquefaction (HTL) and gasification followed by Fischer-Tropsch synthesis (G + FT) were compared. Both routes included biomass production, hydrotreatment for biofuel upgrading, and product fractionation. Secondary data obtained from the literature were used for the cradle-to-gate LCA. G + FT had a higher impact than HTL in the 18 impact categories assessed, with human carcinogenic toxicity exerting the most harmful pressure on the environment. The catalysts were the inputs that caused the most adverse emissions. The solvent used for bio-oil separation also stood out in terms of impacts. In HTL, emissions for global warming were −51.6 g CO 2 eq/MJ, while in G + FT, they were 250 g CO 2 eq/MJ. At the Endpoint level, HTL resulted in benefits to human health and ecosystems, while G + FT caused environmental damage in these two categories, as well as in the resources category. In the improvement scenarios, besides considering solid, aqueous, and gaseous products as co-products rather than just as waste/emissions, a 20% reduction in catalyst consumption and 90% recovery were applied. Thus, in HTL, 39.47 kg CO 2 eq was avoided, compared to 35.44 kg CO 2 eq in the base scenario. In G + FT, emissions decreased from 147.55 kg CO 2 eq to the capture of 8.60 kg CO 2 eq. [Display omitted] • Gasification + Fischer-Tropsch caused more impacts than liquefaction. • The environment has suffered more harmful pressure on human carcinogenic toxicity. • The catalysts used were the inputs that most caused adverse emissions. • Liquefaction route captured 39.47 kg CO 2 eq with improvement scenario. • Gasification + Fischer-Tropsch captured 8.6 kg CO 2 eq with the improvement scenario. [ABSTRACT FROM AUTHOR]

Rapid economic growth and human activities have seriously damaged the environment and hindered the achievement of Sustainable Development Goals (SDGs). Hence, this study aims to explore the impact of economic complexity, uncertainty, and remittance on environmental degradation in 134 countries from 2000 to 2022. In addition, it examines whether uncertainty moderates the relationship between remittance and environmental degradation. Two proxies (ecological footprint and CO 2) were used to measure environmental degradation. The analysis was conducted using a cross-sectional dependency test, second-generation unit root test, and panel quantile regression. The results revealed that economic complexity significantly and positively impacted environmental degradation, while uncertainty and remittance significantly and negatively impacted environmental degradation. Furthermore, uncertainty weakened the negative relationship between remittance and environmental degradation. Accordingly, this paper discusses various recommendations and policy implications regarding economic complexity, uncertainty, remittance, and environmental degradation. • We examined the impact of economic complexity, uncertainty, and remittance on environmental degradation in 134 countries. • Ecological footprint and CO 2 were used to measure environmental degradation. • Economic complexity significantly and positively impacted environmental degradation. • Uncertainty and remittance significantly and negatively impacted environmental degradation. [ABSTRACT FROM AUTHOR]

The dwarf planets Sedna, Gonggong, and Quaoar are interesting in being somewhat smaller than the methane-rich bodies of the Kuiper Belt (Pluto, Eris, Makemake), yet large enough to be spherical and to have possibly undergone interior melting and differentiation. They also reside on very different orbits, making them an ideal suite of bodies for untangling effects of size and orbit on present day surface composition. We observed Sedna, Gonggong, and Quaoar with the NIRSpec instrument on the James Webb Space Telescope (JWST). All three bodies were observed in the low-resolution prism mode at wavelengths spanning 0.7 to 5.2 μm. Quaoar was additionally observed at 10× higher spectral resolution from 0.97 to 3.16 μm using medium-resolution gratings. Sedna's spectrum shows a large number of absorption features due to ethane (C 2 H 6), as well as acetylene (C 2 H 2), ethylene (C 2 H 4), H 2 O, and possibly CO 2. Gonggong's spectrum also shows several, but fewer and weaker, ethane features, along with stronger and cleaner H 2 O features and CO 2 complexed with other molecules. Quaoar's prism spectrum shows even fewer and weaker ethane features, the deepest and cleanest H 2 O features, a feature at 3.2 μm possibly due to HCN, and CO 2 ice. The higher-resolution medium grating spectrum of Quaoar reveals several overtone and combination bands of ethane and methane (CH 4). Spectra of all three objects show steep red spectral slopes and strong, broad absorptions between 2.7 and 3.6 μm indicative of complex organic molecules. The suite of light hydrocarbons and complex organic molecules are interpreted as the products of irradiation of methane. We infer that the differences in apparent abundances of irradiation products among these three similarly-sized bodies are likely due to their distinctive orbits, which lead to different timescales of methane retention and to different charged particle irradiation environments. In all cases, however, the continued presence of light hydrocarbons implies a resupply of methane to the surface. We suggest that these three bodies have undergone internal melting and geochemical evolution similar to the larger dwarf planets and distinct from all smaller KBOs. The feature identification presented in this paper is the first step of analysis, and additional insight into the relative abundances and mixing states of materials on these surfaces will come from future spectral modeling of these data. • New JWST NIRSpec infrared spectral observations of Sedna, Gonggong, and Quaoar. • Absorptions due to C 2 H 6 , C 2 H 2 , and C 2 H 4 indicate active irradiation chemistry. • Differences among the three bodies are likely due to different orbits. • The spectra are distinct from those of smaller KBOs. • These bodies may have undergone internal melting and geochemical evolution. [ABSTRACT FROM AUTHOR]

Livestock is one of major sources of greenhouse gas (GHG) emissions in China. Clarifying spatiotemporal characteristics of GHG emissions from livestock and exploring influencing factors can provide reference for grasping regional changes of GHG emission and formulate strategies of carbon reduction for livestock industry. However, existing literatures considered both spatial and temporal impacts and dynamic evolution trend of these factors seldomly. This paper used the life cycle assessment (LCA) method to estimate GHG emissions of livestock in 114 cities of the YRB from 2000 to 2021. On this basis, spatiotemporal heterogeneity of influencing factors was analyzed by using geographically and temporally weighted regression (GTWR) model. Finally, future evolution trend of GHG emissions from livestock was predicted by combining traditional and spatial Markov chain. Four main results were listed as follows. Firstly, GHG emission in the life cycle of livestock industry increased from 57.202 million tons (Mt) carbon dioxide equivalent (CO 2 e) in 2000 to 77.568 Mt CO 2 e in 2021. Secondly, structure of livestock industry, labor flow and mechanization were vital factors that led to increase of GHG emissions from livestock. Positive effects of labor flow and mechanization were increasing year by year, while negative effect of urbanization and positive effect of economic development were decreasing year by year. Markov chain analysis shown that probability of keeping high level of GHG emissions of livestock in the YRB unchanged were 96% (T = 1) and 90% (T = 5), and there also existed a Matthew effect. In addition, probability of level transfer of GHG emission in urban livestock was spatially dependent. Government should formulate strategies for livestock development and optimize low-carbon transformation of energy structure for livestock and poultry husbandry based on local conditions and key driving factors in the future. Meanwhile, boundaries of administrative divisions should be broken to promote reduction of GHG emissions in livestock comprehensively. • GHG emissions from livestock in cities of the YRB continued to rise from 2000 to 2021. • GHG emissions per unit of GDP of livestock shown a downward trend. • Analyzing parameter of factors from spatiotemporal aspect by using GTWR model. • Probability of GHG emission transfer in urban livestock was spatially dependent. [ABSTRACT FROM AUTHOR]

Onsite sanitation systems (OSS) are significant sources of greenhouse gases (GHG) including carbon dioxide (CO 2), methane (CH 4) and nitrous oxide (N 2 O). While a handful of studies have been conducted on GHG emissions from OSS, systematic evaluation of literature on this subject is limited. Our systematic review and meta-analysis provides state-of-the- art information on GHG emissions from OSS and identifies novel areas for investigation. The paper analyzes GHG emission rates from different OSS, the influence of various design, operational, and environmental factors on emission rates and proffers mitigation measures. Following the Preferred Reporting Items for Systematic reviews and Meta-analysis (PRISMA) guidelines, we identified 16 articles which quantified GHG emissions from OSS. Septic tanks emit substantial amounts of CO 2 and CH 4 ranging from 1.74 to 398.30 g CO 2 /cap/day and 0.06–110.13 g CH 4 /cap/day, respectively, but have low N 2 O emissions (0.01–0.06 g N₂O/cap/day). CH 4 emissions from pit latrines range from 0.77 to 20.30 g CH 4 /cap/day N 2 O emissions range from 0.76 to 1.20 gN 2 O/cap/day. We observed statistically significant correlations (p < 0.05) between temperature, biochemical oxygen demand, chemical oxygen demand, dissolved oxygen, storage period, and GHG emissions from OSS. However, no significant correlation (p > 0.05) was observed between soil volumetric water content and CO 2 emissions. CH 4 emissions (expressed as CO 2 equivalents) from OSS estimated following Intergovernmental Panel for Climate Change (IPCC) guidelines were found to be seven times lower (90.99 g CO 2 e/cap/day) than in-situ field emission measurements (704.7 g CO 2 e/cap/day), implying that relying solely on IPCC guidelines may lead to underestimation of GHG emission from OSS. Our findings underscore the importance of considering local contexts and environmental factors when estimating GHG emissions from OSS. Plausible mitigation measures for GHG emissions from OSS include converting waste to biogas in anaerobic systems (e.g. biogas), applying biochar, and implementing mitigation policies that equally address inequalities in sanitation service access. Future research on GHG from OSS should focus on in-situ measurements of GHGs from pit latrines and other common OSS in developing countries, understanding the fate and transport of dissolved organics like CH 4 in OSS effluents and impacts of microbial communities in OSS on GHG emissions. Addressing these gaps will enable more holistic and effective management of GHG emissions from OSS. [Display omitted] • Onsite sanitation systems (OSS) are major sources of greenhouse gas (GHG) emission in the environment • Emissions from septic systems vary between 1.74 and 398.30 g/cap/day for CO 2 , and 0.06 and 110.13 g/cap/day for CH 4. • CH 4 emissions from OSS estimated following IPCC guidelines are seven times lower than field-measured emissions. • Local contexts and environmental factors should be considered when assessing GHG emissions from OSS. • Future GHG research on OSS should prioritize in-situ measurements of pit latrines and other OSS in developing nations. [ABSTRACT FROM AUTHOR]

The persistent combustion of fossil fuels has resulted in a widespread greenhouse effect attributable to the continual elevation of carbon dioxide (CO 2) levels in the atmosphere. Recent research indicates that utilizing CO 2 as a pyrolysis gasification medium diminishes CO 2 emissions and concurrently augments the value of the resultant pyrolysis gasification products. This paper reviews recent advancements in the pyrolysis gasification of organic solid wastes under a CO 2 atmosphere. Meanwhile, the mechanisms of CO 2 influence in the pyrolysis and gasification processes were also discussed. In comparison to noble gases, CO 2 exhibits reactivity with char at≥710 °C, resulting in additional mass loss of the sample. In addition, CO 2 was able to increase the specific surface area and stability of biochar and reduce biooil toxicity by lowering the content of cyclic compounds in the biooil, while CO 2 was able to react with GPRs with some volatile products (e.g., light hydrocarbons) to increase biogas yield. Finally, CO 2 also prevents catalyst deactivation by reducing secondary coke formation. We also recommend directing future attention toward utilizing unpurified CO 2 in pyrolysis and gasification. This review aims to expand the utilization of CO 2 and advocate for applying pyrolysis gasification products. [Display omitted] • An overview of recent studies on pyrolysis gasification in CO 2 atmosphere. • The effect of CO 2 on the pyrolysis behavior as well as on the catalyst is illustrated. • The mechanism of the effect of CO 2 on pyrolysis products is described in detail. • In the future, CO 2 and waste heat from industrial flue gases should be utilized directly. [ABSTRACT FROM AUTHOR]

Previous experimental work has systematically investigated the radiolytic sulphur chemistry arising as a result of the implantation of reactive sulphur ions into various oxygen-bearing molecular ices (e.g., H 2 O, CO 2) so as to better understand the surface chemistry of the Galilean moons of Jupiter, where sulphur ions are sourced from the giant Jovian magnetosphere. However, significantly less attention has been paid to analogous sulphur chemistry occurring under conditions relevant to the Kuiper Belt, where sulphur ions supplied by the solar wind may implant into the surfaces of icy bodies that are rich in volatile oxygen-bearing molecular ices such as O 2 , CO, or CO 2. This paper presents the results of a study on the implantation of 290–400 keV S+ ions into pure O 2 , CO, and CO 2 ices under temperature, pressure, radiation dose, and ice deposition conditions relevant to the Kuiper Belt, with a particular focus on the potential synthesis of simple inorganic sulphur-bearing molecules (e.g., SO 2 , OCS, CS 2). Experiments involving CO 2 ices were also performed at higher temperatures more typically associated with the Galilean moon system so as to determine whether there exist any differences in the chemistry resulting from the implantation of reactive sulphur ions in these two regions of the Solar System. Our results constitute the first systematic investigation of solid-phase sulphur chemistry in the Kuiper Belt mediated by the sulphur ion component of the solar wind, and thus represent an important step forward in our understanding of the astrochemical processes occurring in the outermost depths of the Solar System. [Display omitted] • S+ ions were implanted into CO, CO 2 , and O 2 ices up to a fluence of 1016 ions cm−2. • S+ ion implantation into O 2 ice yielded SO 2. • No sulphurous molecules were unambiguously detected after implantation into CO ice. • SO 2 was observed after implantation into CO 2 ice at 20 K, but not at 70 K. • Other sulphurous species (e.g., OCS, CS 2) were not observed after ion implantation. [ABSTRACT FROM AUTHOR]

[Display omitted] • Atomically dispersed Ru/Mg-CeO 2 catalyst was prepared and possessed excellent catalytic performance for photo-thermal catalytic CO 2 methanation reaction. • The photo-electron excitation/migration path and the surface structure changes induced by light were systematically characterized by operando experiments. • All potential micro-reaction steps and light intensification steps were determined by in situ DRIFTs experiments. • The reversible dynamic structural evolution between Ru-O-Ce structure and Ru-O v -Ce structure could be induced by light. It is a promising green technology to reduce CO 2 to CH 4 by using renewable solar energy driving photo-thermal catalysis route. However, the efficiency of photo-thermal catalytic CO2 methanation remained to be improved, and the mechanism of this reaction still required further investigation. In this paper, a Ru/Mg-CeO 2 catalyst was designed based on the concepts of single atom catalyst and photo-thermal catalysis concept. The catalyst achieved the CH 4 formation rate of 469 mmol·gcat−1·h−1 at 400 °C under photo-thermal conditions with good catalytic stability. Besides, the superiority of the single-atom of Ru, Ru-O-Ce structure and doping of alkaline metals in catalytic process was proved by a series of physicochemical and optical characterization, and electron migration direction from Ce and Mg elements to Ru sites through Ru-O-Ce and Ru-O-Mg path under photo-thermal catalysis was determined by ISI-XPS experiment. Finally, the comprehensive reaction mechanism and reversible dynamic structural evolution process between Ru-O-Ce and Ru-O v -Ce structures were investigated by in situ DRIFTs experiments, and the source of the excellent performance and structure-function relationship of the catalyst was explored, which provided the theoretical and practical basis for the development of catalyst and industrial application of the reaction. [ABSTRACT FROM AUTHOR]

By introducing functional groups into the isophthalate ligand to decorate the pore of the MOFs, gas adsorption and separation performance can be tunable. In this paper, two isostructural 2D Co-MOFs, [Co(5-MIA)(bpy)]·H 2 O (1) and [Co(5-EIA)(bpy)]·H 2 O (2) (5-H 2 MIA = 5-methoxyl-isophthalic acid; 5-H 2 EIA = 5-ethyoxyl-isophthalic acid; bpy = 4,4′-bipyridine), with different functionalized pore surfaces and channel sizes were designed and constructed. The structures and performance of the two Co-MOFs were analyzed by SCXRD, PXRD, IR, TGA, and gas sorption (CO 2 , C 2 H 2 , CH 4 , CO, and N 2). Attributed to the methoxyl of isophthalate skeleton, 1a (activated 1) shows enhanced CO 2 uptake over other gases. In spite of decreased pore sizes (3.49 Å) compared with 2a (4.38 Å), the CO 2 uptake of 1a (43.41 cm3 g−1) is larger than that of 2a (22.39 cm3 g−1) at 298 K and 100 kPa. Compound 1 incorporates methoxyl groups into the narrow channel, and exhibits the cooperative effect of CO 2 -preferential due to adsorbent-adsorbate coactions and size sieving. GCMC simulation has been used to explore the adsorption coactions of CO 2 and 1 , and the results confirmed that the methoxyl groups in the channel are the main binding sites of CO 2. At ambient temperature and 100 kPa, the IAST selectivities of CO 2 /C 2 H 2 (1:1), CO 2 /CH 4 (1:1), C 2 H 2 /CH 4 (1:1), CO 2 /CO (1:2) and CO 2 /N 2 (15:85) on 1a were 2.6, 39.3, 13.3, 282 and 1433, respectively. The easy activation and regeneration, excellent thermal and humidity stability, and good reusability, make 1 a hopeful adsorbent for adsorption and separation of CO 2. By introducing functional groups into the isophthalate ligand to decorate the pore of the MOFs, gas adsorption and separation performance can be tunable. Two isostructural 2D Co-MOFs with different functionalized pore surfaces and channel sizes were constructed and show different C 2 H 2 /CH 4 and C 2 H 2 /CO 2 gas separation properties. [Display omitted] • Title compound represent the first example of 3D MOF based on 5-H 2 MIA and bpy. • 1a (activated 1) shows enhanced CO 2 uptake over C 2 H 2 , CH 4 , CO and N 2. • 1a shows an excellent reuse performance. [ABSTRACT FROM AUTHOR]

Reducing the environmental footprint of the global food system significantly depends on shifting to more plant-based diets. However, deep-rooted eating habits and a general lack of awareness about food-related emissions hinder large-scale dietary shifts. Demand-side food policies can accelerate this transition towards plant-based diets. One policy instrument that may increase awareness of diet-related emissions and facilitate climate-friendly food consumption choices is a CO2 food label. The success of such demand-side food policies depends on socio-political and market acceptance. However, there is a lack of empirical evidence regarding the socio-political (i.e., feasibility) and market acceptance (i.e., effectiveness at changing behavioral intentions) of CO2 food labels. We also require more knowledge about the potential spillover effects of CO2 food labels on support for more ambitious demand-side food policies. The paper presents evidence from a survey experiment with a sample of Swiss residents (N = 2372) who were randomly provided with information about an established CO2 food label. The survey experiment was embedded in a cooperation throughout a larger long-term project with the second-largest Swiss retailer, which launched one of the world's first CO2 food labels in 2021. Findings show that providing information on a CO2 food label strengthens individuals' behavioral change intentions and support for a mandatory governmental CO2 food label. However, no spillover effect on support for other food policy instruments is identified, which also means that the study finds no crowding out effect by voluntary CO2 labelling initiatives on the support of governmental food policy measures. The results imply that a CO2 food label enjoys high market and socio-political acceptance. • Information on a CO2 label strengthens attitudes and behavioral change intentions. • Information on a CO2 label strengthens support for mandatory CO2 food labels. • A CO2 label enjoys high market and socio-political acceptance. • There is no spillover effect on the support of other more stringent food policies. [ABSTRACT FROM AUTHOR]

This paper analyses the impact of geopolitical risk on carbon dioxide (CO 2) emissions inequality in the panel dataset of 38 developed and developing economies from 1990 to 2019. At this juncture, the empirical models control for the effects of globalisation, capital-labour ratio, and per capita income on CO 2 emissions inequality. The panel cointegration tests show a significant long-run relationship among the related variables in the empirical models. The panel data regression estimations indicate that geopolitical risk, capital-labour ratio, and per capita income increase CO 2 emissions inequality. However, globalisation negatively affects CO 2 emissions inequality in the panel dataset of 38 developed and developing countries. The pairwise panel heterogeneous causality test results align with these benchmark results and indicate no reverse causality issue. Potential policy implications are also discussed. • Geopolitical risk, capital-labour ratio, and income increase CO 2 emissions inequality. • Globalisation negatively affects CO 2 emissions inequality. • Long-run relationship exists among Geopolitical risk, capital-labour ratio, income, and CO 2 emissions inequality. [ABSTRACT FROM AUTHOR]