Search

The development of nanoribbon-like structures is an effective strategy to harness the potential benefits of graphenic materials due to their excellent electrical properties, advantageous edge sites, rapid electron transport, and large specific area. Herein, parallel and connected magnetic nanostructured nanoribbons are obtained through the synthesis of reduced graphene oxide (rGO) using NiCl2 as a precursor with potential applications in nascent electronic and magnetic devices. Several analytical techniques have been used for the thorough characterization of the modified surfaces. Atomic force microscopy (AFM) shows the characteristic topographical features of the nanoribbons. While X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy provided information on the chemical state of Ni and graphene-like structures, magnetic force microscopy (MFM) and scanning Kelvin probe microscopy (SKPFM) confirmed the preferential concentration of Ni onto rGO nanoribbons. These results indicate that the synthesized material shows 1D ordering of nickel nanoparticles (NiNPs)-decorating tiny rGO flakes into thin threads and the subsequent 2D arrangement of the latter into parallel ribbons following the topography of the HOPG basal plane. [ABSTRACT FROM AUTHOR]

In alignment with the increasing demand for larger storage capacity and longer data retention, the electrical control of magnetic anisotropy has been a research focus in the realm of spintronics. Typically, magnetic anisotropy is determined by grain dimensionality, which is set during the fabrication of magnetic thin films. Despite the intrinsic correlation between magnetic anisotropy and grain dimensionality, there is a lack of experimental evidence for electrically controlling grain dimensionality, thereby impairing the efficiency of magnetic anisotropy modulation. Here, we demonstrate an electric field control of grain dimensionality and prove it as the active mechanism for tuning interfacial magnetism. The reduction in grain dimensionality is associated with a transition from ferromagnetic to superparamagnetic behavior. We achieve a nonvolatile and reversible modulation of the coercivity in both the ferromagnetic and superparamagnetic regimes. Subsequent electrical and elemental analysis confirms the variation in grain dimensionality upon the application of gate voltages, revealing a transition from a multidomain to a single-domain state, accompanied by a reduction in grain dimensionality. Furthermore, we exploit the influence of grain dimensionality on domain wall motion, extending its applicability to multilevel magnetic memory and synaptic devices. Our results provide a strategy for tuning interfacial magnetism through grain size engineering for advancements in high-performance spintronics.

Circulating tumor DNA (ctDNA) detection has been acknowledged as a promising liquid biopsy approach for cancer diagnosis, with various ctDNA assays used for early detection and treatment monitoring. Dispersible magnetic nanoparticle-based electrochemical detection methods have been proposed as promising candidates for ctDNA detection based on the detection performance and features of the platform material. This study proposes a nanoparticle surface-localized genetic amplification approach by integrating Fe 3 O 4 -Au core-shell nanoparticles into polymerase chain reactions (PCR). These highly dispersible and magnetically responsive superparamagnetic nanoparticles act as nano-electrodes that amplify and accumulate target ctDNA in situ on the nanoparticle surface upon PCR amplification. These nanoparticles are subsequently captured and subjected to repetitive electrochemical measurements to induce reconfiguration-mediated signal amplification for ultrasensitive (∼3 aM) and rapid (∼7 min) metastatic breast cancer ctDNA detection in vitro . The detection platform can also detect metastatic biomarkers from in vivo samples, highlighting the potential for clinical applications and further expansion to rapid and ultrasensitive multiplex detection of various cancers.