As a rapidly evolving 2D monolayer material, tungsten tetraboride MBene exhibits innate advantages in electrochemical applications because of its unique graphene-like structure and metallic properties. In this study, we utilized first-principles calculations to identify the potential applications of WB 4 as an anode material in rechargeable alkali-metal-ion batteries. The findings imply that the Li, Na, and K adsorption on the WB 4 surface results in exceptionally high conductivity, and the WB 4 monolayer can effectively adsorb these ions with significant adsorption energies of −2.516 eV, −2.356 eV, and −2.941 eV for Li, Na, and K ions, respectively. The results indicate that WB 4 exhibits excellent stability during lithiation, sodiation, and potassiation. Notably, we propose high storage capacities for LIBs (708mAh/g), SIBs (472mAh/g), and KIBs (177 mAh/g), with maintained structural stability for the adsorption of these metal ions. The measured average open circuit voltages for WB 4 were found to be 0.77 V (Li), 0.73 V (Na), and 0.80 V (K), and metallicity remain good maintained within the entire adsorption process. The calculated migration energy barriers for Li, Na, and K were 0.47 eV,0.21 eV and 0.13 eV respectively. The notable properties of WB 4 make it an advantageous electrode material for alkali-metal ion batteries. [Display omitted] • This research investigates recent advancements in alkali-metal ion batteries, focusing on WB 4. • Key aspects such as metal-ion adsorption, diffusion, storage capacity, and charge/discharge processes are examined. • The material upholds its metallicity consistently throughout the adsorption stages. • WB 4 showed remarkable stability during lithiation, sodiation, and potassiation, highlighting its significant potential for practical use in advanced battery systems. [ABSTRACT FROM AUTHOR]