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This study focuses on the effect of Cu doping on the thermoelectric properties of BiSbTe3 (BST) alloys. Firstly, we successfully prepared high-quality BST alloys using the KCl solvent method and selected the most promising BST(KCl)3.5 sample from them, followed by Cu doping experiments. The experimental results show that Cu doping significantly improves the crystal quality and density of the alloy, thereby increasing the material's mobility and reducing the resistivity, leading to an improvement in the power factor. However, Cu doping also introduces a large number of dislocations and lattice distortions. Additionally, the highly doped samples contain Cu2Te and BST superlattice structures, which further enhance the scattering of heat transfer phonons, significantly reducing the lattice thermal conductivity. In the experiment, Cu-doped samples exhibited extremely low lattice thermal conductivity, as low as 0.32 W m−1 K−1 at 300 K. These improvements in structure and performance have greatly enhanced the thermoelectric efficiency of Cu-doped samples, leading to a significant increase in their ZT values. Particularly, in samples with a Cu doping level of x = 0.01, the maximum ZT value was 1.47 at 400 K, and the average ZT value reached 1.28 in the temperature range of 300 K to 450 K. These findings underscore the wide-ranging application potential of Cu-doped BiSbTe3 alloys in room temperature refrigeration and power generation. The study provides crucial insights into the characteristics of Cu-doped BiSbTe3 alloys, while also contributing to the optimization of thermoelectric material design and the advancement of sustainable energy conversion technologies. [ABSTRACT FROM AUTHOR]