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Premise: The Aptian-Albian (121.4-100.5 Ma) was a greenhouse period with global temperatures estimated as 10-15°C warmer than pre-industrial conditions, so it is surprising that the most reliable CO 2 estimates from this time are <1400 ppm. This low CO 2 during a warm period implies a very high Earth-system sensitivity in the range of 6 to 9°C per CO 2 doubling between the Aptian-Albian and today., Methods: We applied a well-vetted paleo-CO 2 proxy based on leaf gas-exchange principles (Franks model) to two Pseudotorellia species from three stratigraphically similar samples at the Tevshiin Govi lignite mine in central Mongolia (~119.7-100.5 Ma)., Results: Our median estimated CO 2 concentration from the three respective samples was 2132, 2405, and 2770 ppm. The primary reason for the high estimated CO 2 but with relatively large uncertainties is the very low stomatal density in both species, where small variations propagate to large changes in estimated CO 2 . Indeed, we found that at least 15 leaves are required before the aggregate estimated CO 2 approaches that of the full data set., Conclusions: Our three CO 2 estimates all exceeded 2000 ppm, translating to an Earth-system sensitivity (~3-5°C/CO 2 doubling) that is more in keeping with the current understanding of the long-term climate system. Because of our large sample size, the directly measured inputs did not contribute much to the overall uncertainty in estimated CO 2 ; instead, the inferred inputs were responsible for most of the overall uncertainty and thus should be scrutinized for their value choices., (© 2024 Botanical Society of America.)

This paper is intended to summarize the research conducted during the first 2 years of the Dragon 5 project 59,332 (geophysical and atmospheric retrieval from Synthetic Aperture Radar (SAR) data stacks over natural scenarios). Monitoring atmospheric phenomena, encompassing both tropospheric and ionospheric conditions, holds pivotal significance for various scientific and practical applications. In this paper, we present an exploration of advanced techniques for estimating tropospheric and ionospheric phase screens using stacks of Synthetic Aperture Radar (SAR) images. Our study delves into the current state-of-the-art in atmospheric monitoring with a focus on spaceborne SAR systems, shedding light on their evolving capabilities. For tropospheric phase screen estimation, we propose a novel approach that jointly estimates the tropospheric component from all the images. We discuss the methodology in detail, highlighting its ability to recover accurate tropospheric maps. Through a series of quantitative case studies using real Sentinel-1 satellite data, we demonstrate the effectiveness of our technique in capturing tropospheric variability over different geographical regions. Concurrently, we delve into the estimation of ionospheric phase screens utilizing SAR image stacks. The intricacies of ionospheric disturbances pose unique challenges, necessitating specialized techniques. We dissect our approach, showcasing its capacity to mitigate ionospheric noise and recover precise phase information. Real data from the Sentinel-1 satellite are employed to showcase the efficacy of our method, unraveling ionospheric perturbations with improved accuracy. The integration of our techniques, though presented separately for clarity, collectively contributes to a comprehensive framework for atmospheric monitoring. Our findings emphasize the potential of SAR-based approaches in advancing our knowledge of atmospheric processes, thus fostering advancements in weather prediction, geophysics, and environmental management. [ABSTRACT FROM AUTHOR]

This paper reviews how excessive lighting in historical sites can negatively affect the enjoyment of social gatherings. Because light pollution has the potential to affect socialization negatively, we need the appropriate tools to handle these effects. As part of this research, three techniques were used to analyze these effects: a bibliographical examination of relevant concepts, field measurements of illumination levels at historical sites in Cairo, Egypt, as well as questionnaires sent out to users around the world to determine what influences their perceptions of historical sites at night. Based on the results of a systematic review, we developed the concept of toolkits for creating a lively ambiance for evening events. Furthermore, based on the spatial measurements made in the case study, it was determined that the challenge of visual pollution hinders creating a vibrant atmosphere at historical sites. An online survey that investigated the factors influencing the enjoyment of historical sites at night around the world found that positioning the lighting fixtures and illumination is one of the most critical factors. The results of the current study confirm that the urban form of the context provides a pleasant visual and perceptual experience at night as well. The findings of this study have led to three design considerations that can help urban planners and designers when it comes to implementing lighting in public spaces. As a result of these considerations, the historical site in the case study, Al-Hussein Square, Cairo, presents a livelier ambiance at night; hence they can be used by urban designers to enhance the ambiance in similar settings to the present case study. This toolkit provides valuable insights into how local authorities and citizens can work together to reduce lighting pollution by examining the causes of the pollution. [ABSTRACT FROM AUTHOR]

This paper is concerned with exploring legal atmospheres during colonial expansionism and the early period of confederation of British Columbia. By describing the theatrical and performative aspects of legal colonialism, the archival documents from this time represent interesting, yet oft-overlooked, significances that attention to sensory and affective experiences captures. Examining "affective atmospheres" disclosed in such colonial settings reveals ways that the colonial regime promulgated its influence in non-rational, non-legal manners. As well, drawing out the material conditions of topography shows how the environment acts more than just a backdrop for the staging of legal expansionism, as it acts also as a constitutive force in the development of colonial legal arrangements. At the same time, the colonial regime was forgetful of these same contextual, topographical, and atmospheric origins of law insofar as it promulgated myths of the universality, objectivity, and superiority of English law. [ABSTRACT FROM AUTHOR]

In the Earth's atmosphere, greenhouse gases (GHGs) and reactive trace gases are essential components of chemistry–climate interactions. These trace gases are emitted from both natural and anthropogenic sources over terrestrial and marine regions. Air–sea exchange is the dominant process controlling the distribution of several important trace gases over remote marine regions. Although the ocean–atmosphere interface covers ~70% of the Earth's surface, the quantitative air–sea exchange of reactive trace gases is estimated over the limited oceanic regions. The production and air–sea exchange of trace gases are controlled by physical conditions at both sides of the interface and ocean biogeochemistry. The northern Indian Ocean (NIO) experiences strong seasonal monsoon winds and intense tropical cyclones. Consisting of the Arabian Sea and the Bay of Bengal, it is one of the most biologically productive regimes of the world ocean and home to the intense oxygen minimum zone (OMZ) of the Arabian Sea with dissolved oxygen concentrations. Thus, the NIO offers a unique system to investigate the air–sea exchange processes of reactive trace gases. So far, most of the studies of air–sea exchange of trace gases is focused on the Atlantic and Pacific Oceans, while studies over the northern Indian Ocean are very limited and reported mainly for CH4, CO2 and N2O. Although progress has been made in recent years, studies of air–sea exchange of reactive trace gases such as non-methane hydrocarbon (NMHCs), oxygen-, sulfur- and halogen-containing hydrocarbons remain scarce. This paper addresses the current understanding of air–sea exchange processes and fluxes of reactive trace gases, including NMHCs, dimethyl sulfide (DMS), oxygenated volatile organic compounds (OVOCs), halocarbons, carbon monoxide (CO) and ozone (O3) in the northern Indian Ocean. This review summarizes the studies on the air–sea exchange of trace gases over the northern Indian Ocean and common parametrization approaches used to estimate the air–sea flux of gases. Flux range for ethene (3–10.35 µmol m–2 d–1), isoprene (0.215–0.172 µmol m–2 d–1), acetaldehyde (–6.75–11.35 µmol m–2 d–1), acetone (–9–9 µmol m–2 d–1), DMS (0.03–41.4 µmol m–2 d–1) and CO (1.4–5.4 µmol m–2 d–1) over the NIO were summarized from various in-situ and modelling studies. The paper addresses the importance of the northern Indian Ocean apropos the production and exchange of reactive trace gases, the knowledge gaps and the future scientific scope. Additionally, it emphasizes the need for a multidisciplinary study of oceanic reactive trace gas cycling and its impact on regional atmospheric chemistry over the northern Indian Ocean. [ABSTRACT FROM AUTHOR]

A new one‐dimensional variational (1D‐Var) retrieval method for ionospheric GNSS radio occultation (GNSS‐RO) measurements is described. The forward model implicit in the retrieval calculates the bending angles produced by a one‐dimensional ionospheric electron density profile, modeled with multiple "Vary‐Chap" layers. It is demonstrated that gradient based minimization techniques can be applied to this retrieval problem. The use of ionospheric bending angles is discussed. This approach circumvents the need for Differential Code Bias (DCB) estimates when using the measurements. This new, general retrieval method is applicable to both standard GNSS‐RO retrieval problems, and the truncated geometry of EUMETSAT's Metop Second Generation (Metop‐SG), which will provide GNSS‐RO measurements up to about 600 km above the surface. The climatological a priori information used in the 1D‐Var is effectively a starting point for the 1D‐Var minimization, rather than a strong constraint on the final solution. In this paper the approach has been tested with 143 COSMIC‐1 measurements. We find that the method converges in 135 of the cases, but around 25 of those have high "cost at convergence" values. In the companion paper (Elvidge et al., 2023), a full statistical analysis of the method, using over 10,000 COSMIC‐2 measurements, has been made. Plain Language Summary: This paper presents a new way of estimating the density of electrons in the ionosphere—the part of the Earth's atmosphere in which atoms are ionized by radiation from the Sun. Radio signals sent between GNSS navigational satellites and receivers in a low orbit around the Earth are delayed, and their paths are bent, by the presence of electrons in the ionosphere. Previous attempts to use these observations to estimate the electron density have been based on the delay of the signals. The new approach outlined in this paper uses the bending incurred by the radio waves instead. Such "bending angles" have been used to infer some properties of the lower atmosphere for many years, and are widely available. We demonstrate that by extending these measurements to greater heights, they can provide useful information about the ionosphere as well. Key Points: A new method of deriving ionospheric electron densities, using the difference between bending angles at two different frequenciesIt is based on a 1D variational retrieval, the solution of which is the best fit to the a priori background and the observationsThe forward model assumes the ionosphere to consist of several idealized "Vary‐Chap" electron density layers [ABSTRACT FROM AUTHOR]

This paper describes an attempt to use data obtained from sodar (sound detection and ranging) for short-term forecasting of PM 10 concentration levels in Krakow. Krakow is one of the most polluted cities in central Europe (CE) in terms of PM 10 concentration. This is due to the high municipal emissions. Thanks to intensive corrective actions taken by the city authorities, these are being effectively eliminated, but the unfavourable topographic location of the city limits natural ventilation. The article describes all these conditions, focusing on presenting the method of short-term correction of air quality for the time needed to take quick corrective actions by the city authorities in the event of anticipated exceedances of the permissible values. Based on several years of measurements of the physical properties of the atmosphere with sodar, the authors of the paper suggest that sodar data could be considered for operational use to generate short-term predictions. The proposed method is based on the use of the spectrum, i.e. the set of amplitudes of signals returning to the sodar receiver from the reflection of a single-frequency sound transmission and its characteristic properties depending on the physical state of the atmosphere. Similar spectra were parameterised with a single numerical value using statistical methods. It was found that, in some cases preceding high concentrations of PM 10 , the spectral parameters had similar values. This made it possible to develop a forecasting method for such concentrations by using data mining to search for conditions in historical data closest to the state of the atmosphere at the time of forecasting. In this part of the study, data from 2017–2018 were used. In the next step, three methods of using the sodar data developed for PM 10 prediction were proposed, comparing them with the method without sodar use. The study results were tested on independent material using data concerning the episodes of high concentrations of pollutants from October 2021 to March 2022 in Krakow. The findings were considered to be encouraging, also taking into account the speed and low cost of preparing the forecast. [ABSTRACT FROM AUTHOR]

Optical beam propagation through the atmosphere is suffering from turbulence condition and scattering due to the refractive index effects on propagation. In this paper, we study optical beam propagation under the UAE's weather conditions. An outdoor test was carried out to gather the atmosphere parameters (temperature, wind, humidity, and refractive index) and feed them to a beam propagation model. The beam centroid was determined to study and predict the effects on it at different periods of the day. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Remote Sensing is the property of Editorial Office of Journal of Remote Sensing & Science Publishing Co. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Glacial bodies in the Peruvian Andes Mountains store and supply freshwater to hundreds of thousands of people in central Peru. Atmospheric black carbon (BC) is known to accelerate melting of snow and ice, in addition to contributing to air pollution and the health of people. Currently there is limited understanding on the sources and temporal variability of BC in valley and mountain environments in Peru. To address this problem, this study combined surface observations of BC collected during 2022-2023 with WRF model simulations and HYSPLIT trajectories to analyze the dispersion and sources of BC in valley and high elevation environments and the associated local atmospheric circulations. Results show high BC concentrations are associated with the valley-mountain wind system that occurs on both sides of the Huaytapallana mountain range. A pronounced circulation occurs on the western slopes of Huaytapallana when concentrations of BC increase during daylight hours, which transports atmospheric pollutants from cities in the Mantaro River Valley to the Huaytapallana mountain range. Low concentrations of BC are associated with circulations from the east that are channeled by the pronounced ravines of the Andes-Amazon transition. On average, during the season of highest BC concentrations (July-November), the relative contributions of fossil fuels are dominant to biomass burning at the valley observatory and are slightly lower at the Huaytapallana observatory. These results demonstrate the need to promote mitigation actions to reduce emissions of BC and air pollution associated with forest fires and local anthropogenic activity., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:Elver Villalobos Puma reports was provided by National Institute for Research on Glaciers and Mountain Ecosystems. Elver Villalobos-Puma reports a relationship with National Institute for Research on Glaciers and Mountain Ecosystems that includes: employment. Elver Villalobos-Puma has patent pending to Lincensee. co-author previously employed by INAIGEM Company-A.M If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Lake Erhai is a potentially phosphorus (P)-limited lake and its water quality may have been affected by atmospheric P deposition. However, there have been few studies on atmospheric P deposition in this lake. In this study, we established five wet deposition monitoring sites and two dry deposition monitoring sites around Lake Erhai to quantify the wet and dry deposition of total phosphorus (TP), including dissolved inorganic phosphorus (DIP), dissolved organic phosphorus (DOP) and particulate phosphorus (PP) from July 2022 to June 2023. Wet deposition fluxes of P species were collected by automatic rainfall collection instrument, and dry deposition fluxes were estimated using airborne concentration measurements and inferential models. The results reveal that among the different P components, DOP had the highest contribution (50%) to wet TP deposition (average all sites 12.7 ± 0.7 mg P m 2 /yr), followed by PP (40%) and DIP (10%). Similarly, DOP (51%) was the major contributor to dry TP deposition (average two sites 2.4 ± 0.9 mg P m 2 /yr), followed by DIP (35%) and PP (14%). Wet deposition dominated the annual total TP deposition (wet plus dry), accounting for approximately 83%. The key seasons for dry deposition were spring and autumn, which accounted for 64% of the annual total dry TP deposition. In comparison, wet deposition was significantly higher in the summer, accounting for 73% of the annual total wet TP deposition. The results of the potential source contribution function and concentration-weighted trajectories analysis indicate that local source emission and long-range transport from surrounding cities jointly exerted a substantial influence on aerosol P concentrations, particularly in the eastern and northwestern regions of the lake. These findings provide a comprehensive understanding of the different P components in atmospheric deposition, which is beneficial for developing effective strategies to manage the P cycle in Lake Erhai., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Triphenyl phosphate (TPhP) and transition metal elements have been ubiquitously detected in the atmosphere, which can participate in atmospheric chemical reactions and induce damage to human health. Currently the understanding of TPhP degradation, transformation and cytotoxicity on atmospheric particles surface are still limited. Therefore, this study used laboratory simulation methods to investigate the influence of irradiation time, transition metal salts, relative humidity (RH) to TPhP degradation, transformation and relative cytotoxicity. TPhP was coated on particle surfaces of four transition metal salts (MnSO 4 , CuSO 4 , FeSO 4 and Fe 2 (SO 4 ) 3 ) in the experiment. Within 12 h irradiation, the significant TPhP photodegradation can be observed on all particles surface. Among these influence factors, the irradiation and RH were the crucial aspects to TPhP degradation, which primarily affect the OH concentration in the atmosphere. The transition metal elements only exhibited slightly catalytic effect to TPhP degradation. The mechanism study indicated that the major degradation products of TPhP are diphenyl hydrogen phosphate (DPhP) and OH-DPhP, which originated from the phenoxy bond cleavage and hydroxylation of TPhP induced by OH. As for the cytotoxicity to A549 cells, all the transition metal particles coated with TPhP can cause cellular injury, which was chiefly induced by the transition metal salt. The possible cytotoxicity mechanism of these particles to A549 cells can be attributed to the excessive reactive oxygen species (ROS) production. This study may provide a further understanding of TPhP degradation and related cytotoxicity with the coexistent transition metal salts in the atmosphere., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The Earth's atmosphere contains ultrafine particles known as aerosols, which can be either liquid or solid particles suspended in gas. These aerosols originate from both natural sources and human activities, termed primary and secondary sources respectively. They have significant impacts on the environment, particularly when they transform into ultrafine particles or aerosol nanoparticles, due to their extremely fine atomic structure. With this context in mind, this review aims to elucidate the fundamentals of atmospheric-derived aerosol nanoparticles, covering their various sources, impacts, and methods for control and management. Natural sources such as marine, volcanic, dust, and bioaerosols are discussed, along with anthropogenic sources like the combustion of fossil fuels, biomass, and industrial waste. Aerosol nanoparticles can have several detrimental effects on ecosystems, prompting the exploration and analysis of eco-friendly, sustainable technologies for their removal or mitigation.Despite the adverse effects highlighted in the review, attention is also given to the generation of aerosol-derived atmospheric nanoparticles from biomass sources. This finding provides valuable scientific evidence and background for researchers in fields such as epidemiology, aerobiology, and toxicology, particularly concerning atmospheric nanoparticles., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Understanding the transport of 137 Cs emitted during the Fukushima accident is challenging because the critical emissions that produced the high-deposition area are not adequately resolved in existing source terms. This paper presents an objective inverse reconstruction of these emissions by fusing atmospheric concentrations with a-priori emissions extracted from total depositions. This extraction, previously considered impossible for complex real-world accidents, is achieved by identifying the critical temporal formation process of depositions in the high-deposition area and estimating the corresponding emissions by using an atmospheric transport model. The reconstructed source term reveals two emission peaks from 10:00-11:00 and 14:00-15:00 on March 15, which agree with the in situ pressure measurements and accident analysis, suggesting that they came from pressure drops in the primary containment vessels of Units 3 and 2, respectively. This finding explains the environmental observations of spherical 137 Cs particles. The source term also objectively and independently confirms the widely used reverse estimate. The corresponding 137 Cs transport simulations better match the various observations than those produced by other source terms, proving that the two-peak emission creates a high-deposition area. The proposed method outperforms the direct fusion of deposition and atmospheric concentration observations, providing a robust tool for multiobservation fusion.

The interactions of the micro-mechanism of hydroxymethanesulfonic acid (HMSA) with the typical small organic molecule in atmospheric (X = methanol, formaldehyde, formic acid, methyl formate, dimethyl ether, acetone) has been investigated by density functional theory (DFT), quantum theory of atoms in molecules (QTAIM), Generalized Kohn-Sham Enery Decomposition Analysis (GKS-EDA) and the atmospheric clusters dynamic code (ACDC). The results of DFT show that the stable six- to eight-membered ring structures are easily formed in HMSA-X clusters. According to the topological analysis results of the AIM theory and the IRI method, a strong hydrogen bonding interaction is present in the complex. GKS-EDA results show that electrostatic energy is the main contributor to the interaction energy as it accounts for 51 %-55 % of the total attraction energy. The evaporation rates of HMSA-HMSA and HMSA-HCOOH clusters were much lower than those of the other HMSA complexes. In addition, the Gibbs energy of formation (ΔG) of HMSA-X dimers is investigated under atmosphere temperature T = 217-298 K and p = 0.19-1.0 atm, the ΔG decreased with decreasing of the atmosphere temperature and increased with the decrease of atmospheric pressure, indicating that the low temperature and high pressure may significantly facilitate to the formation of dimers., Competing Interests: Declaration of competing interest First of all, thank you very much for your busy schedule to view the submitted manuscripts. I confirm that this manuscript has not been submitted to some other journal. There are no financial conflicts to declare, I guarantee that the above statement is true, and I shall bear corresponding responsibilities arising from any violation of the statement therefrom. All data is provided in full in the results section of this paper. I guarantee that the above statement is true, and I shall bear corresponding responsibilities arising from any violation of the statement therefrom., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Beryllium-7 activity concentrations in the atmosphere and precipitation were continuously measured every day between April 2011 and December 2015 in Dazaifu, western Japan. The measured data were quantitatively analyzed to determine the precipitation-induced variation in 7 Be activity concentrations. The average concentrations on nonprecipitation and precipitation days were 5.5 and 3.8 mBq/m 3 , respectively. This difference of 31% (1.7 mBq/m 3 ) on average, was attributable to the washout effect, which was more significant in the summer. Regarding the association between 7 Be activity concentration and precipitation, the concentration remained at a similar level for the small precipitation amount of <5.0 mm/day and showed a decreasing trend (but was insignificant) for the precipitation of 5.0-10.0 mm/day. A significant decrease in the concentration was observed for ≥10 mm/day. Furthermore, when precipitation occurred on two successive days, the 7 Be activity concentrations on the second day significantly decreased regardless of precipitation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Plutonium, as well as fission products such as 137 Cs, had been released into the earth environment in 1945 after the first atmospheric nuclear explosion of plutonium bomb in the desert of New Mexico (USA, July 16) and later over Nagasaki (August 9), followed then by many other explosions. Thus, plutonium cycling in the atmosphere and ocean has become a major public concern as a result of the radiological and chemical toxicity of plutonium. However, plutonium isotopes and 137 Cs are important transient tracers of biogeochemical and physical processes in the environment, respectively. In this review, we show that both physical and chemical approaches are needed to comprehensively understand the behaviors of plutonium in the atmosphere and ocean. In the atmosphere, plutonium and 137 Cs attach with aerosols; thus, plutonium moves according to physical and chemical processes in connection with aerosols; however, since plutonium is a chemically reactive element, its behavior in an aqueous environment is more complicated, because biogeochemical regulatory factors, in addition to geophysical regulatory factors, must be considered. Meanwhile, 137 Cs is chemically inert in aqueous environments. Therefore, the biogeochemical characteristics of plutonium can be elucidated through a comparison with those of 137 Cs, which show conservative properties and moves according to physical processes. Finally, we suggest that monitoring of both plutonium and 137 Cs can help elucidate geophysical and biogeochemical changes from climate changes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

CH 4 serves as an important greenhouse gas, yet limited knowledge is available in global and regional CH 4 cycling, particularly in widely distributed karst terrain. In this study, we investigated an upland in Puding Karst Ecosystem Research Station, and explored CH 4 concentration and/or flux in atmosphere, soil and cave using a closed static chamber method and an eddy covariance system. Meanwhile, we monitored atmospheric temperature, precipitation, temperature and wind velocity in the cave entrance. The results demonstrated that atmospheric CH 4 and actual soil CH 4 fluxes in the source area of eddy covariance system were -0.19 ± 8.64 nmols -1 m -2 and -0.16 nmols -1 m -2 respectively. The CH 4 concentrations in Shawan Cave exhibited 10 ∼ 100-fold lower than that of the external atmosphere. CH 4 oxidation rate dominated by methane-oxidizing bacteria was 1.98 nmols -1 m -2 in Shawan Cave when it combined with temperature difference between cave and external atmosphere. Therefore, CH 4 sink in global karst subterranean spaces was estimated at 106.2 Tg CH 4 yr -1 . We supplemented an understanding of CH 4 cycling paths and fluxes in karst terrain, as well as CH 4 sinks in karst subterranean space. Further works require to establish a karst ecosystem observation network to conduct long-term integrated studies on CH 4 fluxes regarding atmosphere, soils, plants and caves., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Anthropogenic shifts in seas are reshaping fishing trends, with significant implications for aquatic food sources throughout this century. Examining a 21-year abundance dataset of Argentine shortfin squids Illex argentinus paired with a regional oceanic analysis, we noted strong correlations between squid annual abundance and sea surface temperature (SST) in January and February and eddy kinetic energy (EKE) from March to May in the Southwest Atlantic. A deeper analysis revealed combined ocean-atmosphere interactions, pinpointed as the primary mode in a rotated empirical orthogonal function analysis of SST. This pattern produced colder SST and amplified EKE in the surrounding seas, factors crucial for the unique life stages of squids. Future projections from the CMIP6 archive indicated that this ocean-atmosphere pattern, referred to as the Atlantic symmetric pattern, would persist in its cold SST phase, promoting increased squid abundance. However, rising SSTs due to global warming might counteract the abundance gains. Our findings uncover a previously unrecognized link between squids and specific environmental conditions governed by broader ocean-atmosphere interactions in the Southwest Atlantic. Integrating these insights with seasonal and decadal projections can offer invaluable information to stakeholders in squid fisheries and marine conservation under a changing climate., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)

Copyright of Aerospace Research in Bulgaria is the property of Bulgarian Academy of Sciences, Space Research & Technology Institute (SRTI-BAS) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

This study aimed to investigate the occurrence of eight nitrosamines (NAs) in particulate (PM 2.5 ) and gaseous phases and assess the human health risk associated with these compounds in an urban area of Chuncheon, Gangwon State, South Korea, across four sampling seasons. The findings revealed that the total concentrations of eight NAs measured during the sampling period exceeded the public health recommendation of 0.3 ng/m 3 provided by the Norwegian Institute of Public Health, indicating a potential human health risk from NA exposures. In particular, the average total NA concentration observed in the gaseous samples during the winter of 2021 was 18.1 ± 6.46 ng/m 3 . The primary emission sources could potentially impact the concentrations of NAs in the atmosphere due to their significant positive correlation with primary emission species such as NO 2 , CO, and SO 2 . Moreover, the levels of particulate NAs during the summer were negatively correlated with O 3 , suggesting that their formation might be influenced by ozonation in the aqueous aerosol phase. In addition, the total NA concentrations measured in the gaseous phase were four to six times higher than those measured in the PM 2.5 phase throughout the sampling period. Thus, domestic sources have the potential to impact the pollution levels of the research area more significantly than long-range atmospheric transport. In particular, the highest concentrations of NAs in the gas phase were observed during the winter, while the lowest concentrations were recorded in the summer, possibly influenced by photolysis. Nevertheless, the study suggested that tertiary amines might contribute to the presence of gaseous NAs in sunlight. Consequently, further studies focusing on the occurrence of tertiary amines in the gas phase should be considered. The cumulative lifetime cancer risks estimated from inhalation exposure exceeded the acceptable risk level of 10 ⁻6 for all age groups across all four seasons. Therefore, it is crucial to implement effective control measures to mitigate potential health risks associated with exposure to NAs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

The Martian environment, characterized by extreme aridity, frigid temperatures, and a lack of atmospheric oxygen, presents a formidable challenge for potential terraforming endeavors. This review article synthesizes current research on utilizing algae as biocatalysts in the proposed terraforming of Mars, assessing their capacity to facilitate Martian atmospheric conditions through photosynthetic bioengineering. We analyze the physiological and genetic traits of extremophile algae that equip them for survival in extreme habitats on Earth, which serve as analogs for Martian surface conditions. The potential for these organisms to mediate atmospheric change on Mars is evaluated, specifically their role in biogenic oxygen production and carbon dioxide sequestration. We discuss strategies for enhancing algal strains' resilience and metabolic efficiency, including genetic modification and the development of bioreactors for controlled growth in extraterrestrial environments. The integration of algal systems with existing mechanical and chemical terraforming proposals is also examined, proposing a synergistic approach for establishing a nascent Martian biosphere. Ethical and ecological considerations concerning introducing terrestrial life to extra-planetary bodies are critically appraised. This appraisal includes an examination of potential ecological feedback loops and inherent risks associated with biological terraforming. Biological terraforming is the theoretical process of deliberately altering a planet's atmosphere, temperature, and ecosystem to render it suitable for Earth-like life. The feasibility of a phased introduction of life, starting with microbial taxa and progressing to multicellular organisms, fosters a supportive atmosphere on Mars. By extending the frontier of biotechnological innovation into space, this work contributes to the foundational understanding necessary for one of humanity's most audacious goals-the terraforming of another planet., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Committee on Space Research (COSPAR). Published by Elsevier B.V. All rights reserved.)

In September 2017, numerous measurement stations recorded large surface concentrations of Ru106 in Europe. This event was well recorded by various monitoring stations worldwide and offer a valuable framework to compare the modelling strategies deployed to quickly evaluate where the plume goes and with what concentrations. In general, the source and its intensity are not known and hypotheses have to be done. Models have to be fast and accurate: Lagrangian and Eulerian are often used but rarely compared. In this study, the FLEXPART Lagrangian model and the WRF-CHIMERE Eulerian models are used to simulate the emissions, transport and deposition of this source of Ru106. First, it is shown that the hypothesis of location, timing and intensity of the source is realistic, by comparison to surface measurements. Second, sensitivity analysis performed with the Eulerian model and several transport scheme showed that this model may provide better results than the Lagrangian one. It opens the door to further development, including chemistry and mixing with other pollutants during these specific events., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Aminoamides are formed in the atmospheric environments by the auto-oxidation of the parent diamines. In this work, the oxidation chemistry of diamine (1,3-Diaminopropane, Dap) to the amino amide (3- aminopropanamide, 3-APA) and its new particle formation potential with small atmospheric molecules such as NH 3 (A), H 2 O (W) and H 2 SO 4 (SA) are theoretically investigated using the M062X/6-311++G** theory. The bimolecular rate coefficient of the ·OH initiated H-atom abstraction is computed to be 1.01 × 10 -11  cm 3 molecule -1 s -1 . Further reaction of the peroxy radical intermediate indicates that the pathway involving γ H- shift of the initially formed radical intermediates to be more favourable on kinetic grounds with the effective bimolecular rate coefficient of 3.87 × 10 -14  cm 3 molecule -1 s -1 . The thermodynamic barrier associated with the H-shifts involved in this pathway is in the range of 13-20 kcal/mol. The cluster formation of APA with SA is more favourable than the clusters with W and A, wherein the free energy of formation of (APA)(SA) and (APA)(SA) 2 are -11.3 and -22.6 kcal/mol, respectively. However, the feasibility of cluster formation with W and A increases with the altitude and becomes spontaneous in the case of water at an altitude of 12 km. The present work indicates that aminoamides like 3-APA can participate in the initial stages of new particle formation events by forming clusters with SA molecules. The scattering parameters and topological analysis of different (Amide)(SA) clusters indicate more scattering properties for the (APA)(SA) cluster, which has an adverse effect on the atmosphere. Furthermore, topological analysis indicates that H-bond formation is more prominent in the (APA)(SA) cluster., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Powerful lightning strikes generate broadband electromagnetic signals. At Extremely Low Frequencies (ELF), the signal partly leaks into the ionosphere and produces whistlers that can be detected by satellites. Indeed, the satellites of the European Space Agency (ESA) Swarm Earth Explorer mission can detect those signals during 250 Hz burst‐mode acquisition campaigns of their Absolute Scalar Magnetometers (ASM). The dispersion of these whistlers depends on their propagation path and the distribution of ionization in the ionosphere crossed along that path. In this paper, we introduce a technique to derive a new measure of ionosphere electron content, the Total square‐Root Electron Content (TREC), using the arrival times of two frequencies of the whistler signal. We validate this approach by using data from ionosondes and from in situ measurements of the electron density at Swarm location. This technique brings new opportunities for sounding the ionosphere in regions poorly observed by other techniques. Plain Language Summary: A lightning strike generates an electromagnetic impulse that propagates within Earth's atmosphere and eventually leaks out into the ionosphere. As it propagates through the ionosphere toward low‐Earth orbiting (LEO) satellites, it gets converted into a so‐called whistler, with high frequencies arriving earlier than low frequencies. This frequency dispersion depends on the state of the ionosphere. Here, we analyse such whistler waves detected by magnetometers onboard the European Space Agency Swarm satellites to recover information about the state of the ionosphere below the satellites. We first introduce a new metric, the Total Root Electron Content (TREC), which quantifies the cumulative value of the square root of electron density along the path of the whistler. We next propose a method to recover the TREC from the analysis of the whistler dispersion. We finally validate this method by using independently derived ionospheric electron density profiles to infer expected TREC values. Our results show that whistlers detected by LEO satellites can be used to locally improve the widely used empirical International Reference Ionosphere model. Such whistler inferred TREC values could be used to sound the ionosphere above places difficult to sample with conventional measuring techniques, and help better model and understand the highly dynamic ionosphere. Key Points: Total square‐Root Electron Content (TREC) is a new measure of the ionospheric electron content for electromagnetic signals in the ELF bandA method to retrieve TREC from fractional‐hop whistlers in the ELF detected by the ESA Swarm mission is proposedThe method is validated using TREC computed with independently constrained electron density profiles close to the Swarm whistler locations [ABSTRACT FROM AUTHOR]

This study investigates the effects of sea spray on extreme precipitation forecast in Beijing of China between 28 July and 2 August 2023 as a case test. In this case, fully coupled model increased upward moisture in the Bohai and Yellow Seas and increased accumulated rainfall by 21% in North China. For the extreme precipitation events with the 5‐day accumulated precipitation exceeding 500 mm, the atmosphere‐only model did not forecast the events; the coupled model without sea spray performed well with the 0.29 threat score (TS) and 88 mm root mean square error (RMSE); in the fully coupled model, the effects of sea spray increased atmospheric instability, which increased the precipitation around Beijing and yielded a more accurate forecast with the 0.37 TS and 65 mm RMSE. This paper suggests a scientific clue to improve numerical simulation for extreme rainfall events, however, more cases are still needed for statistical evaluation. Plain Language Summary: Although meteorological forecasting ability has been improved considerably during the past decades, precipitation during extreme events remains typically underestimated. Improving model accuracy for heavy rainfall events is, indeed, a ground challenge. In this study, we conducted three numerical experiments under different conditions to evaluate the effects of sea spray on extreme precipitation forecasts for the Beijing extreme rainfall event between 28 July and 2 August 2023. Our results indicated that for this 5‐day forecasting case, including sea spray in the simulations enhanced precipitation in North China by transporting more moisture from the Bohai and Yellow Seas upward into the atmosphere. The moister and warmer air caused by sea spray effects was transported to Beijing through northwestward wind and lifted by the local terrain, then caused a more unstable atmosphere and higher intensity of precipitation around Beijing. By using statistical indicators and setting different precipitation thresholds for this extreme rainfall case, we determined that in this case, the fully coupled model including sea spray yielded more accurate forecast. To statistically evaluate the effects of sea spray in extreme precipitation forecasts, more cases are still needed. Key Points: Fully coupled model led more upward moisture in the Bohai and Yellow Seas and increased 5‐day accumulated rainfall by 21% in North ChinaFully coupled model improved the forecasting threat score from 0 to 0.37 with the 5‐day accumulated precipitation exceeding 500 mmSea spray led to more unstable atmosphere for the Beijing extreme rainfall event, yielding a more accurate forecast [ABSTRACT FROM AUTHOR]

The Stratospheric Total Aerosol Counter (STAC) is a lightweight balloon‐borne instrument that utilizes condensational growth techniques to measure the total aerosol concentration. STAC is a miniaturized version of the legacy Wyoming condensation particle counter that operated from 1974 through 2020 in the middle latitudes and polar regions, with a few measurements in the tropics. Here we provide a description of the STAC instrument and the total aerosol measurement record, demonstrating that typical total aerosol profiles exhibit a peak in number mixing ratio, with values between 800 and 2,000 particles per mg of air (mg−1), just below the lapse rate tropopause (LRT). In the tropics and middle latitudes, mixing ratios decrease above the LRT likely due to coagulation and scavenging that results in a transfer of mass to the fewer but larger aerosol particles of the Junge layer. Exceptions to this occur in the spring time in the middle latitudes where a new particle layer between 20 and 25 km is frequently observed. In the poles, total aerosol profiles exhibit two distinct features: new particle formation in austral spring, and an increasing mixing ratio above 17 km likely due to the presence of meteoric smoke that has been concentrated within the polar vortex. High observed stratospheric particle mixing ratios, in excess of 2,000 mg−1, are observed in the polar new particle layer and at the top of polar profiles. Plain Language Summary: Particles in the stratosphere range in size from a few nanometers to many micrometers in diameter. These particles are important to the radiation balance of Earth as well as chemical processes that occur in the atmosphere. Particles with diameters greater than about 50 nm are detectable by a wide variety of scientific instruments using various techniques to measure light scattered by the particles. Particles smaller than this need to be grown to larger diameters before their concentration can be measured, and therefore these measurements must be done in situ. This paper describes the design and capabilities of an instrument, the Stratospheric Total Aerosol Counter, that makes in situ measurements from high‐altitude balloons of the total aerosol concentration. Versions of this instrument have been flown around the globe since 1974. The second portion of this paper provides an overview of the total aerosol concentration record since 1989, comprising more than 250 profiles. The key findings are that in tropical regions there is a significant source of particles from the total aerosol concentration maximum at the top of the troposphere. In polar regions, a significant source of particles is from meteorites burning up when they strike the Earth's atmosphere. Key Points: The hardware and operation of a balloon‐borne Stratospheric Total Aerosol Counter (STAC) is detailed for measurements in the lower and middle stratosphereSome of the highest total aerosol mixing ratios are found in the polar mid‐stratosphere suggesting an under appreciation of this region's importanceVolcanic injections of sulfur have minimal impact on the total aerosol concentration, but significantly increase the mass of larger aerosol [ABSTRACT FROM AUTHOR]

In this paper, we explore different prognostic methods to account for skin sea surface temperature diurnal variations in a coupled ocean–atmosphere regional model of the Mediterranean Sea. Our aim is to characterise the sensitivity of the considered methods with respect to the underlying assumption of how the solar radiation shapes the warm layer of the ocean. All existing prognostic methods truncate solar transmission coefficient at a warm-layer reference depth that is constant in space and time; instead, we implement a new scheme where this latter is estimated from a chlorophyll dataset as the e -folding depth of solar transmission, which thus allows it to vary in space and time depending on seawater's transparency conditions. Comparison against satellite data shows that our new scheme, compared to the one already implemented within the ocean model, improves the spatially averaged diurnal signal, especially during winter, and the seasonally averaged one in spring and autumn, while showing a monthly basin-wide averaged bias smaller than 0.1 K year-round. In April, when most of the drifters' measurements are available, the new scheme mitigates the bias during nighttime, keeping it positive but smaller than 0.12 K during the rest of the monthly averaged day. The new scheme implemented within the ocean model improves the old one by about 0.1 K, particularly during June. All the methods considered here showed differences with respect to objectively analysed profiles confined between 0.5 K during winter and 1 K in summer for both the eastern and the western Mediterranean regions, especially over the uppermost 60 m. The new scheme reduces the RMSE on the top 15 m in the central Mediterranean for summertime months compared to the scheme already implemented within the ocean model. Overall, the surface net total heat flux shows that the use of a skin sea surface temperature (SST) parameterisation brings the budget about 1.5 Wm-2 closer to zero on an annual basis, despite all simulations showing an annual net heat loss from the ocean to the atmosphere. Our "chlorophyll-interactive" method proved to be an effective enhancement of existing methods, its strength relying on an improved physical consistency with the solar extinction implemented in the ocean component. [ABSTRACT FROM AUTHOR]

The divergence method, a lightweight approach for estimating emission fluxes from satellite images, rests on a few implicit assumptions. This paper explicitly outlines these assumptions by deriving the method from first principles. The assumptions are: the enhanced mass flux is dominated by advection, normal fluxes vanish at the top and bottom of the atmosphere, steady‐state conditions apply, sources are multiplications of temporal and spatial functions, sinks are described as first‐order reactions, and effective wind fields are concentration‐weighted wind fields. No such assumptions have to be made for the background field. A "topography correction term" does not follow from the theory, but is rather shown to be a practical correction for topography‐dependent effective wind speed errors. The cross‐sectional flux method follows naturally from the derived theory, and the methods are compared. Effects of discrete pixels and finite‐difference operations are explored, leading to recommendations, primarily the recommendation to integrate over small regions only to minimize the influence of noise. Numerical examples featuring Gaussian plumes and COSMO‐GHG simulated plumes are provided. The Gaussian plume example suggests that the divergence method might underestimate emissions when assuming only advection in the presence of cross‐wind diffusion. Conversely, the cross‐sectional flux method remains unaffected, provided fluxes are integrated across the entire plume. The COSMO‐GHG example reveals frequent violations of the steady‐state assumption, although the assumption remains valid proximal to the source (<20 km in this example). It is the hope that this paper provides a solid theoretical foundation for the divergence and cross‐sectional flux methods. Plain Language Summary: Power plants, megacities, and other regions can be places where considerable amounts of gases are emitted into the atmosphere. Satellite data is capable of recording the enhanced concentrations in the atmosphere due to these sources. How does one estimate emissions of these sources based on this data? Typically by running an atmospheric inverse model; but one computationally lightweight method gaining popularity is the "divergence method." With this method, one applies a simple mathematical operation to the satellite image multiplied by the horizontal wind speeds—the result of which is related to the emissions. The method has been used before, but here we systematically state the assumptions involved; factors like how gases are transported horizontally and over time, and what happens when we apply the method on pixelated data (such as satellite images). We find that some other analyses in the literature may be partially incorrect. Another popular method (the "cross‐sectional flux") is easily derived from the same theory. Synthetic examples are used to illustrate that various assumptions are not met in realistic data; although the examples also show that one can work around these limitations by a careful application of the methods, and by acquiring more estimates over many days. Key Points: The divergence method for estimating emissions from satellite images is derived from first principlesAssumptions made on the way are made explicit, highlighting discrepancies with existing literatureA comparison is made against the cross‐sectional flux method which follows from the same theory [ABSTRACT FROM AUTHOR]

For the requirements of the multi-means observation and emergency monitoring of space objects, including space debris and near-earth asteroids, this paper analyzes the astronomical observation conditions in the stratosphere, which is the region of the earth's atmosphere between 18 km and 55 km of altitude. The results reveal that near space has a significantly superior sky background and observation environment than ground-based observation, with the values of transmittance in the visible band and near-infrared bands more than 0.91 and 0.988, respectively. The sky background radiance at 20 km is 2.5% of the ground in the visible band and near-infrared band, which is practical for daytime observation, and there is an advantage in the availability of observable hours without the influence of aerosols and turbulence, etc. Based on near-space aerostats, such as a high-altitude balloon, a new method of space object floating observation has been proposed, including the observation facilities and scheme. The simulation shows that it has an all-weather/all-day ability while adopting multi-band observation. Applying a telescope with 9.5 mag detective ability located on the aerostat, debris with the size of about 0.36 m can be observed at a 1000 km distance and phase angle of 100°, while the near-earth asteroid with the size of about 980 km can be observed at a 5 million km distance and phase angle of 40° during the daytime. With these advantages, the aerostat-based observation would be a beneficial supplement to the ground-based observation network. [ABSTRACT FROM AUTHOR]

Simple Summary: How can human–animal studies benefit from philosophy, especially the new phenomenology, which was founded by Hermann Schmitz? This article discuss that question, using the example of human–horse relationships. Based on the results of qualitative social research, three basic concepts of new phenomenology are empirically examined and transferred to human–horse encounters: embodied communication, atmosphere, and joint situation. This article shows that the German philosopher Hermann Schmitz's new phenomenology can make a valuable contribution to human–animal studies. The three concepts suitable for this purpose are, first, Schmitz's concept of embodied communication, which can be applied to trans-species encounters; second, his understanding of atmospheres, which are always co-communicated in trans-species encounters; and, third, his conception of situation, which can help with analyzing the relationship of society to animals. My contribution applies these three basic elements of new phenomenology—embodied communication, atmosphere, and situation—to the analysis of the encounters between humans and horses. This paper demonstrates that embodied communication in particular is not only a worthwhile object of research but can also serve as a mode of producing scientific insight. [ABSTRACT FROM AUTHOR]

This paper explores the ideological valence of atmosphere, grounding the notion of interpellation in investigating the widely welcomed light shows at Civic Centre in Shenzhen, China. Combining theoretical development and empirical research, this paper examines how these light shows generated particular atmospheres that impinged upon the formation of spectators' subjectivity. In a time when atmospheric staging is widely adopted to engineer urban space and events, ideological interpellation has become increasingly atmospherically diffused. Meanwhile, material contingencies and lived varieties of atmosphere also condition and potentially disturb the communication of ideological messages. Atmosphere thus needs to be considered in terms of its conceived, perceived and lived dimensions. This paper draws from Henri Lefebvre's space triad and rhythmanalysis to outline a framework for tracing the production of atmosphere, and applies it to empirical data to illustrate how light shows at Civic Centre generated ideological appeals through the atmospheric constellation of content, environmental materiality and subjects. It is through atmosphere that we grasp and imagine what the world is. In critical response to atmospheric interpellation, new modes of the reproduction of life derive not from an atmospheric outside but precisely through a reorientation from within. [ABSTRACT FROM AUTHOR]

It follows from the observational data that variations of the atmospheric electric field occur during geomagnetic storms. In this paper, we present the simulation results of ionospheric electric fields during the main phase of the geomagnetic storm on March 17, 2015, within the framework of a quasi-stationary model of a conductor consisting of the atmosphere and the ionosphere. For this purpose, the satellite data on the global distribution of currents between the magnetosphere and the ionosphere are used to describe the magnetospheric source of the electric field. A variation of the electric potential in the ionosphere leads to a variation of the electric field in the entire atmosphere, including its surface layer. It is important that during a geomagnetic storm, the observatory in which the atmospheric electric field is measured significantly changes its position relative to the direction of the Sun. This leads to significant changes in the ionospheric conductivity above the observatory, which affects both the ionospheric electric field and the atmospheric part of the global electrical circuit (GEC). Therefore, when assessing the effect of a geomagnetic storm on the atmospheric electric field in a particular observatory, it is necessary to take into account the local time when comparing the measurement data with the geomagnetic activity indices. For the storm on March 17–18, 2015, we found that taking into account the variations of the ionospheric electric field when calculating the atmospheric electric field allowed us to reproduce the disturbances of the fair weather electric field observed at the Borok Geophysical Observatory. Based on the simulation results, it is shown that during extremely strong magnetic storms, additional atmospheric electric field variations in some places on the Earth have the same scale as the fair-weather field itself. [ABSTRACT FROM AUTHOR]

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In this paper, the coherent properties of partially coherent Bessel–Gaussian optical beams propagating through a uniform medium (free space) or a turbulent atmosphere are examined theoretically. The consideration is based on the analytical solution of the equation for the transverse second-order mutual coherence function of the field of partially coherent optical radiation in a turbulent atmosphere. For the partially coherent Bessel–Gaussian beam, the second-order mutual coherence function of the source field is taken as a Gaussian–Schell model. In this approximation, we analyze the behavior of the coherence degree and the integral coherence scale of these beams as a function of the propagation pathlength, propagation conditions, and beam parameters, such as the radius of the Gauss factor of the beam, parameter of the Bessel factor of the beam, topological charge, and correlation width of the source field of partially coherent radiation. It was found that, as a partially coherent vortex Bessel–Gaussian beam propagates through a turbulent atmosphere, there appear not two (as might be expected: one due to atmospheric turbulence and another due to the partial coherence of the source field), but only one ring dislocation of the coherence degree (due to the simultaneous effect of both these factors on the optical radiation). In addition, it is shown that the dislocation of the coherence degree that significantly affects the beam coherence level is formed only for beams, for which the coherence width of the source field is larger than the diameter of the first Fresnel zone. [ABSTRACT FROM AUTHOR]

In this paper, presents solutions to application internet of things (IoT) technology in the field of high-tech agriculture, livestock in Vietnam is currently a new problem. The system includes an application on a smartphone; access the parameters via the web, on the computer. The product has a monitoring function: the ambient atmosphere indicators of the pig farm (temperature, humidity, CO2, NH3, H2S gas, and Biogas pressure), on the website 24/24 hour and control automatic control monitoring system. This is a problem of researching, designing and manufacturing products to automatically control the quality of the ambient atmosphere to improve productivity and quality of pig raising in practice at Bach Khoa Production, Trade and Service Joint Stock Company Bach Phuong (Address: Vinh Hao Commune, Vu Ban District, Nam Dinh Province, Vietnam). [ABSTRACT FROM AUTHOR]

The H i 21 cm global signal from the Cosmic Dawn and the Epoch of Reionization (EoR) offers critical insights into the evolution of our Universe. Yet, its detection presents significant challenges, due to its extremely low signal-to-contamination ratio and complex instrumental systematics. In this paper, we examine the effects of the ionosphere and antenna beam on data analysis. The ionosphere, an ionized plasma layer in the Earth's atmosphere, refracts, absorbs, and emits radio waves in the relevant frequency range. This interaction results in additional spectral distortion of the observed signal, complicating the process of foreground subtraction. Additionally, chromatic variations in the beam can also introduce further contamination into the global spectrum measurement. Notably, the ionospheric effect, being dependent on the direction of incoming light, interacts with the instrumental beam, adding another layer of complexity. To address this, we evaluate three different fitting templates of foreground: the logarithmic polynomial, the physically motivated Experiment to Detect the Global EoR Signature (EDGES) template, and a singular value decomposition (SVD)-based template. Our findings indicate that the EDGES and SVD templates generally surpass logarithmic polynomials in performance. Recognizing the significance of beam chromaticity, we further investigate specific beam distortion models and their impacts on the signal extraction process. [ABSTRACT FROM AUTHOR]

Produced by both nature and human activities, sulfur dioxide (SO2) is an important species in the earth's atmosphere. SO2 has also been found in the atmospheres of other planets and satellites in the solar system. The photoabsorption cross sections and photodissociation of SO2 have been studied for several decades. In this paper, we reported the experimental results for photodissociation dynamics of SO2 via the G ̃ 1B1 state. By analyzing the images from the time-sliced velocity map ion imaging method, the vibrational state population distributions and anisotropy parameters were obtained for the O(1D2) + SO(X3Σ−, a1Δ, b1Σ+) and O(1S0) + SO(X3Σ−) channels, and the branching ratios for the channels O(1D2) + SO(X3Σ−), O(1D2) + SO(a1Δ), and O(1D2) + SO(b1Σ+) were determined to be ∼0.3, ∼0.6, and ∼0.1, respectively. The SO products were dominant in electronically and rovibrationally excited states, which may have yet unrecognized roles in the upper planetary atmosphere. [ABSTRACT FROM AUTHOR]

Active lidar remote sensing has been used to obtain detailed and quantitative information about the properties of aerosols. We have analyzed the spatio-temporal classification of aerosols using the parameters of particle linear depolarization ratio and single scattering albedo from Aerosol Robotic Network (AERONET) over seven megacities of Asia namely; Lahore, Karachi, Kanpur, Pune, Beijing, Osaka, and Bandung. We find that pollution aerosols dominate during the winter season in all the megacities. The concentrations, however, vary concerning the locations, i.e., 70-80% pollution aerosols are present over Lahore, 40-50% over Karachi, 90-95% over Kanpur and Pune, 60-70% and over Beijing and Osaka. Pure Dust (PD), Pollution Dominated Mixture (PDM), and Dust Dominated Mixture (DDM) are found to be dominant during spring and summer seasons.This proposes that dust over Asia normally exists as a mixture with pollution aerosols instead of pure form. We also find that black carbon (BC) dominated pollution aerosols., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Peroxyl radicals (RO 2 ) are important components of atmospheric radical cycling and generation, but their formation, distribution and evolution mechanisms in the atmospheric environment have not been investigated. In this paper, we propose a novel atmospheric RO 2 radical trapping membrane that can trap low carbon number (Rc ≤ 5) RO 2 radicals and identify their R-group structures by fluorescence spectroscopy and chromatography. We also analyzed the composition and evolution mechanism of RO 2 species under different meteorological conditions in the atmospheric environment of Lanzhou, China, to provide scientific support for the treatment and research of atmospheric chemical pollution., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Atmospheric oxidation of the p-chloroaniline-OH • adduct [C 6 H 4 ClNH 2 -OH] • (AD-C2) by ∑ g - 3O 2 and internal isomerization processes of peroxy radical [C 6 H 4 ClNH 2 -OH] • -O 2 are theoretically investigated at the M06-2X/aug-cc-pVTZ and CBS-QB3//M06-2X/aug-cc-pVTZ level of theories. Potential energy surfaces (PESs) for the most efficient pathways indicated that the oxidation process begins via the complexation of individual reactants in syn mode forming PRCy-iOO-syn (y = 2,5) in an exothermic and endogenic step. The syn mode addition is favored over the anti one due to the formation of internal hydrogen bond between the hydroxyl and peroxy groups. Formation of new C5-OO bond in PRCy-iOO-syn complex is an unimolecular process which is exothermic and exoergic. This pathway is predominated over other internal conversions due to the presence of stronger intramolecular hydrogen bond. Cyclization of the produced [C 6 H 4 ClNH 2 -OH] • -O 2 peroxy radical AD-C2-5OO-syn into the bicyclic peroxy radical AD-C2-5,6OO-syn is the last step which is strongly endothermic and endogenic. The rate coefficients are calculated by means of the RRKM theory over the temperature range 250-350 K and at a pressure range of 0.1 bar to the high-pressure limit. The RRKM rate coefficients at the M06-2X/aug-cc-pVTZ level for the first bimolecular and last unimolecular steps are in order of 10 -16  cm 3 molecule -1 s -1 and 10 -7 s -1 , respectively, while the obtained rate coefficients at the CBS-QB3//M06-2X/aug-cc-pVTZ are overestimated about two order of magnitude., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Inc. All rights reserved.)

The cloud feedback may result in amplification or damping of Arctic warming. Two common techniques used to diagnose the top‐of‐the‐atmosphere cloud feedback are the Adjusted Cloud Radiative Effect (AdjCRE) method and the Cloud Radiative Kernel (CRK) method. We apply both to CMIP5 and CMIP6 model data, finding that the AdjCRE calculated Arctic shortwave cloud feedback is twice as correlated with sea ice loss in CMIP5, and four times in CMIP6, as the CRK method. We find that the CRK method produces Arctic all‐sky residual percentages exceeding 20% in 15 of 18 models. We use the CRK method to decompose the feedback in CMIP5 and CMIP6 finding that its median value changed from negative to positive driven by a less‐negative cloud optical depth feedback. Despite its lack of closure, we conclude that the CRK method is better suited for Arctic SW feedbacks as it is less impacted by surface albedo changes. Plain Language Summary: The cloud feedback is the process by which cloud property changes in a warming climate can either further enhance warming or damp it. The Arctic is warming faster than the rest of the globe, and one of the largest sources of uncertainty in its climate projections is the cloud feedback. There are two popular methods to calculate the cloud feedback: the Adjusted Cloud Radiative Effect technique, and the Cloud Radiative Kernel technique. In this paper we compare the two methods in a suite of climate models by considering the extent to which changes in Arctic sea ice impact the cloud feedbacks. From this analysis we conclude that the Cloud Radiative Kernel method is less affected by sea ice loss. We then apply the Cloud Radiative Kernel technique to data from the two most recent generations of global climate models to investigate how polar day Arctic cloud feedbacks have changed between these generations. We find that the median value of these Arctic feedbacks is slightly positive in the newest generation of models, a change from slightly negative in the previous generation that is largely fueled by a weakening of the feedback associated with changes in cloud optical depth. Key Points: The Cloud Radiative Kernel method is less sensitive to surface albedo changes than the Adjusted Cloud Radiative Effect techniqueThe Cloud Radiative Kernel method provides poor radiative closure in a suite of global climate modelsThe median shortwave Arctic cloud feedback in recent climate models is slightly positive due to a weakened cloud optical depth feedback [ABSTRACT FROM AUTHOR]

Quantifying water vapor and carbon dioxide (CO 2) exchange dynamics between the land and the atmosphere through observations and modeling is necessary in order to reproduce and project near-surface climate in coupled land–atmosphere models. The exchange of water and CO 2 occurs at the leaf surface (leaf level) and in a net manner through exchanges at all the leaf surfaces composing the vegetation canopy and at the soil surface (canopy level). These exchanges depend on the meteorological forcings imposed by the overlying atmosphere (atmospheric boundary layer level). In this paper, we investigate the effect of four canopy environmental variables (photosynthetic active radiation (PAR), water vapor pressure deficit (VPD), air temperature (T), and atmospheric CO 2 concentration (Ca)) on the local individual leaf exchange and canopy exchange of water and CO 2 at hourly timescales. Additionally, we investigate the effect of atmospheric boundary layer (ABL) processes on the local exchange. To that end, we simultaneously investigated the exchanges of water and CO 2 at leaf level and canopy level for an alfalfa field in northern Spain over 1 day in summer 2021. We used comprehensive observations ranging from stomatal conductance to ABL measurements collected during the Land Surface Interactions with the Atmosphere in the Iberian Semi-Arid Environment (LIAISE) experiment. To support the observational analysis, we used a coupled land–atmosphere model (CLASS model) that has representations at all levels considered. To relate how temporal changes of the four environmental variables modify the fluxes of water and CO 2 , we studied tendency equations of the leaf gas exchange. These mathematical expressions quantify the temporal evolution of the leaf gas exchange as a function of the temporal evolution of PAR, VPD, T , and Ca. To investigate the effects of ABL processes on the local exchange, we developed three modeling experiments that impose surface radiative perturbations by a cloud passage (which perturbed PAR, T , and VPD), entrainment of dry air from the free troposphere (which perturbed VPD), and advection of cold air (which perturbed T and VPD). The model results and observations matched the leaf gas exchange (r2 between 0.23 and 0.67) and canopy gas exchange (r2 between 0.90 and 0.95). The tendency equations of the modeled leaf gas exchange during the study day revealed that the temporal dynamics of PAR were the main contributor to the temporal dynamics of the leaf gas exchange, with atmospheric CO 2 temporal dynamics being the least important contributor. From the three modeling experiments with ABL perturbations, the surface radiative changes induced by a cloud perturbed the CO 2 exchange the most, whereas all of them perturbed the water exchange to a similar extent. Second-order effects on the dynamics of the leaf gas exchange were also identified using the tendency equations. For instance, the decrease in the net CO 2 assimilation rate during the cloud passage caused by a decrease in surface radiation was further enhanced due to the decrease in air temperature also associated with the cloud. With this research we showcase that the proposed tendency equations can disentangle the effect of environmental variables on the leaf exchange of water and CO 2 with the atmosphere, as represented in land–surface parameterization schemes. As such, this framework can become a useful tool with which to analyze these schemes in weather and climate models. [ABSTRACT FROM AUTHOR]

Since the tropopause was first identified, the quality and resolution of weather balloons has dramatically improved. NOAA Earth System Research Laboratories (ESRL) have provided high resolution and very high quality ozonesondes from eight locations: Fiji; American Samoa; Greenland; Antarctica; and several locations in USA (Hawai'i, Colorado, California and Alabama). These locations collectively cover polar regions, mid‐latitudes and tropics. Using this publicly archived data set, we studied the variability of the tropopause for all eight locations for one complete year (2016). Along with the standard estimates of the tropopause provided by NOAA ESRL, we developed four alternative tropopause definitions each based on changes in one of the following: (a) molar density; (b) temperature lapse rates; (c) water vapor content; (d) ozone content. These old and new tropopause definitions appear to hold over all eight locations—for all seasons and from the tropics to the poles. The cohesiveness between all five of these independent tropopause definitions is remarkable, although the NOAA ESRL estimates sometimes identify higher tropopause onsets than the other estimates. Therefore, each tropopause definition could potentially be used as proxies for other tropopause definitions. However, it also confirms that the troposphere/tropopause transition is a multi‐faceted physical and chemical phenomenon associated with more than just temperature changes. Finally, these high‐resolution results suggest that the original term "tropopause" might be a misnomer since they suggest increases in temperature lapse rate variability, rather than the "pausing" implied by lower resolution data or by lapse rates that are averaged over large distances. Plain Language Summary: In the lower atmosphere ("the troposphere"), the temperature decreases with height. This is why it is colder on mountaintops. Since 1902, it has been known that higher up in the atmosphere, in the region near where commercial airplanes fly, temperatures remain relatively constant with height. This region is called "the tropopause." In 1957, the World Meteorological Organization (WMO) defined the start of the tropopause in terms of a set of rules, that were complex, but designed to be applicable for all latitudes and seasons. However, these rules are often hard to implement and can give ambiguous results. So, other definitions have been developed for specific regions, such as the tropics, that are more straightforward and easier to interpret. In this paper, we have developed four new tropopause definitions that can be used with modern high resolution "ozonesondes" (weather balloons that also measure ozone). These four independent definitions describe different aspects of the atmosphere but each give very similar estimates of the tropopause. This reveals that the tropopause involves many different but synchronous changes in the atmosphere. It also shows that the name "tropopause" is confusing because it is a part of the atmosphere involving lots of changes instead of "pausing." Key Points: Four new tropopause definitions have been developed for use with high‐resolution ozonesondes that work for all latitudes and seasonsAll these definitions yield almost identical tropopause estimates yet are derived from independent physical or chemical metricsSurprisingly, the "tropopause" marks a region with increased lapse rate variability over short altitudes as opposed to long‐term averages [ABSTRACT FROM AUTHOR]

A multi-season convection-permitting regional climate simulation of the Maritime Continent (MC) using the Met Office Unified Model (MetUM) with 2.2 km grid spacing is presented and evaluated. The simulations pioneer the use of atmosphere–ocean coupling with the multi-column K profile parametrisation (KPP) mixed-layer ocean model in atmospheric convection-permitting climate simulations. Comparisons are made against a convection-parametrised simulation in which it is nested and which in turn derives boundary conditions from the ERA5 reanalysis. This paper describes the configuration, performance of the mean state and variability in the two simulations compared against observational datasets. The models have both minor sea surface temperature (SST) and wet precipitation biases. The diurnal cycle, representation of equatorial waves, and relationship between SST and precipitation are all improved in the convection-permitting model compared to the convection-parametrised model. The Madden–Julian oscillation (MJO) is present in both models with a faster-than-observed propagation speed. However, it is unclear whether fidelity of the MJO simulation is inherent to the model or whether it predominantly arises from the forcing at the boundaries. [ABSTRACT FROM AUTHOR]