This work investigates the decarbonization potential of large-scale implementation of BECCS (in the form of biomass co-firing and post-combustion amine-based CO2 capture) in over 150 existing coal-fired power plants in China, combining GIS-based geospatial analysis of biomass availability from agricultural residues and modelling of the techno-environmental performance of the retrofitted power plants. Using a 500-m resolution map of cropland in China, the availability of residual biomass at a radius of 25–100 km from each power plant is estimated. The biomass yield is then matched with the required input for a set of co-firing scenarios, identified by the optimal mix of different co-firing ratios (10%, 25%, and 40%) and increasing % of total plant's capacity to be retrofitted with the chosen BECCS system. Power generation performance and required biomass for the retrofitted plants are modelled in the Integrated Environmental Control Model (IECM). According to the results, the total decarbonization potential of the modelled large-scale implementation of BECCS ranges from 0.3 to 1.8 Gt CO2/yr (15–81% of BAU emissions), depending on the biomass collection radius. The Chinese provinces of Shandong, Jiangsu, Anhui, and Henan have the most potential for BECCS implementation, while coal-rich regions (e.g. Inner Mongolia) or highly developed coastal areas (Guangdong, Zhejiang) are constrained by local biomass availability. Overall, this work demonstrates the significant potential of the sustainable large-scale implementation of BECCS in China and provides suggestions to policymakers to include this technology in the portfolio of solutions towards carbon neutrality. [ABSTRACT FROM AUTHOR]