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In this study, Zn 8 B 3 H 3 O 14 nanosheets were synthesized through a one-step coprecipitation process and employed as both a boron source and substrate templates for the fabrication of boron nitride nanosheets (BNNSs), which were synthesized efficiently at low temperatures by the borate nitration method using ammonia as the nitrogen source. The thickness of the synthesized BNNSs ranged from 3 to 10 nm with a flake dimension of about 2.56 μm. The prepared BNNSs using this method realized 98.8% boron source utilization and single batch yields up to gram level. In addition, BNNSs/SiO 2 microwave-transparent composites were prepared to investigate the potential for large-scale applications of the BNNSs produced by using this method. The composites demonstrated a remarkable increase in bending strength and fracture toughness, reaching 122.02 MPa and 2.31 MPa·m1/2, respectively, with the addition of only 0.5 wt% BNNSs. Compared with SiO 2 without BNNSs, the fracture toughness of the composites is increased by 106%. A novel crack plugging strong toughening mechanism of BNNSs is proposed. Simultaneously, the composites exhibit exceptional microwave-transparent properties, with dielectric constants below 4 in the real part and below 0.03 in the imaginary part. Therefore, this study has successfully achieved the low-temperature and efficient synthesis of micron-scale BNNSs, laying the groundwork for their large-scale application. [Display omitted] • Zn 8 B 3 H 3 O 14 nanosheets were used as substrate templates for the synthesis of BNNSs. • BNNSs were synthesized with high efficiency at low temperatures (900 °C). • The single batch yield of BNNSs reached up to the gram level. • The BNNSs/SiO 2 wave-transparent composites with ultrahigh toughness were obtained. • A novel mechanism for strengthening and toughening (BNNSs plugging) is proposed. [ABSTRACT FROM AUTHOR]