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SiC/multi-walled carbon nanotube (MWCNT) composites are considered to be promising materials for high-temperature electromagnetic wave (EMW) absorption due to their strong thermal stability and tunable dielectric properties. However, the EMW absorption performance of these composites is limited by poor impedance matching. This study proposes a novel multiscale structure synergistic regulation approach to enhance EMW absorption performance, which involves constructing a heterointerface structure and a triple periodic minimal surface (TPMS) meta-structure. The addition of a SiO 2 shell as an impedance layer to the SiC/MWCNT core to improve the intrinsic impedance. Meanwhile, the heterointerface between the core-shell structure leads to multiple interface polarization, significantly enhancing EMW energy dissipation. Consequently, the effective absorption bandwidth (EAB) of SiO 2 –SiC/MWCNT composites increased from 0.88 to 4.56 GHz. Furthermore, a TPMS meta-structure, fabricated by three-dimensional (3D) printing and sol infiltration technology, is developed to further improve impedance matching with the equivalent electromagnetic effect. Simulation and experimental results demonstrate that the SiO 2 –SiC/MWCNT TPMS meta-structure exhibits broadband EMW absorption performance, with the EAB reaching 7.2 GHz. This improvement is attributed to the synergistic regulation of the heterointerface structure and TPMS meta-structure, which provides a good balance between the requirements of electromagnetic loss and impedance matching. Additionally, the composites exhibit excellent oxidation resistance, as their EAB remains almost unchanged after exposure to 1000 °C for 6 h. This research offers a new design paradigm for ultrabroadband design of the nonmagnetic high-temperature absorbing materials. [Display omitted] [ABSTRACT FROM AUTHOR]

The recent identification of superconductive effects in multilayer graphene systems exhibiting coexistence of rhombohedral and Bernal structural phases has attracted great attention. Complex effects have been reported in the presence of dislocations and/or solitons between graphene layers. Local magnetic fields and percolative effects have also been identified in the presence of wrinkling and disclinations. Interestingly, a recent report has also demonstrated the local stabilization of disorder-rich rhombohedral phases in low dimensional systems comprising of multiwalled carbon nanotubes modified with sulfur. In this work we identify a variation in the predicted ABA Bernal graphitic ordering of multiwalled carbon nanotubes (CNTs) fabricated in the presence of dichlorobenzene as a growth-promoter. The presented results highlight the stabilization of a high density of dislocations in samples produced by pyrolysis of low concentrations of ferrocene. We present an in-depth investigation of the dislocation-rich interfaces, especially by employing HRTEM analyses, evidencing a spontaneous local-insertion of low-dimensional atomic-lines (or solitons) into neighbouring atomic layers of curved graphene. Furthermore, by employing a methodology involving highly controllable cooling-rates and subsequential characterization through X-ray diffraction (XRD), we demonstrate a rapid migration of interstitial carbon, with relaxation of Fe3C into α-Fe and stabilization of local body centred tetragonal phases within the body centred cubic lattice of the nanowires. [ABSTRACT FROM AUTHOR]

Highly purified and uniformly distributed carbon nanotube (CNT) network is one of the key issues for developing advanced nanocomposites. However, the challenge for mitigation of the aggregation of CNT bundles during the CNT film fabrication still remained. In this work, debundling and reorganization of CNT bundles have been realized simultaneously by using a high-temperature thermal treatment. The debundling of large CNT bundles into small ones started after they were heat treated under 1400 °C and uniformly distributed CNT networks with small bundles were obtained after heat treated under 1800 °C. The tensile strength of the CNT film significantly increased by about 64% compared to the pristine film. Microstructural observations showed that the iron nanoparticles started to evaporate at 1400 °C and were completely removed at 1800 °C. Hollow amorphous carbon shells wrapped on the nanoparticles were left inside the CNT networks after the removal of the iron nanoparticles. Interestingly, these amorphous carbon shells act as carbon source for the deposition of a carbon layer on the CNT surface when the heat treatment temperature was up to 2000 °C, and they were completely consumed after being treated at 2800 °C. The microstructural evolution process of CNT bundles during heat treatment suggests the simple high-temperature treatment strategy could be applied for fabrication of highly purified CNT networks with well-distributed small bundles, enabling the development of advanced multifunctional nanocomposites in the near future. A high-temperature heat treatment is used to investigate the microstructure evolution and mechanical properties of CNT films. Benefiting from the high-purity and uniformly distributed CNT networks with small bundles after heat treated under 1800 °C, the tensile strength of the CNT film has significantly increased by ∼64% compared to the pristine film. When heat treated under 2800 °C, the hollow amorphous carbon shells are completely consumed and act as carbon source for deposition of carbon layer on the CNT surface. [Display omitted] • Debundling of large CNT bundles was observed after a high temperature treatment. • A regenerative carbon layer was deposited on CNT surface under high temperature. • The microstructural evolution of CNT networks under high temperature was proposed. [ABSTRACT FROM AUTHOR]

• The curing residual stress is beneficial for the compression strength of composite risers. • The effect of curing process parameters on the compressive strength was not significant. • The addition of nano-reinforced particles reduces the curing residual stresses. • The performance of the composite riser is enhanced with the increase of nanoparticle content. • The addition of nano-reinforced particles affects the failure mode of the composite riser. The present study is dedicated to the numerical analysis of progressive failure damage in multiangle nano-reinforced filament wound risers, with due consideration for process-induced residual stresses. Utilizing a multi-model coupling strategy, we introduce an integrated methodology predicated upon the time-varying material characteristics at a macroscopic scale. Initially, the process-induced residual stresses are anticipated via a sequential coupled numerical simulation methodology based on the time-varying attributes of the material. Subsequently, the curing residual stresses serve as the initial stress for the composite wound riser to prognosticate its axial compressive strength, grounded in the progressive damage model. Finally, the multiparametric effects on the strength properties of the composite risers are further investigated to reveal the intrinsic mechanism. The numerical findings evince that curing-induced residual stress retards both fiber and matrix failure while augmenting the axial compressive strength of the composite riser. Furthermore, the escalation in nanoparticle content diminishes the process-induced residual stresses. Additionally, the incorporation of 5 % nanoparticles yields an enhancement in the strength of the composite risers by approximately 16.26 % relative to those devoid of nanoparticles. [ABSTRACT FROM AUTHOR]