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• The preferentially dissolved ferrite in pearlite and shedding of cementite lamellae contribute to the formation of corrosion pits. • Corrosion fatigue crack initiation and growth mechanism of U75V rail steel is clarified. • Corrosion fatigue crack initiation behavior is related to morphology ratio and local shape of corrosion pits. Understanding the corrosion fatigue mechanism of rail materials is of great importance to guide the assessment of the structural integrity of modern railway components. To this purpose, the corrosion fatigue crack (CFC) initiation and growth behaviors of heat-treated U75V rail steel are investigated under 3.5 wt% NaCl solution in terms of high-cycle fatigue, fatigue crack growth (FCG) rate, together with surface morphology and microstructure. Experimental results reveal that the U75V rail steel is susceptible to corrosion fatigue failure. Examinations on fractured samples clearly show that the electric potential difference between ferrite and cementite triggers the preferential anodic dissolution of ferrite, leading to corrosion fatigue crack initiation. The crack initiation is not only solely determined by the size of the corrosion pit, but also strongly influenced by its local shape. In comparison with the fatigue crack growth in air, the corrosion FCG tends to grow in a relatively straight path, because of hydrogen embrittlement. Additionally, the CFC behaviors indicate a tendency to transverse through soft-oriented grains and deflect upon encountering hard-oriented grains. [ABSTRACT FROM AUTHOR]