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This paper explores the connection between the H3BO3 flux concentration and the co-existence of Eu2+ and Eu3+ dopants within CaMgSi2O6 crystals (diopside). The samples were synthesised using a solid-state synthesis method under varying atmospheric conditions, including oxidative (air), neutral (N2), and reductive (H2/N2 mixture) environments. Additionally, some materials underwent chemical modification by partially substituting Si4+ with Al3+ ions acting as charge compensation defects stabilizing Eu3+ luminescence. Depending on the specific synthesis conditions, the materials predominantly displayed either the orangered luminescence of Eu3+ (under oxidising conditions) or the blue luminescence of Eu2+; however, the comprehensive results confirmed the co-existence of Eu3+/Eu2+ luminescence in both cases. This work shows that varying flux concentrations added during synthesis significantly affect the relative strength of Eu2+ and Eu3+ emissions in a manner dependent on the synthesis atmosphere. The emission of Eu2+ increases with a higher flux concentration in materials synthesised under oxidative and neutral atmospheres independent of the chemical modification. In contrast, for materials obtained under a reductive atmosphere, the changes in the Eu3+ emission intensity depended on the presence or absence of Al3+ ions namely the increase of flux increased the Eu3+ intensity in the case of unmodified materials and decreased in the Al-modified ones. All observed effects were qualitatively explained considering the double role of the flux in the studied system, which besides facilitating the diffusion of chemical species during synthesis acts as a charge compensating agent by creating B'Si centres stabilizing Eu3+ emission. [ABSTRACT FROM AUTHOR]

The paper presents the first terrestrial record of millennial-scale palaeo-ice margin oscillations at the southern fringe of the last Fennoscandian Ice Sheet (FIS) during the last glacial cycle. The study area is located in northern Poland close to the last FIS maximum limit. The chronology and dynamics of palaeo-ice margin oscillations at the southern fringe of the FIS are based on combined luminescence and 10 Be surface exposure dating. Optically stimulated luminescence (OSL) was used to date sandy deposits (fluvioglacial sediments and aeolian deposits filling fossil periglacial wedges) intercalating basal till layers. The most likely age of the tills was constrained by Bayesian modelling of the sequence of OSL ages and lithostratigraphy. 10 Be surface exposure dating was used on erratic boulders left during the final retreat of the last FIS and resting on the surface of glacial landforms. Our results, which are mainly based on OSL chronology and Bayesian modelling, indicate millennial-scale oscillations of the last FIS in northern Poland between ∼19 and ∼17 ka. The last FIS retreated and re-advanced over a relatively short period of time (2–3 ka), leaving lithostratigraphic records (basal tills) of three ice re-advances over a millennial-scale cycle: 19.2±1.1 , 17.8±0.5 and 16.9±0.5 ka. Despite 10 Be surface exposure ages obtained for 14 erratic boulders being poorly clustered, the main mode of age distribution occurs at ∼18 ka and indicates a possible signal of the ice sheet retreat after one of the re-advances. We explore the dynamics of these oscillations and compare the proposed cycles of the southern FIS advances and retreats with existing patterns of the last deglaciation and millennial-scale fluctuations of the last FIS inferred from marine records. [ABSTRACT FROM AUTHOR]