1. Characterization and performance evaluation of colorimetric pH-sensitive indicator based on Ҡ-carrageenan/quince seed mucilage hydrogel as freshness/spoilage monitoring of rainbow trout fillet.
- Author
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Forghani, Samira and Almasi, Hadi
- Subjects
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FIELD emission electron microscopy , *COLOR of fish , *COLOR variation (Biology) , *FISH spoilage , *HYDROGEN bonding interactions , *CARRAGEENANS - Abstract
The aim of research was to fabricate a novel indicator by using κ-carrageenan and quince seed mucilage (QSM) hydrogels and red cabbage anthocyanin. The porosity of the hydrogel was controlled using different ratios of κ-carrageenan(C):QSM(Q) (C90:Q10, C70:Q30, and C50:Q50). The hardness of hydrogels decreased from 28.6 ± 0.3 N for C90Q10 to 11.0 ± 1.0 N for C50Q50 sample. However, according to field emission scanning electron microscopy (FE-SEM) analysis, the C50R50 sample had the best morphology with smooth surface and uniform interconnected porous network. Hydrogen bonding interactions among anthocyanins, QSM, and κ-carrageenan were confirmed by Fourier transforms infrared (FT-IR) spectroscopy. The indicator showed a color variation from red to yellow over the pH range of 2–12. Also, the indicator exhibited high sensitivity to ammonia vapors (S RGB = 115%) and good color stability. The C50QRA indicator was used for monitoring rainbow trout fillet spoilage and revealed a visually-detectable color change from red to green upon detecting total volatile basic nitrogen (TVB-N) content produced throughout storage at 4 °C. Generally, the halochromic hydrogel developed in this research can be suggested as a more sensitive and accurate freshness indicator than conventional indicator solid supports. • Novel Ҡ-carrageenan/quince seed mucilage/RCA based hydrogel was prepared. • Quince seed mucilage improved the thermal/morphological properties of hydrogels. • Distinct color variation of intelligent hydrogel over the pH range was observed. • Hydrogel-based indicators had high sensitivity to ammonia and color stability. • Smart hydrogel had excellent accuracy in monitoring the freshness of fish fillets. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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