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Rechargeable sodium-chlorine (Na-Cl2) batteries show high theoretical specific energy density and excellent adaptability for extreme environmental applications. However, the reported cycle life is mostly less than 500 cycles, and the understanding of battery failure mechanisms is quite limited. In this work, we demonstrate that the substantially increased voltage polarization plays a critical role in the battery failure. Typically, the passivation on the porous cathode caused by the deposition of insulated sodium chloride (NaCl) is a crucial factor, significantly influencing the three-phase chlorine (NaCl/Na+, Cl-/Cl2) conversion kinetics. Here, a self-depassivation strategy enabled by iodine anion (I-)-tuned NaCl deposition was implemented to enhance the chlorine reversibility. The nucleation and growth of NaCl crystals are well balanced through strong coordination of the NaI deposition-dissolution process, achieving depassivation on the cathode and improving the reoxidation efficiency of solid NaCl. Consequently, the resultant Na-Cl2 battery delivers a super-long cycle life up to 2000 cycles. An iodine-induced self-depassivation strategy extends Na-Cl2 battery life to 2000 cycles by forming high-reactivity NaCl and lowering the chlorine conversion polarization, which successfully solves a key failure mechanism for superior reversibility. [ABSTRACT FROM AUTHOR]

A fundamental challenge in soil macroecology is to understand how microbial community structure shapes ecosystem function along environmental gradients of the land surface at broad spatial scales (i.e. the horizontal dimension). However, little is known about microbial community structure–function relationships in extreme environments along environmental gradients of soil depth at finer spatial scales (i.e. the vertical dimension). Here, we propose a general spatial dimension partitioning approach for assessing the patterns and drivers of soil microbial community structure–function relationships across horizontal and vertical spatial gradients simultaneously. We leveraged a 200‐km desert soil salinity gradient created by a 12‐year saline‐water irrigation in the Tarim basin of Taklamakan Desert. Specifically, using a general linear model, hierarchical variance partitioning, and a path model, we assessed the patterns and key ecological processes controlling spatial turnover in microbial community structure (i.e. β‐diversity) and enzymatic activity relevant to carbon, nitrogen, and phosphorus cycling along soil salinity gradients across study sites (horizontal dimension) and soil depths (vertical dimension). We found a decoupled relationship between soil microbial β‐diversity and enzymatic activity. Differences in soil depth (on the scale of meters) were as important as geographic distance (on the scale of kilometers) in shaping bacterial and fungal β‐diversity. However, the vertical and horizontal turnover in enzymatic activity was largely attributed to an increase in the heterogeneity of soil properties, such as soil texture, water content, and pH. Our findings suggest that dispersal limitation controls microbial community β‐diversity and that environmental heterogeneity, rather than soil salinization, controls enzymatic activity. Taken together, this work highlights that in the face of ongoing environmental alterations, soil depth is an under‐explored spatial dimension that must be considered in soil conservation efforts as a critical factor in determining microbial community structure and function in extreme environments. [ABSTRACT FROM AUTHOR]

Consumers usually endorse tourism products differently when sharing positive electronic word-of-mouth (eWOM). This research examines the relative persuasiveness of two endorsement styles, that is, explicit endorsement (e.g., "I recommend it") and implicit endorsement (e.g., "I love it"). Drawing on the persuasion knowledge model, we propose that explicit endorsements are less persuasive than implicit endorsements because the former trigger stronger persuasion knowledge. We further argue that source trustworthiness mitigates the persuasion effect difference between the two endorsement styles. This article assesses these hypotheses across different sources (anonymous reviewers, friends, influencers), channels (online community, social commerce platform, social networking app), and products (hotels, restaurants) using secondary data analysis and two experiments. Three studies provide support for our hypotheses. By revealing the relationship between endorsement styles and eWOM persuasiveness, this article provides important implications for implementing effective product endorsement. [ABSTRACT FROM AUTHOR]

AbstractIn the post-pandemic era, tourists are increasingly interested in sustainable consumption, particularly focusing on green hotels. Given the ongoing endemic nature of COVID-19, our research explores the effects of tourists’ residential locations, specifically pandemic-affected areas, on their intention to choose green hotels. Drawing on the Protection Motivation Theory, we discuss how and why residential location influences risk perception, which in turn motivates tourists to contribute to environmental protection by opting for green hotels. Results from five experiments suggest that the influence of pandemic areas on green hotel consumption can fluctuate over time. During the initial outbreak, a positive correlation emerges between tourists’ risk perception and their distance from the pandemic’s epicenter. Those residing in marginal areas show greater threat appraisal and stronger intentions toward choosing green hotels than tourists in central areas. However, this relationship is found to reverse during the mitigation and post-pandemic phases. Furthermore, our research reveals that hotels can significantly sway tourists toward green consumption through the strategic use of hope or fear appeals in advertising. These findings enrich the literature on pandemic-related influences on green consumption and offer practical insights for hotel managers and policymakers seeking to promote sustainable travel more effectively in the post-pandemic era. [ABSTRACT FROM AUTHOR]

Rechargeable sodium-chlorine (Na-Cl 2 ) batteries show high theoretical specific energy density and excellent adaptability for extreme environmental applications. However, the reported cycle life is mostly less than 500 cycles, and the understanding of battery failure mechanisms is quite limited. In this work, we demonstrate that the substantially increased voltage polarization plays a critical role in the battery failure. Typically, the passivation on the porous cathode caused by the deposition of insulated sodium chloride (NaCl) is a crucial factor, significantly influencing the three-phase chlorine (NaCl/Na + , Cl - /Cl 2 ) conversion kinetics. Here, a self-depassivation strategy enabled by iodine anion (I - )-tuned NaCl deposition was implemented to enhance the chlorine reversibility. The nucleation and growth of NaCl crystals are well balanced through strong coordination of the NaI deposition-dissolution process, achieving depassivation on the cathode and improving the reoxidation efficiency of solid NaCl. Consequently, the resultant Na-Cl 2 battery delivers a super-long cycle life up to 2000 cycles., (© 2024. The Author(s).)

Introduction: The issue of tobacco control remains a significant concern for public health worldwide. In recent years, remarkable progress has been made toward adopting smoke-free measures in indoor public places. Although China has yet to introduce a national regulation, specifically for smoke-free public places, more than a dozen cities have successively approved and implemented comprehensive smoke-free regulations. Different cities in China have diverse attitudes and behaviors toward smoke-free policies; however, the reasons for these policy differences and the influencing factors have not received sufficient attention and research., Methods: On the basis of the multiple streams framework, this study selects 36 key Chinese cities as research samples and uses a directed dyad-year event history analysis method to analyze the factors influencing the implementation of comprehensive smoke-free policies in cities., Results: Results show that the adoption of such policies is positively influenced by scientific evidence, focal events, media coverage, institutional foundations, economic comparisons, and the influence of health departments and of tobacco control groups. By contrast, policy adoption is negatively affected by the differences in administrative levels, central policy signals, and the influence of the tobacco industry., Discussion: This study contributes to understanding the internal logic behind local governments' adoption of comprehensive smoke-free policies, offering insights for further advocacy at the city and national levels in China and providing experiences that can promote the global tobacco control movement., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2024 Feng, Qin, Jin and Li.)