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We perform a set of reactive transport simulations in three‐dimensional fracture networks to characterize the impact of geochemical reactions on flow channelization. Flow channelization, a frequently observed phenomenon in porous and fractured subsurface rock formations, results from the spatially variable hydraulic resistance offered by a geological structure. In addition to geo‐structural features such as network connectivity, geometry, and hydraulic resistance, geochemical reactions, for example, dissolution and precipitation, can dynamically inhibit or enhance flow channelization. These geochemical processes can change the fracture permeability leading to increased flow channelization, which are localized connected regions of high volumetric flow rates that are seemingly ubiquitous in the subsurface. In our simulations, fractures partially filled with quartz are gradually dissolved until quasi‐steady state conditions are obtained. We compare the flow field's initial unreacted and final dissolved states in terms of flow and transport observations. We observe that the dissolved fracture networks provide less resistance to flow and exhibit increased flow channelization when compared to their unreacted counterparts. However, there is substantial variability in the magnitude of these changes which implies that the channelization strongly depends on the network structure. In turn, we identify the interplay between the particular network structure and the impact of geochemical dissolution on flow channelization. The presented results indicate that geological systems that have been weathering or reactive for longer times in older landscapes are likely to have increased flow channelization compared to their equivalent but younger counterparts, which implies a time dependence on flow channelization in fractured media. Plain Language Summary: Fractures are the primary pathways for fluid flow and solute transport in Earth's subsurface. In many of these systems, fluids passing through the fractures are out of equilibrium with the resident minerals, and various geochemical reactions occur. These geochemical processes can change the resistance to flow offered by the fractures, leading to increased flow channelization, which are localized connected regions of high flow rates. However, quantification of these impacts has been limited to the computational burden of performing requisite simulations. Through a series of reactive transport simulations in fractured media, we characterize the influence of dissolution on flow channelization using observations of flow and transport properties. We compare flow and transport in the initial unreacted state and in the final dissolved state to better understand how geochemical reactions influences the flow properties of the network medium. We observe that the unreacted fracture networks provide lower resistance to flow and exhibit increased flow channelization. The results suggest that older geological systems ought to have increased flow channelization when compared to their younger counterparts. Key Points: We characterize the impact of geochemical dissolution on flow channelization in fractured media using reactive transport simulationsWe observe that the dissolved fracture networks provide less resistance to flow and exhibit increased flow channelizationThere is a dissolution feedback loop between primary sub‐networks and geochemical reactions on flow channelization [ABSTRACT FROM AUTHOR]