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For a reliable and risk-free power source, dye-sensitized solar cells (DSSCs) have been the subject of much research. The method is very attractive because of its cheap manufacturing cost, environmentally friendly manufacture, and competitive efficiency. This study constructed a heterojunction as a photoanode for DSSCs using a combination of TiO2 and graphene using a wet chemical technique. According to the XRD and TEM findings, the graphene sheets consist of evenly wrapped spherical nanoparticles with diameters ranging from 30 to 40 nm, and the TiO2 exhibits a tetragonal (anatase) phase. It is common for anatase to have a bandgap energy of 3.15 eV for TiO2, whereas graphene/TiO2 has a bandgap energy of 2.77 eV. With a power conversion efficiency (PCE) of 7.2%, graphene/TiO2 DSSCs outperform cells based on pure TiO2 electrodes by a margin of 2.22%. In particular, graphene's ability to absorb solar light has the potential to improve the power conversion efficiency of DSSCs by increasing the light harvest of dye molecules. In addition, graphene/TiO2 had an average electron transit time of 1.765 ms while TiO2 had an average of 2.981 ms. The research shows that DSSCs' power conversion efficiency may be greatly improved by strategically adding graphene, which can be affordably synthesized, to certain layers of the photoanode. [ABSTRACT FROM AUTHOR]