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Objective: This study delves into the correlation between individual income inequality as measured by the relative deprivation index and charitable giving, while also examining urban–rural heterogeneity. Additionally, it further explores the mechanisms by which online and offline forms of social interaction operate in this context. Methods: Utilizing data from the 2014–2020 China Family Panel Studies, we employed several methodologies including Probit regression models, cross‐model average marginal effects difference testing based on bootstrap method, instrumental variable method, and the Karlson–Holm–Breen (KHB) effect decomposition method. Results: The findings reveal that individual income inequality measured by the relative deprivation index significantly reduces charitable giving among Chinese households. The inhibitory effect of individual income inequality on social charitable giving is higher than that on charitable giving directed toward friends or colleagues. Furthermore, this impact exhibits some heterogeneity between urban and rural areas. Mechanism analysis indicates that the adverse effect of income inequality on charitable giving operates through reducing social interaction, including both online and offline forms. Conclusion: Our results demonstrate that income inequality has distinct adverse effects on two types of charitable giving and explain the mechanisms underlying these effects through social interaction. A pattern of the differential mode of association similar to "ripples" in Chinese society is beneficial for understanding these differentiated impacts. We believe it is necessary to improve economic inequality conditions and enhance the enthusiasm of the Chinese public for participating in charitable donations by promoting various forms of social interaction. [ABSTRACT FROM AUTHOR]

The objective of this research is to investigate the characteristics of the deformation response in adjacent subway tunnels caused by deep foundation excavation of reclaimed land. Focusing on a deep foundation excavation project situated in proximity to Line 11 of the subway in Shenzhen, this study employs theoretical analysis, numerical simulation, and on-site measurements to thoroughly investigate the deformation issues induced by the unloading of the excavation. The research results are as follows: using the energy method to calculate the uneven deformation of adjacent subway tunnels caused by the excavation can overcome the limitations of traditional algorithms, which treat the subway tunnel as a uniformly elastic foundation beam, resulting in more reasonable calculation results. Increasing the self-stiffness (EI)eq of the tunnel can effectively reduce the maximum displacement (wmax) of the tunnel, and as (EI)eq increases, its "weakening effect" on wmax gradually diminishes. Underground continuous walls can effectively control tunnel deformation, with tunnel displacement decreasing as the thickness and concrete strength of the continuous walls increase. "Long excavation" deep foundation excavations can impact the displacement and uplift range of the tunnel, with the maximum tunnel displacement showing a nonlinear decrease with increasing excavation depth. Tunnel displacement decreases as geotechnical parameters (elastic modulus E, internal friction angle φ, and cohesion C) increase, with the elastic modulus being the most sensitive parameter. The research findings can be applied to tunnel construction, maintenance, and safety evaluations, providing valuable references for similar engineering projects in the future. [ABSTRACT FROM AUTHOR]

A new π-conjugated bridging-type dicarboxylic acid with a functional alkynyl group, 4,4′-(ethynylimino)bis[benzoic acid] (H2L), was designed and synthesized to construct a Zn(II)-based coordination compound [ZnL(dpa)]n (dpa = 4,4′-dipyridylamine). Compound 1 has two-dimensional layers with alkynyl groups protruding on each side of the layer. The introduction of the ligand dpa ensured the existence of uncoordinated nitrogen atoms. Through Hg⋯C (alkynyl group) and Hg⋯N (amino group) coordination interactions, 1 can effectively detect Hg2+ ions (Ksv = 1.34 × 104 M−1 and LOD = 3.75 × 10−4 mM) by fluorescence quenching. Meanwhile, for Fe3+, in addition to the coordination interactions between Fe3+ ions and the uncoordinated amino groups, competitive absorption was the major contributor to the fluorescence quenching of compound 1. Competitive absorption prompted the sensitive sensing of Fe3+ (Ksv = 3.09 × 104 M−1 and LOD = 1.94 × 10−4 mM) and 4-nitrophenol (Ksv = 7.46 × 104 M−1 and LOD = 4.32 × 10−4 mM). [ABSTRACT FROM AUTHOR]

Currently, most wheel-legged robots need to complete the switching of the wheel-and-leg modal in a stationary state, and the existing algorithms of statically switching the wheel-leg modal cannot meet the control requirements of multimodal switching dynamically for robots. In this paper, to achieve efficient switching of the wheel-and-leg modal for a quadruped robot, the novel transformable mechanism is designed. Then, a multimodal coordination operation control framework based on multiple algorithms is presented, incorporating the minimum foot force distribution method (algorithm No.1), the minimum joint torque distribution method (algorithm No.2), and the method of combining the single rigid body dynamic model with quadratic programming (algorithm No.3). In the process of switching wheel-leg modal dynamically, the existing algorithm No.3 is prone to produce the wrong optimal force due to the change of the whole-body rotational inertia. Therefore, an improved algorithm No.1 and algorithm No.2 are proposed, which do not consider the change in the body's inertia. The control effects of the three algorithms are compared and analyzed by simulation. The results show that algorithm No.3 can maintain a small error in attitude angle and speed tracking regardless of whether the robot is under multilegged support or omnidirectional walking compared to the other two algorithms. However, proposed algorithms No.1 and No.2 can more accurately track the target speed when the robot is walking with wheels raising and falling. Finally, a multi-algorithm combination control scheme formulated based on the above control effects has been demonstrated to be effective for the dynamic switching of the wheel-and-leg modal. [ABSTRACT FROM AUTHOR]

Calcium ion batteries (CIBs) are considered as an important candidate for post‐lithium energy storage devices due to their abundance of resources and low cost. However, CIBs still suffer from slow kinetics due to the large solvation structure and high desolvation energy of Ca2+ ions. Here, a solvation regulation strategy based on donor number (DN) is reported to achieve easy‐desolvation and rapid storage of Ca2+ in sodium vanadate (Na2V6O16·2H2O, NVO). Specially, the solvent with a low DN, represented by propylene carbonate (PC), forms the first solvation shell of calcium ions with weak binding energy and small shell structure, which facilitates the migration of Ca2+ in the electrolyte. More importantly, the low DN solvent is preferentially desolvated at the cathode/electrolyte interface, promoting the insertion of Ca2+ into the NVO electrode. Mechanism studies further confirm the highly reversible uptake/release of Ca2+ in the NVO cathode, along with the VO distance change in the coordination structure. Therefore, the NVO cathode achieves high capacity (376 mAh g−1 at 0.3 A g−1) and high‐rate performance (151 mAh g−1 at 5 A g−1). The weak solvation effect strategy further improves the electrochemical performance and provides great importance for the design of the long‐term development of CIBs. [ABSTRACT FROM AUTHOR]

Background: Inflammation serves as a key pathologic mediator in the progression of infections and various diseases, involving significant alterations in the gut microbiome and metabolism. This study aims to probe into the potential causal relationships between gut microbial taxa and human blood metabolites with various serum inflammatory markers (CRP, SAA1, IL-6, TNF-α, WBC, and GlycA) and the risks of seven common infections (gastrointestinal infections, dysentery, pneumonia, bacterial pneumonia, bronchopneumonia and lung abscess, pneumococcal pneumonia, and urinary tract infections)., Methods: Two-sample Mendelian randomization (MR) analysis was performed using inverse variance weighted (IVW), maximum likelihood, MR-Egger, weighted median, and MR-PRESSO., Results: After adding other MR models and sensitivity analyses, genus Roseburia was simultaneously associated adversely with CRP (Beta IVW = -0.040) and SAA1 (Beta IVW = -0.280), and family Bifidobacteriaceae was negatively associated with both CRP (Beta IVW = -0.034) and pneumonia risk (Beta IVW = -0.391). After correction by FDR , only glutaroyl carnitine remained significantly associated with elevated CRP levels (Beta IVW = 0.112). Additionally, threonine (Beta IVW = 0.200) and 1-heptadecanoylglycerophosphocholine (Beta IVW = -0.246) were found to be significantly associated with WBC levels. Three metabolites showed similar causal effects on different inflammatory markers or infectious phenotypes, stearidonate (18:4n3) was negatively related to SAA1 and urinary tract infections, and 5-oxoproline contributed to elevated IL-6 and SAA1 levels. In addition, 7-methylguanine showed a positive correlation with dysentery and bacterial pneumonia., Conclusion: This study provides novel evidence confirming the causal effects of the gut microbiome and the plasma metabolite profile on inflammation and the risk of infection. These potential molecular alterations may aid in the development of new targets for the intervention and management of disorders associated with inflammation and infections., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2024 Liu, Zhu, Guo, Xie, Li, Lai, Wu, Wang and Zhong.)

Acetylene (C 2 H 2 ) monitoring in real time and online is essential for erasing transformer risks and guaranteeing normal equipment operation and operator safety. This study examines the direct fabrication of ultrathin SnO 2 nanowalls on Ag-Pd substrates using a simple solvothermal method that doesn't demand the use of any additional motivators or templates. The thickness and shape of the nanowalls can be controlled by varying the cetyl trimethyl ammonium bromide (CTAB) concentration in the solvent. As observed, the gas sensor (SnO 2 -3) fabricated by 2.4 g CTAB exhibits superior gas-sensing features. This is primarily due to the hollow structure constructed by the arrangement of nanowalls, which delivers not only enough gas diffusion pathways but also enough reaction sites during the gas sensing processes. The findings suggest that low-cost SnO 2 nanowalls created using a straightforward procedure could be taken into consideration as prospective candidates for use in industrial C 2 H 2 sensing applications., (© 2024 Wiley-VCH GmbH.)

Alkaline metal-air batteries are advantageous in high voltage, low cost, and high safety. However, metal anodes are heavily eroded in strong alkaline electrolytes, causing serious side reactions including dendrite growth, passivation, and hydrogen evolution. To address this limitation, we successfully synthesized an organic N-heterocycle compound (NHCC) to serve as an alternative anode. This compound not only exhibits remarkable stability but also possesses a low redox potential (-1.04 V vs. Hg/HgO) in alkaline environments. To effectively complement the low redox potential of the NHCC anode, we designed a dual-salt highly concentrated electrolyte (4.0 M KOH+10.0 M KCF 3 SO 3 ). This electrolyte expands the electrochemical stability window to 2.3 V through the robust interaction between the O atom in H 2 O molecule with the K + of KCF 3 SO 3 (H-O⋅⋅⋅KCF 3 SO 3 ). We further demonstrated the K + uptaken/extraction storage mechanism of NHCC anodes. Consequently, the alkaline aqueous NHCC anode-air batteries delivers a high battery voltage of 1.6 V, high-rate performance (101.9 mAh g -1 at 100 A g -1 ) and long cycle ability (30,000 cycles). Our work offers a molecular engineering strategy for superior organic anode materials and develops a novel double superconcentrated conductive salt electrolyte for the construction of high-rate, long-cycle alkaline aqueous organic anode-air batteries., (© 2024 Wiley-VCH GmbH.)