1. σ-hole effect of halogen-bonded cocrystals causing tunable photoelectric properties for photocatalytic uranium removal.
- Author
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Wu, Qiong, Li, Ya-Jie, Jiang, Qiao-Qiao, Wang, Ying-Ao, Zhang, Rui, Luo, Qiu-Xia, Ke, Hua, Liang, Ru-Ping, and Qiu, Jian-Ding
- Abstract
[Display omitted] • Cocrystals based on I-, Br-based halogen-bond donors and N-based halogen-bond acceptor were constructed. • Strength and density of σ-hole could affect degree of electron-hole separation and charge carrier transport. • Tuning photoelectric response of halogen-bonded cocrystals can be achieved employing the σ-hole effect. • Halogen-bonded cocrystals are enable to effectively photocatalytic reduce U(VI) of uranium contamination. The mechanism of how the internal composition of halogen-bonded cocrystals affecting photoelectric properties is ambiguous. Herein, we report a series of stable halogen-bonded cocrystals containing I-, Br-based halogen bond donors and N-based halogen bond acceptor. The halogen bonds served an intrinsic hub, and the two parts (donor and acceptor) were spliced into a highly ordered periodic network with a tight electronic configuration. The charge transfer within lattice induced by the σ-hole effect activates disparate photoelectric phenomena. The results uncover that the degree of photoelectric response of cocrystals can be adjusted rationally by manipulating the intensity and density of σ-holes with an atomic precision at the molecular level. The experimental and theoretical studies of the σ-hole effect pave the way to simplify the design principle of functional cocrystals. Eventually, benefiting from the fascinating photoelectric activity, halogen-bonded cocrystals exhibited excellent photocatalytic reduction ability of radionuclide uranium. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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