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Carbon sphere@layered double hydroxides filled cellulose nanofibers (ACS@LDHs/CNF) aerogel was successfully synthesized. The removal rate of Cr(VI) using ACS@LDHs/CNFs aerogel at a solid-liquid ratio of 1 g/L was 89.4%, which was higher compared to the removal rate of 65.2% using LDHs alone. The adsorption capacity of ACS@LDHs/CNFs for Cr(VI) was determined to be 44.9 mg/g. The adsorption kinetics followed the pseudo-second-order kinetic equation, and the isotherm data showed good agreement with the Langmuir model. The adsorption mechanism of Cr(VI) onto ACS@LDHs/CNFs aerogel was also investigated. Additionally, the ACS@LDHs/CNFs aerogel demonstrated consistent high adsorption efficiency over 4 consecutive cycles of adsorption-regeneration. [ABSTRACT FROM AUTHOR]

The density of the ocean varies unevenly along the vertical axis. In the presence of external disturbances, internal solitary waves (ISWs) are generated. The strong shear flow field induced by ISW seriously threatens the operational safety of marine structures. Therefore, it has become a hot spot to study the force law of marine structures in ISW. The existing studies are conducted when the ISW parameters are known. However, ISW is not visible in real situations, which leads to difficulties in obtaining ISW parameters. Therefore, it is of great engineering value to accomplish real-time force prediction of marine structures without knowing the ISW parameters in advance. To fill the gap, this study proposes a novel hydrodynamic prediction model with a sensor array as the sensing system and a deep learning algorithm as the decision-making system. The model successfully achieves accurate prediction of the shear stress on the cylinder in the ISW. In addition, a technique for optimizing sensor placement is proposed. This will help identify critical regions in the graphical representations to enhance exploration of flow field information. The results demonstrate that the prediction accuracy of the optimized sensor layout scheme surpasses that of randomly deployed sensors. As a result, this study will provide an important assurance for the safe operation of marine structures. [ABSTRACT FROM AUTHOR]

Understanding the spatial and temporal distribution of different paleontological communities in the southern South China Sea (SCS) is fundamental to explore its paleoclimatic and paleoenvironmental changes. In this study, foraminifera, pollen and diatoms from 100 surface sediment samples covering 40 000 km2 of sea floor in the southern SCS were comprehensively investigated in terms of their assemblage and distribution. The results showed the existence of abundant foraminifera and pollen in most of the samples, although diatom communities were relatively scarce. Foraminifera were dominated by G. sacculifer, G. menardii, G. ruber, while diatoms were characterized by T. simonsenii, T. nitzschioides and T. longissima, indicating a typical tropical marine environment. The pollen assemblages showed a better reflection of montane rainforest, tropical rainforest and mangrove. The spatial differences among foraminifera assemblages may indicate the effect of water depth and a warmer environment in the southeast part of the study area, while the spatial patterns of diatom and pollen assemblages imply the influence of coastal current. Our study also noted that the compositions of paleontological communities in the SCS can vary significantly in a short distance, and synthesized studies on multiple biological groups are needed to reconstruct the Quaternary climate and the oceanographic environment. [ABSTRACT FROM AUTHOR]

Observations of currents and temperatures from four moorings deployed around the deep slope (∼2500 m) of Caiwei Guyot in the Pacific Prime Crust Zone were utilized to investigate topographically trapped waves at low-latitude seamounts. Contrasting with commonly reported persistent diurnal seamount-trapped wave cases at middle and high latitudes, the subinertial variability in deep currents and temperatures at the slope of Caiwei Guyot was primarily characterized by two distinct lower-frequency bands (i.e., 13–24 and 3.3–4.7 days). These subinertial variabilities are interpreted as intermittent seamount-trapped waves and topographic Rossby waves (TRWs). During certain time periods, the observations include key signatures of seamount-trapped waves, such as near-opposite phases of azimuthal velocity (and temperature) on opposite flanks of the seamount, and patterns of temporal current rotation consistent with counterrotating cells of horizontal current propagating counterclockwise around the seamount. After comparing these observations to idealized seamount-trapped wave solutions, we conclude that the 13–24-day (3.3–4.7-day) energy is mainly due to radial–vertical mode 5 (3) for azimuthal wavenumber 1 (3). Sometimes the subinertial energy remained pronounced at only one flank of the seamount, primarily explained as TRWs with 192–379-m vertical trapping scale and 14–28-km wavelength. Upper-layer mesoscale perturbations might provide energy for deep seamount-trapped waves and TRWs. This study highlights the role of topographically trapped waves in modulating the deep circulation at low-latitude seamounts. [ABSTRACT FROM AUTHOR]

With the exploration, development, and research of deep‐sea resources, there is an urgent need for long‐term and continuous observation data of the deep‐sea seabed boundary layer. The traditional method of deep‐sea seabed survey and sampling based on scientific research vessels has the discontinuity of observation data in space and time scales. There are some problems in the seabed in situ observation method based on the seabed observation network for low mobility and high operation and maintenance costs, restricting the in‐depth understanding of the dynamic change process of the deep‐sea floor. To solve the above problems, an open and modular data acquisition control system was designed based on an embedded system and signal processing technology. In terms of the physical, chemical, geological, and ecosystem characteristics of the seafloor or near the seafloor boundary layer, various functional sensors and instrumentation were matched to form an independent underwater integrated measurement or experimental device, eventually realizing in situ multiparameter and long‐time series observations of the seafloor. The system data acquisition and control test were completed through laboratory experiments, which verified the feasibility of the system design. The research showed important theoretical and technical reference significance for the exploration and development of resources in the submarine boundary layer and the promotion of deep‐sea scientific research. [ABSTRACT FROM AUTHOR]

During the period from July 2016 to July 2018, a mooring system deployed in the central Andaman Sea recorded a significant number of highly intense mode-2 internal solitary waves (ISWs), with wave-induced current strengths comparable to those of local mode-1 ISWs. Distinct propagation characteristics and seasonal variations are uncovered, with mode-2 ISWs being identified as primarily propagating eastward and exhibiting a notable frequency peak from November to March. A significant correlation is established between the occurrence of mode-2 ISWs and higher-mode internal tides (ITs), particularly characterized by a high correlation with the third Empirical Orthogonal Function (EOF) mode. Combined with satellite remote sensing images, it is further confirmed that mode-2 ISWs are generated by the nonlinear steepening of ITs and propagate over long distances through resonance with higher-mode ITs. In contrast, our findings suggest that mode-1 ISWs are predominantly generated by the Lee-wave mechanism, especially south of the Ten Degree Channel, and typically propagate northeastward. This study underscores the complex interplay of ocean stratification and seabed topography in the genesis and propagation of ISWs. • A two-year long in-situ observation has been conducted on the strong mode-2 internal solitary waves in the central Andaman Sea. • The mode-2 internal solitary waves are primarily generated by the nonlinear steepening of internal tides in the Ten Degree Channel, while most mode-1 internal solitary waves originate south of the Ten Degree Channel, produced by the Lee-wave mechanism. • The internal solitary waves of both modes occur more frequently from November to March and less so from May to August. This is primarily attributed to the local oceanic stratification. • The resonant coupling between the mode-2 internal solitary waves and the higher-mode internal tides is the main reason for the stable propagation of the mode-2 internal solitary waves. [ABSTRACT FROM AUTHOR]

Understanding the controls on the sulfur isotope compositions of syndepositional pyrite (δ34S py) during early diagenesis is critical for environmental reconstructions, especially for the reconstruction of the marine sulfur cycle. Commonly, δ34S py values increase with depth in marine sediments; this phenomenon has been extensively studied, fostering the reconstruction of both global and regional depositional environments. However, more recently a decrease of δ34S py values with depth has been increasingly observed, but the corresponding controls on sulfur stable isotopes remain poorly constrained. This study investigated a gravity core collected from the northern continental slope of the South China Sea. Morphology, content, and δ34S values of pyrite, concentration and sulfur isotopic composition of porewater sulfate (δ34S SO4), carbon, nitrogen, and sulfur contents, and grain sizes of terrigenous sediments were analyzed and AMS14C dating of planktonic foraminifera was conducted. The δ34S py values were found to decrease with depth from −16.8‰ to −42.8‰, indicating low sulfur isotope fractionation (<38‰) during microbial sulfate reduction in the uppermost sediments and a larger fractionation (>64‰) at greater depth. Significant contributions of relatively 34S-enriched pyrite formed at shallow depth leads to overall δ34S py variations >26‰, whereby low δ34S py values coincide with higher sedimentation rates and higher organic matter supply. This study highlights the potential significance for relatively 34S-enriched, shallow-depth pyrite for δ34S py records, which may affect the reconstruction of depositional conditions and the global sulfur cycle. • Relatively 34S-enriched pyrite formed at shallow depth results from low sulfur isotope fractionation during MSR (<38‰). • Higher sedimentation rate and high organic matter supply led to lower δ34S py values. • Relatively 34S-enriched pyrite formed in uppermost sediments causes overall δ34S py variation >26‰. • δ34S py values provide new insight into the global sulfur cycle and past depositional processes. [ABSTRACT FROM AUTHOR]

Internal solitary waves are a special type of non-linear ocean internal waves. Due to their high peak and deep valley, they can cause motion instability and loss of control of submersibles. This work investigates the interaction between large-scale continuously stratified internal solitary waves and an advancing submersible. Based on the fully nonlinear internal solitary wave theory, i.e. Dubriel-Jacobin-Long (DJL) equation, combined with Computational Fluid Dynamics (CFD) simulation, a three-dimensional wave tank is established using an initial flow field wave-making method. The effects of three key parameters, namely submergence depth, wave amplitude, and advancing speed, on the motion response and load characteristics are studied. The results show that the submergence depth has a great influence on the motion response of the submersible, especially for the submersible near the pycnocline. The wave amplitude and advancing speed mainly affect the load on the submersible and the duration of wave-body interaction. Due to the flow characteristics of internal solitary waves, the submersible will experience a bow moment. If the buoyancy suddenly decreases, the submersible will lose its "support" of fluid and sink rapidly. The mechanism of the "falling deep" phenomenon is finally revealed. [ABSTRACT FROM AUTHOR]

Upward diffusion of dissolved methane and associated anaerobic oxidation of methane (AOM) coupled with microbial sulfate reduction (MSR) are widespread in normal hemipelagic sediments of continental margins. The occurrence of authigenic sulfur enrichment in such sediments is usually regarded as an indicator of AOM; however, extensive MSR and authigenic iron sulfide generation also occur in turbidites. Therefore, research attention should be directed toward determining the geochemical features of authigenic sulfur mineralization in methane-rich background sediments and turbidites. Here we report the sedimentology and geochemical composition of sediments from four piston cores (CL30, CL44, CL47, and CL3A) containing turbidite layers from methane-rich areas of the South China Sea. The turbidite layers were deposited at 17–15 kyr BP or earlier during the last glacial period and were located above the present sulfate–methane transition zone (SMTZ). The median grain size, proportion of sand-sized grains, and Si, Ti, K, and Zr contents show marked elevation in the turbidite layers compared with the background sediments, indicating the input of large amounts of terrigenous detrital matter with coarser grains. High total sulfur (TS) contents and low δ34S AIS values (AIS: acid-insoluble sulfur) (−35.2‰ to −26.1‰) are observed within turbidite layers relative to the background hemipelagic sediments in core CL44. These results suggest that intensive sulfidization occurred as a result of enhanced organoclastic sulfate reduction rates in turbidite horizons, which were probably caused by the resultant decrease in downward oxygen flux and waning bioturbation after rapid deposition of turbidites. In comparison, TS contents are higher and δ34S AIS values are positive (0.2‰–46.8‰) within the SMTZ on account of the rapid consumption of sulfate and build-up of isotopically heavier hydrogen sulfide pools via intensive AOM. Moreover, authigenic barium (Ba) enrichments commonly occur in the depth interval immediately above the SMTZ rather than within turbidite layers; therefore, they serve as a useful indicator of the position of the SMTZ. This study presents distinct differences in the geochemical compositions of turbidity deposits and methane-rich background sediments and highlights that a multi-proxy approach including sedimentological and geochemical analyses should be used to constrain the types of MSR in deep-sea sediments, given the common occurrence of turbidites and subsurface methane release in marginal deep-sea areas. It is also suggested that if applied with caution, S–C–Ba geochemical patterns can be used to identify palaeo-SMTZs and palaeo methane-rich zones in turbidite-containing strata. • Both authigenic sulfur enrichment occurred in turbidite and seep sediments in the SCS. • Sulfidization in turbidite layer may be characterized by OSR with high SRR. • Combined S, C, and Ba geochemical patterns can be used to identify turbidite and seeps. [ABSTRACT FROM AUTHOR]