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Biomass tar, an inevitable byproduct of biomass pyrolysis and gasification, poses a significant challenge due to its tendency to condense in pipelines, causing clogging and operational issues. Catalytic steam reforming can convert tar into syngas, addressing the tar issue while simultaneously producing hydrogen. However, the reforming catalyst is highly susceptible to deactivation by coking, especially when dealing with highly concentrated polymeric hydrocarbons such as tar. This study focused on enhancing the durability of tar-reforming catalysts. Nickel-based catalysts were prepared using carbon supports known for their high coking resistance, such as carbon black (CB), activated carbon (AC), and low-rank coal (LRC). Their performance was then tested for the steam reforming of high-concentration toluene, a representative tar. All three carbon supports (CB, AC, LRC) showed high catalytic performance with NiMg catalysts at 500 °C. Among them, the mesoporous CB support exhibited the highest stability when exposed to steam, with NiMg on CB (NiMg/CB) remaining stable for long-term continuous operation without any deactivation due to coking or thermal degradation. [ABSTRACT FROM AUTHOR]

As the global quest for sustainable energy keeps rising, exploring novel efficient and practical photocatalysts remains a research and industrial urge. Particularly, metal organic frameworks were proven to contribute to various stages of the carbon cycle, from CO2 capture to its conversion. Herein, we report the photo-methanation activity of three isostructural, nickel-based metal organic frameworks incorporating additional niobium, iron, and aluminum sites, having demonstrated exceptional CO2 capture abilities from thin air in previous reports. The niobium version exhibits the highest performance, with a CO2 to CH4 conversion rate in the order of 750–7500 µmol*gcatalyst−1*h−1 between 180 °C and 240 °C, achieving 97% selectivity under light irradiation and atmospheric pressure. The in-depth characterization of this framework before and after catalysis reveals the occurrence of an in-situ restructuring process, whereas active surface species are formed under photocatalytic conditions, thus providing comprehensive structure-performance correlations for the development of efficient CO2 conversion photocatalysts.This study correlates the structure and the CO2 photohydrogenation performance of a series of isostructural Ni-based MOFs. Comparative characterization reveals the occurrence of an in situ restructuring, yielding different surface active sites. [ABSTRACT FROM AUTHOR]