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The effect of pressure on Raman scattering (RS) in bulk H f S 2 is investigated under hydrostatic and non-hydrostatic pressure conditions. The RS line shape does not change significantly in the hydrostatic regime up to P = 9.6 GPa, showing a systematic blueshift of the spectral features. In a non-hydrostatic environment, seven peaks appear in the spectrum at P = 7 GPa, which dominate the RS line shape up to P = 10.5 GPa. The change in the RS line shape manifests a pressure-induced phase transition in H f S 2. The simultaneous observation of both low-pressure (LP) and high-pressure (HP) related RS peaks suggests the coexistence of two different phases over a wide pressure range. It is found that the HP-related phase is metastable and persists during the decompression cycle down to P = 1.2 GPa, while the LP-related features eventually recover at even lower pressure. The angle-resolved polarized RS performed under P = 7.4 GPa revealed a strong in-plane anisotropy of both the LP-related A 1 g mode and the HP peaks. The anisotropy is related to the possible distortion of the structure induced by the non-hydrostatic component of the pressure. The results are explained in terms of a distorted P n m a phase as a possible pressure-induced phase of H f S 2. [ABSTRACT FROM AUTHOR]

The effect of pressure on Raman scattering (RS) in bulk H f S 2 is investigated under hydrostatic and non-hydrostatic pressure conditions. The RS line shape does not change significantly in the hydrostatic regime up to P = 9.6 GPa, showing a systematic blueshift of the spectral features. In a non-hydrostatic environment, seven peaks appear in the spectrum at P = 7 GPa, which dominate the RS line shape up to P = 10.5 GPa. The change in the RS line shape manifests a pressure-induced phase transition in H f S 2. The simultaneous observation of both low-pressure (LP) and high-pressure (HP) related RS peaks suggests the coexistence of two different phases over a wide pressure range. It is found that the HP-related phase is metastable and persists during the decompression cycle down to P = 1.2 GPa, while the LP-related features eventually recover at even lower pressure. The angle-resolved polarized RS performed under P = 7.4 GPa revealed a strong in-plane anisotropy of both the LP-related A 1 g mode and the HP peaks. The anisotropy is related to the possible distortion of the structure induced by the non-hydrostatic component of the pressure. The results are explained in terms of a distorted P n m a phase as a possible pressure-induced phase of H f S 2. [ABSTRACT FROM AUTHOR]

Congestive heart failure (CHF) is a fatal disease with progressive severity and no cure; the hearts inability to adequately pump blood leads to fluid accumulation and frequent hospital readmissions after initial treatments. Therefore, it is imperative to continuously monitor CHF patients during its early stages to slow its progression and enable timely medical interventions for optimal treatment. An increase in interstitial fluid pressure (IFP) is indicative of acute CHF exacerbation, making IFP a viable biomarker for predicting upcoming CHF if continuously monitored. In this paper, we present an inductor-capacitor (LC) sensor for subcutaneous wireless and continuous IFP monitoring. The sensor is composed of inexpensive planar copper coils defined by a simple craft cutter, which serves as both the inductor and capacitor. Because of its sensing mechanism, the sensor does not require batteries and can wirelessly transmit pressure information. The sensor has a low-profile form factor for subcutaneous implantation and can communicate with a readout device through 4 layers of skin (12.7 mm thick in total). With a soft silicone rubber as the dielectric material between the copper coils, the sensor demonstrates an average sensitivity as high as -8.03 MHz/mmHg during in vitro simulations.

The search for magnetic topological materials has been at the forefront of condensed matter research for their potential to host exotic states such as axion insulators, magnetic Weyl semimetals, Chern insulators, etc. To date, the MnBi2nTe3n+1 family is the only group of materials showcasing van der Waals-layered structures, intrinsic magnetism and non-trivial band topology without trivial bands at the Fermi level. The interplay between magnetism and band topology in this family has led to the proposal of various topological phenomena, including the quantum anomalous Hall effect, quantum spin Hall effect and quantum magnetoelectric effect. Among these, the quantum anomalous Hall effect has been experimentally observed at record-high temperatures, highlighting the unprecedented potential of this family of materials in fundamental science and technological innovation. In this paper, we provide a comprehensive review of the research progress in this intrinsic magnetic topological insulator family, with a focus on single-crystal growth, characterization of chemical disorder, manipulation of magnetism through chemical substitution and external pressure, and important questions that remain to be conclusively answered.

[This corrects the article DOI: 10.3389/fnut.2022.926814.].

Ion wind propulsion systems have potential applications in the field of unmanned aerial vehicle due to their compactness, quiet operation, and simple design. Previous studies have focused on the influences of power source, electrode arrangement, size, and shape on the output thrust characteristics. However, few studies have been performed on the environmental conditions, which can be beneficial for the practical applications of ion wind aircraft in various climatic conditions. In this work, a measurement platform of the output characteristics of ion wind propulsion system under various environmental conditions has been established. The experimental pressure range was 1–0.7 atm, and the relative humidity (RH) range was 30%–92%. The effects of air pressure and humidity, and voltage level on the thrust, thrust-to-power radio (TPR) corona current have been investigated. The results showed that the corona current and thrust of the wire-wing electrode array decreased with RH within the range of 30%– to 80%. Under higher humidity, the corona current and thrust tend to increase at most voltage levels. Moreover, the thrust and current both decreased with reduced pressure when keeping the voltage-to-pressure ratio (U/P) unchanged. It was also found that the thrust was roughly proportional to the square of the pressure. Finally, the possible explanations of the coupled influences on the output characteristics were discussed. [ABSTRACT FROM AUTHOR]

Background: Most existing animal models of acute compartment syndrome (ACS) rely on exogenous manipulation of intra-compartmental pressures to model ACS. The purpose of the current study was to evaluate the endogenous effect of a blast injury on porcine lower leg intra-compartmental pressures (ICP). Methods: The hindlimb of juvenile Landrace pigs was fractured at the diaphyseal tibia and subjected to blasts of compressed air to mimic a blast injury. Injured and control legs underwent pre-operative continuous ICP monitoring. At 4.5 h post injury, the fracture was stabilized followed by closure of the anterior compartment fascia (continued compartment pressure model, CCPM) or four compartment fasciotomy. Pressure measurements were made after operative fixation. Select pigs in CCPM were harvested between 48 and 72 h post-injury to evaluate the duration of ICP elevation. Results: Post-injury, the model created significantly elevated ICP compared to control limbs (54.5 ± 18.2 vs. 18.2 ± 4.9 mmHg; p < 0.001). Operative fixation and anterior compartment fascial closure further increased the ICP (Mean: 87.4 ± 42.5 mmHg) relative to the pre-operative state (p = 0.037). Fasciotomy returned baseline compartment pressures (Mean: 13.7 ± 10.2 mmHg) which were equivalent to control limbs (p = 0.117). Pressure measurements at the time of delayed harvest (48–72 h) demonstrated that elevated ICP persisted following injury (69.7 ± 55.12 mmHg). Conclusion: The current study demonstrates that a pilot porcine blast model elevates ICP comparable to existing animal models of compartment syndrome without exogenous ICP manipulation. ICP remained elevated at 48–72 h in the absence of fasciotomy. [ABSTRACT FROM AUTHOR]

Introduction: Dysphagia after anti-reflux surgery (ARS) is one of the most common indications for re-operative anti-reflux surgery and a leading cause of patient dissatisfaction. Unfortunately, the factors affecting its development are poorly understood. We investigated the correlation between pre-operative manometric and the intra-operative impedance planimetry (EndoFLIP™) measurements and development of post-operative dysphagia. Methods: A review of patients who underwent index robotic ARS in our institution. Patients who underwent pre-operative manometry and intra-operative EndoFLIP™ were included in our study. Dysphagia was assessed pre-operatively and at 3-month after surgery. Results: Fifty-five patients (26.9%) reported post-operative dysphagia, and 34 (16.6%) reported new or worsening dysphagia. On pre-operative manometry, patients with post-operative dysphagia had a lower distal contractile integral [868.7 (IQR 402.2–1447) mmHg s cm vs 1207 (IQR 612.1–2111) mmHg s cm, p = 0.006) and lower esophageal sphincter (LES) pressure [14.7 IQR (8.9–23.6) mmHg vs 20.7 IQR (10.2–32.6) mmHg, p = 0.01] compared to those without post-operative dysphagia. They were also found to have higher pre-operative cross-sectional surface area (CSA) [83 IQR (44.5–112) mm2 vs 66 IQR (42–93) mm2, p = 0.02], and distensibility index (DI) [4.2 IQR (2.2–5.5) mm2/mmHg vs 2.9 IQR (1.6–4.6) mm2/mmHg, p = 0.003] compared to patients without post-operative dysphagia. Additionally, the decrease in CSA [− 34 (− 18.5, − 74.5) mm2 vs − 26.5 (− 10.5, − 53.7) mm2, p = 0.03] and DI [− 2.3 (− 1.2, − 3.7) mm2/mmHg vs − 1.6 (− 0.7, − 3.3) mm2/mmHg, p = 0.03] measurements were greater in patients with post-operative dysphagia. Conclusion: Patients who developed dysphagia post-operatively had poorer pre-operative motility and a greater change in LES characteristics intra-operatively. This finding suggests the utility of pre-operative manometry and intra-operative EndoFLIP in identifying patients at risk of developing dysphagia post-operatively. [ABSTRACT FROM AUTHOR]

Swirl stabilized combustion is a common technique used in gas turbine engine combustors and is accomplished by introducing swirl into the inlet flow, which enhances mixing and stabilizes the combustion event. Coaxial swirlers introduce the fuel and air axially through concentric inlets and use vanes to impart a tangential component to either the fuel, air, or both flows. The present study conducted a parametric analysis of coaxial swirler design by manufacturing an array of 14 coaxial swirlers scaled for use in low flow, small engine operations which incorporated the same base design but varied the swirl number, Sn, by changing the vane angle between 0 deg and 63 deg, vane count between four and ten, and vane shape between traditional and helical. Each design was experimentally evaluated using nonpremixed air and propane at different flow conditions to correlate swirler design with lean blowout limits, pressure loss, and flame liftoff. Lean blowout was primarily influenced by swirl number, while vane count and shape had significant impact at Sn = 0.8 but little impact at Sn = 1.5. Pressure loss was unchanged below a Sn of 0.6, and unlike lean blowout, Sn had little impact at 0.8 but significant impact at 1.5. Additionally, an initial equation correlating pressure loss with swirler number, vane count, and mass flowrate was developed. Finally, flame liftoff was mainly driven by swirl number, with vane count and shape the next significant design parameters. [ABSTRACT FROM AUTHOR]

Seasonal-based energy storage is expected to be one of the main options for the decarbonization of the space heating sector by increasing the renewables dispatchability. Technologies available today are mainly based on hot water and can only partially fulfill the efficiency, energy density and affordability requirements. This work analyzes a novel system based on pumped thermal energy storage (PTES) concept to maximize renewables and waste heat exploitation during summer and make them available during winter. Organic fluid-based cycles are adopted for the heat upgrade during hot season (heat pump (HP)) and to produce electricity and hot water during cold season (power unit (PU)). Upgraded thermal energy drives an endothermic reaction producing dehydrated solid salts, which can be stored for months using inexpensive and high energy density solutions. This paper focuses on thermodynamic cycles design, comparing the performance attainable with several working fluids. Two different configurations are investigated: coupled systems, sharing the fluid and heat exchangers in both operating modes, and decoupled systems. A preliminary economic assessment completes the study, including a sensitivity analysis on electricity and heat prices. Cyclopentane is identified as a promising working fluid for coupled systems, reaching competitive round trip efficiencies (RTEs), maximizing the ratio between performance and HX surfaces, without excessive turbomachinery volume ratios and volumetric flows. Economic analysis shows that solutions with lower efficiency, but also lower capital cost, can achieve competitive payback times (PBT). On the contrary, decoupled systems are less attractive, as they reach slightly higher thermodynamic performance, but require higher capital costs, possibly being of interest only in specific applications. [ABSTRACT FROM AUTHOR]

Dry low emissions (DLE) systems are well-known to be susceptible to thermoacoustic instabilities. In particular, transverse, spinning modes of high frequency may appear, and lead to severe damage in a matter of seconds. The thermoacoustic response of an engine is usually specific to the combustor geometry, operating conditions and difficult to reproduce at the lab-scale. In this work, details of high frequency dynamics (HFD) observed during the early development phase of a new DLE system are provided, where a multipeaked spectrum was noticed during testing. Beginning with an analysis of the measured pressure spectra from three different concepts, an analytical model of the clockwise and anticlockwise transverse waves was fitted to the experimental data using a nonlinear curve fitting approach to produce a simple yet useful understanding of the phenomena. A flamelet-based large eddy simulation (LES) of the entire combustion system was used to complement this analysis and confirm the mode shapes using dynamic mode decomposition (DMD). Both approaches independently identified a spinning second-order mode as the dominant one in the high frequency regime. The LES indicates the coupling of a distortion of swirl profile with a precessing vortex core as a possible cause for the onset of instability. With regard to modeling sensitivities, it is shown that subgrid scale combustion modeling has a strong impact on predicted amplitudes. Ultimately, a thickened-flame model with a modified efficiency function provided consistent results. [ABSTRACT FROM AUTHOR]

This is the first study where a single variable sweep of SN is conducted to assess its impact on lean blowout limits (LBO) in a liquid-fueled lean direct injection (LDI) combustor. This study uses a scaled NASA SV-LDI (Swirl Venturi--Lean Direct Injection) hardware and is concerned with the impact of swirl number on the lean blow-out limit of a single-element LDI system at atmospheric pressure. The swirl numbers (SN) were varied from 0.31 to 0.66 using continuously variable active swirl number control system that was developed in-house. It is shown that the minimum operating equivalence ratio is a linearly increasing function of swirl number. While previous literature agrees with the positive slope for this correlation, past work has suggested that the LBO limit is proportional to the swirler vane angle which is shown to be untrue for LDI systems. By actively varying the swirl number, it is proven that LBO is proportional to SN, and it is well known that SN is not proportional to swirler vane angle. Increased SN reduces LBO margin because the better-mixed, high swirl dilutes locally rich pockets of fuel-air mixture in a globally lean flow. In addition to a baseline venturi, which was scaled from NASA's geometry, two other venturis were tested. A low-pressure loss venturi with a large throat diameter showed poor blow-out performance whereas a parabolically profiled venturi improved LBO over the baseline for the same swirl number. [ABSTRACT FROM AUTHOR]

Owing to their high specific energy capabilities, ultramicrogas turbines (UMGT) are a high-potential technology to provide portable electric power supply for applications with demand of less than 1 kW. UMGT conceptual design is challenged by small-scale effects augmenting interdisciplinary dependencies leading to highly coupled, nonlinear component interactions. This work provides a novel approach to conceptual UMGT design by combining reduced order component and system modeling with constrained multi-objective optimization. Hereby, Part I presents integrated design and performance modeling of compressor, turbine, combustor, and generator. In Part II, the heat engine and generator modules are merged into a system framework by establishing conceptual UMGT rotor geometry and engine design. Following bearing selection and lifetime assessment, experimentally validated reduced order models are developed for heat transfer and rotordynamic analysis. Using the elaborated framework, a constrained multi-objective system optimization of a 300 W engine is performed based on ten design parameters and comparing SiAlON and Inconel 718 as potential rotor materials available for additive manufacturing. Hereby, bearing lifetime, system efficiency, and specific power are maximized while meeting rotordynamic, structural, and thermal requirements. Evaluating the results, interdisciplinary effects are highlighted, and two optimum engine configurations are suggested. [ABSTRACT FROM AUTHOR]

Ultramicrogas turbines (UMGTs) for electric power generation up to 1 kW are a viable replacement technology for lithium batteries in drones due to their high energy density. Previous research has shown that small-scale effects disqualify conceptual design practices applied to larger gas turbines owing to highly coupled, nonlinear component interactions. To fill this gap, we propose an interdisciplinary conceptual design and analysis framework based on reduced order models. To this end, the current work is divided into two parts covering component design and system integration, analysis, and optimization. In Part I, automated conceptual design of all engine subcomponents is elaborated facilitating interdependent reduced order models for compressor, turbine, combustor and high-speed generator while also considering additive manufacturing constraints. In a second step, the reduced order performance models are compared to computational fluid dynamics (CFD) Reynolds-averaged-Navier-Stokes (RANS) simulations of various turbomachinery geometries as well as experimental data of combustor and high-speed generator prototypes, showing good agreement and thus validating the component modules. In conclusion, the first part of this work elaborates an automated and efficient method to conceptual design of all components required for a functional UMGT. Since the strategy is applicable independent of component arrangement and engine layout, the proposed methods offer a universal framework for small gas turbine generators. [ABSTRACT FROM AUTHOR]

While the permeation mechanism of solute (e.g., ions and glucose) through biological membrane has been studied extensively, the mechanical role of water transport in intracellular phenomena has not received much attention. In the present study, to investigate the effect of water permeation on the intracellular pressure response, a novel permeation flux model through a biological membrane is developed by incorporating the coupling permeabilities (between water and ion fluxes) as the water-ion interaction in the ion channels. The proposed model is applied to a two-dimensional permeation problem of water and ions in a closed cell separated by a thin membrane. The permeation flux model reproduces the typical time response of intracellular pressure to action potentials with reasonable agreement with experimental results in the literature, indicating that the pressure response can be characterized by the following three parameters: water permeability, the mass ratio of water and ion, and the ratio of the permeation fluxes of water and ion. In particular, the permeation flux ratio plays an essential role in intracellular phenomena; depending on the value of the permeation flux ratio, the time lag between the action potential and the pressure response is 0.1 times smaller than that expected by the previous researchers, indicating that water transport associated with ions may trigger a pressure response. This study demonstrates the importance of water permeation in intracellular mechanical response through coupling of the fluid motion and electric fields. [ABSTRACT FROM AUTHOR]

Mechanical ventilation is a common invasive intervention in intensive care units. While respiratory failure remains the most common indication for mechanical ventilation, the application and indications of this intervention are far more variable. Ventilation causes marked alteration to human physiology and is associated with complications and iatrogenic injuries. This article highlights practical aspects of patient management during invasive ventilation. [ABSTRACT FROM AUTHOR]

The correlation between seismic and acoustic signals can be used to quantify the influence of earthquake ground motion on the output signals of infrasound sensors and thus evaluate the performance of infrasound sensors under field conditions. However, there have been relatively few studies, and earthquakes considered in those studies are large magnitude events. There remains a need to quantify correlation mechanisms at high frequencies using small earthquakes. In this study, we utilize a collocated seismoacoustic station BJT and a six-element infrasound array DQS to study different coupling mechanisms for infrasound sensors. From 2019 to 2021, 11 and 37 small magnitude earthquakes were detected by BJT and DQS, respectively. Seismoacoustic signals from these small magnitude earthquakes are used to compute the seismoacoustic spectral ratio and the observed spectral ratios are then compared with theoretical estimates. For local seismic-to-acoustic coupling (local infrasound), the highly local pressure field induced by high-frequency ground motion and the separation between seismoacoustic sensors reduce seismic and acoustic signal correlation, which prevents the use of small earthquakes in current studies. The seismic sensitivity of the infrasound sensor, MB3a is shown to be for ground acceleration or for ground velocity and may be an important source of high-frequency noise for an infrasound station using this sensor. Furthermore, an empirical relation is developed to constrain the characteristics of earthquakes that can generate coupled signals on the infrasound sensor. Our study complements previous work and provides insight into the improved interpretation of infrasound signals and methods of seismoacoustic station calibration. [ABSTRACT FROM AUTHOR]

Calender process is important to improve the mechanical and electrochemical properties of cathode materials. To explore pressure effect on structure and resistance of electrode powder, the morphology and surface area of lithium cobalt oxide (LCO) powder under different pressure are investigated. Meanwhile, the real‐time stress, density, and conductivity of LCO powder upon compaction are tested by a self‐made detection system. Moreover, the battery performance of LCO powder after compaction is compared in coin cells. This work elucidates the relationship between compaction density, powder resistance, and electrochemical performance of cathode materials for lithium‐ion batteries. [ABSTRACT FROM AUTHOR]

This paper presents an experimental investigation into lift generation during the tangential motion of an inclined surface over a compressible porous layer, focusing on an exceptionally slow sliding speed, a condition that has not been considered in previous studies. Specifically, we validated Pascovici's one-dimensional lubrication model for an inclined slider under the above condition. Additionally, we explore the use of woven fibrous material for soft porous lubrication, broadening the range of media for future studies. [ABSTRACT FROM AUTHOR]

Pitch bearings are the key components of wind turbines (WTs). The reliability of pitch bearings affects the electric energy output efficiency of WTs. Due to its large loading ability, constant contact angle and high stiffness, the three-row roller slewing bearing (TRSB) is becoming a more attractive choice as a pitch bearing, especially in large-scale WTs. The contact force and pressure distributions significantly affect the fatigue life of a three-row roller pitch bearing (TRPB). Therefore, it is essential to propose a precise calculation method for the contact force and pressure. The present work establishes a quasi-static five degree-of-freedom (DOF) mathematical model for TRPBs, in which the bearing under general loading conditions is considered. The influences of combined external forces, overturning moments and inner ring misalignment angle on the contact force and pressure distributions of TRPBs are comprehensively investigated. According to the analysis results, the overturning moment and axial force can significantly affect the number of load-carrying rollers in each row. Furthermore, a slight variation of the inner ring angular misalignment has a significant effect on the contact force and pressure of TRPBs. Finally, it is more prone to pressure concentration in the non-crowned roller than that in the crowned roller, especially in the case of the inner ring with a misalignment angle. Since the high calculation efficiency and accuracy, the proposed method has remarkable potential applications in the fatigue life prediction and design of TRPBs. [ABSTRACT FROM AUTHOR]

Peri-urban landscapes are transitional areas between urban and rural areas that are constantly changing. They are characterised by land use mixes and land cover changes, leading to significant changes in wildlife habitats. These changes, combined with an increasing anthropogenic presence, turn peri-urban landscapes into arenas of intensified human-wildlife interactions. In many scientifically documented cases, scientists are focusing on negative interactions. Furthermore, research about appropriate policy instruments for managing human-wildlife interactions is rare. This study focused on case studies and their characteristics from around the world on positive, neutral, or negative interactions between humans and wildlife at local level. In addition, influencing factors of human-wildlife interactions and policy instruments for managing human-wildlife interactions in peri-urban landscapes were addressed. A survey was conducted with an international group of scientists and practitioners working in this field. The results showed that various species were involved in human-wildlife interactions in peri-urban landscapes worldwide, with mammals as being the most common taxon. Contemporary changes in land use and land cover could be identified as a significant factor for increasing human-wildlife interactions in peri-urban landscapes. It can be highlighted that a policy mix consisting mainly of social and cultural instruments in combination with legal and regulatory instruments could be most suitable to address this situation. [ABSTRACT FROM AUTHOR]

In the current study, wedge effects on a planing hull's friction and pressure resistance components have been numerically investigated. This study also assesses how the variation of pressure and friction resistance components can be predicted by trim angle variation. The obtained results indicate that at $Fr_b \lt 0.9$ F r b < 0.9 , stern wedges slightly increase the vessel's pressure resistance. By increasing the speed, pressure, and friction resistance components of the wedge-mounted model descends and increases, respectively, compared to the baseline model. The results indicate that the wedge-mounted planing hull experience a decrease in pressure resistance of up to 27% and an increase in friction resistance of up to 34%. After $Fr_b = 2.15$ F r b = 2.15 , some interaction effects between the wedge length and height on the total and pressure resistance appear. The findings also indicate that wedge effects on the planing hulls' pressure and friction resistance components are much different from those of displacement hulls. [ABSTRACT FROM AUTHOR]

Background: To discuss whether decreasing the pressure of endotracheal tube cuff slowly with a constant speed can decrease the incidence of coughing during extubation. Methods: Ninety patients undergoing elective noncardiac surgery under general anesthesia with endotracheal intubation were randomly divided into two groups: group P, the pilot balloon was connected to a syringe and an aneroid manometer through a three-way stopcock, respectively, and the decrease of cuff pressure was controlled at 3 cmH2O/s during deflating before extubation; group C, the pressure in endotracheal tube cuff was decreased suddenly with a syringe extracting the air from the cuff rapidly at once exactly before extubation. The incidence of coughing during extubation period was recorded. Mean arterial pressure (MAP) and heart rate (HR) were recorded before general anesthesia induction (T0), just before cuff deflation (T1), immediately after deflation (T2), at 1 min (T3), 3 min (T4), and 5 min after extubation (T5). The occurrence of adverse reactions was also recorded. Results: The initiation of coughing during extubation period occurs at immediately the time of balloon deflation. Compared with group C, the incidence of coughing was significantly decreased (P = 0.001), MAP and HR were significantly decreased at T2-T4 and T2-T5, respectively (P < 0.05 for all), and the incidence of pharyngolaryngeal discomfort after extubation was significantly reduced (P = 0.021) in group P. Conclusions: Decreasing the pressure of endotracheal tube cuff slowly with a constant speed can significantly reduce the incidence of coughing during extubating period, stabilize hemodynamics, and reduce the incidence of adverse reactions. [ABSTRACT FROM AUTHOR]

In this paper, we report the optoelectronic, thermoelectric properties and dynamic stability under the pressure of LiGaC half-Heusler within the Density Functional Theory (DFT) and semi-classical Boltzmann Transport Theory (BTT). The obtained results of the ground state show that the compound is structural, chemical, mechanical and dynamically stable in type I structure and maintains its stability under pressure. The obtained electronic properties reveal that the compound has a semiconducting nature with an indirect bandgap and the bandgap values slightly increase with pressure increase. The optical properties such as real and imaginary parts of dielectric function, refractive index and extinction coefficient, reflectivity and absorption coefficient and optical conductivity are calculated and discussed. The highest peaks of reflectivity and absorption coefficient are found in the ultra-violet (UV) region, suggesting that the compound LiGaC has a high potential for use in UV optoelectronic applications. The thermoelectric properties are also calculated in the temperature range from 300 K to 900 K and pressure range from 0 GPa to 40 GPa. At 300 K and for all pressures selected, the maximum value of figure of merit is close to unity. Finally, we could make our conclusion that LiGaC is well suitable for multiple optical and thermoelectric applications. [ABSTRACT FROM AUTHOR]

Nonwovens have wide application areas due to their advantageous properties like low cost, high production efficiency, and tuneable properties. They are mostly used for disposable products. Combining bicomponent fiber spinning with hydroentanglement method is one of the innovative methods to obtain nonwovens for durable applications. On the other hand, ultrasonic welding is an alternative assembling method for disposable products made of low weight nonwovens. In this study, the ultrasonic weldability of relatively heavier weight and thicker nonwoven fabrics made of polyester: polyamide bicomponent microfilaments were examined in order to combine the advantages of nonwovens and ultrasonic welding. Relatively higher thickness and weight, and also fiber composition of the nonwoven fabrics were compelling effects of the study that drove the motivation. Overall 60 samples were produced using five nonwoven fabrics with varying unit masses and 12 selected ultrasonic welding types. Seam strength and strain assessments were supported with stereomicroscope and visual inspections in evaluating the welds. Results showed that despite having thick seam lines up to 1.6 mm, successful welded seams could be obtained. Depending on the welding parameters, seam lines of some samples exhibited waviness, color changes, and deformations but these situations did not drastically affect the seam strength of samples. [ABSTRACT FROM AUTHOR]

Introduction While the 44-mm clay penetration criterion was developed in the 1970s for soft body armor applications, and the researchers acknowledged the need to conduct additional tests, the same behind the armor blunt trauma displacement limit is used for both soft and hard body armor evaluations and design considerations. Because the human thoraco-abdominal contents are heterogeneous, have different skeletal coverage, and have different functional requirements, the same level of penetration limit does not imply the same level of protection. It is important to determine the regional responses of different thoraco-abdominal organs to better describe human tolerance and improve the current behind armor blunt trauma standard. The purpose of this study was to report on the methods, procedures, and data collected from swine. Materials and Methods Live swine tests were conducted after obtaining approvals from the local institution and the Army Care and Use Review Office of the U.S. Department of Defense. Trachea tubes and an intravenous line were introduced before administering anesthesia. Pressure transducers were inserted into the lungs and aorta. An indenter simulating the backface deformation profiles produced by body armor from military-relevant ballistics to human cadavers was used to deliver impact loading to the liver region. A triaxial accelerometer was included in the indenter design. The animals were monitored for 6 hours, necropsies were performed, and injuries were identified. Biomechanical data of the energy, velocity, deflection, viscous criterion, force, and impulse variables were obtained for each test. Results Peak accelerations, velocities, deflections, forces, impulse, and energies ranged from 897 to 5,808 g, 21 to 59 m/s, 1.96 to 8.87 cm, 2.3 to 13.1 kN, 1.1 to 7.1 Ns, and 58 to 387 J, respectively. The peak viscous criterion ranged from 0.8 to 5.8 m/s. All animals survived the 6-hour survival period. Three animals responded with liver lacerations while the remaining 4 did not have any injuries. Conclusion The experimental design based on parallel tests with whole body human cadavers and cadaver swine was found to be successful in delivering controlled impacts to the liver region of live swine and reproducing liver injuries. Previously used biomechanical measures as potential candidates for injury criteria development were obtained. Using this proven model, tests with additional samples are needed to develop injury risk curves for liver impacts and obtain regional (liver) injury criteria. [ABSTRACT FROM AUTHOR]

Objective: Although it has been suggested that a decline in oral function is one of the potential risk factors affecting mild cognitive impairment (MCI), evidence is insufficient to draw clear conclusions. This Japanese cross‐sectional study examined the association between tongue pressure (TP) and MCI in middle‐aged and older adults aged 36–84 years. Methods: Study participants were 1019 (368 men and 651 women). TP was evaluated using a TP measurement device. The maximum value of three measurements was used for analysis. MCI was defined as being present if a participant had a Japanese version of the Montreal Cognitive Assessment score of <26. Adjustment was made for age, smoking status, alcohol consumption, leisure‐time physical activity, body mass index, hypertension, dyslipidemia, diabetes mellitus, history of depression, number of teeth, employment, education, and household income. Results: The prevalence of MCI was 45.3%. Among women, compared with the lowest tertile of TP, the second and highest tertiles were significantly associated with a lower prevalence of MCI with a clear dose–response relationship; the adjusted odds ratio (95% confidence intervals) in the second and highest tertiles of TP were 0.54 (0.36–0.83) and 0.55 (0.36–0.84), respectively (p for trend = 0.005). In contrast, no statistically significant association was observed between TP and the prevalence of MCI among men. Conclusions: Our findings suggest that higher TP might be inversely associated with the prevalence of MCI in middle‐aged and older Japanese women. [ABSTRACT FROM AUTHOR]

The primary purpose of this study is the reduction of local entropy production in a contra-rotating stage. As such, the unsteady flow phenomena and the impact of radial load distribution on these phenomena and local entropy production need to be clarified. In this study, the stress-blended eddy simulation (SBES) turbulence model is utilized to capture the vortices in the flow separation zone, and the γ-Reθ transition model is employed to predict the transition phenomenon within the boundary layer. Entropy production rate models suitable for different turbulence models are constructed separately to calculate local entropy production. Vortex visualization is achieved according to the λci criterion, and the relative vorticity change rate is used to analyze the components of the tip clearance vortices. The transition phenomenon is analyzed from the perspectives of both the Euler and the Lagrange descriptions. The primary findings can be summarized as follows: the transition begins earlier and progresses more rapidly in the rear rotor. Wake propagation, occurring at double the frequency, entropy production rate within the boundary layer changes in synchrony with the wall shear stress at the same frequency. Additionally, an investigation of the tip clearance vortices concludes that the main structure of the tip clearance vortices coincides with the flow pattern of the high entropy production rate region, and the flow structure related to the high divergence area is essential for considering subsequent optimization with the aim of reducing the entropy production rate. [ABSTRACT FROM AUTHOR]

This study investigates turbine rim seal geometry effects within the rotationally-driven ingestion regime. Computations were performed with a wall-resolved unsteady Reynolds-averaged Navier-Stokes (URANS) model and a large-eddy simulation (LES) model including near-wall boundary layer modeling, that is, wall-modeled LES (WMLES). Use of simplified rim sealing models is proposed as an efficient method of ranking seal designs and investigating sensitivity to seal geometry. Four rim seal configurations, two chute seals, an axial seal and a radial seal which are representative of those used in gas turbines and in previous research were investigated. Furthermore, hybrid seals combining geometric characteristics from both the chute and radial seal were considered. Significant sensitivities of sealing performance to turbulence modeling are identified, but URANS and WMLES show similar trends in ranking of seal performance, and these are consistent with previous experimental work. The addition of an outer radial clearance section to a chute seal is effective in reducing ingestion levels. [ABSTRACT FROM AUTHOR]

Micro gas turbines (mGT) have not yet succeeded in conquering the small-scale combined heat and power (CHP) market. One reason is that their electrical efficiency is not high enough to maintain a cost-effective operation. A two-shaft intercooled mGT has the potential to meet the current market demand. This technology maintains a high electrical efficiency even at part-load and coupled with its fuel-flexible combustion chamber, it is an ideal candidate for CHP concepts in a renewable future. In this paper, performance analysis on two-spool mGT is carried out with various fuel blends. Attention is given to the low-pressure and high-pressure compressors and the variation of surge margin by adding hydrogen and syngas. Two control strategies for the mGT are adopted. In the first scenario, the two shafts have equal rotational speeds while in the second, the speeds are controlled independently. As the engine is operated at equal speeds, the maximum performance with 100 vol. % of syngas is observed at 85% of the nominal load while 100 vol. % of hydrogen shows maximum efficiency at a load of 63.7%. At electric power lower than 60% and for high amounts of syngas in natural gas, the low-pressure compressor (LPC) operates closely to surge line. In the second scenario, the efficiency increases as the load decreases and the LPC runs in an efficient and safe operating region. Additionally, the amount of nitrogen in syngas affects the part-load performance of the two-spool mGT. [ABSTRACT FROM AUTHOR]

The predictive capability of the lattice-Boltzmann very large eddy simulation (LBM-VLES) methodology was evaluated for industrial gas turbine exhaust diffuser-collector applications. The effort focused on evaluating the accuracy of performance predictions against experimental rig data gathered at engine representative conditions including the Reynolds number, Mach number, and inlet flow conditions. The performance prediction capability of LBM-VLES simulations was also compared against Reynolds-averaged Navier-Stokes (RANS) simulations. Evaluations were completed for two distinct exhaust rig geometries at conditions indicative of their respective design points, and the performance prediction capability was also evaluated at conditions depicting two off-design cases. The off-design conditions were represented by an increase in inlet swirl angle and associated incidence on the diffuser struts. Overall, the authors found that LBM-VLES simulations were a suitable approach for predicting the performance of gas turbine exhaust diffuser-collector systems at both on- and off-design conditions. The LBM-VLES simulation accuracy was substantially better than that achieved by RANS simulations, with 66% lower RMS pressure recovery error between computational fluid dynamics (CFD) and experiments for the four cases studied, and an 89% reduction in error for the furthest off-design case. The computational cost of the transient LBM-VLES simulations was roughly the same as the RANS simulations performed using best practices for that solver. [ABSTRACT FROM AUTHOR]

In Part I, a companion paper of the two-part article, a subsonic turbine stage and a transonic one conditioned at the same Reynolds number, flow coefficient, loading coefficient and reaction, but two different exit Mach numbers are designed to provide a direct contrast between a high-subsonic and a transonic flow conditioning for rotor blade squealer tips. In this paper as Part II, further analyses are carried out to address the main issues of interest arising from Part I: first, to identify the driving flow physical mechanisms for the contrasting aerodynamic efficiency sensitivities of the two stages; second to seek a more suitable heat transfer objective function for the tip aerothermal design optimization, given the seemingly strong conflicts among those conventionally adopted heat transfer objective functions. Two counter-rotating tip vortical structures, the pressure side vortex (PSV) and the casing-driven cavity vortex (CCV), are shown to impact the aero-performance differently between the two stages. For the subsonic stage, the leakage flow is strongly affected by a stronger residual PSV at the squealer cavity exit. For the transonic stage however, the tip choking in limiting the over tip leakage (OTL) mass flow and favorable pressure gradient in a transonic flow over a separation bubble led to a much stronger and more persistent CCV and thus lower aero-effectiveness of squealer tip for the transonic stage. The two vortices also show major heat transfer signatures on the cavity surfaces by impingement. For the PSV, the impingement impact is mainly on the cavity floor. For the CCV, on the other hand, its impact is mainly on the inner side-wall of the suction side rim. The latter is found to be mainly responsible for the overall linear variations of the heat load with the squealer height. Again, the relative strength between PSV and CCV serves as an effective differentiator in the heat transfer performance. The stronger and more persistent CCV in the transonic stage results in a strong signature on a large portion of the suction side cavity inner sidewall, thus a much higher increment in heat transfer with the squealer height than that for the subsonic stage. In seeking to establish a more consistent heat transfer objective function for combined aerothermal design and optimization, a coolability weighted nonuniformity parameter is proposed to integrate the local heat transfer and the coolability. The proposed objective function is shown to lead to consistent Pareto fronts for the combined aerothermal performance sensitivities, particularly for the present cases with strong heat transfer nonuniformity which are particularly challenging to those conventional treatments as shown in Part I. The coolability-augmented objective function should thus serve as an enabler to help practical applications of blade tip aerothermal design optimizations. [ABSTRACT FROM AUTHOR]

Gold-assisted exfoliation can fabricate centimeter- or larger-sized monolayers of van der Waals (vdW) semiconductors, which is desirable for their applications in electronic and optoelectronic devices. However, there is still a lack of control over the exfoliation processes and a limited understanding of the atomic-scale mechanisms. Here, we tune the MoS2-Au interface using controlled external pressure and reveal two atomic-scale prerequisites for successfully producing large-area monolayers of MoS2. The first is the formation of strong MoS2-Au interactions to anchor the top MoS2 monolayer to the Au surface. The second is the integrity of the covalent network of the monolayer, as the majority of the monolayer is non-anchored and relies on the covalent network to be exfoliated from the bulk MoS2. Applying pressure or using smoother Au films increases the MoS2-Au interaction, but may cause the covalent network of the MoS2 monolayer to break due to excessive lateral strain, resulting in nearly zero exfoliation yield. Scanning tunneling microscopy measurements of the MoS2 monolayer-covered Au show that even the smallest atomic-scale imperfections can disrupt the MoS2-Au interaction. These findings can be used to develop new strategies for fabricating vdW monolayers through metal-assisted exfoliation, such as in cases involving patterned or non-uniform surfaces. [ABSTRACT FROM AUTHOR]

Heterochrony acts as a fundamental process affecting the early development of organisms in creating a subtle shift in the timing of initiation or the duration of a developmental process. In flowers this process is linked with mechanical forces that cause changes in the interaction of neighbouring floral organs by altering the timing and rate of initiation of organs. Heterochrony leads to a delay or acceleration of the development of neighbouring primordia, inducing a change in the morphospace of the flowers. As changes in the timing of development may affect organs differently at different stages of development, these shifts eventually lead to major morphological changes such as altered organ positions, fusions, or organ reductions with profound consequences for floral evolution and the diversification of flowers. By concentrating on early developmental stages in flowers it is possible to understand how heterochrony is responsible for shifts in organ position and the establishment of a novel floral Bauplan. However, it remains difficult to separate heterochrony as a process from pattern, as both are intimately linked. Therefore it is essential to connect different patterns in flowers through the process of developmental change. Examples illustrating the importance of heterochronic shifts affecting different organs of the flower are presented and discussed. These cover the transition from inflorescence to flower through the interaction of bracts and bracteoles, the pressure exercised by the perianth on the androecium and gynoecium, the inversed influence of stamens on petals, and the centrifugal influence of carpels on the androecium. Different processes are explored, including the occurrence of obdiplostemony, the onset of common primordia, variable carpel positions, and organ reduction and loss. [ABSTRACT FROM AUTHOR]

Interacting particle systems in a finite-volume in equilibrium are often described by a grand-canonical ensemble induced by the corresponding Hamiltonian, i.e. a finite-volume Gibbs measure. However, in practice, directly measuring this Hamiltonian is not possible, as such, methods need to be developed to calculate the Hamiltonian potentials from measurable data. In this work, we give an expansion of the chemical potential in terms of the correlation functions of such a system in the thermodynamic limit. This is a justification of a formal approach of Nettleton and Green from the 50’s, that can be seen as an inverse cluster expansion. [ABSTRACT FROM AUTHOR]

This research proposes a robust method for designing functionally graded disks subject to internal and external pressures. The design objective is to find the profile of equi-strength disks. The von Mises yield criterion controls the initiation of plastic yielding. The yield stress and Young's modulus are entirely arbitrary functions of the polar radius. Poisson's ratio is constant. The solution is facilitated using the dimensionless yield stress as an independent variable instead of the polar radius. In particular, a numerical technique is only required to solve two ordinary differential equations. Moreover, one of these equations is independent of the other. Therefore, the equations can be solved individually, simplifying the solution method. The limitation imposed by the thickness gradient on the acceptability of plane stress conditions is considered. Particular designs are proposed assuming that the power function describes the radial distribution of material properties. A critical condition that allows for deriving relatively simple design solutions is emphasized. It is shown that this condition is satisfied for many specific material property distributions used in the literature. [ABSTRACT FROM AUTHOR]

The aim of this study was to analyse the effect of swimming goggles on swimming hydrodynamics by numerical simulations. An elite swimmer volunteered for this research. The swimmer's head was scanned both without goggles, and while wearing 3 different types of goggles (Nikko, Ankor and Swedish). Numerical simulations were conducted at 2 m/s with the Fluent code. The condition without goggles showed the highest viscous drag (1.65 N), followed by the Ankor (1.64 N), Swedish (1.63 N) and Nikko (1.62 N) goggles, respectively. The highest pressure drag was found in the situation without goggles (11.34 N), followed by the Ankor (10.87 N), Nikko (10.78 N) and Swedish (10.20 N) goggles. The condition without goggles presented the highest total drag (12.99 N), followed by the Ankor (12.52 N), Nikko (12.40 N) and Swedish (11.83 N) goggles. Thus, Swedish goggles yields the best hydrodynamics, followed by the Nikko and Ankor goggles and lastly without goggles. Thus, goggles minimise the swimmer's drag comparing to not wearing any. The design of the goggles may impose varying drag forces and therefore it is advised to use goggles at least in competition. [ABSTRACT FROM AUTHOR]

"Double-loop" theory was determined by deriving a correlation between turbulent fluctuating kinetic energy and water vapor volume fraction from the momentum equation, which further logically revealed the mystery of cavitation breaking around a three-dimensional symmetry hydrofoil based on the numerical results of large eddy simulation and Zwart-Gerber-Belamri cavitation model. When the second-order fluctuation moment V'xV'x and the streamwise velocity Vx are depleted, a vortex is generated, leading to alternating cavitation interface fluctuations. In one state, cavitation naturally breaks outward from the inner zone, triggering an up-and-down fluctuation in the normal velocity in the gap vortex and transferring external energy to the inner zone. In another state, cavitation collapse caused by a reentrant jet stagnates the reverse Vx so that V'xV'x tends to zero. It triggers a rise in an upward normal velocity in the attached vortex, creating an exchange of energy through the wake. The pressure implosion resulting from the Shrinkage of the "Like-Rayleigh-Plesset" cavity at the cavitation onset is stronger than the pressure implosion created by the vortex field during cavitation breaking. [ABSTRACT FROM AUTHOR]

Bernoulli pads are traditionally used for noncontact pick-and-place operations in industry. The normal force produced by a Bernoulli pad allows it to adhere to an object or workpiece. In addition to the normal force, the pad produces shear forces, which allows it to clean a workpiece without contact. A direct relationship between the inlet fluid power and the shear losses motivates us to explore other methods of providing power to the system with the objective of increasing shear forces and thereby improving cleaning efficacy. Here, we numerically investigate a system in which additional mechanical power is added by rotating the Bernoulli pad. The rotating system provides additional fluid forces (normal and shear) for the same inlet fluid power. For a specific pad that we investigated, the maximum wall shear stress increased by ≈15% and the normal force changed from +1.4 N (repulsive) to -6.6 N (attractive) for change in the rotational speed by 60 rad/s. Also, for a given normal attractive force, a stable equilibrium configuration can exist for two mass flow rates, with the higher mass flowrate resulting in a higher stiffness of the flow field. [ABSTRACT FROM AUTHOR]

Direct dry-cooled power plants typically operate numerous large-diameter axial flow fans in air-cooled condensers (ACCs) to facilitate the condensation of steam in the plant's thermodynamic cycle. Enhanced fan efficiency may, at scale, lead to significant parasitic power reductions and subsequent increases in plant power output. The performance of these fans may be increased by adding blade-tip modifications, which act to control blade-tip leakage flow. Previous studies have shown that manipulating the tip leakage vortex (TLV) increases the blade-to-air momentum transfer and stabilizes the air flow structures as it traverses the fan blade. This paper takes a step toward the development of improved tip vortex manipulators for an ACC fan. Three-dimensional computational fluid dynamics (CFD) simulations, and experimental testing of the modified and unmodified fan within an ISO test facility are performed. The results are then utilized to assess the accuracy of the simulation model, visualize the manipulated flow structures at the blade tip, and ultimately quantify the effect of the endplate designs on fan performance. Excellent correlation between numerical and test results for the unmodified fan is observed, and the benefit of blade-tip modification on fan performance is again confirmed experimentally. The simulation model, however, fails to predict improvements in fan performance under modification, and simulated tip leakage flows are investigated for clarification. It is hypothesized that deflection of tip endplates under operation account for differences between simulation and experiment, and that fluid-structure interaction analyses could potentially resolve discrepancies. [ABSTRACT FROM AUTHOR]

Under unsteady operating conditions in turbomachinery, the performance is unable to respond rapidly enough to follow characteristic curves for the steady condition. To design a reliable turbomachinery under unexpected unsteady conditions, we evaluated the dynamic transfer matrix of a three-dimensional centrifugal impeller. The working fluid is incompressible air. To make the current results more applicable in a broader sense such as pumps, all parameters and results were normalized. The experimental results showed a more significant negative slope in the unsteady performance curve compared to that in the steady performance curve. This was mainly caused by the phase delay of the pressure rise to the pulsating flowrate. We clarified the changes in gain and phase delay under unsteady conditions by conducting numerical simulations. The numerical results showed that the unsteady pressure rise was primarily generated by inertia and power terms in the unsteady energy conservation equation. The power term was predominantly influenced by the angular momentum flowrate difference and the change rate of angular momentum. Each term was quantitatively evaluated, and its contribution to the unsteady pressure rise was discussed. Within the range of frequencies tested in this study, the transfer matrix for the three-dimensional centrifugal impeller could be effectively approximated through a first-order lag approximation considering a series-connected derivative system. We believe that our findings can be extended to centrifugal pumps when disregarding the compressibility effects such as cavitation. [ABSTRACT FROM AUTHOR]

Equations of plasticity of a porous body proposed by different authors and obtained under the condition that the yield surface of a porous body has the shape of an ellipsoid of revolution are considered in this paper. Such equations have two independent parameters which are the functions of relative density. Various theoretical dependences of these parameters on the relative density and, as a result, various equations for describing the die-compaction of powders are presented. It is shown that the correction of two density-dependent parameters, taking into account the initial density, makes it possible to significantly increase the accuracy of approximation of experimental data on the powder compaction process (PCP) of various powders. Among the considered "continuum" equations of powder die-compaction, the PCP to a density of 0.95 is the most accurately described by the equation in which the corrected Skorokhod's theoretical density functions are used and which contains one constant as a result. Another equation which contains four constants allows one to accurately (R2 > 0.9990–0.9999) describe the PCP to a density of >0.95. This equation is obtained by replacing one of two independent parameters in the traditional continuum equation with the lateral pressure coefficient followed by substituting, instead of those parameters, their dependencies on the density in the form of power function. The adequacy of the PCP description by this equation was verified by approximating experimental data on the die-compaction of iron powders to a relative density greater than 0.95, as well as highly plastic powders with a final density of ~1.0. [ABSTRACT FROM AUTHOR]

Radical or partial nephrectomy, commonly used for the treatment of kidney tumors, is a surgical procedure with a risk of high blood loss. The primary aim of this study is to quantify blood loss and elucidate the redistribution of blood flux and pressure between the two kidneys and the abdominal aorta during renal resection. We have developed a robust research methodology that introduces a new lumped-parameter mathematical model, specifically focusing on the vasculature of both kidneys using a non-Newtonian Carreau fluid. This model, a first-order approximation, accounts for the variation in the total impedance of the vasculature when various vessels are severed in the diseased kidney (assumed to be the left in this work). The model offers near real-time estimations of the flow–pressure redistribution within the vascular network of the two kidneys and the downstream aorta for several radical or partial nephrectomy scenarios. Notably, our findings indicate that the downstream aorta receives an approximately 1.27 times higher percentage of the redistributed flow from the diseased kidney compared to that received by the healthy kidney, in nearly all examined cases. The implications of this study are significant, as they can inform the development of surgical protocols to minimize blood loss and can assist surgeons in evaluating the adequacy of the remaining kidney vasculature. [ABSTRACT FROM AUTHOR]

High-density polyethylene (HDPE) pipes have gradually become the first choice for gas networks because of their excellent characteristics. As the use of pipes increases, there will unavoidably be a significant amount of waste generated when the pipes cease their operation life, which, if improperly handled, might result in major environmental contamination issues. In this study, the thermal degradation of polyethylene materials is simulated for different pressures (10, 50, 100, and 150 MPa) and temperatures (2300, 2500, 2700, and 2900 K) in the framework of Reactive Force Field (ReaxFF) molecular dynamics simulation. The main gas products, density, energy, and the mean square displacement with temperature and pressure are also calculated. The findings indicate that raising the temperature leads to an increase in the production of gas products, while changing the pressure has an impact on the direction in which the products are generated; the faster the temperature drops, the less dense the air; both temperature and pressure increase impact the system's energy conversion or distribution mechanism, changing the system's potential energy as well as its total energy; the rate at which molecules diffuse increases with temperature, and decreases with pressure. The results of this investigation provide a theoretical basis for the development of the pyrolytic treatment of polyethylene waste materials. [ABSTRACT FROM AUTHOR]

Drought dynamics can be significantly influenced by conflicts, while drought itself has the potential to generate or exacerbate conflicts between parties involved. Interest in researching the dynamics of drought amidst conflict has significantly grown within academic circles, even though the existing literature remains fragmented regarding definitions, measurements, and the variables that influence this concept. Consequently, there is a necessity to consolidate existing knowledge in these areas and organize them systematically to establish a solid foundation in this field. I implemented a meticulously organized systematic review approach with content analysis. This study provides (1) a comprehensive summary of the literature on drought dynamics under the pressures of conflict spanning from January 2014 to May 2024, encompassing 46 articles, and (2) particular emphasis, within that summary, on mainly developing countries. I identify and analyse the conceptual, empirical and methodological approaches utilized in the examined literature, then integrate the overarching findings of the research. The primary research inquiries centre around uncovering significant findings and patterns from previous reviews, examining the geographical regions most explored in the context of drought‐conflict interactions, discerning similarities and disparities in findings across regions, and pinpointing deficiencies in the literature alongside areas necessitating additional exploration or theoretical advancement. A significant proportion of authors attribute drought primarily to climate change rather than human activities, while most scholars perceive drought as a catalyst for conflict rather than the reverse. Many researchers opt to utilize the terms 'Drought' and 'Conflict' in their studies over alternative options. The majority of studies focus on specific countries, with a noticeable increase in publications over recent years, particularly in the last 4 years. However, there remains a gap in geographical studies, with several countries receiving relatively fewer research endeavours. [ABSTRACT FROM AUTHOR]

In the present study, the hydrogen-absorption properties of the LaNi5 and the La0.7Ce0.1Ga0.3Ni5 compounds were determined and compared. This work is therefore divided into two parts: an experimental part that presents and discusses the kinetics and isotherms of hydrogen absorption in the two compounds at two different temperatures (298 K and 318 K). In addition, the temperature variations inside the hydride bed were determined. In the second section, the experimental isotherms were compared to a numerical model processed using statistical physics. Following that, thanks to the perfect agreement between the experimental data and the proposed model, the stereographic and energetic parameters associated with the hydrogen absorption reaction, such as the number of hydrogen atoms per receptor site (n1, n2), the densities of the sites (Nm1, Nm2), the half-saturation pressures (P1, P2) and the absorption energies (ΔE1, ΔE2) for each receptor site, were calculated. All of these parameters are acquired by making numerical adjustments to the experimental data. Thermodynamic functions, such as internal energy and Gibbs energy, which regulate the absorption process, were then identified using these parameters. For both compounds, all of the aforementioned were compared and discussed in relation to initial temperature and pressure. The results demonstrated that the hydrogen-storage properties in LaNi5 are enhanced by more than 30% of stored mass and kinetics when Ce and Ga are substituted at the La sites. [ABSTRACT FROM AUTHOR]

The article presents the discussion on correction notice "Application of downhole throttling technology to mitigate sustained casing pressure."

Background and Objectives: Orienteering is a sport characterized by high physical exertion and intense mental demands, which increase susceptibility to errors. Understanding the impact of such errors on psychophysiological responses, particularly on heart rate variability (HRV), is essential. This study aimed to investigate the relationship between psychophysiological indicators and checkpoint errors made by elite orienteers during official competition. Materials and Methods: Fifty-three orienteers participated in this study, and their performance was continuously monitored and recorded by using a global positioning system (GPS) and HRV data. Errors made during the orienteering events were identified and analyzed. HRV data were examined in three temporal segments: before, during, and after the identified and standardized errors. Results: The analyses indicated that errors significantly impacted HRV indices across multiple domains: the time domain, frequency domain, and nonlinear domain. Additionally, a significant effect of sex on the normalized the root mean square of successive differences (r-MSSD) before and after the error was observed. Conclusions: The findings of this study underscore the significant impact of errors made by orienteers on cardiovascular responses, as evidenced by measurable alterations in HRV metrics. Cardiovascular activity, represented by the HRV, can provide useful information for coaches and sport psychologists to adopt effective training programs for athletes. [ABSTRACT FROM AUTHOR]

Comprehensive Summary Salicylaldehyde Schiff base is a kind of important photochromism system, whose photochromism process is widely acknowledged to be co‐determined by the electronic structure and molecular conformation. Normally, salicylaldehyde Schiff base derivatives with α‐type structures tend to exhibit photochromism while those with β‐type structures tend to be photostable. However, more and more counterexamples are found, and the root cause of photochromism property of salicylaldehyde Schiff base is still unclear. In this work, a series of chiral salicylaldehyde Schiff bases and their racemates were prepared. The formers are photochromic while the latters are photostable. Influenced by Wallach's rule, the homochiral counterparts have looser packing modes than that of the racemic counterparts. Mechanism study revealed that the pressure should be the root cause of photochromism property. Close molecule packing can restrict the photochromism property effectively after being pressed, which also explains why the photochromism of salicylaldehyde Schiff base is usually observed in solid state. This work not only reports the unique photo‐responsive difference between the chiral salicylaldehyde Schiff bases and their racemates, more importantly, provides a new perspective to understand the influence of molecule pressure on their photophysical properties. [ABSTRACT FROM AUTHOR]

The Bohai Sea, known for being the lowest latitude seasonally frozen sea area in the world, experienced severe ice conditions with a 30-year recurrence period during the winter of 2009-2010. Water-sediment flux is a crucial parameter for water quality management in marine environment. Using a highly accurate three-dimensional hydrodynamic and sediment transport numerical model, the significant wave height (Hs), current velocity, suspended sediment concentration (SSC) and water-sediment flux in the Bohai Sea during ice-covered and ice-free conditions are compared. Our findings indicate that the current velocity and sediment resuspension decrease under the ice coverage, but increase at the edge of the ice. The net outflow tidal flux (TF) in winter under ice-free conditions accounts for 24.5% of the whole year. The net outflow TF increases by 32.7% during ice-covered conditions, primarily due to the pressure difference between high air pressure superimposing heavy sea ice in the northwest Bohai Sea and the low air pressure in Bohai Strait, resulting in increased ebb velocity and decreased flood velocity. The net outflow suspended sediment flux (SSF) during ice-free conditions in the winter is 2.32×109 kg, while SSF increases by 1.24 times during ice-covered conditions, leading to worse water quality in the outer sea. The decrease of TF in the southern part of the Bohai Strait and the reduction of suspended sediment concentration by nearly 15 mg/l lead to the significant decrease in SSF. This study has significance guiding value for understanding the source-sink sedimentation system and water quality research in East China Sea. [ABSTRACT FROM AUTHOR]