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Ceramic coatings containing two-dimensional materials (2D materials) provide effective protection for light alloys during wear, significantly improving their anti-friction performance. MoS2 has proven highly effective in enhancing the anti-friction performance of ceramic coatings, particularly when synthesized via plasma electrolytic oxidation (PEO). However, dislocation pinning due to the incoherent interfaces in MoS2/TiO2 coatings tends to cause localized stress concentrations and brittle fracture, requiring effectively improve nanomechanical properties by optimizing interface design. To address these issues, this study used ultrasonic-assisted PEO to disperse graphene oxide (GO), which provided more possibility for in-situ synthesis MoS2, ultimately resulting in MoS2 with modified interlayer spacing. The change in interlayer spacing induced dislocation evolution at incoherent interface, leading to dual interface formation. At MoS2 (0.534 nm)/TiO2 interface: dislocation dipoles evolve to create considerable distortion, facilitating releasing shear stresses and inhibiting crack propagations. This process is followed by dislocation annihilation, keeping to stable interfacial bonding. Additionally, the others form strong dislocation pinning to obstruct dislocation slip and enhancing deformation resistance at MoS2 (0.227 nm)/TiO2 interface. The combined effects of dual interfacial enhancements resulted in a 90.0 % reduction in friction coefficients of the MoS2/GO/TiO2 coating compared to the traditional ceramic coating. This facile technique provides a new strategy to fabricate self-lubricating ceramic coatings on light alloys, while the introduction of ultrasound during PEO offers valuable guidance for applying ultrasound in the synthesis of 2D materials.