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Utilizing data from the $Solar$ $Magnetism$ and $Activity$ $Telescope$ (SMAT), analytical solutions of polarized radiative transfer equations, and in-orbit test data from the Full-disk Magnetograph (FMG) onboard the Advanced Space based Solar Observatory (ASO-S), this study reveals the magnetic-sensitivity spectral positions for the Fe {\sc i} $\lambda$5234.19 A, working line used by FMG. From the experimental data of SMAT, it is found that the most sensitivity position is located at the line center for linear polarization (Stokes-Q/U), while it is about -0.07 A away from the line center for circular polarization (Stokes-V). Moreover, both the theoretical analysis and the in-orbit test data analysis of FMG prove again the above results. Additionally, the theoretical analysis suggests the presence of distinct spectral pockets (centered at 0.08-0.15 A) from the line, harboring intense magnetic sensitivity across all three Stokes parameters. Striking a balance between high sensitivity for both linear and circular polarization while capturing additional valuable information, a spectral position of -0.08 A emerges as the champion for routine FMG magnetic-field observations., Comment: 12pages,8figures