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The Groundwater Ubiquity Score (GUS) is widely used to indicate the relative leachability of pesticides based on the soil half-life and the adsorption partition coefficient. In this manuscript, we derive mathematically the Theoretical Groundwater Ubiquity Score (TGUS) that, based on considerations of the preferential movement of pesticides to groundwater and a first-order pesticide degradation model, leads to a similar function as the GUS model. In the preferential flow model, movement to groundwater is fast, and the adsorption partition coefficient is thus not used for calculating the travel time to the groundwater (as it is in the advective-dispersive equation) but rather only determines the distribution of the pesticide between the water and soil phases. Both the GUS and TGUS models well predict the groundwater contamination of the originally studied pesticides for rainfall event(s) that caused pesticide leaching from 30 days after application. The theoretically derived Groundwater Ubiquity Score (TGUS) shows, in accordance with experimental evidence, that for leaching events shortly after spraying, the mass lost to (and resulting concentration in) groundwater is inversely related to the adsorption partition coefficient and not necessarily to the GUS index.

Finding effective ecosystem services (ESS) management practices to counteract land degradation and poverty is becoming increasingly urgent in the Ethiopian highlands, where livelihood security is strongly dependent on local ESS, particularly those provided by water and soil. In this paper, we test the effects of widely implemented soil and water conservation (SWC) interventions on storm flow and sediment concentration in the Debre Mawi watershed (representative of watersheds in the upper Blue Nile basin and Ethiopian highlands). The SWC interventions were tested with a Parameter Efficient Distributed (PED) model. The PED model simulates saturation excess runoff from degraded and saturated valley bottoms, and base and interflow from hillsides. The model was calibrated with observed runoff and sediment data in a 95-ha subcatchment. We found that the PED model simulated the discharge and soil loss well by decreasing the proportion of degraded lands due to installing SWC practices. The results show that four years after the implementation of SWC practices, the infiltration of rainwater was improved in 53% of the degraded lands. Thus, installing SWC practices on hillsides where infiltration is limited is most beneficial and will result in greater water availability during the dry phase, especially in locations where volcanic dikes block the lateral flow. [ABSTRACT FROM AUTHOR]