1. Influence of sulfurization process in tin sulfide and sulfur mixed vapors on the morphology of Cu2SnS3 thin films.
- Author
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Igarashi, Yuki, Ohashi, Ray, Kanai, Ayaka, and Tanaka, Kunihiko
- Subjects
SOLAR cells ,THIN films ,ABSORPTION coefficients ,CRYSTAL grain boundaries ,CRYSTAL structure - Abstract
Cu
2 SnS3 (CTS) is expected to be an absorber material for next-generation solar cells because it is composed of nontoxic, low-cost elements and has an absorption coefficient of >104 cm−1 . In this study, the effects of sulfurization in tin sulfide (Snx Sy ) and S mixed vapors on various properties of CTS were investigated by using a 3-zone tube furnace to suppress carrier recombination at the grain boundaries and control the composition of the CTS. The CTS deposited via sulfurization in S vapor only (1-zone CTS) contained different monoclinic and tetragonal CTS structures. The grain size of the CTS thin films deposited via sulfurization in Snx Sy and S mixed vapors was not increased. On the other hand, crystal structure analysis revealed that the CTS had grown to single-phase monoclinic CTS. The results suggest that precipitation in Snx Sy and S mixed vapors contributes to the growth of monoclinic CTS with suitable power-generation characteristics. This finding is important for realizing high-efficiency CTS-based solar cells. [ABSTRACT FROM AUTHOR]- Published
- 2025
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