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2. An extremely electron poor Au(III) trication bearing acetonitrile ligands.

Author

Barwise, Lachlan, Moon, Lachlan J., Dhakal, Bibidh, Hogan, Conor F., White, Keith F., and Dutton, Jason L.

Subjects
ACETONITRILE, LIGANDS (Chemistry), ELECTRONS, METALATION, CYCLOHEXENE, IMIDAZOLES
Abstract

The synthesis and structural characterization of an electron poor Au(III) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C–H metalation with the formation of a monomesitylene complex and also demonstrated to be highly oxidizing in the rapid room temperature conversion of cyclohexene to benzene. [ABSTRACT FROM AUTHOR]

Published
2024
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