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Polymers are ideally utilized as damping materials due to the high internal friction of molecular chains, enabling effective suppression of vibrations and noises in various fields. Current strategies rely on broadening the glass transition region or introducing additional relaxation components to enhance the energy dissipation capacity of polymeric damping materials. However, it remains a significant challenge to achieve high damping efficiency through structural control while maintaining dynamic characteristics. In this work, we propose a new strategy to develop hyperbranched vitrimers (HBVs) containing dense pendant chains and loose dynamic crosslinked networks. A novel yet weak dynamic transesterification between the carboxyl and boronic acid ester was confirmed and used to prepare HBVs based on poly (hexyl methacrylate‐2‐(4‐ethenylphenyl)‐5,5‐dimethyl‐1,3,2‐dioxaborinane) P(HMA‐co‐ViCL) copolymers. The ABn ${{AB}_{n}}$ ‐type of macromonomers, the crosslinking points formed by the dynamic covalent connection via the associative exchange, and the weak yet dynamic exchange reaction are the three keys to developing high‐performance HBV damping materials. We found that P(HMA‐co‐ViCL) 20k‐40‐60 HBV exhibited ultrahigh energy‐dissipation performance over a broad frequency and temperature range, attributed to the synergistic effect of dense pendant chains and weak dynamic covalent crosslinks. This unique design concept will provide a general approach to developing advanced damping materials. [ABSTRACT FROM AUTHOR]

A dense suspension of the cornstarch flowing on a very inclined wall finally forms some ridge-like patterns of the free surface. The onset of pattern formation is the primary target to elucidate the mechanism. In this work, based on the continuity of fluids and the force balance, we show that the flat free surface is unstable when the second normal stress difference N2 is negatively proportional to shear stress and the gravity component perpendicular to the wall is weak enough. Such instability is inevitable for the growth of a ridge-like surface profile oriented parallel to the flow direction. We use the instability criterion to predict the critical slope angle for the formation of ridge patterns. The estimated critical angle was found to be in agreement with experimental observations for a cornstarch suspension. [ABSTRACT FROM AUTHOR]