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This study explores the disparities in older adults' self-rated health within the urban landscape of China. Drawing on the 1% national population survey of China in 2015, it highlights how variations in city development contribute to geographical health disparities among older residents. In the era of the decentralized fiscal system, a crucial mechanism identified is the role of cities' local fiscal revenue in connecting their socioeconomic development and the health status among older adults. Despite efforts by cities in lower socioeconomic positions to increase fiscal expenditure and address deficits through central transfer payments, they prove inadequate in effectively mitigating population health disparities. The prioritization of economic growth and neglect of public service provision responsibilities are fundamental causes within this fiscal framework. The findings underscore the urgent need for increased central transfer payments in public services to address the growing disparities in older adults' health. • Revealing health disparity among urban older adults amidst fiscal decentralization. • Local fiscal revenue connecting cities' development and individual health. • Ineffectiveness of local fiscal expenditure and deficit in alleviating disparities. • Urgency for leveraging public transfer payments toward public health services. [ABSTRACT FROM AUTHOR]

Rechargeable lithium‐oxygen (Li‐O2) batteries with high theoretical energy density are regarded as a promising candidate for the booming electric vehicle manufacturing industry, whereas their commercial application is hindered due to poor cyclic stability caused by the sluggish kinetics and inevitable cathode passivation. Herein, a synergistic working mechanism of Li‐O2 battery is initiated by implementing well‐designed hollow carbon shells with hierarchically porous hollow structure (HCS) assisted by dual redox mediators (RMs) simultaneously, so as to systemically address issues of diminished discharge capacity and reaction kinetics. The hierarchically porous structure of HCS constructs more space to accommodate Li2O2, increases the accessibility of active sites, and enhances discharge capacity. More importantly, the dual RMs regulate the growth mechanism of Li2O2 in surface‐mediated mode, resulting in an easily decomposed film‐like Li2O2 with higher electron transport capacity and improving the reaction kinetics. As a result of the synergistic effort, an HCS‐based Li‐O2 battery with dual RMs manifests a total discharge capacity of 24580 mA h g−1 and a prolonged cycle life of 2500 h at the current density of 100 mA g−1. This design philosophy will open up a new way to optimize and upgrade the cathode materials of Li‐O2 batteries. [ABSTRACT FROM AUTHOR]