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The synthesis of deuterated gem-difluoroalkenes via selective deuterodefluorination of β-CF3-cinnamates using a nickel catalyst has been reported for the first time. Commercially available deuterated formic acid is a cheap and convenient deuterium source. The nickel-catalyst showed high selectivity for monodefluorination and avoided competitive reactions such as multiple defluorination or hydrogenation. [ABSTRACT FROM AUTHOR]

The low-carbon development of new energy vehicles (NEVs) is critical to achieving the goals of carbon peaking and carbon neutrality. As such, combining gray model theory with system dynamics (SD-GM) and based on the bidirectional-cycle prediction theory, we propose a NEV annual average mileage algorithm considering the impact of the epidemic in China, taking private cars as an example. Then, combining a voluntary advocacy strategy (VA) with the SD-GM theory (VA-SD-GM integration), we establish an energy-saving and carbon-reduction management model. To evaluate the proposed algorithm, we performed a dynamic simulation. The results indicate that the enhanced green scenario enabled significant energy-saving and CO2 reduction performance but would cause side effects in the long term. Compared with the enhanced green scenario, the linkage mode reduced the impact of parking space tension, the number of NEV trips, and the intensification of traffic congestion by approximately 33%, 50%, and 34%, respectively. It effectively suppressed the continuous increase in side effects and had a synergistic effect of carbon reduction, energy conservation, congestion alleviation, and side-effect reduction. The study provides a theoretical basis for optimizing the energy-saving and CO2 reduction path of NEVs. [ABSTRACT FROM AUTHOR]

Summary: High penetration of renewable energy is the development trend of the future power system. As one of the clean energy sources, wind power generation has an increasing share in the energy market. However, due to the harsh working environment, the high fault rate and poor accessibility of the wind farms, resulting in the difficult maintenance process and high cost. This article proposes a fault diagnosis (FD) method based on long short‐term memory (LSTM) and feature optimization strategies for wind turbines (WTs), thus reducing the operation and maintenance costs of WTs. First, Pearson correlation coefficient analysis is performed on the collected data features to remove redundant features, and wavelet transform is adopted to remove the redundant data, so as to optimize the fault features and fault data. Then the selected features samples are used to train LSTM‐based FD model. Finally, the actual production data is adopted to verify the proposed method. The proposed method can effectively locate the faults, and provide data support for wind farms, thus improving the reliability, safety, and economic benefits of wind farms. [ABSTRACT FROM AUTHOR]

The synthesis of deuterated gem -difluoroalkenes via selective deuterodefluorination of β-CF 3 -cinnamates using a nickel catalyst has been reported for the first time. Commercially available deuterated formic acid is a cheap and convenient deuterium source. The nickel-catalyst showed high selectivity for monodefluorination and avoided competitive reactions such as multiple defluorination or hydrogenation.