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In recent years, there have been significant advancements in Al‐ion battery development, resulting in high voltage and capacity. Traditionally, only carbon‐based materials with layered structures and strong bonding capabilities can deliver superior performance. However, most other materials exhibited low discharge voltages of 1.4 V, especially in aqueous Al‐ion battery systems lacking anion intercalation. Thus, the development of high‐voltage cathode materials has become crucial. This study introduces 2D MoS2 as a high‐performance cathode for aqueous Al‐ion batteries. The material's interlayer structure enables the intercalation of AlCl4− anions, resulting in high‐voltage intercalation. The resulting battery achieved a high voltage of 1.8 V with a capacity of 750 mAh g−1, contributing to a high energy density of 890 Wh kg−1 and an impressive retention rate of ≈100% after 200 cycles. This research not only sheds light on the high‐voltage anion‐intercalation mechanism of MoS2 but also paves the way for the further development of advanced cathode materials in the field of Al‐ion batteries. By demonstrating the potential of using 2D MoS2 as a cathode material, this finding can lead to the development of more efficient and innovative energy storage technologies, ultimately contributing to a sustainable and green energy future. [ABSTRACT FROM AUTHOR]

In recent years, super-long and super-large diameter pipe piles have been gradually applied to the foundation in the Yellow River flood area. However, its bearing mechanism is not clear, especially the unclear bearing characteristics of the pile under the eccentric state, which limits its application and development. In this regard, this paper uses the method of combining field test and numerical simulation to analyze the bearing characteristics of super-long and super-large diameter pipe piles under different pile lengths, different pile diameters, different diameter-thickness ratios, and different offsets. Combined with the specific deviation form of the pipe pile, the calculation formula of the vertical ultimate bearing capacity of the super-long and super-long diameter pipe pile in the Yellow River flooding area under the influence of the construction effect is modified. The results show that when the length of the pipe pile changes, the vertical bearing capacity changes the most, and the vertical ultimate bearing capacity of the pipe pile increases linearly with the increase of the length of the pipe pile. When the wall thickness of the pipe pile increases, the vertical bearing capacity increases approximately linearly, but the reduction of the pile displacement decreases exponentially. The greater the deflection of the pipe pile, the smaller the vertical ultimate bearing capacity. When the deflection of the pipe pile is greater than 0.35°, the vertical ultimate bearing capacity decreases rapidly with the increase of the deflection. On the basis of the traditional formula, considering the deviation form of the pipe pile, the reduction coefficient of the bearing capacity correction formula of the super-long and super-large diameter pipe pile is proposed, and the correction formula is compared with the field example. It is proved that the formula can accurately calculate the bearing capacity of the superlong and super-large diameter pipe pile. The research results of this paper are of great significance to the application and promotion of super-long and super-large diameter pipe piles in the Yellow River flood area and the evaluation of vertical ultimate bearing capacity. At the same time, the research results of this paper can also provide a reference for the study of bearing characteristics of super-long and super-large diameter pipe piles in other foundations. [ABSTRACT FROM AUTHOR]

The air-water interface of microbubbles represents a crucial microenvironment that can dramatically accelerate reactive oxidative species (ROS) reactions. However, the dynamic nature of microbubbles presents challenges in probing ROS behaviors at the air-water interface, limiting a comprehensive understanding of their chemistry and application. Here we develop an approach to investigate the interfacial ROS via coupling microbubbles with a Fenton-like reaction. Amphiphilic single-Co-atom catalyst (Co@SCN) is employed to efficiently transport the oxidant peroxymonosulfate (PMS) from the bulk solution to the microbubble interface. This triggers an accelerated generation of interfacial sulfate radicals (SO 4 •- ), with 20-fold higher concentration (4.48 × 10 -11 M) than the bulk SO 4 •- . Notably, the generated SO 4 •- is preferentially situated at the air-water interface due to its lowest free energy and the strong hydrogen bonding interactions with H 3 O + . Moreover, it exhibits the highest oxidation reactivity toward gaseous pollutants like toluene, with a rate constant of 10 10  M -1 s -1 -over 100 times greater than bulk reactions. This work demonstrates a promising strategy to harness the air-water interface for accelerating ROS-induced reactions, highlighting the importance of interfacial ROS and its potential application., (© 2024. The Author(s).)

This review examines various modification techniques, including metal doping, non-metal doping, multi doping, mixed doping, and the construction of heterojunction photocatalysts, for enhancing the performance of pure TiO 2 and ZnO in the photodegradation of antibiotics. The study finds that mixed and multi doping approaches are more effective in improving photodegradation performance compared to single doping. Furthermore, the selection of suitable semiconductors for constructing heterojunction photocatalysts is crucial for achieving an efficient charge carrier separation. The environmental impacts, recent research, and real application of photocatalysis process have been discussed. The review also investigates the impact of operating parameters on the degradation pathways and the generation of by-products for different antibiotics. Additionally, the toxicity of the by-products resulting from the photodegradation of antibiotics using modified ZnO and TiO 2 photocatalysts is explored, revealing that these by-products may exhibit higher toxicity than the original antibiotics. Consequently, to enable the widespread implementation of photodegradation systems, researchers should focus on optimizing degradation systems to control the conversion pathways of by-products, developing innovative photoreactors, and evaluating toxicity in real wastewater matrices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In recent years, there have been significant advancements in Al-ion battery development, resulting in high voltage and capacity. Traditionally, only carbon-based materials with layered structures and strong bonding capabilities can deliver superior performance. However, most other materials exhibited low discharge voltages of 1.4 V, especially in aqueous Al-ion battery systems lacking anion intercalation. Thus, the development of high-voltage cathode materials has become crucial. This study introduces 2D MoS 2 as a high-performance cathode for aqueous Al-ion batteries. The material's interlayer structure enables the intercalation of AlCl 4 - anions, resulting in high-voltage intercalation. The resulting battery achieved a high voltage of 1.8 V with a capacity of 750 mAh g -1 , contributing to a high energy density of 890 Wh kg -1 and an impressive retention rate of ≈100% after 200 cycles. This research not only sheds light on the high-voltage anion-intercalation mechanism of MoS 2 but also paves the way for the further development of advanced cathode materials in the field of Al-ion batteries. By demonstrating the potential of using 2D MoS 2 as a cathode material, this finding can lead to the development of more efficient and innovative energy storage technologies, ultimately contributing to a sustainable and green energy future., (© 2023 The Authors. Small Methods published by Wiley‐VCH GmbH.)