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The deposition of oxygen-defective ZnO films exhibiting varied nanostructures via Solution Precursor Plasma Spray (SPPS) route, a one-step, minute-scaled duration and large scale method, is reported. The in situ formation of oxygen vacancies in ZnO films was confirmed by UV-Visible, Raman and photoluminescence (PL) spectroscopy and the as-prepared samples exhibit a bandgap as low as 3.02 eV. Density functional theory (DFT) simulation demonstrates that the polarization of ZnO is enhanced by the created oxygen vacancies, leading to substantially improved photocatalytic activity. The comparative experiments also revealed that forming and preserving appropriate ZnO precursor clusters inside the plasma plume is requisite for obtaining propitious ZnO nanostructures, which was followed by the in situ transfer and growth of the clusters on the preheated substrate. The ZnO-NRs films fully degrade the aqueous Orange II dye solutions within 120 min and maintain a quasi-intact activity (95.8% retention) after five test runs, which highlight their good stability. The oxygen vacancies and the narrowing of the bandgap also enable a visible light-driven photodegradation activity with conversions as high as 54.1%. In summary, this work not only reveals that the photocatalytic activity of SPPS-deposited ZnO films benefit from oxygen vacancies and well nanostructures, but also suggests that the SPPS route is of high potential for preparing metal oxides films destined to functional applications., (Copyright © 2018 Elsevier Inc. All rights reserved.)

ZnO with graphene oxide (GO-ZnO) & reduced graphene oxide (rGO-ZnO) buffer layers were fabricated. Photoluminescence (PL) properties of GO-ZnO and rGO-ZnO compositions induced by oxygen vacancies defects were investigated using photoluminescence spectroscopy. The results showed that blue emission is quenched while yellow-orange emissions from GO-ZnO and rGO-ZnO compositions are significantly increased as compared to that of ZnO films. In stark contrast to enhanced yellow-orange emissions, PL spectra show three sharp, discrete emissions that characterize the dominant optical active defect, which is the oxygen vacancies and extended oxygen vacancies. Our results highlight the ability of GO & rGO buffer layers to modulate defect concentrations in ZnO and contribute to understanding the optical properties of deep-level defects, which is significant for development of long-wavelength photoelectric devices related with graphene materials., (Crown Copyright © 2013. Published by Elsevier Inc. All rights reserved.)